A porous proton-relaying metal-organic framework material that accelerates electrochemical hydrogen evolution
Abstract
The availability of efficient hydrogen evolution reaction (HER) catalysts is of high importance for solar fuel technologies aimed at reducing future carbon emissions. Even though Pt electrodes are excellent HER electrocatalysts, commercialization of large-scale hydrogen production technology requires finding an equally efficient, low-cost, earth-abundant alternative. Here, high porosity, metal-organic framework (MOF) films have been used as scaffolds for the deposition of a Ni-S electrocatalyst. Compared with an MOF-free Ni-S, the resulting hybrid materials exhibit significantly enhanced performance for HER from aqueous acid, decreasing the kinetic overpotential by more than 200 mV at a benchmark current density of 10 mA cm-2. In conclusion, although the initial aim was to improve electrocatalytic activity by greatly boosting the active area of the Ni-S catalyst, the performance enhancements instead were found to arise primarily from the ability of the proton-conductive MOF to favourably modify the immediate chemical environment of the sulfide-based catalyst.
- Authors:
-
- Northwestern Univ., Evanston, IL (United States); Northwestern Univ., Evanston, IL (United States). Argonne-Northwestern Solar Energy Research (ANSER) Center
- Northwestern Univ., Evanston, IL (United States)
- Northwestern Univ., Evanston, IL (United States); Warsaw Univ. of Technology, Warsaw (Poland)
- Northwestern Univ., Evanston, IL (United States); Northwestern Univ., Evanston, IL (United States). Argonne-Northwestern Solar Energy Research (ANSER) Center; National Taiwan Univ., Taipei (Taiwan)
- Univ. of California, San Diego, CA (United States)
- Northwestern Univ., Evanston, IL (United States); Northwestern Univ., Evanston, IL (United States). Argonne-Northwestern Solar Energy Research (ANSER) Center
- Northwestern Univ., Evanston, IL (United States); Northwestern Univ., Evanston, IL (United States). Argonne-Northwestern Solar Energy Research (ANSER) Center; King Abdulaziz Univ., Jeddah (Saudi Arabia)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1258602
- Grant/Contract Number:
- SC0001059
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 6; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Hod, Idan, Deria, Pravas, Bury, Wojciech, Mondloch, Joseph E., Kung, Chung-Wei, So, Monica, Sampson, Matthew D., Peters, Aaron W., Kubiak, Cliff P., Farha, Omar K., and Hupp, Joseph T. A porous proton-relaying metal-organic framework material that accelerates electrochemical hydrogen evolution. United States: N. p., 2015.
Web. doi:10.1038/ncomms9304.
Hod, Idan, Deria, Pravas, Bury, Wojciech, Mondloch, Joseph E., Kung, Chung-Wei, So, Monica, Sampson, Matthew D., Peters, Aaron W., Kubiak, Cliff P., Farha, Omar K., & Hupp, Joseph T. A porous proton-relaying metal-organic framework material that accelerates electrochemical hydrogen evolution. United States. https://doi.org/10.1038/ncomms9304
Hod, Idan, Deria, Pravas, Bury, Wojciech, Mondloch, Joseph E., Kung, Chung-Wei, So, Monica, Sampson, Matthew D., Peters, Aaron W., Kubiak, Cliff P., Farha, Omar K., and Hupp, Joseph T. Mon .
"A porous proton-relaying metal-organic framework material that accelerates electrochemical hydrogen evolution". United States. https://doi.org/10.1038/ncomms9304. https://www.osti.gov/servlets/purl/1258602.
