X-ray Absorption Spectroscopy Characterization of a Li/S Cell

Ye, Yifan; Kawase, Ayako; Song, Min-Kyu; Feng, Bingmei; Liu, Yi-Sheng; Marcus, Matthew A.; Feng, Jun; Cairns, Elton J.; Guo, Jinghua; Zhu, Junfa

doi:10.3390/nano6010014

Title: X-ray Absorption Spectroscopy Characterization of a Li/S Cell

Journal Article · 11 January 2016 · Nanomaterials

DOI: https://doi.org/10.3390/nano6010014 · OSTI ID:1254009

Ye, Yifan ^[1]; Kawase, Ayako ^[2]; Song, Min-Kyu ^[3]; Feng, Bingmei ^[4]; Liu, Yi-Sheng ^[5]; Marcus, Matthew A. ^[5]; Feng, Jun ^[5]; Cairns, Elton J. ^[2]; Guo, Jinghua ^[6]; Zhu, Junfa ^[7]

Univ. of Science and Technology of China, Hefei (China); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Environmental Energy Technologies Division; Univ. of California, Berkeley, CA (United States)
Washington State Univ., Pullman, WA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS); Harbin Inst. of Technology (China)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS); Univ. of California, Santa Cruz, CA (United States)
Univ. of Science and Technology of China, Hefei (China)

The X-ray absorption spectroscopy technique has been applied to study different stages of the lithium/sulfur (Li/S) cell life cycle. We investigated how speciation of S in Li/S cathodes changes upon the introduction of CTAB (cetyltrimethylammonium bromide, CH₃(CH₂)₁₅N+(CH₃)₃Br₋) and with charge/discharge cycling. The introduction of CTAB changes the synthesis reaction pathway dramatically due to the interaction of CTAB with the terminal S atoms of the polysulfide ions in the Na₂S_x solution. For the cycled Li/S cell, the loss of electrochemically active sulfur and the accumulation of a compact blocking insulating layer of unexpected sulfur reaction products on the cathode surface during the charge/discharge processes make the capacity decay. Lastly, a modified coin cell and a vacuum-compatible three-electrode electro-chemical cell have been introduced for further in-situ/in-operando studies.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231; 2013CB834605; U1232102; 21173200; 21473178; (2015SRG-HSC031; 2015HSC-UP022

OSTI ID:: 1254009

Alternate ID(s):: OSTI ID: 1379029

Journal Information:: Nanomaterials, Vol. 6, Issue 1; ISSN 2079-4991

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 30 works

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References (55)

