Phase coexistence and domain configuration in Pb(Mg1/3Nb2/3)O3-0.34PbTiO3 single crystal revealed by synchrotron-based X-ray diffractive three-dimensional reciprocal space mapping and piezoresponse force microscopy

Wang, Ruixue; Xu, Han; Yang, Bin; Luo, Zhenlin; Sun, Enwei; Zhao, Jiangtao; Zheng, Limei; Dong, Yongqi; Zhou, Hua; Ren, Yang; Gao, Chen; Cao, Wenwu

doi:10.1063/1.4946776

Title: Phase coexistence and domain configuration in Pb(Mg_1/3Nb_2/3)O₃-0.34PbTiO₃ single crystal revealed by synchrotron-based X-ray diffractive three-dimensional reciprocal space mapping and piezoresponse force microscopy

Abstract

The crystalline phases and domain configuration in the morphotropic phase boundary composition Pb(Mg_1/3Nb_2/3)O₃-0.34PbTiO₃ (PMN-0.34PT) single crystal have been investigated by synchrotronbased X-ray 3D Reciprocal Space Mapping (3D-RSM) and Piezoresponse Force Microscopy. The coexistence of tetragonal (T) and monoclinic MC phases in this PMN-0.34PT single crystal is confirmed. The affiliation of each diffraction spot in the 3D-RSM was identified with the assistance of qualitative simulation. Most importantly, the twinning structure between different domains in such a mixed phase PMN-PT crystal is firmly clarified, and the spatial distribution of different twin domains is demonstrated. Additionally, the lattice parameters of T and MC phases in PMN-0.34PT single crystal as well as the tilting angles of crystal lattices caused by the interfacial lattice mismatch are determined.

Authors:

Wang, Ruixue ^[1]; Xu, Han ^[2]; Yang, Bin ^[1]; Luo, Zhenlin ^[2]; Sun, Enwei ^[1]; Zhao, Jiangtao ^[2];

^[1]; Dong, Yongqi ^[2]; Zhou, Hua ^[3]; Ren, Yang ^[3]; Gao, Chen ^[2];

^[4]

Harbin Inst. of Technology, Harbin (China)
Univ. of Science and Technology of China, Anhui (China)
Argonne National Lab. (ANL), Argonne, IL (United States)
Harbin Inst. of Technology, Harbin (China); Pennsylvania State Univ., University Park, PA (United States)

Publication Date:: Fri Apr 15 00:00:00 EDT 2016

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Natural Science Foundation of China (NSFC)

OSTI Identifier:: 1256890

Alternate Identifier(s):: OSTI ID: 1420601

Grant/Contract Number:: AC02-06CH11357; 2013CB632900; 11374010; 11434009

Resource Type:: Accepted Manuscript

Journal Name:: Applied Physics Letters

Additional Journal Information:: Journal Volume: 108; Journal Issue: 15; Journal ID: ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 3D reciprocal space mapping; domain distribution; phase coexistence; piezoresponse force microscopy

Citation Formats


                    Wang, Ruixue, Xu, Han, Yang, Bin, Luo, Zhenlin, Sun, Enwei, Zhao, Jiangtao, Zheng, Limei, Dong, Yongqi, Zhou, Hua, Ren, Yang, Gao, Chen, and Cao, Wenwu. Phase coexistence and domain configuration in Pb(Mg1/3Nb2/3)O3-0.34PbTiO3 single crystal revealed by synchrotron-based X-ray diffractive three-dimensional reciprocal space mapping and piezoresponse force microscopy.  United States: N. p., 2016. 
Web.  doi:10.1063/1.4946776.

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                    Wang, Ruixue, Xu, Han, Yang, Bin, Luo, Zhenlin, Sun, Enwei, Zhao, Jiangtao, Zheng, Limei, Dong, Yongqi, Zhou, Hua, Ren, Yang, Gao, Chen, & Cao, Wenwu. Phase coexistence and domain configuration in Pb(Mg1/3Nb2/3)O3-0.34PbTiO3 single crystal revealed by synchrotron-based X-ray diffractive three-dimensional reciprocal space mapping and piezoresponse force microscopy.  United States.  https://doi.org/10.1063/1.4946776

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                    Wang, Ruixue, Xu, Han, Yang, Bin, Luo, Zhenlin, Sun, Enwei, Zhao, Jiangtao, Zheng, Limei, Dong, Yongqi, Zhou, Hua, Ren, Yang, Gao, Chen, and Cao, Wenwu. Fri .  
"Phase coexistence and domain configuration in Pb(Mg1/3Nb2/3)O3-0.34PbTiO3 single crystal revealed by synchrotron-based X-ray diffractive three-dimensional reciprocal space mapping and piezoresponse force microscopy".  United States.  https://doi.org/10.1063/1.4946776.  https://www.osti.gov/servlets/purl/1256890.

