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Title: Disentangling formation of multiple-core holes in aminophenol molecules exposed to bright X-FEL radiation

Abstract

Competing multi-photon ionization processes, some leading to the formation of double core hole states, have been examined in 4-aminophenol. The experiments used the linac coherent light source (LCLS) x-ray free electron laser, in combination with a time-of-flight magnetic bottle electron spectrometer and the correlation analysis method of covariance mapping. Furthermore, the results imply that 4-aminophenol molecules exposed to the focused x-ray pulses of the LCLS sequentially absorb more than two x-ray photons, resulting in the formation of multiple core holes as well as in the sequential removal of photoelectrons and Auger electrons (so-called PAPA sequences).

Authors:
 [1];  [2];  [3];  [4];  [5];  [6];  [7];  [8];  [9];  [8];  [8];  [8];  [8];  [8];  [8];  [10];  [10];  [10];  [10];  [10] more »;  [11];  [12];  [13];  [13];  [13];  [14];  [14];  [14];  [15];  [15];  [15];  [16];  [1] « less
+ Show Author Affiliations
  1. Univ. of Gothenburg, Gothenburg (Sweden); Uppsala Univ., Uppsala (Sweden)
  2. Uppsala Univ., Uppsala (Sweden); Stockholm Univ., Stockholm (Sweden); Jan Kochanowski Univ., Kielce (Poland)
  3. Uppsala Univ., Uppsala (Sweden)
  4. Univ. of Gothenburg, Gothenburg (Sweden); Uppsala Univ., Uppsala (Sweden); Imperial College London, London (United Kingdom)
  5. Univ. of Gothenburg, Gothenburg (Sweden); Uppsala Univ., Uppsala (Sweden); Oxford Univ., Oxford (United Kingdom)
  6. Uppsala Univ., Uppsala (Sweden); LCPMR, UPMC and CNRS, Paris (France)
  7. Imperial College London, London (United Kingdom)
  8. SLAC National Accelerator Lab., Menlo Park, CA (United States)
  9. SLAC National Accelerator Lab., Menlo Park, CA (United States); Graz Univ. of Technology, Graz (Austria)
  10. Stockholm Univ., Stockholm (Sweden)
  11. Max-Planck-Institut fur Medizinische Forschung, Heidelberg (Germany)
  12. Max Planck-Institut fur Kernphysik, Heidelberg (Germany); Physikalisch-Technische Bundesanstalt, Braunschweig (Germany)
  13. Tohoku Univ., Sendai (Japan)
  14. Elettra-Sincrotrone Trieste, Trieste (Italy)
  15. Western Michigan Univ., Kalamazoo MI (United States)
  16. Western Michigan Univ., Kalamazoo MI (United States); Univ. of Connecticut, Storrs, CT (United States)
Publication Date:
Research Org.:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1257226
Grant/Contract Number:  
AC02-76SF00515
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Physics. B, Atomic, Molecular and Optical Physics
Additional Journal Information:
Journal Volume: 48; Journal Issue: 24; Journal ID: ISSN 0953-4075
Publisher:
IOP Publishing
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; multiple ionization processes; double core hole; covariance mapping

