Experimental calibration of silicon and oxygen isotope fractionations between quartz and water at 250°C by in situ microanalysis of experimental products and application to zoned low δ30Si quartz overgrowths
Abstract
The interpretation of silicon isotope data for quartz is hampered by the lack of experimentally determined fractionation factors between quartz and fluid. Further, there is a large spread in published oxygen isotope fractionation factors at low temperatures, primarily due to extrapolation from experimental calibrations at high temperature. We report the first measurements of silicon isotope ratios from experimentally precipitated quartz and estimate the equilibrium fractionation vs. dissolved silica using a novel in situ analysis technique applying secondary ion mass spectrometry to directly analyze experimental products. These experiments also yield a new value for oxygen isotope fractionation. Quartz overgrowths up to 235 μm thick were precipitated in silica–H2O–NaOH–NaCl fluids, at pH 12–13 and 250 °C. At this temperature, 1000lnα30Si(Qtz–fluid) = 0.55 ± 0.10‰ and 1000lnα18O(Qtz–fluid) = 10.62 ± 0.13‰, yielding the relations 1000lnα30Si(Qtz–fluid) = (0.15 ± 0.03) * 106/T2 and 1000lnα18O(Qtz–fluid) = (2.91 ± 0.04) * 106/T2 when extended to zero fractionation at infinite temperature. Values of δ30Si(Qtz) from diagenetic cement in sandstones from the basal Cambrian Mt. Simon Formation in central North America range from 0 to ₋5.4‰. Paired δ18O and δ30Si values from individual overgrowths preserve a record of Precambrian weathering and fluid transport. In conclusion, the application ofmore »
- Authors:
-
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of Wisconsin, Madison, WI (United States)
- Univ. of Wisconsin, Madison, WI (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Trent Univ., Peterborough, ON (Canada)
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1255066
- Alternate Identifier(s):
- OSTI ID: 1286769; OSTI ID: 1398564
- Report Number(s):
- LA-UR-15-24608
Journal ID: ISSN 0009-2541; PII: S0009254115301005
- Grant/Contract Number:
- AC52-06NA25396; 93ER14389; EAR-1053466; 1355590; AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemical Geology
- Additional Journal Information:
- Journal Volume: 421; Journal Issue: C; Journal ID: ISSN 0009-2541
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 58 GEOSCIENCES; isotope fractionation; SIMS; experimental calibration; Precambrian weathering; d³⁰Si, d¹⁸O; δ30Si; δ18O
Citation Formats
Pollington, Anthony D., Kozdon, Reinhard, Anovitz, Lawrence M., Georg, R. Bastian, Spicuzza, Michael J., and Valley, John W. Experimental calibration of silicon and oxygen isotope fractionations between quartz and water at 250°C by in situ microanalysis of experimental products and application to zoned low δ30Si quartz overgrowths. United States: N. p., 2015.
Web. doi:10.1016/j.chemgeo.2015.11.011.
Pollington, Anthony D., Kozdon, Reinhard, Anovitz, Lawrence M., Georg, R. Bastian, Spicuzza, Michael J., & Valley, John W. Experimental calibration of silicon and oxygen isotope fractionations between quartz and water at 250°C by in situ microanalysis of experimental products and application to zoned low δ30Si quartz overgrowths. United States. https://doi.org/10.1016/j.chemgeo.2015.11.011
Pollington, Anthony D., Kozdon, Reinhard, Anovitz, Lawrence M., Georg, R. Bastian, Spicuzza, Michael J., and Valley, John W. Tue .
"Experimental calibration of silicon and oxygen isotope fractionations between quartz and water at 250°C by in situ microanalysis of experimental products and application to zoned low δ30Si quartz overgrowths". United States. https://doi.org/10.1016/j.chemgeo.2015.11.011. https://www.osti.gov/servlets/purl/1255066.