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@article{osti_1256890,

  title        = {Phase coexistence and domain configuration in Pb(Mg1/3Nb2/3)O3-0.34PbTiO3 single crystal revealed by synchrotron-based X-ray diffractive three-dimensional reciprocal space mapping and piezoresponse force microscopy},

  author       = {Wang, Ruixue and Xu, Han and Yang, Bin and Luo, Zhenlin and Sun, Enwei and Zhao, Jiangtao and Zheng, Limei and Dong, Yongqi and Zhou, Hua and Ren, Yang and Gao, Chen and Cao, Wenwu},

  abstractNote = {The crystalline phases and domain configuration in the morphotropic phase boundary composition Pb(Mg1/3Nb2/3)O3-0.34PbTiO3 (PMN-0.34PT) single crystal have been investigated by synchrotronbased X-ray 3D Reciprocal Space Mapping (3D-RSM) and Piezoresponse Force Microscopy. The coexistence of tetragonal (T) and monoclinic MC phases in this PMN-0.34PT single crystal is confirmed. The affiliation of each diffraction spot in the 3D-RSM was identified with the assistance of qualitative simulation. Most importantly, the twinning structure between different domains in such a mixed phase PMN-PT crystal is firmly clarified, and the spatial distribution of different twin domains is demonstrated. Additionally, the lattice parameters of T and MC phases in PMN-0.34PT single crystal as well as the tilting angles of crystal lattices caused by the interfacial lattice mismatch are determined.},

  doi          = {10.1063/1.4946776},

  journal      = {Applied Physics Letters},

  number       = 15,

  volume       = 108,

  place        = {United States},

  year         = {Fri Apr 15 00:00:00 EDT 2016},

  month        = {Fri Apr 15 00:00:00 EDT 2016}

}

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Works referenced in this record:

Origin of morphotropic phase boundaries in ferroelectrics
journal, January 2008

Ahart, Muhtar; Somayazulu, Maddury; Cohen, R. E.
Nature, Vol. 451, Issue 7178
DOI: 10.1038/nature06459

Monoclinic phases arising across thermal inter-ferroelectric phase transitions
journal, July 2014

Gu, Yijia; Xue, Fei; Lei, Shiming
Physical Review B, Vol. 90, Issue 2
DOI: 10.1103/PhysRevB.90.024104

High performance ferroelectric relaxor-PbTiO ₃ single crystals: Status and perspective
journal, February 2012

Zhang, Shujun; Li, Fei
Journal of Applied Physics, Vol. 111, Issue 3
DOI: 10.1063/1.3679521

Monoclinic phase in the relaxor-based piezoelectric/ferroelectric ${P b (M g}_{1 / 3} {Nb}_{2 / 3} {) O}_{3} {- P b T i O}_{3}$ system
journal, October 2001

Ye, Z. -G.; Noheda, B.; Dong, M.
Physical Review B, Vol. 64, Issue 18
DOI: 10.1103/PhysRevB.64.184114

Reciprocal space mapping
journal, June 1997

Fewster, Paul F.
Critical Reviews in Solid State and Materials Sciences, Vol. 22, Issue 2
DOI: 10.1080/10408439708241259

Composition and phase dependence of the intrinsic and extrinsic piezoelectric activity of domain engineered (1−x)Pb(Mg1/3Nb2/3)O3−xPbTiO3 crystals
journal, August 2010

Li, Fei; Zhang, Shujun; Xu, Zhuo
Journal of Applied Physics, Vol. 108, Issue 3
DOI: 10.1063/1.3466978

Evidence for $M_{B}$ and $M_{C}$ phases in the morphotropic phase boundary region of $(1 - x) [Pb ({Mg}_{1 / 3} {Nb}_{2 / 3}) O_{3}] - x {PbTiO}_{3} :$ A Rietveld study
journal, February 2003

Singh, Akhilesh Kumar; Pandey, Dhananjai
Physical Review B, Vol. 67, Issue 6
DOI: 10.1103/PhysRevB.67.064102

