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Title: Adsorption of dysprosium on the graphite (0001) surface: Nucleation and growth at 300 K

Abstract

We have studied nucleation and growth of Dy islands on the basal plane of graphite at 300 K using scanning tunneling microscopy, density functional theory (DFT) in a form that includes van der Waals interactions, and analytic theory. The interaction of atomic Dy with graphite is strong, while the diffusion barrier is small. Experiment shows that at 300 K, the density of nucleated islands is close to the value predicted for homogeneous nucleation, using critical nucleus size of 1 and the DFT-derived diffusion barrier. Homogeneous nucleation is also supported by the monomodal shape of the island size distributions. Comparison with the published island density of Dy on graphene shows that the value is about two orders of magnitude smaller on graphite, which can be attributed to more effective charge screening in graphite. The base of each island is 3 atomic layers high and atomically ordered, forming a coincidence lattice with the graphite. Islands resist coalescence, probably due to multiple rotational orientations associated with the coincidence lattice. Upper levels grow as discernible single-atom layers. Analysis of the level populations reveals significant downward interlayer transport, which facilitates growth of the base. As a result, this island shape is metastable, since more compactmore » three-dimensional islands form at elevated growth temperature.« less

Authors:
ORCiD logo [1]; ORCiD logo [1];  [1];  [2];  [2];  [1];  [1]; ORCiD logo [1];  [1]
  1. Ames Lab. and Iowa State Univ., Ames, IA (United States)
  2. Ames Lab., Ames, IA (United States)
Publication Date:
Research Org.:
Ames Lab., Ames, IA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1257367
Alternate Identifier(s):
OSTI ID: 1256781
Report Number(s):
IS-J-8894
Journal ID: ISSN 0021-9606; JCPSA6
Grant/Contract Number:  
CHE-1111500; AC02-07CH11358
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Volume: 145; Journal Issue: 21; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; graphite; dysprosium; nucleation; adsorption; homogeneous nucleation; magnetic islands; density functional theory

Citation Formats

Kwolek, Emma J., Lei, Huaping, Lii-Rosales, Ann, Wallingford, Mark, Zhou, Yinghui, Wang, Cai -Zhuang, Tringides, Michael C., Evans, James W., and Thiel, Patricia A.. Adsorption of dysprosium on the graphite (0001) surface: Nucleation and growth at 300 K. United States: N. p., 2016. Web. https://doi.org/10.1063/1.4953611.
Kwolek, Emma J., Lei, Huaping, Lii-Rosales, Ann, Wallingford, Mark, Zhou, Yinghui, Wang, Cai -Zhuang, Tringides, Michael C., Evans, James W., & Thiel, Patricia A.. Adsorption of dysprosium on the graphite (0001) surface: Nucleation and growth at 300 K. United States. https://doi.org/10.1063/1.4953611
Kwolek, Emma J., Lei, Huaping, Lii-Rosales, Ann, Wallingford, Mark, Zhou, Yinghui, Wang, Cai -Zhuang, Tringides, Michael C., Evans, James W., and Thiel, Patricia A.. Mon . "Adsorption of dysprosium on the graphite (0001) surface: Nucleation and growth at 300 K". United States. https://doi.org/10.1063/1.4953611. https://www.osti.gov/servlets/purl/1257367.
@article{osti_1257367,
title = {Adsorption of dysprosium on the graphite (0001) surface: Nucleation and growth at 300 K},
author = {Kwolek, Emma J. and Lei, Huaping and Lii-Rosales, Ann and Wallingford, Mark and Zhou, Yinghui and Wang, Cai -Zhuang and Tringides, Michael C. and Evans, James W. and Thiel, Patricia A.},
abstractNote = {We have studied nucleation and growth of Dy islands on the basal plane of graphite at 300 K using scanning tunneling microscopy, density functional theory (DFT) in a form that includes van der Waals interactions, and analytic theory. The interaction of atomic Dy with graphite is strong, while the diffusion barrier is small. Experiment shows that at 300 K, the density of nucleated islands is close to the value predicted for homogeneous nucleation, using critical nucleus size of 1 and the DFT-derived diffusion barrier. Homogeneous nucleation is also supported by the monomodal shape of the island size distributions. Comparison with the published island density of Dy on graphene shows that the value is about two orders of magnitude smaller on graphite, which can be attributed to more effective charge screening in graphite. The base of each island is 3 atomic layers high and atomically ordered, forming a coincidence lattice with the graphite. Islands resist coalescence, probably due to multiple rotational orientations associated with the coincidence lattice. Upper levels grow as discernible single-atom layers. Analysis of the level populations reveals significant downward interlayer transport, which facilitates growth of the base. As a result, this island shape is metastable, since more compact three-dimensional islands form at elevated growth temperature.},
doi = {10.1063/1.4953611},
journal = {Journal of Chemical Physics},
number = 21,
volume = 145,
place = {United States},
year = {2016},
month = {6}
}