Solution-Based Processing of Graphene-Li ₂ S Composite Cathodes for Lithium-Ion and Lithium-Sulfur Batteries Wu, Feixiang; Lee, Jung Tae; Magasinski, Alexandre Particle & Particle Systems Characterization, Vol. 31, Issue 6 https://doi.org/10.1002/ppsc.201300358	journal	February 2014
Investigation of surface effects through the application of the functional binders in lithium sulfur batteries Ai, Guo; Dai, Yiling; Ye, Yifan Nano Energy, Vol. 16 https://doi.org/10.1016/j.nanoen.2015.05.036	journal	September 2015
Mg deposition observed by in situ electrochemical Mg K-edge X-ray absorption spectroscopy Arthur, Timothy S.; Glans, Per-Anders; Matsui, Masaki Electrochemistry Communications, Vol. 24 https://doi.org/10.1016/j.elecom.2012.08.018	journal	October 2012
Copper-Stabilized Sulfur-Microporous Carbon Cathodes for Li-S Batteries Zheng, Shiyou; Yi, Feng; Li, Zhipeng Advanced Functional Materials, Vol. 24, Issue 26 https://doi.org/10.1002/adfm.201304156	journal	March 2014
Understanding the Nature of Absorption/Adsorption in Nanoporous Polysulfide Sorbents for the Li–S Battery Evers, Scott; Yim, Taeeun; Nazar, Linda F. The Journal of Physical Chemistry C, Vol. 116, Issue 37 https://doi.org/10.1021/jp304380j	journal	September 2012
Graphene Oxide as a Sulfur Immobilizer in High Performance Lithium/Sulfur Cells Ji, Liwen; Rao, Mumin; Zheng, Haimei Journal of the American Chemical Society, Vol. 133, Issue 46, p. 18522-18525 https://doi.org/10.1021/ja206955k	journal	November 2011
A Review on the Structural Studies of Batteries and Host Materials by X-Ray Absorption Spectroscopy Giorgetti, Marco ISRN Materials Science, Vol. 2013 https://doi.org/10.1155/2013/938625	journal	January 2013
Sulfur Speciation in Li–S Batteries Determined by Operando X-ray Absorption Spectroscopy Cuisinier, Marine; Cabelguen, Pierre-Etienne; Evers, Scott The Journal of Physical Chemistry Letters, Vol. 4, Issue 19 https://doi.org/10.1021/jz401763d	journal	September 2013
Progress and prospective of solid-state lithium batteries Takada, Kazunori Acta Materialia, Vol. 61, Issue 3, p. 759-770 https://doi.org/10.1016/j.actamat.2012.10.034	journal	February 2013
A Long-Life, High-Rate Lithium/Sulfur Cell: A Multifaceted Approach to Enhancing Cell Performance Song, Min-Kyu; Zhang, Yuegang; Cairns, Elton J. Nano Letters, Vol. 13, Issue 12 https://doi.org/10.1021/nl402793z	journal	November 2013
High-Rate, Ultralong Cycle-Life Lithium/Sulfur Batteries Enabled by Nitrogen-Doped Graphene Qiu, Yongcai; Li, Wanfei; Zhao, Wen Nano Letters, Vol. 14, Issue 8 https://doi.org/10.1021/nl5020475	journal	July 2014
Challenges and Prospects of Lithium–Sulfur Batteries Manthiram, Arumugam; Fu, Yongzhu; Su, Yu-Sheng Accounts of Chemical Research, Vol. 46, Issue 5 https://doi.org/10.1021/ar300179v	journal	June 2012
Using X-ray absorption to probe sulfur oxidation states in complex molecules Vairavamurthy, A. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 54, Issue 12 https://doi.org/10.1016/S1386-1425(98)00153-X	journal	October 1998
Understanding the degradation mechanism of rechargeable lithium/sulfur cells: a comprehensive study of the sulfur–graphene oxide cathode after discharge–charge cycling Feng, Xuefei; Song, Min-Kyu; Stolte, Wayne C. Phys. Chem. Chem. Phys., Vol. 16, Issue 32 https://doi.org/10.1039/C4CP01341G	journal	January 2014
Advances in Li–S batteries Ji, Xiulei; Nazar, Linda F. Journal of Materials Chemistry, Vol. 20, Issue 44, p. 9821-9826 https://doi.org/10.1039/b925751a	journal	January 2010
Diamond xenolith and matrix organic matter in the Sutter's Mill meteorite measured by C-XANES Kebukawa, Yoko; Zolensky, Michael E.; Kilcoyne, A. L. David Meteoritics & Planetary Science, Vol. 49, Issue 11 https://doi.org/10.1111/maps.12312	journal	October 2014
Porous Hollow Carbon@Sulfur Composites for High-Power Lithium-Sulfur Batteries Jayaprakash, N.; Shen, J.; Moganty, Surya S. Angewandte Chemie International Edition, Vol. 50, Issue 26, p. 5904-5908 https://doi.org/10.1002/anie.201100637	journal	May 2011
Electronic structure and chemical bonding of a graphene oxide–sulfur nanocomposite for use in superior performance lithium–sulfur cells Zhang, Liang; Ji, Liwen; Glans, Per-Anders Physical Chemistry Chemical Physics, Vol. 14, Issue 39 https://doi.org/10.1039/c2cp42866k	journal	January 2012
X-ray Absorption Spectra of Dissolved Polysulfides in Lithium–Sulfur Batteries from First-Principles Pascal, Tod A.; Wujcik, Kevin H.; Velasco-Velez, Juan The Journal of Physical Chemistry Letters, Vol. 5, Issue 9 https://doi.org/10.1021/jz500260s	journal	April 2014