Growth, characterization and properties of relaxor ferroelectric PMN-PT single crystals
journal, May 1999

Yin, Zhi-Wen; Luo, Hao-Su; Wang, Ping-Chu
Ferroelectrics, Vol. 229, Issue 1
DOI: 10.1080/00150199908224341

Mesoscale Domains and Nature of the Relaxor State by Piezoresponse Force Microscopy
journal, July 2013

Shvartsman, V. V.; Dkhil, B.; Kholkin, A. L.
Annual Review of Materials Research, Vol. 43, Issue 1
DOI: 10.1146/annurev-matsci-071312-121632

Monoclinic structure of unpoled morphotropic high piezoelectric PMN-PT and PZN-PT compounds
journal, January 2002

Kiat, Jean-Michel; Uesu, Yoshiaki; Dkhil, Brahim
Physical Review B, Vol. 65, Issue 6
DOI: 10.1103/PhysRevB.65.064106

Periodic elastic nanodomains in ultrathin tetragonal-like BiFeO $_{3}$ films
journal, August 2013

Luo, Zhenlin; Chen, Zuhuang; Yang, Yuanjun
Physical Review B, Vol. 88, Issue 6
DOI: 10.1103/PhysRevB.88.064103

Tetragonal micro/nanotwins in 0.91Pb(Zn1/3Nb2/3)O3−0.09PbTiO3 revealed by reciprocal space mapping
journal, May 2009

Chang, W. S.; Lim, L. C.; Yang, P.
Applied Physics Letters, Vol. 94, Issue 20
DOI: 10.1063/1.3133874

A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution
journal, April 1999

Noheda, B.; Cox, D. E.; Shirane, G.
Applied Physics Letters, Vol. 74, Issue 14
DOI: 10.1063/1.123756

The giant piezoelectric effect: electric field induced monoclinic phase or piezoelectric distortion of the rhombohedral parent?
journal, May 2003

Kisi, E. H.; Piltz, R. O.; Forrester, J. S.
Journal of Physics: Condensed Matter, Vol. 15, Issue 21
DOI: 10.1088/0953-8984/15/21/311

Phase coexistence and transformations in field-cooled ternary piezoelectric single crystals near the morphotropic phase boundary
journal, December 2014

Luo, Chengtao; Wang, Yaojin; Wang, Zhiguang
Applied Physics Letters, Vol. 105, Issue 23
DOI: 10.1063/1.4903476

Elastic, piezoelectric, and dielectric properties of multidomain 0.67Pb(Mg1/3Nb2/3)O3–0.33PbTiO3 single crystals
journal, October 2001

Zhang, Rui; Jiang, Bei; Cao, Wenwu
Journal of Applied Physics, Vol. 90, Issue 7
DOI: 10.1063/1.1390494

Adaptive ferroelectric state at morphotropic phase boundary: Coexisting tetragonal and rhombohedral phases
journal, June 2014

Zhang, Yang; Xue, Dezhen; Wu, Haijun
Acta Materialia, Vol. 71
DOI: 10.1016/j.actamat.2014.03.007

High-resolution three-dimensional reciprocal space mapping of semiconductor nanostructures
journal, August 2009

Mariager, Simon O.; Schlepütz, Christian M.; Aagesen, Martin
physica status solidi (a), Vol. 206, Issue 8
DOI: 10.1002/pssa.200881612

Ultrahigh strain and piezoelectric behavior in relaxor based ferroelectric single crystals
journal, August 1997

Park, Seung-Eek; Shrout, Thomas R.
Journal of Applied Physics, Vol. 82, Issue 4
DOI: 10.1063/1.365983

Domain wall orientations in ferroelastics and ferroelectrics
journal, December 2004

Erhart *, J.
Phase Transitions, Vol. 77, Issue 12
DOI: 10.1080/01411590410001710744

Direct high-resolution transmission electron microscopy observation of tetragonal nanotwins within the monoclinic MC phase of Pb(Mg1∕3Nb2∕3)O3-0.35PbTiO3 crystals
journal, April 2008

Bhattacharyya, Somnath; Jinschek, J. R.; Cao, Hu
Applied Physics Letters, Vol. 92, Issue 14
DOI: 10.1063/1.2908228

Temperature-induced and electric-field-induced phase transitions in rhombohedral ${Pb (In}_{1 / 2} {Nb}_{1 / 2}) O_{3} − {Pb (Mg}_{1 / 3} {Nb}_{2 / 3} {) O}_{3} − {PbTiO}_{3}$ ternary single crystals
journal, October 2014