@article{osti_1255066,
title = {Experimental calibration of silicon and oxygen isotope fractionations between quartz and water at 250°C by in situ microanalysis of experimental products and application to zoned low δ30Si quartz overgrowths},
author = {Pollington, Anthony D. and Kozdon, Reinhard and Anovitz, Lawrence M. and Georg, R. Bastian and Spicuzza, Michael J. and Valley, John W.},
abstractNote = {The interpretation of silicon isotope data for quartz is hampered by the lack of experimentally determined fractionation factors between quartz and fluid. Further, there is a large spread in published oxygen isotope fractionation factors at low temperatures, primarily due to extrapolation from experimental calibrations at high temperature. We report the first measurements of silicon isotope ratios from experimentally precipitated quartz and estimate the equilibrium fractionation vs. dissolved silica using a novel in situ analysis technique applying secondary ion mass spectrometry to directly analyze experimental products. These experiments also yield a new value for oxygen isotope fractionation. Quartz overgrowths up to 235 μm thick were precipitated in silica–H2O–NaOH–NaCl fluids, at pH 12–13 and 250 °C. At this temperature, 1000lnα30Si(Qtz–fluid) = 0.55 ± 0.10‰ and 1000lnα18O(Qtz–fluid) = 10.62 ± 0.13‰, yielding the relations 1000lnα30Si(Qtz–fluid) = (0.15 ± 0.03) * 106/T2 and 1000lnα18O(Qtz–fluid) = (2.91 ± 0.04) * 106/T2 when extended to zero fractionation at infinite temperature. Values of δ30Si(Qtz) from diagenetic cement in sandstones from the basal Cambrian Mt. Simon Formation in central North America range from 0 to ₋5.4‰. Paired δ18O and δ30Si values from individual overgrowths preserve a record of Precambrian weathering and fluid transport. In conclusion, the application of the experimental quartz growth results to observations from natural sandstone samples suggests that precipitation of quartz at low temperatures in nature is dominated by kinetic, rather than equilibrium, processes.},
doi = {10.1016/j.chemgeo.2015.11.011},
journal = {Chemical Geology},
number = C,
volume = 421,
place = {United States},
year = {Tue Dec 01 00:00:00 EST 2015},
month = {Tue Dec 01 00:00:00 EST 2015}
}
Web of Science
Works referenced in this record:
δ 30 Si and δ 29 Si Determinations on USGS BHVO-1 and BHVO-2 Reference Materials with a New Configuration on a Nu Plasma Multi-Collector ICP-MS
journal, June 2008
- Abraham, Kathrin; Opfergelt, Sophie; Fripiat, François
- Geostandards and Geoanalytical Research, Vol. 32, Issue 2
Isothermal Time-Series Determination of the Rate of Diffusion of Water in Pachuca Obsidian*
journal, May 2004
- Anovitz, L. M.; Elam, J. M.; Riciputi, L. R.
- Archaeometry, Vol. 46, Issue 2
High precision measurements of17O/16O and18O/16O ratios in H2O
journal, January 2005
- Barkan, Eugeni; Luz, Boaz
- Rapid Communications in Mass Spectrometry, Vol. 19, Issue 24
Si stable isotopes in the Earth's surface: A review
journal, January 2006
- Basile-Doelsch, Isabelle
- Journal of Geochemical Exploration, Vol. 88, Issue 1-3
Another continental pool in the terrestrial silicon cycle
journal, January 2005
- Basile-Doelsch, Isabelle; Meunier, Jean Dominique; Parron, Claude
- Nature, Vol. 433, Issue 7024
Comments on oxygen isotope geothermometry
journal, October 1973
- Bottinga, Y.; Javoy, M.
- Earth and Planetary Science Letters, Vol. 20, Issue 2
Depositional and diagenetic variability within the Cambrian Mount Simon Sandstone: Implications for carbon dioxide sequestration
journal, June 2011
- Bowen, Brenda B.; Ochoa, Raul I.; Wilkens, Nathan D.