Mechanistic insights into operational lithium–sulfur batteries by in situ X-ray diffraction and absorption spectroscopy Lowe, Michael A.; Gao, Jie; Abruña, Héctor D. RSC Advances, Vol. 4, Issue 35 https://doi.org/10.1039/c4ra01388c	journal	January 2014
Rechargeable Lithium–Sulfur Batteries Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500062v	journal	July 2014
High-Resolution X-ray Emission and X-ray Absorption Spectroscopy de Groot, Frank Chemical Reviews, Vol. 101, Issue 6 https://doi.org/10.1021/cr9900681	journal	June 2001
Characterization of Polysulfide Radicals Present in an Ether-Based Electrolyte of a Lithium-Sulfur Battery During Initial Discharge Using In Situ X-Ray Absorption Spectroscopy Experiments and First-Principles Calculations Wujcik, Kevin H.; Pascal, Tod A.; Pemmaraju, C. D. Advanced Energy Materials, Vol. 5, Issue 16 https://doi.org/10.1002/aenm.201500285	journal	June 2015
Perspectives of in situ/operando resonant inelastic X-ray scattering in catalytic energy materials science Liu, Yi-Sheng; Glans, Per-Anders; Chuang, Cheng-Hao Journal of Electron Spectroscopy and Related Phenomena, Vol. 200 https://doi.org/10.1016/j.elspec.2015.07.004	journal	April 2015
XANES spectra of a variety of widely used organic polymers at the C K-edge Kikuma, J.; Tonner, B. P. Journal of Electron Spectroscopy and Related Phenomena, Vol. 82, Issue 1-2 https://doi.org/10.1016/S0368-2048(96)03049-6	journal	November 1996
The probing depth of total electron yield in the sub-keV range: TEY-XAS and X-PEEM Frazer, Bradley H.; Gilbert, Benjamin; Sonderegger, Brandon R. Surface Science, Vol. 537, Issue 1-3 https://doi.org/10.1016/S0039-6028(03)00613-7	journal	July 2003
X-ray absorption near edge structure spectroscopic study of Hayabusa category 3 carbonaceous particles Yabuta, Hikaru; Uesugi, Masayuki; Naraoka, Hiroshi Earth, Planets and Space, Vol. 66, Issue 1 https://doi.org/10.1186/s40623-014-0156-0	journal	December 2014
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F. Nature Materials, Vol. 8, Issue 6, p. 500-506 https://doi.org/10.1038/nmat2460	journal	May 2009
Effects of Nanosized Adsorbing Material on Electrochemical Properties of Sulfur Cathodes for Li/S Secondary Batteries Song, Min-Sang; Han, Sang-Cheol; Kim, Hyun-Seok Journal of The Electrochemical Society, Vol. 151, Issue 6, p. A791-A795 https://doi.org/10.1149/1.1710895	journal	January 2004
High-performance lithium/sulfur cells with a bi-functionally immobilized sulfur cathode Lin, Zhan; Nan, Caiyun; Ye, Yifan Nano Energy, Vol. 9 https://doi.org/10.1016/j.nanoen.2014.08.003	journal	October 2014
X-ray Absorption Near-Edge Structure and Nuclear Magnetic Resonance Study of the Lithium-Sulfur Battery and its Components Patel, Manu U. M.; Arčon, Iztok; Aquilanti, Giuliana ChemPhysChem, Vol. 15, Issue 5 https://doi.org/10.1002/cphc.201300972	journal	February 2014
Distinct charge dynamics in battery electrodes revealed by in situ and operando soft X-ray spectroscopy Liu, Xiaosong; Wang, Dongdong; Liu, Gao Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3568	journal	October 2013
Porous Hollow Carbon@Sulfur Composites for High-Power Lithium-Sulfur Batteries Jayaprakash, N.; Shen, J.; Moganty, Surya S. Angewandte Chemie, Vol. 123, Issue 26, p. 6026-6030 https://doi.org/10.1002/ange.201100637	journal	May 2011
Sulfur: Not a “Silent” Element Any More Jalilehvand, Farideh ChemInform, Vol. 38, Issue 18 https://doi.org/10.1002/chin.200718240	journal	May 2007
Copper-Stabilized Sulfur-Microporous Carbon Cathodes for Li-S Batteries Zheng, Shiyou; Yi, Feng; Li, Zhipeng Advanced Functional Materials, Vol. 24, Issue 26 https://doi.org/10.1002/adfm.201304156	journal	March 2014
Sulfur: Not a “Silent” Element Any More Jalilehvand, Farideh ChemInform, Vol. 38, Issue 18 https://doi.org/10.1002/chin.200718240	journal	May 2007
X-ray Absorption Near-Edge Structure and Nuclear Magnetic Resonance Study of the Lithium-Sulfur Battery and its Components Patel, Manu U. M.; Arčon, Iztok; Aquilanti, Giuliana ChemPhysChem, Vol. 15, Issue 5 https://doi.org/10.1002/cphc.201300972	journal	February 2014
Solution-Based Processing of Graphene-Li ₂ S Composite Cathodes for Lithium-Ion and Lithium-Sulfur Batteries Wu, Feixiang; Lee, Jung Tae; Magasinski, Alexandre Particle & Particle Systems Characterization, Vol. 31, Issue 6 https://doi.org/10.1002/ppsc.201300358	journal	February 2014
Progress and prospective of solid-state lithium batteries Takada, Kazunori Acta Materialia, Vol. 61, Issue 3, p. 759-770 https://doi.org/10.1016/j.actamat.2012.10.034	journal	February 2013