Wang, Yaojin; Wang, Zhiguang; Ge, Wenwei
Physical Review B, Vol. 90, Issue 13
DOI: 10.1103/PhysRevB.90.134107

Temperature and electric-field induced phase transitions, and full tensor properties of ${[011]}_{C}$ -poled domain-engineered tetragonal $0 . 63 Pb (M g_{1 / 3} N b_{2 / 3}) − 0 . 37 PbTi O_{3}$ single crystals
journal, March 2016

Zheng, Limei; Jing, Yujia; Lu, Xiaoyan
Physical Review B, Vol. 93, Issue 9
DOI: 10.1103/PhysRevB.93.094104

Coexistence of MA and MC phases in Pb(Mg1∕3Nb2∕3)0.68Ti0.32O3 single crystals
journal, February 2006

Bao, Peng; Yan, Feng; Lu, Xiaomei
Applied Physics Letters, Vol. 88, Issue 9
DOI: 10.1063/1.2177370

Origin of the High Piezoelectric Response in ${PbZr}_{1 - x} {Ti}_{x} O_{3}$
journal, June 2000

Guo, R.; Cross, L. E.; Park, S-E.
Physical Review Letters, Vol. 84, Issue 23
DOI: 10.1103/PhysRevLett.84.5423

Hysteretic phase transition sequence in $0.67 Pb (M g_{1 / 3} N b_{2 / 3}) O_{3} - 0.33 PbTi O_{3}$ single crystal driven by electric field and temperature
journal, May 2015

Zheng, Limei; Lu, Xiaoyan; Shang, Hengshan
Physical Review B, Vol. 91, Issue 18
DOI: 10.1103/PhysRevB.91.184105

Formation of monoclinic nanodomains at the morphotropic phase boundary of ferroelectric systems
journal, December 2013

Ke, X. Q.; Wang, D.; Ren, X.
Physical Review B, Vol. 88, Issue 21
DOI: 10.1103/PhysRevB.88.214105

In Situ Three-Dimensional Reciprocal-Space Mapping of Diffuse Scattering Intensity Distribution and Data Analysis for Precursor Phenomenon in Shape-Memory Alloy
journal, January 2012

Cheng, Tian-Le; Ma, Fengde D.; Zhou, Jie E.
JOM, Vol. 64, Issue 1
DOI: 10.1007/s11837-011-0228-6

Phase diagram of the ferroelectric relaxor $(1 - x) {PbMg}_{1 / 3} {Nb}_{2 / 3} O_{3} - x {PbTiO}_{3}$
journal, August 2002

Noheda, B.; Cox, D. E.; Shirane, G.
Physical Review B, Vol. 66, Issue 5
DOI: 10.1103/PhysRevB.66.054104

Probing the domain structure of BiFeO ₃ epitaxial films with three-dimensional reciprocal space mapping
journal, May 2014

Luo, Z. L.; Huang, H.; Zhou, H.
Applied Physics Letters, Vol. 104, Issue 18
DOI: 10.1063/1.4875579

Monoclinic and triclinic phases in higher-order Devonshire theory
journal, January 2001

Vanderbilt, David; Cohen, Morrel H.
Physical Review B, Vol. 63, Issue 9
DOI: 10.1103/PhysRevB.63.094108

Three-dimensional mapping of diffuse scattering in $Pb ({Zn}_{1 ∕ 3} {Nb}_{2 ∕ 3}) O_{3} − x Pb Ti O_{3}$
journal, November 2004

Xu, Guangyong; Zhong, Z.; Hiraka, H.
Physical Review B, Vol. 70, Issue 17
DOI: 10.1103/PhysRevB.70.174109

Domain structure in the monoclinic Pm phase of Pb(Mg1/3Nb2/3)O3–PbTiO3 single crystals
journal, June 2004

Bokov, A. A.; Ye, Z. -G.
Journal of Applied Physics, Vol. 95, Issue 11
DOI: 10.1063/1.1703830

Monoclinic nanodomains in morphotropic phase boundary Pb(Mg _1/3 Nb _2/3 )O ₃ –PbTiO ₃
journal, February 2014

Sato, Y.; Hirayama, T.; Ikuhara, Y.
Applied Physics Letters, Vol. 104, Issue 8
DOI: 10.1063/1.4866791