- Environmental Geosciences, Vol. 18, Issue 2
Coupling of surface temperatures and atmospheric CO2 concentrations during the Palaeozoic era
journal, September 2007
- Came, Rosemarie E.; Eiler, John M.; Veizer, Ján
- Nature, Vol. 449, Issue 7159
Regional fluid migration in the Illinois basin: Evidence from in situ oxygen isotope analysis of authigenic K-feldspar and quartz from the Mount Simon Sandstone
journal, January 2001
- Chen, Zhensheng; Riciputi, Lee R.; Mora, Claudia I.
- Geology, Vol. 29, Issue 12
Oxygen isotope exchange between quartz and water
journal, June 1972
- Clayton, Robert N.; O'Neil, James R.; Mayeda, Toshiko K.
- Journal of Geophysical Research, Vol. 77, Issue 17
Oxygen isotope fractionation in quartz, albite, anorthite and calcite
journal, March 1989
- Clayton, Robert N.; Goldsmith, Julian R.; Mayeda, Toshiko K.
- Geochimica et Cosmochimica Acta, Vol. 53, Issue 3
Isotopic standards for carbon and oxygen and correction factors for mass-spectrometric analysis of carbon dioxide
journal, January 1957
- Craig, Harmon
- Geochimica et Cosmochimica Acta, Vol. 12, Issue 1-2
Silicon isotope fractionation by marine sponges and the reconstruction of the silicon isotope composition of ancient deep water
journal, January 2003
- De La Rocha, Christina L.
- Geology, Vol. 31, Issue 5
Fractionation of silicon isotopes by marine diatoms during biogenic silica formation
journal, December 1997
- de la Rocha, Christina L.; Brzezinski, Mark A.; DeNiro, Michael J.
- Geochimica et Cosmochimica Acta, Vol. 61, Issue 23
Silicon isotopic fractionation during adsorption of aqueous monosilicic acid onto iron oxide
journal, February 2009
- Delstanche, S.; Opfergelt, S.; Cardinal, D.
- Geochimica et Cosmochimica Acta, Vol. 73, Issue 4
Silicon isotope compositions of dissolved silicon and suspended matter in the Yangtze River, China
journal, January 2004
- Ding, T.; Wan, D.; Wang, C.
- Geochimica et Cosmochimica Acta, Vol. 68, Issue 2
The geochemistry of the stable isotopes of silicon
journal, August 1982
- Douthitt, C. B.
- Geochimica et Cosmochimica Acta, Vol. 46, Issue 8
The dissolution kinetics of quartz in sodium chloride solutions at 25 degrees to 300 degrees C
journal, June 1994
- Dove, P. M.
- American Journal of Science, Vol. 294, Issue 6
Evidence for Biological and Hydrological Controls on the Development of a Paleoproterozoic Paleoweathering Profile in the Baraboo Range, Wisconsin, U.S.A.
journal, July 2008
- Driese, S. G.; Medaris, L. G.
- Journal of Sedimentary Research, Vol. 78, Issue 7
Differentiating Pedogenesis from Diagenesis in Early Terrestrial Paleoweathering Surfaces Formed on Granitic Composition Parent Materials
journal, July 2007
- Driese, Steven G.; Medaris Jr., L. Gordon; Ren, Minghua
- The Journal of Geology, Vol. 115, Issue 4
Fractionation of silicon isotopes in liquids: The importance of configurational disorder
journal, March 2015
- Dupuis, Romain; Benoit, Magali; Nardin, Elise
- Chemical Geology, Vol. 396
Variation of O18 content of waters from natural sources
journal, November 1953
- Epstein, S.; Mayeda, T.
- Geochimica et Cosmochimica Acta, Vol. 4, Issue 5
Silicon isotope fractionation during abiotic silica precipitation at low temperatures: Inferences from flow-through experiments
journal, October 2014
- Geilert, Sonja; Vroon, Pieter Z.; Roerdink, Desiree L.