Mg deposition observed by in situ electrochemical Mg K-edge X-ray absorption spectroscopy Arthur, Timothy S.; Glans, Per-Anders; Matsui, Masaki Electrochemistry Communications, Vol. 24 https://doi.org/10.1016/j.elecom.2012.08.018	journal	October 2012
High-performance lithium/sulfur cells with a bi-functionally immobilized sulfur cathode Lin, Zhan; Nan, Caiyun; Ye, Yifan Nano Energy, Vol. 9 https://doi.org/10.1016/j.nanoen.2014.08.003	journal	October 2014
Investigation of surface effects through the application of the functional binders in lithium sulfur batteries Ai, Guo; Dai, Yiling; Ye, Yifan Nano Energy, Vol. 16 https://doi.org/10.1016/j.nanoen.2015.05.036	journal	September 2015
Challenges and Prospects of Lithium–Sulfur Batteries Manthiram, Arumugam; Fu, Yongzhu; Su, Yu-Sheng Accounts of Chemical Research, Vol. 46, Issue 5 https://doi.org/10.1021/ar300179v	journal	June 2012
Rechargeable Lithium–Sulfur Batteries Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500062v	journal	July 2014
Graphene Oxide as a Sulfur Immobilizer in High Performance Lithium/Sulfur Cells Ji, Liwen; Rao, Mumin; Zheng, Haimei Journal of the American Chemical Society, Vol. 133, Issue 46, p. 18522-18525 https://doi.org/10.1021/ja206955k	journal	November 2011
Understanding the Nature of Absorption/Adsorption in Nanoporous Polysulfide Sorbents for the Li–S Battery Evers, Scott; Yim, Taeeun; Nazar, Linda F. The Journal of Physical Chemistry C, Vol. 116, Issue 37 https://doi.org/10.1021/jp304380j	journal	September 2012
Sulfur Speciation in Li–S Batteries Determined by Operando X-ray Absorption Spectroscopy Cuisinier, Marine; Cabelguen, Pierre-Etienne; Evers, Scott The Journal of Physical Chemistry Letters, Vol. 4, Issue 19 https://doi.org/10.1021/jz401763d	journal	September 2013
X-ray Absorption Spectra of Dissolved Polysulfides in Lithium–Sulfur Batteries from First-Principles Pascal, Tod A.; Wujcik, Kevin H.; Velasco-Velez, Juan The Journal of Physical Chemistry Letters, Vol. 5, Issue 9 https://doi.org/10.1021/jz500260s	journal	April 2014
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F. Nature Materials, Vol. 8, Issue 6, p. 500-506 https://doi.org/10.1038/nmat2460	journal	May 2009
Advances in Li–S batteries Ji, Xiulei; Nazar, Linda F. Journal of Materials Chemistry, Vol. 20, Issue 44, p. 9821-9826 https://doi.org/10.1039/b925751a	journal	January 2010
Mechanistic insights into operational lithium–sulfur batteries by in situ X-ray diffraction and absorption spectroscopy Lowe, Michael A.; Gao, Jie; Abruña, Héctor D. RSC Advances, Vol. 4, Issue 35 https://doi.org/10.1039/c4ra01388c	journal	January 2014
Carbon K -edge spectra of carbonate minerals Brandes, Jay A.; Wirick, Sue; Jacobsen, Chris Journal of Synchrotron Radiation, Vol. 17, Issue 5 https://doi.org/10.1107/s0909049510020029	journal	July 2010
Diamond xenolith and matrix organic matter in the Sutter's Mill meteorite measured by C-XANES Kebukawa, Yoko; Zolensky, Michael E.; Kilcoyne, A. L. David Meteoritics & Planetary Science, Vol. 49, Issue 11 https://doi.org/10.1111/maps.12312	journal	October 2014
A Review on the Structural Studies of Batteries and Host Materials by X-Ray Absorption Spectroscopy Giorgetti, Marco ISRN Materials Science, Vol. 2013 https://doi.org/10.1155/2013/938625	journal	January 2013
X-ray absorption near edge structure spectroscopic study of Hayabusa category 3 carbonaceous particles Yabuta, Hikaru; Uesugi, Masayuki; Naraoka, Hiroshi Earth, Planets and Space, Vol. 66, Issue 1 https://doi.org/10.1186/s40623-014-0156-0	journal	December 2014

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The improvement of pitch activation by graphene for long-cycle Li–S batteries Cheng, Miao; Zhao, Huifang; Zhao, Zheng Green Chemistry, Vol. 20, Issue 20 https://doi.org/10.1039/c8gc01799a	journal	January 2018
A versatile liquid-jet/sessile droplet system for operando studies of reactions in liquid dispersions and solutions by X-ray absorption spectroscopy Chang, S. -Y.; Kathyola, T. A.; Willneff, E. A. Reaction Chemistry & Engineering, Vol. 4, Issue 4 https://doi.org/10.1039/c8re00207j	journal	January 2019
Method for Creation of Fine Sulfur Particles with Graphene Oxide for Lithium/Sulfur Cells Kawase, Ayako; Cairns, Elton J. Journal of The Electrochemical Society, Vol. 165, Issue 14 https://doi.org/10.1149/2.0181814jes	journal	January 2018

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Title: X-ray Absorption Spectroscopy Characterization of a Li/S Cell

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