Domain rotation induced strain effect on the magnetic and magneto-electric response in CoFe ₂ O ₄ /Pb(Mg,Nb)O ₃ -PbTiO ₃ heterostructures
journal, February 2012

Wang, Zhiguang; Viswan, Ravindranath; Hu, Bolin
Journal of Applied Physics, Vol. 111, Issue 3
DOI: 10.1063/1.3684546

Relaxor-based ferroelectric single crystals: Growth, domain engineering, characterization and applications
journal, August 2014

Sun, Enwei; Cao, Wenwu
Progress in Materials Science, Vol. 65
DOI: 10.1016/j.pmatsci.2014.03.006

Theory of tetragonal twin structures in ferroelectric perovskites with a first-order phase transition
journal, July 1991

Cao, Wenwu; Cross, L. E.
Physical Review B, Vol. 44, Issue 1
DOI: 10.1103/PhysRevB.44.5

Electric field dependence of piezoelectric properties for rhombohedral 0.955Pb(Zn1/3Nb2/3)O3– 0.045PbTiO3 single crystals
journal, March 1999

Liu, Shi-Fang; Park, Seung-Eek; Shrout, Thomas R.
Journal of Applied Physics, Vol. 85, Issue 5
DOI: 10.1063/1.369599

Thermotropic phase boundaries in classic ferroelectrics
journal, January 2014

Lummen, Tom T. A.; Gu, Yijia; Wang, Jianjun
Nature Communications, Vol. 5, Issue 1
DOI: 10.1038/ncomms4172

Diffuse scattering in relaxor ferroelectrics: true three-dimensional mapping, experimental artefacts and modelling
journal, November 2011

Bosak, A.; Chernyshov, D.; Vakhrushev, Sergey
Acta Crystallographica Section A Foundations of Crystallography, Vol. 68, Issue 1
DOI: 10.1107/S0108767311040281

Works referencing / citing this record:

Phase structure and quasi-single-domain mechanism in Pb(Mg _1/3 Nb _2/3 )O ₃ - x PbTiO ₃ single crystals near morphotropic phase boundary
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journal, March 2018

Hu, Q.; Ushakov, A. D.; Esin, A. A.
Ferroelectrics, Vol. 525, Issue 1
DOI: 10.1080/00150193.2018.1432819

Local twin domains and tip-voltage-induced domain switching of monoclinic $M_{C}$ phase in $Pb (M g_{1 / 3} N b_{2 / 3}) O_{3} - 0.34 PbTi O_{3}$ single crystal revealed by piezoresponse force microscopy
journal, August 2016

Wang, Ruixue; Yang, Bin; Luo, Zhenlin
Physical Review B, Vol. 94, Issue 5
DOI: 10.1103/physrevb.94.054115

Structural and electrical properties of ZnO‐modified (1− x )Pb(Mg _1/3 Nb _2/3 )O ₃ − x PbTiO ₃ ceramics with wide MPB regions
journal, September 2018

Zhang, Ji; Wang, Rui‐Xue; Sun, Lei
Journal of the American Ceramic Society
DOI: 10.1111/jace.16081

Multi‐scale domain structure observation and piezoelectric responses for [001]‐oriented PMN‐33PT single crystal
journal, June 2019

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Journal of the American Ceramic Society, Vol. 102, Issue 12
DOI: 10.1111/jace.16667

Frontiers in strain-engineered multifunctional ferroic materials
journal, August 2016

Agar, Joshua C.; Pandya, Shishir; Xu, Ruijuan
MRS Communications, Vol. 6, Issue 3
DOI: 10.1557/mrc.2016.29

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Title: Phase coexistence and domain configuration in Pb(Mg1/3Nb2/3)O3-0.34PbTiO3 single crystal revealed by synchrotron-based X-ray diffractive three-dimensional reciprocal space mapping and piezoresponse force microscopy

Abstract

Citation Formats

Origin of morphotropic phase boundaries in ferroelectrics journal, January 2008

Monoclinic phases arising across thermal inter-ferroelectric phase transitions journal, July 2014

High performance ferroelectric relaxor-PbTiO 3 single crystals: Status and perspective journal, February 2012

Monoclinic phase in the relaxor-based piezoelectric/ferroelectric P b ( M g 1 / 3 Nb 2 / 3 ) O 3 − P b T i O 3 system journal, October 2001

Reciprocal space mapping journal, June 1997

Composition and phase dependence of the intrinsic and extrinsic piezoelectric activity of domain engineered (1−x)Pb(Mg1/3Nb2/3)O3−xPbTiO3 crystals journal, August 2010