@article{osti_1258602,
title = {A porous proton-relaying metal-organic framework material that accelerates electrochemical hydrogen evolution},
author = {Hod, Idan and Deria, Pravas and Bury, Wojciech and Mondloch, Joseph E. and Kung, Chung-Wei and So, Monica and Sampson, Matthew D. and Peters, Aaron W. and Kubiak, Cliff P. and Farha, Omar K. and Hupp, Joseph T.},
abstractNote = {The availability of efficient hydrogen evolution reaction (HER) catalysts is of high importance for solar fuel technologies aimed at reducing future carbon emissions. Even though Pt electrodes are excellent HER electrocatalysts, commercialization of large-scale hydrogen production technology requires finding an equally efficient, low-cost, earth-abundant alternative. Here, high porosity, metal-organic framework (MOF) films have been used as scaffolds for the deposition of a Ni-S electrocatalyst. Compared with an MOF-free Ni-S, the resulting hybrid materials exhibit significantly enhanced performance for HER from aqueous acid, decreasing the kinetic overpotential by more than 200 mV at a benchmark current density of 10 mA cm-2. In conclusion, although the initial aim was to improve electrocatalytic activity by greatly boosting the active area of the Ni-S catalyst, the performance enhancements instead were found to arise primarily from the ability of the proton-conductive MOF to favourably modify the immediate chemical environment of the sulfide-based catalyst.},
doi = {10.1038/ncomms9304},
journal = {Nature Communications},
number = ,
volume = 6,
place = {United States},
year = {Mon Sep 14 00:00:00 EDT 2015},
month = {Mon Sep 14 00:00:00 EDT 2015}
}
Web of Science
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Metal‐Organic‐Framework‐Derived Nitrogen‐Doped Hybrid Nickel‐Iron‐Sulfide Architectures on Carbon Cloth as Efficient Electrocatalysts for the Oxygen Evolution Reaction
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MoS 2 @HKUST-1 Flower-Like Nanohybrids for Efficient Hydrogen Evolution Reactions
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The Design of Water Oxidation Electrocatalysts from Nanoscale Metal–Organic Frameworks
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Role of Organic Components in Electrocatalysis for Renewable Energy Storage
journal, June 2018
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Electrochemically Facile Hydrogen Evolution Using Ruthenium Encapsulated Two Dimensional Covalent Organic Framework (2D COF)
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Electrocatalytic Metal-Organic Frameworks for Energy Applications
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Dinuclear Manganese Carbonyl Complexes: Electrocatalytic Reduction of Protons to Dihydrogen
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Metal-Organic Frameworks for CO 2 Chemical Transformations
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Electrocatalytic and Enhanced Photocatalytic Applications of Sodium Niobate Nanoparticles Developed by Citrate Precursor Route
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Modulating the rate of charge transport in a metal–organic framework thin film using host:guest chemistry
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MOF-derived Co-doped nickel selenide/C electrocatalysts supported on Ni foam for overall water splitting
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Direct photoactivation of a nickel-based, water-reduction photocathode by a highly conjugated supramolecular chromophore
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Metal–organic framework derived hollow CoS 2 nanotube arrays: an efficient bifunctional electrocatalyst for overall water splitting
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A general approach to synthesise ultrathin NiM (M = Fe, Co, Mn) hydroxide nanosheets as high-performance low-cost electrocatalysts for overall water splitting
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Copper-modulated bismuth nanocrystals alter the formate formation pathway to achieve highly selective CO 2 electroreduction
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Facile synthesis of amorphous MoS x –Fe anchored on Zr-MOFs towards efficient and stable electrocatalytic hydrogen evolution
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An efficient bifunctional electrocatalyst based on a nickel iron layered double hydroxide functionalized Co 3 O 4 core shell structure in alkaline media
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Electrodeposition of sulfur-engineered amorphous nickel hydroxides on MIL-53(Fe) nanosheets to accelerate the oxygen evolution reaction
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On the potential for nanoscale metal–organic frameworks for energy applications
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Metal-Organic Frameworks-Based Electrocatalysis: Insight and Future Perspectives
journal, September 2018
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Artificial photosynthesis with metal and covalent organic frameworks (MOFs and COFs): challenges and prospects in fuel‐forming electrocatalysis
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Metal–Organic Framework Thin Film-Based Dye Sensitized Solar Cells with Enhanced Photocurrent
journal, October 2018
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Mechanochemically Assisted Synthesis of a Ru Catalyst for Hydrogen Evolution with Performance Superior to Pt in Both Acidic and Alkaline Media
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Polymeric coatings for applications in electrocatalytic and photoelectrosynthetic fuel production
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A metal–organic framework film with a switchable anodic and cathodic behaviour in a photo-electrochemical cell
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Accelerated proton transmission in metal–organic frameworks for the efficient reduction of CO 2 in aqueous solutions
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