One Dimensional(1D)-to-2D Crossover of Spin Correlations in the 3D Magnet ZnMn2O4

Disseler, S. M.; Chen, Y.; Yeo, S.; Gasparovic, G.; Piccoli, P. M.  B.; Schultz, A. J.; Qiu, Y.; Huang, Q.; Cheong, S. -W.; Ratcliff, W.

doi:10.1038/srep17771

Title: One Dimensional(1D)-to-2D Crossover of Spin Correlations in the 3D Magnet ZnMn₂O₄

Abstract

In this paper we report on the intriguing evolution of the dynamical spin correlations of the frustrated spinel ZnMn₂O₄. Inelastic neutron scattering and magnetization studies reveal that the dynamical correlations at high temperatures are 1D. At lower temperature, these dynamical correlations become 2D. Surprisingly, the dynamical correlations condense into a quasi 2D Ising-like ordered state, making this a rare observation of two dimensional order on the spinel lattice. Remarkably, 3D ordering is not observed down to temperatures as low as 300 mK. This unprecedented dimensional crossover stems from frustrated exchange couplings due to the huge Jahn-Teller distortions around Mn³⁺ ions on the spinel lattice.

Authors:

Disseler, S. M. ^[1]; Chen, Y. ^[2]; Yeo, S. ^[3]; Gasparovic, G. ^[2]; Piccoli, P. M. B. ^[4]; Schultz, A. J. ^[4]; Qiu, Y. ^[2]; Huang, Q. ^[1]; Cheong, S. -W. ^[5]; Ratcliff, W. ^[1]

National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Center for Neutron Research
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Center for Neutron Research; Univ. of Maryland, College Park, MD (United States)
Rutgers Univ., Piscataway, NJ (United States); Korea Atomic Energy Research Inst., Daejeon (Korea)
Argonne National Lab. (ANL), Argonne, IL (United States)
Rutgers Univ., Piscataway, NJ (United States)

Publication Date:: Tue Dec 08 00:00:00 EST 2015

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1258606

Grant/Contract Number:: FG02-07ER46382; AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Scientific Reports

Additional Journal Information:: Journal Volume: 5; Journal ID: ISSN 2045-2322

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS

Citation Formats


                    Disseler, S. M., Chen, Y., Yeo, S., Gasparovic, G., Piccoli, P. M.  B., Schultz, A. J., Qiu, Y., Huang, Q., Cheong, S. -W., and Ratcliff, W. One Dimensional(1D)-to-2D Crossover of Spin Correlations in the 3D Magnet ZnMn2O4.  United States: N. p., 2015. 
Web.  doi:10.1038/srep17771.

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                    Disseler, S. M., Chen, Y., Yeo, S., Gasparovic, G., Piccoli, P. M.  B., Schultz, A. J., Qiu, Y., Huang, Q., Cheong, S. -W., & Ratcliff, W. One Dimensional(1D)-to-2D Crossover of Spin Correlations in the 3D Magnet ZnMn2O4.  United States.  https://doi.org/10.1038/srep17771

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                    Disseler, S. M., Chen, Y., Yeo, S., Gasparovic, G., Piccoli, P. M.  B., Schultz, A. J., Qiu, Y., Huang, Q., Cheong, S. -W., and Ratcliff, W. Tue .  
"One Dimensional(1D)-to-2D Crossover of Spin Correlations in the 3D Magnet ZnMn2O4".  United States.  https://doi.org/10.1038/srep17771.  https://www.osti.gov/servlets/purl/1258606.