Evidence for M B and M C phases in the morphotropic phase boundary region of ( 1 − x ) [ Pb ( Mg 1 / 3 Nb 2 / 3 ) O 3 ] − x PbTiO 3 : A Rietveld study journal, February 2003

Growth, characterization and properties of relaxor ferroelectric PMN-PT single crystals journal, May 1999

Mesoscale Domains and Nature of the Relaxor State by Piezoresponse Force Microscopy journal, July 2013

Monoclinic structure of unpoled morphotropic high piezoelectric PMN-PT and PZN-PT compounds journal, January 2002

Periodic elastic nanodomains in ultrathin tetragonal-like BiFeO 3 films journal, August 2013

Tetragonal micro/nanotwins in 0.91Pb(Zn1/3Nb2/3)O3−0.09PbTiO3 revealed by reciprocal space mapping journal, May 2009

A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution journal, April 1999

The giant piezoelectric effect: electric field induced monoclinic phase or piezoelectric distortion of the rhombohedral parent? journal, May 2003

Phase coexistence and transformations in field-cooled ternary piezoelectric single crystals near the morphotropic phase boundary journal, December 2014

Elastic, piezoelectric, and dielectric properties of multidomain 0.67Pb(Mg1/3Nb2/3)O3–0.33PbTiO3 single crystals journal, October 2001

Adaptive ferroelectric state at morphotropic phase boundary: Coexisting tetragonal and rhombohedral phases journal, June 2014

High-resolution three-dimensional reciprocal space mapping of semiconductor nanostructures journal, August 2009

Ultrahigh strain and piezoelectric behavior in relaxor based ferroelectric single crystals journal, August 1997

Domain wall orientations in ferroelastics and ferroelectrics journal, December 2004

Direct high-resolution transmission electron microscopy observation of tetragonal nanotwins within the monoclinic MC phase of Pb(Mg1∕3Nb2∕3)O3-0.35PbTiO3 crystals journal, April 2008

Temperature-induced and electric-field-induced phase transitions in rhombohedral Pb ( In 1 / 2 Nb 1 / 2 ) O 3 − Pb ( Mg 1 / 3 Nb 2 / 3 ) O 3 − PbTiO 3 ternary single crystals journal, October 2014

Temperature and electric-field induced phase transitions, and full tensor properties of [ 011 ] C -poled domain-engineered tetragonal 0 . 63 Pb ( M g 1 / 3 N b 2 / 3 ) − 0 . 37 PbTi O 3 single crystals journal, March 2016

Coexistence of MA and MC phases in Pb(Mg1∕3Nb2∕3)0.68Ti0.32O3 single crystals journal, February 2006

Origin of the High Piezoelectric Response in PbZr 1 − x Ti x O 3 journal, June 2000

Hysteretic phase transition sequence in 0.67 Pb ( M g 1 / 3 N b 2 / 3 ) O 3 − 0.33 PbTi O 3 single crystal driven by electric field and temperature journal, May 2015

Formation of monoclinic nanodomains at the morphotropic phase boundary of ferroelectric systems journal, December 2013

In Situ Three-Dimensional Reciprocal-Space Mapping of Diffuse Scattering Intensity Distribution and Data Analysis for Precursor Phenomenon in Shape-Memory Alloy journal, January 2012

Phase diagram of the ferroelectric relaxor ( 1 − x ) PbMg 1 / 3 Nb 2 / 3 O 3 − x PbTiO 3 journal, August 2002

Probing the domain structure of BiFeO 3 epitaxial films with three-dimensional reciprocal space mapping journal, May 2014

Monoclinic and triclinic phases in higher-order Devonshire theory journal, January 2001

Three-dimensional mapping of diffuse scattering in Pb ( Zn 1 ∕ 3 Nb 2 ∕ 3 ) O 3 − x Pb Ti O 3 journal, November 2004

Domain structure in the monoclinic Pm phase of Pb(Mg1/3Nb2/3)O3–PbTiO3 single crystals journal, June 2004

Monoclinic nanodomains in morphotropic phase boundary Pb(Mg 1/3 Nb 2/3 )O 3 –PbTiO 3 journal, February 2014

Domain rotation induced strain effect on the magnetic and magneto-electric response in CoFe 2 O 4 /Pb(Mg,Nb)O 3 -PbTiO 3 heterostructures journal, February 2012