- Geochimica et Cosmochimica Acta, Vol. 142
New sample preparation techniques for the determination of Si isotopic compositions using MC-ICPMS
journal, November 2006
- Georg, R. B.; Reynolds, B. C.; Frank, M.
- Chemical Geology, Vol. 235, Issue 1-2
Silicon isotope variations accompanying basalt weathering in Iceland
journal, September 2007
- Georg, R. B.; Reynolds, B. C.; West, A. J.
- Earth and Planetary Science Letters, Vol. 261, Issue 3-4
Stable silicon isotopes of groundwater, feldspars, and clay coatings in the Navajo Sandstone aquifer, Black Mesa, Arizona, USA
journal, April 2009
- Georg, R. B.; Zhu, C.; Reynolds, B. C.
- Geochimica et Cosmochimica Acta, Vol. 73, Issue 8
Secondary K-feldspar at the Precambrian–Paleozoic unconformity, southwestern Ontario
journal, September 1995
- Harper, David A.; Longstaffe, Fred J.; Wadleigh, Moire A.
- Canadian Journal of Earth Sciences, Vol. 32, Issue 9
SIMS analyses of silicon and oxygen isotope ratios for quartz from Archean and Paleoproterozoic banded iron formations
journal, October 2011
- Heck, Philipp R.; Huberty, Jason M.; Kita, Noriko T.
- Geochimica et Cosmochimica Acta, Vol. 75, Issue 20
The activity-composition relationship of oxygen and hydrogen isotopes in aqueous salt solutions: II. Vapor-liquid water equilibration of mixed salt solutions from 50 to 100°C and geochemical implications
journal, October 1993
- Horita, Juske; Cole, David R.; Wesolowski, David J.
- Geochimica et Cosmochimica Acta, Vol. 57, Issue 19
The activity-composition relationship of oxygen and hydrogen isotopes in aqueous salt solutions: I. Vapor-liquid water equilibration of single salt solutions from 50 to 100°C
journal, June 1993
- Horita, Juske; Wesolowski, David J.; Cole, David R.
- Geochimica et Cosmochimica Acta, Vol. 57, Issue 12
The activity-composition relationship of oxygen and hydrogen isotopes in aqueous salt solutions: III. Vapor-liquid water equilibration of NaCl solutions to 350°C
journal, March 1995
- Horita, Juske; Cole, David R.; Wesolowski, David J.
- Geochimica et Cosmochimica Acta, Vol. 59, Issue 6
Oxygen isotope salt effects at high pressure and high temperature and the calibration of oxygen isotope geothermometers
journal, September 2003
- Hu, Guixing; Clayton, Robert N.
- Geochimica et Cosmochimica Acta, Vol. 67, Issue 17
Evolution of quartz cementation and burial history of the Eau Claire Formation based on in situ oxygen isotope analysis of quartz overgrowths
journal, September 2014
- Hyodo, Ayumi; Kozdon, Reinhard; Pollington, Anthony D.
- Chemical Geology, Vol. 384
Determination of δ17O values of reference water samples VSMOW and SLAP
journal, November 1997
- Jabeen, Iffat; Kusakabe, Minoru
- Chemical Geology, Vol. 143, Issue 1-2
The oxygen isotope evolution of seawater: A critical review of a long-standing controversy and an improved geological water cycle model for the past 3.4 billion years
journal, July 2007
- Jaffrés, Jasmine B. D.; Shields, Graham A.; Wallmann, Klaus
- Earth-Science Reviews, Vol. 83, Issue 1-2
Calculation of oxygen isotope fractionation in quartz-water system with special reference to the low temperature fractionation
journal, June 1978
- Kawabe, Iwao
- Geochimica et Cosmochimica Acta, Vol. 42, Issue 6
Optically continuous silcrete quartz cements of the St. Peter Sandstone: High precision oxygen isotope analysis by ion microprobe
journal, August 2007
- Kelly, Jacque L.; Fu, Bin; Kita, Noriko T.
