DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Application of air classification and formulation to manage feedstock cost, quality and availability for bioenergy

Abstract

Biomass such as agricultural residues, energy crops and yard waste has significant potential to be used as renewable feedstocks for production of fuels, chemicals and energy. However, in a given location, biomass availability, cost and quality can vary markedly. Strategies to manage these traits must be identified and implemented so that consistent low-cost and high-quality feedstocks can be delivered to biorefineries year round. In this study, we examine air classification as a method to mitigate high ash concentrations in corn stover, switchgrass, and grass clippings. Formulation techniques were then used to produce blends that met ash quality and biomass quantity specifications at the lowest possible cost for biopower and biochemical conversion applications. It was found that air classification can separate the biomass into light fractions which contain concentrated amounts of elemental ash components introduced through soil contamination such as sodium, alumina, silica, iron and titania; and heavy fractions that are depleted in these components and have relatively lower total ash content. Light fractions of corn stover and grass clippings were found to be suitable for combustion applications since they had less propensity to slag than the whole biomass material. The remaining heavy fractions of corn stover or grass clippings couldmore » then be blended with switchgrass to produce blends that met the 5% total ash specifications suggested for biochemical conversions. However, ternary blends of the three feedstocks were not possible due to the high ash content of grass clippings. Lastly, it was determined that air classification by itself was not suitable to prepare these feedstocks for pyrolysis due to high ash content.« less

Authors:
 [1];  [1];  [1];  [1];  [1];  [1]
  1. Idaho National Lab. (INL), Idaho Falls, ID (United States)
Publication Date:
Research Org.:
Idaho National Laboratory (INL), Idaho Falls, ID (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1259468
Alternate Identifier(s):
OSTI ID: 1328219
Report Number(s):
INL/JOU-15-36707
Journal ID: ISSN 0016-2361; PII: S001623611630196X
Grant/Contract Number:  
AC07-05ID14517
Resource Type:
Accepted Manuscript
Journal Name:
Fuel
Additional Journal Information:
Journal Volume: 180; Journal Issue: C; Journal ID: ISSN 0016-2361
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
09 BIOMASS FUELS; air classification; formulation; biochemical conversion; biopower; quality; ash

Citation Formats

Thompson, Vicki S., Lacey, Jeffrey A., Hartley, Damon, Jindra, Michael A., Aston, John E., and Thompson, David N. Application of air classification and formulation to manage feedstock cost, quality and availability for bioenergy. United States: N. p., 2016. Web. doi:10.1016/j.fuel.2016.04.040.
Thompson, Vicki S., Lacey, Jeffrey A., Hartley, Damon, Jindra, Michael A., Aston, John E., & Thompson, David N. Application of air classification and formulation to manage feedstock cost, quality and availability for bioenergy. United States. https://doi.org/10.1016/j.fuel.2016.04.040
Thompson, Vicki S., Lacey, Jeffrey A., Hartley, Damon, Jindra, Michael A., Aston, John E., and Thompson, David N. Fri . "Application of air classification and formulation to manage feedstock cost, quality and availability for bioenergy". United States. https://doi.org/10.1016/j.fuel.2016.04.040. https://www.osti.gov/servlets/purl/1259468.
@article{osti_1259468,
title = {Application of air classification and formulation to manage feedstock cost, quality and availability for bioenergy},
author = {Thompson, Vicki S. and Lacey, Jeffrey A. and Hartley, Damon and Jindra, Michael A. and Aston, John E. and Thompson, David N.},
abstractNote = {Biomass such as agricultural residues, energy crops and yard waste has significant potential to be used as renewable feedstocks for production of fuels, chemicals and energy. However, in a given location, biomass availability, cost and quality can vary markedly. Strategies to manage these traits must be identified and implemented so that consistent low-cost and high-quality feedstocks can be delivered to biorefineries year round. In this study, we examine air classification as a method to mitigate high ash concentrations in corn stover, switchgrass, and grass clippings. Formulation techniques were then used to produce blends that met ash quality and biomass quantity specifications at the lowest possible cost for biopower and biochemical conversion applications. It was found that air classification can separate the biomass into light fractions which contain concentrated amounts of elemental ash components introduced through soil contamination such as sodium, alumina, silica, iron and titania; and heavy fractions that are depleted in these components and have relatively lower total ash content. Light fractions of corn stover and grass clippings were found to be suitable for combustion applications since they had less propensity to slag than the whole biomass material. The remaining heavy fractions of corn stover or grass clippings could then be blended with switchgrass to produce blends that met the 5% total ash specifications suggested for biochemical conversions. However, ternary blends of the three feedstocks were not possible due to the high ash content of grass clippings. Lastly, it was determined that air classification by itself was not suitable to prepare these feedstocks for pyrolysis due to high ash content.},
doi = {10.1016/j.fuel.2016.04.040},
journal = {Fuel},
number = C,
volume = 180,
place = {United States},
year = {Fri Apr 22 00:00:00 EDT 2016},
month = {Fri Apr 22 00:00:00 EDT 2016}
}

Journal Article:

Citation Metrics:
Cited by: 30 works
Citation information provided by
Web of Science

Figures / Tables:

Table 1 Table 1: Mass fractionation among air classified fractions of biomass feedstocks. Values represent mean ± 1 standard deviation, n=3.