Relaxor-based ferroelectric single crystals: Growth, domain engineering, characterization and applications journal, August 2014

Theory of tetragonal twin structures in ferroelectric perovskites with a first-order phase transition journal, July 1991

Electric field dependence of piezoelectric properties for rhombohedral 0.955Pb(Zn1/3Nb2/3)O3– 0.045PbTiO3 single crystals journal, March 1999

Thermotropic phase boundaries in classic ferroelectrics journal, January 2014

Diffuse scattering in relaxor ferroelectrics: true three-dimensional mapping, experimental artefacts and modelling journal, November 2011

Phase structure and quasi-single-domain mechanism in Pb(Mg 1/3 Nb 2/3 )O 3 - x PbTiO 3 single crystals near morphotropic phase boundary journal, July 2019

Investigation of domain structure evolution during zero-field temperature treatment in 0.67PMN-0.33PT single crystals journal, March 2018

Local twin domains and tip-voltage-induced domain switching of monoclinic M C phase in Pb ( M g 1 / 3 N b 2 / 3 ) O 3 − 0.34 PbTi O 3 single crystal revealed by piezoresponse force microscopy journal, August 2016

Structural and electrical properties of ZnO‐modified (1− x )Pb(Mg 1/3 Nb 2/3 )O 3 − x PbTiO 3 ceramics with wide MPB regions journal, September 2018

Multi‐scale domain structure observation and piezoelectric responses for [001]‐oriented PMN‐33PT single crystal journal, June 2019

Frontiers in strain-engineered multifunctional ferroic materials journal, August 2016

Title: Phase coexistence and domain configuration in Pb(Mg_1/3Nb_2/3)O₃-0.34PbTiO₃ single crystal revealed by synchrotron-based X-ray diffractive three-dimensional reciprocal space mapping and piezoresponse force microscopy

Origin of morphotropic phase boundaries in ferroelectrics
journal, January 2008

Monoclinic phases arising across thermal inter-ferroelectric phase transitions
journal, July 2014

High performance ferroelectric relaxor-PbTiO ₃ single crystals: Status and perspective
journal, February 2012

Monoclinic phase in the relaxor-based piezoelectric/ferroelectric ${P b (M g}_{1 / 3} {Nb}_{2 / 3} {) O}_{3} {- P b T i O}_{3}$ system
journal, October 2001

Reciprocal space mapping
journal, June 1997

Composition and phase dependence of the intrinsic and extrinsic piezoelectric activity of domain engineered (1−x)Pb(Mg1/3Nb2/3)O3−xPbTiO3 crystals
journal, August 2010

Evidence for $M_{B}$ and $M_{C}$ phases in the morphotropic phase boundary region of $(1 - x) [Pb ({Mg}_{1 / 3} {Nb}_{2 / 3}) O_{3}] - x {PbTiO}_{3} :$ A Rietveld study
journal, February 2003

Growth, characterization and properties of relaxor ferroelectric PMN-PT single crystals
journal, May 1999

Mesoscale Domains and Nature of the Relaxor State by Piezoresponse Force Microscopy
journal, July 2013

Monoclinic structure of unpoled morphotropic high piezoelectric PMN-PT and PZN-PT compounds
journal, January 2002

Periodic elastic nanodomains in ultrathin tetragonal-like BiFeO $_{3}$ films
journal, August 2013

Tetragonal micro/nanotwins in 0.91Pb(Zn1/3Nb2/3)O3−0.09PbTiO3 revealed by reciprocal space mapping
journal, May 2009

A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution
journal, April 1999

The giant piezoelectric effect: electric field induced monoclinic phase or piezoelectric distortion of the rhombohedral parent?
journal, May 2003

Phase coexistence and transformations in field-cooled ternary piezoelectric single crystals near the morphotropic phase boundary
journal, December 2014

Elastic, piezoelectric, and dielectric properties of multidomain 0.67Pb(Mg1/3Nb2/3)O3–0.33PbTiO3 single crystals
journal, October 2001

Adaptive ferroelectric state at morphotropic phase boundary: Coexisting tetragonal and rhombohedral phases
journal, June 2014

High-resolution three-dimensional reciprocal space mapping of semiconductor nanostructures
journal, August 2009

Ultrahigh strain and piezoelectric behavior in relaxor based ferroelectric single crystals
journal, August 1997

Domain wall orientations in ferroelastics and ferroelectrics
journal, December 2004