- Geochimica et Cosmochimica Acta, Vol. 71, Issue 15
High precision SIMS oxygen isotope analysis and the effect of sample topography
journal, June 2009
- Kita, Noriko T.; Ushikubo, Takayuki; Fu, Bin
- Chemical Geology, Vol. 264, Issue 1-4
Oxygen three-isotope ratios of silicate reference materials determined by direct comparison with VSMOW-oxygen
journal, January 2008
- Kusakabe, Minoru; Matsuhisa, Yukihiro
- GEOCHEMICAL JOURNAL, Vol. 42, Issue 4
Toward more accurate quartz cement models: The importance of euhedral versus noneuhedral growth rates
journal, November 2008
- Lander, Robert H.; Larese, Richard E.; Bonnell, Linda M.
- AAPG Bulletin, Vol. 92, Issue 11
Litho-facies and reservoir characterization of the Mt Simon Sandstone at the Illinois Basin - Decatur Project: Litho-facies and reservoir characterization of the Mt Simon Sandstone at the Illinois Basin
journal, September 2014
- Leetaru, Hannes E.; Freiburg, Jared T.
- Greenhouse Gases: Science and Technology, Vol. 4, Issue 5
Experimental study of silicon isotope dynamic fractionation and its application in geology
journal, July 1995
- Yanhe, Li; Tiping, Ding; Defang, Wan
- Chinese Journal of Geochemistry, Vol. 14, Issue 3
Quartz: Synthesis at Earth-Surface Conditions
journal, August 1971
- Mackenzie, F. T.; Gees, R.
- Science, Vol. 173, Issue 3996
Mechanisms of hydrothermal crystallization of quartz at 250°C and 15 kbar
journal, February 1978
- Matsuhisa, Yukihiro; Goldsmith, Julian R.; Clayton, Robert N.
- Geochimica et Cosmochimica Acta, Vol. 42, Issue 2
Oxygen isotopic fractionation in the system quartz-albite-anorthite-water
journal, July 1979
- Matsuhisa, Yukihiro; Goldsmith, Julian R.; Clayton, Robert N.
- Geochimica et Cosmochimica Acta, Vol. 43, Issue 7
Silicon isotope fractionation in silicate minerals: Insights from first-principles models of phyllosilicates, albite and pyrope
journal, June 2014
- Méheut, Merlin; Schauble, Edwin A.
- Geochimica et Cosmochimica Acta, Vol. 134
Si stable isotope fractionation during adsorption and the competition between kinetic and equilibrium isotope fractionation: Implications for weathering systems
journal, July 2014
- Oelze, Marcus; von Blanckenburg, Friedhelm; Hoellen, Daniel
- Chemical Geology, Vol. 380
A method for oxygen isotope analysis of milligram quantities of water and some of its applications
journal, October 1966
- O'Neil, James R.; Epstein, Samuel
- Journal of Geophysical Research, Vol. 71, Issue 20
New sample holder geometry for high precision isotope analyses: New sample holder geometry for high precision isotope analyses
journal, June 2012
- Peres, P.; Kita, N. T.; Valley, J. W.
- Surface and Interface Analysis, Vol. 45, Issue 1
Evolution of quartz cementation during burial of the Cambrian Mount Simon Sandstone, Illinois Basin: In situ microanalysis of δ18O
journal, December 2011
- Pollington, Anthony D.; Kozdon, Reinhard; Valley, John W.
- Geology, Vol. 39, Issue 12
Experimental constraints on kinetic and equilibrium silicon isotope fractionation during the formation of non-biogenic chert deposits
journal, May 2015
- Roerdink, Desiree L.; van den Boorn, Sander H. J. M.; Geilert, Sonja
- Chemical Geology, Vol. 402
Quartz-calcite oxygen isotope thermometry: A calibration based on natural isotopic variations
journal, October 1994
- Sharp, Z. D.; Kirschner, D. L.