Save / Share:

Works referenced in this record:

Advanced Regional Biomass Processing Depots: a key to the logistical challenges of the cellulosic biofuel industry
journal, July 2011

  • Eranki, Pragnya L.; Bals, Bryan D.; Dale, Bruce E.
  • Biofuels, Bioproducts and Biorefining, Vol. 5, Issue 6
  • DOI: 10.1002/bbb.318

Techno-economic analysis of decentralized biomass processing depots
journal, October 2015


Understanding biomass feedstock variability
journal, January 2013

  • Kenney, Kevin L.; Smith, William A.; Gresham, Garold L.
  • Biofuels, Vol. 4, Issue 1
  • DOI: 10.4155/bfs.12.83

The impacts of deacetylation prior to dilute acid pretreatment on the bioethanol process
journal, January 2012

  • Chen, Xiaowen; Shekiro, Joseph; Franden, Mary Ann
  • Biotechnology for Biofuels, Vol. 5, Issue 1
  • DOI: 10.1186/1754-6834-5-8

Field-to-Fuel Performance Testing of Lignocellulosic Feedstocks: An Integrated Study of the Fast Pyrolysis–Hydrotreating Pathway
journal, April 2015


Thermochemical Biomass Gasification: A Review of the Current Status of the Technology
journal, July 2009

  • Kumar, Ajay; Jones, David; Hanna, Milford
  • Energies, Vol. 2, Issue 3
  • DOI: 10.3390/en20300556

Impact of Harvest Equipment on Ash Variability of Baled Corn Stover Biomass for Bioenergy
journal, March 2014



book,  


Biomass yield from an urban landscape
journal, February 2012


Characterising ash of biomass and waste
journal, December 2007


Chemical preconversion: application of low-severity pretreatment chemistries for commoditization of lignocellulosic feedstock
journal, May 2013

  • Thompson, David N.; Campbell, Timothy; Bals, Bryan
  • Biofuels, Vol. 4, Issue 3
  • DOI: 10.4155/bfs.13.15

Removal of introduced inorganic content from chipped forest residues via air classification
journal, November 2015


Optimizing hammer mill performance through screen selection and hammer design
journal, January 2013

  • Yancey, Neal; Wright, Christopher T.; Westover, Tyler L.
  • Biofuels, Vol. 4, Issue 1
  • DOI: 10.4155/bfs.12.77

Coal blending optimization under uncertainty
journal, June 1995


Co-firing of coal and biomass fuel blends
journal, January 2001


Uncertainties in Life Cycle Greenhouse Gas Emissions from Advanced Biomass Feedstock Logistics Supply Chains in Kansas
journal, November 2014

  • Nguyen, Long; Cafferty, Kara; Searcy, Erin
  • Energies, Vol. 7, Issue 11
  • DOI: 10.3390/en7117125

Predicting the slagging potential of co-fired coal with sewage sludge and wood biomass
journal, June 2013


Evaluation of slagging and fouling tendency during biomass co-firing with coal in a fluidized bed
journal, April 2012


Assessing slagging and fouling during biomass combustion: A thermodynamic approach allowing for alkali/ash reactions
journal, December 2007


Effect of anatomical fractionation on the enzymatic hydrolysis of acid and alkaline pretreated corn stover
journal, November 2009


Comparative studies on hydrothermal pretreatment and enzymatic saccharification of leaves and internodes of alamo switchgrass
journal, July 2011


Chemical profiles of switchgrass
journal, May 2010


Structural and chemical properties of grass lignocelluloses related to conversion for biofuels
journal, January 2008

  • Anderson, William F.; Akin, Danny E.
  • Journal of Industrial Microbiology & Biotechnology, Vol. 35, Issue 5
  • DOI: 10.1007/s10295-007-0291-8

Fast Pyrolysis Bio-Oils from Wood and Agricultural Residues
journal, February 2010

  • Oasmaa, Anja; Solantausta, Yrjö; Arpiainen, Vesa
  • Energy & Fuels, Vol. 24, Issue 2
  • DOI: 10.1021/ef901107f

Works referencing / citing this record:

Can we use short rotation coppice poplar for sugar based biorefinery feedstock? Bioconversion of 2-year-old poplar grown as short rotation coppice
journal, June 2017

  • Dou, Chang; Marcondes, Wilian F.; Djaja, Jessica E.
  • Biotechnology for Biofuels, Vol. 10, Issue 1
  • DOI: 10.1186/s13068-017-0829-6

Assessment of municipal solid waste for valorization into biofuels
journal, June 2019

  • Thompson, Vicki S.; Ray, Allison E.; Hoover, Amber
  • Environmental Progress & Sustainable Energy, Vol. 39, Issue 4
  • DOI: 10.1002/ep.13290

Removal of non-structural components from poplar whole-tree chips to enhance hydrolysis and fermentation performance
journal, August 2018


Wear Properties of Ash Minerals in Biomass
journal, November 2018

  • Lacey, Jeffrey A.; Aston, John E.; Thompson, Vicki S.
  • Frontiers in Energy Research, Vol. 6
  • DOI: 10.3389/fenrg.2018.00119