Direct high-resolution transmission electron microscopy observation of tetragonal nanotwins within the monoclinic MC phase of Pb(Mg1∕3Nb2∕3)O3-0.35PbTiO3 crystals
journal, April 2008

Temperature-induced and electric-field-induced phase transitions in rhombohedral ${Pb (In}_{1 / 2} {Nb}_{1 / 2}) O_{3} − {Pb (Mg}_{1 / 3} {Nb}_{2 / 3} {) O}_{3} − {PbTiO}_{3}$ ternary single crystals
journal, October 2014

Temperature and electric-field induced phase transitions, and full tensor properties of ${[011]}_{C}$ -poled domain-engineered tetragonal $0 . 63 Pb (M g_{1 / 3} N b_{2 / 3}) − 0 . 37 PbTi O_{3}$ single crystals
journal, March 2016

Coexistence of MA and MC phases in Pb(Mg1∕3Nb2∕3)0.68Ti0.32O3 single crystals
journal, February 2006

Origin of the High Piezoelectric Response in ${PbZr}_{1 - x} {Ti}_{x} O_{3}$
journal, June 2000

Hysteretic phase transition sequence in $0.67 Pb (M g_{1 / 3} N b_{2 / 3}) O_{3} - 0.33 PbTi O_{3}$ single crystal driven by electric field and temperature
journal, May 2015

Formation of monoclinic nanodomains at the morphotropic phase boundary of ferroelectric systems
journal, December 2013

In Situ Three-Dimensional Reciprocal-Space Mapping of Diffuse Scattering Intensity Distribution and Data Analysis for Precursor Phenomenon in Shape-Memory Alloy
journal, January 2012

Phase diagram of the ferroelectric relaxor $(1 - x) {PbMg}_{1 / 3} {Nb}_{2 / 3} O_{3} - x {PbTiO}_{3}$
journal, August 2002

Probing the domain structure of BiFeO ₃ epitaxial films with three-dimensional reciprocal space mapping
journal, May 2014

Monoclinic and triclinic phases in higher-order Devonshire theory
journal, January 2001

Three-dimensional mapping of diffuse scattering in $Pb ({Zn}_{1 ∕ 3} {Nb}_{2 ∕ 3}) O_{3} − x Pb Ti O_{3}$
journal, November 2004

Domain structure in the monoclinic Pm phase of Pb(Mg1/3Nb2/3)O3–PbTiO3 single crystals
journal, June 2004

Monoclinic nanodomains in morphotropic phase boundary Pb(Mg _1/3 Nb _2/3 )O ₃ –PbTiO ₃
journal, February 2014

Domain rotation induced strain effect on the magnetic and magneto-electric response in CoFe ₂ O ₄ /Pb(Mg,Nb)O ₃ -PbTiO ₃ heterostructures
journal, February 2012

Relaxor-based ferroelectric single crystals: Growth, domain engineering, characterization and applications
journal, August 2014

Theory of tetragonal twin structures in ferroelectric perovskites with a first-order phase transition
journal, July 1991

Electric field dependence of piezoelectric properties for rhombohedral 0.955Pb(Zn1/3Nb2/3)O3– 0.045PbTiO3 single crystals
journal, March 1999

Thermotropic phase boundaries in classic ferroelectrics
journal, January 2014

Diffuse scattering in relaxor ferroelectrics: true three-dimensional mapping, experimental artefacts and modelling
journal, November 2011

Phase structure and quasi-single-domain mechanism in Pb(Mg _1/3 Nb _2/3 )O ₃ - x PbTiO ₃ single crystals near morphotropic phase boundary
journal, July 2019

Investigation of domain structure evolution during zero-field temperature treatment in 0.67PMN-0.33PT single crystals
journal, March 2018

Local twin domains and tip-voltage-induced domain switching of monoclinic $M_{C}$ phase in $Pb (M g_{1 / 3} N b_{2 / 3}) O_{3} - 0.34 PbTi O_{3}$ single crystal revealed by piezoresponse force microscopy
journal, August 2016

Structural and electrical properties of ZnO‐modified (1− x )Pb(Mg _1/3 Nb _2/3 )O ₃ − x PbTiO ₃ ceramics with wide MPB regions
journal, September 2018

Multi‐scale domain structure observation and piezoelectric responses for [001]‐oriented PMN‐33PT single crystal
journal, June 2019

Frontiers in strain-engineered multifunctional ferroic materials
journal, August 2016