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@article{osti_1258606,

  title        = {One Dimensional(1D)-to-2D Crossover of Spin Correlations in the 3D Magnet ZnMn2O4},

  author       = {Disseler, S. M. and Chen, Y. and Yeo, S. and Gasparovic, G. and Piccoli, P. M.  B. and Schultz, A. J. and Qiu, Y. and Huang, Q. and Cheong, S. -W. and Ratcliff, W.},

  abstractNote = {In this paper we report on the intriguing evolution of the dynamical spin correlations of the frustrated spinel ZnMn2O4. Inelastic neutron scattering and magnetization studies reveal that the dynamical correlations at high temperatures are 1D. At lower temperature, these dynamical correlations become 2D. Surprisingly, the dynamical correlations condense into a quasi 2D Ising-like ordered state, making this a rare observation of two dimensional order on the spinel lattice. Remarkably, 3D ordering is not observed down to temperatures as low as 300 mK. This unprecedented dimensional crossover stems from frustrated exchange couplings due to the huge Jahn-Teller distortions around Mn3+ ions on the spinel lattice.},

  doi          = {10.1038/srep17771},

  journal      = {Scientific Reports},

  number       = ,

  volume       = 5,

  place        = {United States},

  year         = {Tue Dec 08 00:00:00 EST 2015},

  month        = {Tue Dec 08 00:00:00 EST 2015}

}

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Works referencing / citing this record:

Temperature dependence of magnetic excitations in the frustrated antiferromagnetic spinel ${ZnMn}_{2} O_{4}$
journal, January 2018

Chang, Hun; Hwang, In-Yong; Chung, Jae-Ho
Physical Review B, Vol. 97, Issue 1
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ZnMn ₂ O ₄ nanorods: an effective Fenton-like heterogeneous catalyst with t _2g ³ e _g ¹ electronic configuration
journal, January 2018

Qiu, Maoqin; Chen, Zhangxian; Yang, Zeheng
Catalysis Science & Technology, Vol. 8, Issue 10
DOI: 10.1039/c8cy00436f

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Title: One Dimensional(1D)-to-2D Crossover of Spin Correlations in the 3D Magnet ZnMn2O4

Abstract

Citation Formats

Two-dimensional behavior of the rare earth ordering in oxide superconductors journal, April 1992

Magnetism in One-Dimensional Systems—The Heisenberg Model for Infinite Spin journal, May 1964

Emergent excitations in a geometrically frustrated magnet journal, August 2002

The upgraded IPNS single crystal diffractometer journal, November 2006

Magnets with strong geometric frustration journal, January 2001

Magnets with strong geometric frustration journal, December 2001

Experiments on simple magnetic model systems journal, January 1974

2D Kagomé ordering in the 3D frustrated spinel Li 2 Mn 2 O 4 journal, September 2005

Accelerating Markov Chain Monte Carlo Simulation by Differential Evolution with Self-Adaptive Randomized Subspace Sampling journal, January 2009

Geometrical Frustration in the Ferromagnetic Pyrochlore Ho 2 Ti 2 O 7 journal, September 1997

Local Spin Resonance and Spin-Peierls-like Phase Transition in a Geometrically Frustrated Antiferromagnet journal, April 2000

Magnetic Reversal of the Ferroelectric Polarization in a Multiferroic Spinel Oxide journal, May 2006

Quasi-one-dimensional antiferromagnetic spinel compound LiCuVO4 journal, July 2000

Orbital and Spin Chains in Z n V 2 O 4 journal, October 2004

Crystal Statistics. I. A Two-Dimensional Model with an Order-Disorder Transition journal, February 1944

High-pressure phase transition and properties of spinel ZnMn 2 O 4 journal, November 1999

Electronic structures and magnetic properties of spinel Zn Mn 2 O 4 under high pressure journal, November 2006

Orbital Ordering in Frustrated Jahn-Teller Systems with 90° Exchange journal, November 2002

Absence of Ferromagnetism or Antiferromagnetism in One- or Two-Dimensional Isotropic Heisenberg Models journal, November 1966

X-Ray Diffraction in Random Layer Lattices journal, May 1941

Neutron scattering study of nitrogen adsorbed on basal-plane-oriented graphite journal, February 1976

Coupled-bilayer two-dimensional magnetic order of the Dy ions in Dy 2 Ba 4 Cu 7 O 15 journal, May 1992

Dynamic Critical Neutron Scattering from a Two-Dimensional Ising System Rb 2 CoF 4 journal, August 1982

Spin-wave analysis in the two-dimensional antiferromagnet K 2 Fe F 4 . I. Neutron scattering journal, April 1982

