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Title: Rapid method to determine 89Sr/ 90Sr in large concrete samples

Here, a new rapid method has been developed that provides high quality low-level measurements of 89,90Sr in concrete samples with an MDA (Minimum Detectable Activity) of <1 mBq g -1. The new method is fast, meets new decommissioning regulatory limits and is robust even if refractory particles are present. The method utilizes a rapid fusion to ensure total dissolution of samples and rapid preconcentration and separation of 89,90Sr from 5-10 g concrete samples. When, the 89Sr/ 90Sr ratio is high, Sr can be isolated from up to 5g concrete samples, total 89/90Sr measured, and then 90Sr determined via 90Y separated after a period of ingrowth. Another approach allows the immediate determination of 90Sr in 10 g concrete aliquots without waiting for 90Y ingrowth, in instances where the shorter lived 89Sr is unlikely to be encountered.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ;  [2] ;  [3]
  1. Savannah River Nuclear Solutions, LLC, Aiken, SC (United States)
  2. Univ. of Nevada, Las Vegas, NV (United States)
  3. PG Research Foundation, Inc., Lisle, IL (United States)
Publication Date:
Report Number(s):
SRNS-STI-2016-00187
Journal ID: ISSN 0236-5731; PII: 4787
Grant/Contract Number:
AC09-08SR22470
Type:
Accepted Manuscript
Journal Name:
Journal of Radioanalytical and Nuclear Chemistry
Additional Journal Information:
Journal Name: Journal of Radioanalytical and Nuclear Chemistry; Journal ID: ISSN 0236-5731
Publisher:
Springer
Research Org:
Savannah River Site (SRS), Aiken, SC (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; rapid method; fusion; strontium; concrete; yttrium-90
OSTI Identifier:
1254435

Maxwell, Sherrod L., Culligan, Brian, Hutchison, Jay B., Utsey, Robin C., Sudowe, Ralf, and McAlister, Daniel R.. Rapid method to determine 89Sr/90Sr in large concrete samples. United States: N. p., Web. doi:10.1007/s10967-016-4787-4.
Maxwell, Sherrod L., Culligan, Brian, Hutchison, Jay B., Utsey, Robin C., Sudowe, Ralf, & McAlister, Daniel R.. Rapid method to determine 89Sr/90Sr in large concrete samples. United States. doi:10.1007/s10967-016-4787-4.
Maxwell, Sherrod L., Culligan, Brian, Hutchison, Jay B., Utsey, Robin C., Sudowe, Ralf, and McAlister, Daniel R.. 2016. "Rapid method to determine 89Sr/90Sr in large concrete samples". United States. doi:10.1007/s10967-016-4787-4. https://www.osti.gov/servlets/purl/1254435.
@article{osti_1254435,
title = {Rapid method to determine 89Sr/90Sr in large concrete samples},
author = {Maxwell, Sherrod L. and Culligan, Brian and Hutchison, Jay B. and Utsey, Robin C. and Sudowe, Ralf and McAlister, Daniel R.},
abstractNote = {Here, a new rapid method has been developed that provides high quality low-level measurements of 89,90Sr in concrete samples with an MDA (Minimum Detectable Activity) of <1 mBq g-1. The new method is fast, meets new decommissioning regulatory limits and is robust even if refractory particles are present. The method utilizes a rapid fusion to ensure total dissolution of samples and rapid preconcentration and separation of 89,90Sr from 5-10 g concrete samples. When, the 89Sr/90Sr ratio is high, Sr can be isolated from up to 5g concrete samples, total 89/90Sr measured, and then 90Sr determined via 90Y separated after a period of ingrowth. Another approach allows the immediate determination of 90Sr in 10 g concrete aliquots without waiting for 90Y ingrowth, in instances where the shorter lived 89Sr is unlikely to be encountered.},
doi = {10.1007/s10967-016-4787-4},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {3}
}