- Geochimica et Cosmochimica Acta, Vol. 58, Issue 20
Calculation of the Reduced Partition Function Ratios of α-, β-Quartzs and Calcite
journal, August 1972
- Shiro, Yuji; Sakai, Hitoshi
- Bulletin of the Chemical Society of Japan, Vol. 45, Issue 8
The rapid heating, defocused beam technique: a CO2-laser-based method for highly precise and accurate determination of δ18O values of quartz
journal, February 1998
- Spicuzza, M. J.; Valley, J. W.; Kohn, M. J.
- Chemical Geology, Vol. 144, Issue 3-4
The thermodynamic properties of isotopic substances
journal, January 1947
- Urey, Harold C.
- Journal of the Chemical Society (Resumed)
UWG-2, a garnet standard for oxygen isotope ratios: Strategies for high precision and accuracy with laser heating
journal, December 1995
- Valley, John W.; Kitchen, Nami; Kohn, Matthew J.
- Geochimica et Cosmochimica Acta, Vol. 59, Issue 24
Precipitation rates for quartz cement in sandstones determined by fluid-inclusion microthermometry and temperature-history modeling
journal, April 1994
- Walderhaug, O.
- Journal of Sedimentary Research, Vol. 64, Issue 2a
Influence of radiation damage on Late Jurassic zircon from southern China: Evidence from in situ measurements of oxygen isotopes, laser Raman, U–Pb ages, and trace elements
journal, December 2014
- Wang, Xiao-Lei; Coble, Matthew A.; Valley, John W.
- Chemical Geology, Vol. 389
Precise Determination of Silicon Isotopes in Silicate Rock Reference Materials by MC-ICP-MS
journal, September 2010
- Zambardi, Thomas; Poitrasson, Franck
- Geostandards and Geoanalytical Research, Vol. 35, Issue 1
Calculation of oxygen isotope fractionation in anhydrous silicate minerals
journal, March 1993
- Yong-Fei, Zheng
- Geochimica et Cosmochimica Acta, Vol. 57, Issue 5
Clay mineral authigenesis along a mid-continental scale fluid conduit in Palaeozoic sedimentary rocks from southern Ontario, Canada
journal, March 2000
- Ziegler, K.; Longstaffe, F. J.
- Clay Minerals, Vol. 35, Issue 1
Natural variations of δ30Si ratios during progressive basalt weathering, Hawaiian Islands
journal, October 2005
- Ziegler, Karen; Chadwick, Oliver A.; Brzezinski, Mark A.
- Geochimica et Cosmochimica Acta, Vol. 69, Issue 19
δ30Si systematics in a granitic saprolite, Puerto Rico
journal, January 2005
- Ziegler, Karen; Chadwick, Oliver A.; White, Art F.
- Geology, Vol. 33, Issue 10
Works referencing / citing this record:
Origin and significance of Si and O isotope heterogeneities in Phanerozoic, Archean, and Hadean zircon
journal, September 2018
- Trail, Dustin; Boehnke, Patrick; Savage, Paul S.
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 41
Silicon isotope composition of subduction zone fluids as recorded by jadeitites from Myanmar
journal, November 2019
- Chen, An-Xia; Li, Yuan-Hong; Chen, Yi
- Contributions to Mineralogy and Petrology, Vol. 175, Issue 1
Predicting instrumental mass fractionation (IMF) of stable isotope SIMS analyses by response surface methodology (RSM)
journal, January 2017
- Fàbrega, C.; Parcerisa, D.; Rossell, J. M.
- Journal of Analytical Atomic Spectrometry, Vol. 32, Issue 4
Pulsed magmatic fluid release for the formation of porphyry deposits: Tracing fluid evolution in absolute time from the Tibetan Qulong Cu-Mo deposit
journal, October 2017
- Li, Yang; Li, Xian-Hua; Selby, David
- Geology, Vol. 46, Issue 1
Silicon Isotope Geochemistry: Fractionation Linked to Silicon Complexations and Its Geological Applications
journal, April 2019
- Wang,
- Molecules, Vol. 24, Issue 7