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Works referenced in this record:

Growth morphology and thermal stability of metal islands on graphene
journal, August 2012


Kondo Quantum Criticality of Magnetic Adatoms in Graphene
journal, January 2011


Determining whether metals nucleate homogeneously on graphite: A case study with copper
journal, November 2014


Evolution of epitaxial semiconductor nanodots and nanowires from supersaturated wetting layers
journal, January 2015

  • Zhang, Jianjun; Brehm, Moritz; Grydlik, Martyna
  • Chemical Society Reviews, Vol. 44, Issue 1
  • DOI: 10.1039/c4cs00077c

Metals on graphene: correlation between adatom adsorption behavior and growth morphology
journal, January 2012

  • Liu, Xiaojie; Wang, C. Z.; Hupalo, M.
  • Physical Chemistry Chemical Physics, Vol. 14, Issue 25
  • DOI: 10.1039/c2cp40527j

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996


Growth morphology and properties of metals on graphene
journal, December 2015


Growth of Ag thin films on complex surfaces of quasicrystals and approximant phases
journal, July 2003


Nucleation and growth of thin films
journal, April 1984

  • Venables, J. A.; Spiller, G. D. T.; Hanbucken, M.
  • Reports on Progress in Physics, Vol. 47, Issue 4
  • DOI: 10.1088/0034-4885/47/4/002

Projector augmented-wave method
journal, December 1994


High Island Densities and Long Range Repulsive Interactions: Fe on Epitaxial Graphene
journal, July 2012


Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/physrevlett.77.3865

Chemical accuracy for the van der Waals density functional
journal, December 2009

  • Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos
  • Journal of Physics: Condensed Matter, Vol. 22, Issue 2
  • DOI: 10.1088/0953-8984/22/2/022201

Thin films of Co on Pt(111): Strain relaxation and growth
journal, July 2000


Transition metals on the (0 0 0 1) surface of graphite: Fundamental aspects of adsorption, diffusion, and morphology
journal, August 2014


Size-Selective Nanoparticle Growth on Few-Layer Graphene Films
journal, March 2010

  • Luo, Zhengtang; Somers, Luke A.; Dan, Yaping
  • Nano Letters, Vol. 10, Issue 3
  • DOI: 10.1021/nl9026605

Smoluchowski ripening of Ag islands on Ag(100)
journal, September 1999

  • Stoldt, C. R.; Jenks, C. J.; Thiel, P. A.
  • The Journal of Chemical Physics, Vol. 111, Issue 11
  • DOI: 10.1063/1.479770

Birth-death models of epitaxy
journal, June 1989


Island-size distributions in submonolayer epitaxial growth: Influence of the mobility of small clusters
journal, February 1996


Epitaxial growth of thin magnetic cobalt films on Au(111) studied by scanning tunneling microscopy
journal, November 1991