Experiments on simple magnetic model systems journal, December 2001

Absence of Ferromagnetism or Antiferromagnetism in One- or Two-Dimensional Isotropic Heisenberg Models journal, December 1966

Magnets with strong geometric frustration text, January 2000

Local spin resonance and spin-Peierls-like phase transition in a geometrically frustrated antiferromagnet text, January 1999

Temperature dependence of magnetic excitations in the frustrated antiferromagnetic spinel ZnMn 2 O 4 journal, January 2018

ZnMn 2 O 4 nanorods: an effective Fenton-like heterogeneous catalyst with t 2g 3 e g 1 electronic configuration journal, January 2018

Title: One Dimensional(1D)-to-2D Crossover of Spin Correlations in the 3D Magnet ZnMn₂O₄

Two-dimensional behavior of the rare earth ordering in oxide superconductors
journal, April 1992

Magnetism in One-Dimensional Systems—The Heisenberg Model for Infinite Spin
journal, May 1964

Emergent excitations in a geometrically frustrated magnet
journal, August 2002

The upgraded IPNS single crystal diffractometer
journal, November 2006

Magnets with strong geometric frustration
journal, January 2001

Magnets with strong geometric frustration
journal, December 2001

Experiments on simple magnetic model systems
journal, January 1974

2D Kagomé ordering in the 3D frustrated spinel Li ₂ Mn ₂ O ₄
journal, September 2005

Accelerating Markov Chain Monte Carlo Simulation by Differential Evolution with Self-Adaptive Randomized Subspace Sampling
journal, January 2009

Geometrical Frustration in the Ferromagnetic Pyrochlore ${Ho}_{2} {Ti}_{2} O_{7}$
journal, September 1997

Local Spin Resonance and Spin-Peierls-like Phase Transition in a Geometrically Frustrated Antiferromagnet
journal, April 2000

Magnetic Reversal of the Ferroelectric Polarization in a Multiferroic Spinel Oxide
journal, May 2006

Quasi-one-dimensional antiferromagnetic spinel compound LiCuVO4
journal, July 2000

Orbital and Spin Chains in ${Z n V}_{2} O_{4}$
journal, October 2004

Crystal Statistics. I. A Two-Dimensional Model with an Order-Disorder Transition
journal, February 1944

High-pressure phase transition and properties of spinel ${ZnMn}_{2} O_{4}$
journal, November 1999

Electronic structures and magnetic properties of spinel $Zn {Mn}_{2} O_{4}$ under high pressure
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Orbital Ordering in Frustrated Jahn-Teller Systems with 90° Exchange
journal, November 2002

Absence of Ferromagnetism or Antiferromagnetism in One- or Two-Dimensional Isotropic Heisenberg Models
journal, November 1966

X-Ray Diffraction in Random Layer Lattices
journal, May 1941

Neutron scattering study of nitrogen adsorbed on basal-plane-oriented graphite
journal, February 1976

Coupled-bilayer two-dimensional magnetic order of the Dy ions in ${Dy}_{2}$ ${Ba}_{4}$ ${Cu}_{7}$ $O_{15}$
journal, May 1992

Dynamic Critical Neutron Scattering from a Two-Dimensional Ising System ${Rb}_{2}$ ${CoF}_{4}$
journal, August 1982

Spin-wave analysis in the two-dimensional antiferromagnet $K_{2}$ Fe $F_{4}$ . I. Neutron scattering
journal, April 1982

Experiments on simple magnetic model systems
journal, December 2001

Absence of Ferromagnetism or Antiferromagnetism in One- or Two-Dimensional Isotropic Heisenberg Models
journal, December 1966

Magnets with strong geometric frustration
text, January 2000

Local spin resonance and spin-Peierls-like phase transition in a geometrically frustrated antiferromagnet
text, January 1999

Temperature dependence of magnetic excitations in the frustrated antiferromagnetic spinel ${ZnMn}_{2} O_{4}$
journal, January 2018

ZnMn ₂ O ₄ nanorods: an effective Fenton-like heterogeneous catalyst with t _2g ³ e _g ¹ electronic configuration
journal, January 2018