Citation Formats

Zhaunerchyk, V., Kaminska, M., Mucke, M., Squibb, R. J., Eland, J. H. D., Piancastelli, M. N., Frasinski, L. J., Grilj, J., Koch, M., McFarland, B. K., Sistrunk, E., Guhr, M., Coffee, R. N., Bostedt, C., Bozek, J. D., Salen, P., Meulen, P. v. d., Linusson, P., Thomas, R. D., Larsson, M., Foucar, L., Ullrich, J., Motomura, K., Mondal, S., Ueda, K., Richter, R., Prince, K. C., Takahashi, O., Osipov, T., Fang, L., Murphy, B. F., Berrah, N., and Feifel, R. Disentangling formation of multiple-core holes in aminophenol molecules exposed to bright X-FEL radiation. United States: N. p., 2015. Web. doi:10.1088/0953-4075/48/24/244003.
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Zhaunerchyk, V., Kaminska, M., Mucke, M., Squibb, R. J., Eland, J. H. D., Piancastelli, M. N., Frasinski, L. J., Grilj, J., Koch, M., McFarland, B. K., Sistrunk, E., Guhr, M., Coffee, R. N., Bostedt, C., Bozek, J. D., Salen, P., Meulen, P. v. d., Linusson, P., Thomas, R. D., Larsson, M., Foucar, L., Ullrich, J., Motomura, K., Mondal, S., Ueda, K., Richter, R., Prince, K. C., Takahashi, O., Osipov, T., Fang, L., Murphy, B. F., Berrah, N., & Feifel, R. Disentangling formation of multiple-core holes in aminophenol molecules exposed to bright X-FEL radiation. United States. https://doi.org/10.1088/0953-4075/48/24/244003
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Zhaunerchyk, V., Kaminska, M., Mucke, M., Squibb, R. J., Eland, J. H. D., Piancastelli, M. N., Frasinski, L. J., Grilj, J., Koch, M., McFarland, B. K., Sistrunk, E., Guhr, M., Coffee, R. N., Bostedt, C., Bozek, J. D., Salen, P., Meulen, P. v. d., Linusson, P., Thomas, R. D., Larsson, M., Foucar, L., Ullrich, J., Motomura, K., Mondal, S., Ueda, K., Richter, R., Prince, K. C., Takahashi, O., Osipov, T., Fang, L., Murphy, B. F., Berrah, N., and Feifel, R. Wed . "Disentangling formation of multiple-core holes in aminophenol molecules exposed to bright X-FEL radiation". United States. https://doi.org/10.1088/0953-4075/48/24/244003. https://www.osti.gov/servlets/purl/1257226.
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@article{osti_1257226,
title = {Disentangling formation of multiple-core holes in aminophenol molecules exposed to bright X-FEL radiation},
author = {Zhaunerchyk, V. and Kaminska, M. and Mucke, M. and Squibb, R. J. and Eland, J. H. D. and Piancastelli, M. N. and Frasinski, L. J. and Grilj, J. and Koch, M. and McFarland, B. K. and Sistrunk, E. and Guhr, M. and Coffee, R. N. and Bostedt, C. and Bozek, J. D. and Salen, P. and Meulen, P. v. d. and Linusson, P. and Thomas, R. D. and Larsson, M. and Foucar, L. and Ullrich, J. and Motomura, K. and Mondal, S. and Ueda, K. and Richter, R. and Prince, K. C. and Takahashi, O. and Osipov, T. and Fang, L. and Murphy, B. F. and Berrah, N. and Feifel, R.},
abstractNote = {Competing multi-photon ionization processes, some leading to the formation of double core hole states, have been examined in 4-aminophenol. The experiments used the linac coherent light source (LCLS) x-ray free electron laser, in combination with a time-of-flight magnetic bottle electron spectrometer and the correlation analysis method of covariance mapping. Furthermore, the results imply that 4-aminophenol molecules exposed to the focused x-ray pulses of the LCLS sequentially absorb more than two x-ray photons, resulting in the formation of multiple core holes as well as in the sequential removal of photoelectrons and Auger electrons (so-called PAPA sequences).},
doi = {10.1088/0953-4075/48/24/244003},
journal = {Journal of Physics. B, Atomic, Molecular and Optical Physics},
number = 24,
volume = 48,
place = {United States},
year = {Wed Oct 28 00:00:00 EDT 2015},
month = {Wed Oct 28 00:00:00 EDT 2015}
}
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https://doi.org/10.1088/0953-4075/48/24/244003
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    Works referencing / citing this record:

    Study of double core hole excitations in molecules by X-ray double-quantum-coherence signals: a multi-configuration simulation
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    Double core hole valence-to-core x-ray emission spectroscopy: A theoretical exploration using time-dependent density functional theory
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    Multiple core-hole formation by free-electron laser radiation in molecular nitrogen
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