Growth of fcc(111) Dy multi-height islands on 6H-SiC(0001) graphene
journal, May 2013


Ultrathin epitaxial cobalt films on graphene for spintronic investigations and applications
journal, October 2010


Morphological evolution during epitaxial thin film growth: Formation of 2D islands and 3D mounds
journal, April 2006


Improved description of soft layered materials with van der Waals density functional theory
journal, October 2012

  • Graziano, Gabriella; Klimeš, Jiří; Fernandez-Alonso, Felix
  • Journal of Physics: Condensed Matter, Vol. 24, Issue 42
  • DOI: 10.1088/0953-8984/24/42/424216

In situ scanning tunneling microscopy study of cobalt thin film electrodeposited on Pt(111) electrode
journal, December 2013


Adsorption of cobalt on graphene: Electron correlation effects from a quantum chemical perspective
journal, August 2012


Formation of surface intercalation compounds at Gd(Dy)/graphite interfaces under thermal annealing
journal, March 2001


Metal Nanostructure Formation on Graphene: Weak versus Strong Bonding
journal, March 2011

  • Hupalo, Myron; Liu, Xiaojie; Wang, Cai-Zhuang
  • Advanced Materials, Vol. 23, Issue 18
  • DOI: 10.1002/adma.201100412

Van der Waals density functionals applied to solids
journal, May 2011


Electronic and magnetic properties of 3 d transition-metal atom adsorbed graphene and graphene nanoribbons
journal, May 2008


Electrodeposition of Co and Ni/Au(111) ultrathin layers. Part I: nucleation and growth mechanisms from in situ STM
journal, May 2004


Kondo Quantum Criticality of Magnetic Adatoms in Graphene
journal, January 2011


Electronic and magnetic properties of 3 d transition-metal atom adsorbed graphene and graphene nanoribbons
journal, May 2008


High Island Densities and Long Range Repulsive Interactions: Fe on Epitaxial Graphene
journal, July 2012


Adsorption of cobalt on graphene: Electron correlation effects from a quantum chemical perspective
journal, August 2012


Formation of surface intercalation compounds at Gd(Dy)/graphite interfaces under thermal annealing
journal, March 2001


Determining whether metals nucleate homogeneously on graphite: A case study with copper
journal, November 2014


Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Projector augmented-wave method
journal, December 1994


Island-size distributions in submonolayer epitaxial growth: Influence of the mobility of small clusters
journal, February 1996


Growth of Ag thin films on complex surfaces of quasicrystals and approximant phases
journal, July 2003


Evolution of epitaxial semiconductor nanodots and nanowires from supersaturated wetting layers
journal, January 2015

  • Zhang, Jianjun; Brehm, Moritz; Grydlik, Martyna
  • Chemical Society Reviews, Vol. 44, Issue 1
  • DOI: 10.1039/C4CS00077C

Thin films of Co on Pt(111): Strain relaxation and growth
journal, July 2000


Epitaxial growth of thin magnetic cobalt films on Au(111) studied by scanning tunneling microscopy
journal, November 1991


Parallel Nanoimprint Forming of One-Dimensional Chiral Semiconductor for Strain-Engineered Optical Properties
journal, August 2020


High-resolution X-ray luminescence extension imaging
journal, February 2021


Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect
journal, February 2020


Nucleation And Growth Of Thin Films
journal, June 1984


    Works referencing / citing this record:

    Spontaneous selective deposition of iron oxide nanoparticles on graphite as model catalysts
    journal, January 2019

    • de Alwis, Chathura; Leftwich, Timothy R.; Mukherjee, Pinaki
    • Nanoscale Advances, Vol. 1, Issue 12
    • DOI: 10.1039/c9na00472f

    Dy adsorption and penetration on defected graphene by first-principles calculations
    journal, February 2018


    Formation of dysprosium carbide on the graphite (0001) surface
    journal, July 2017