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Title: A Molecular Precursor to Phosphaethyne and Its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion

Authors:
 [1];  [1];  [1];  [2];  [1];  [1];  [3];  [3];  [2];  [1];  [1]
  1. Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States
  2. Harvard−Smithsonian Center for Astrophysics, Cambridge, Massachusetts 02138, United States
  3. Physical Sciences Division, Pacific Northwest National Laboratory, Richland, Washington 99352, United States
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL); Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division; National Science Foundation (NSF); USDOE
Contributing Org.:
Smithsonian Astrophysical Observatory
OSTI Identifier:
1253822
Alternate Identifier(s):
OSTI ID: 1326146; OSTI ID: 1597418
Report Number(s):
PNNL-SA-117573
Journal ID: ISSN 0002-7863
Grant/Contract Number:  
FG02-87ER13671; CHE-1362118; AC05-76RL01830
Resource Type:
Published Article
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Name: Journal of the American Chemical Society Journal Volume: 138 Journal Issue: 21; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Transue, Wesley J., Velian, Alexandra, Nava, Matthew, Martin-Drumel, Marie-Aline, Womack, Caroline C., Jiang, Jun, Hou, Gao-Lei, Wang, Xue-Bin, McCarthy, Michael C., Field, Robert W., and Cummins, Christopher C. A Molecular Precursor to Phosphaethyne and Its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion. United States: N. p., 2016. Web. doi:10.1021/jacs.6b03910.
Transue, Wesley J., Velian, Alexandra, Nava, Matthew, Martin-Drumel, Marie-Aline, Womack, Caroline C., Jiang, Jun, Hou, Gao-Lei, Wang, Xue-Bin, McCarthy, Michael C., Field, Robert W., & Cummins, Christopher C. A Molecular Precursor to Phosphaethyne and Its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion. United States. doi:10.1021/jacs.6b03910.
Transue, Wesley J., Velian, Alexandra, Nava, Matthew, Martin-Drumel, Marie-Aline, Womack, Caroline C., Jiang, Jun, Hou, Gao-Lei, Wang, Xue-Bin, McCarthy, Michael C., Field, Robert W., and Cummins, Christopher C. Tue . "A Molecular Precursor to Phosphaethyne and Its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion". United States. doi:10.1021/jacs.6b03910.
@article{osti_1253822,
title = {A Molecular Precursor to Phosphaethyne and Its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion},
author = {Transue, Wesley J. and Velian, Alexandra and Nava, Matthew and Martin-Drumel, Marie-Aline and Womack, Caroline C. and Jiang, Jun and Hou, Gao-Lei and Wang, Xue-Bin and McCarthy, Michael C. and Field, Robert W. and Cummins, Christopher C.},
abstractNote = {},
doi = {10.1021/jacs.6b03910},
journal = {Journal of the American Chemical Society},
number = 21,
volume = 138,
place = {United States},
year = {2016},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1021/jacs.6b03910

Citation Metrics:
Cited by: 7 works
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Works referencing / citing this record:

Generation and reactivity of neutral 1,3-benzazaphosphole and anionic 1,3-benzazaphospholide ytterbium( iii ) complexes
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Terminal Molybdenum Phosphides with d Electrons: Radical Character Promotes Coupling Chemistry
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  • Buss, Joshua A.; Oyala, Paul H.; Agapie, Theodor
  • Angewandte Chemie International Edition, Vol. 56, Issue 46
  • DOI: 10.1002/anie.201707921

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An exploding N-isocyanide reagent formally composed of anthracene, dinitrogen and a carbon atom
journal, January 2017

  • Joost, Maximilian; Nava, Matthew; Transue, Wesley J.
  • Chem. Commun., Vol. 53, Issue 83
  • DOI: 10.1039/c7cc06516g

Copper-Catalyzed [3+2] Cycloaddition Reactions of Isocyanoacetates with Phosphaalkynes to Prepare 1,3-Azaphospholes
journal, December 2018

  • Liang, Wenbin; Nakajima, Kazunari; Sakata, Ken
  • Angewandte Chemie International Edition, Vol. 58, Issue 4
  • DOI: 10.1002/anie.201812779

Diazomethane umpolung atop anthracene: an electrophilic methylene transfer reagent
journal, January 2018

  • Joost, Maximilian; Transue, Wesley J.; Cummins, Christopher C.
  • Chemical Science, Vol. 9, Issue 6
  • DOI: 10.1039/c7sc04506a

Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity
journal, May 2018

  • Joost, Maximilian; Nava, Matthew; Transue, Wesley J.
  • Proceedings of the National Academy of Sciences, Vol. 115, Issue 23
  • DOI: 10.1073/pnas.1804035115

Terminal Molybdenum Phosphides with d Electrons: Radical Character Promotes Coupling Chemistry
journal, October 2017

  • Buss, Joshua A.; Oyala, Paul H.; Agapie, Theodor
  • Angewandte Chemie International Edition, Vol. 56, Issue 46
  • DOI: 10.1002/anie.201707921

Copper-Catalyzed [3+2] Cycloaddition Reactions of Isocyanoacetates with Phosphaalkynes to Prepare 1,3-Azaphospholes
journal, December 2018

  • Liang, Wenbin; Nakajima, Kazunari; Sakata, Ken
  • Angewandte Chemie International Edition, Vol. 58, Issue 4
  • DOI: 10.1002/anie.201812779

An exploding N-isocyanide reagent formally composed of anthracene, dinitrogen and a carbon atom
journal, January 2017

  • Joost, Maximilian; Nava, Matthew; Transue, Wesley J.
  • Chem. Commun., Vol. 53, Issue 83
  • DOI: 10.1039/c7cc06516g

Diazomethane umpolung atop anthracene: an electrophilic methylene transfer reagent
journal, January 2018

  • Joost, Maximilian; Transue, Wesley J.; Cummins, Christopher C.
  • Chemical Science, Vol. 9, Issue 6
  • DOI: 10.1039/c7sc04506a

Generation and reactivity of neutral 1,3-benzazaphosphole and anionic 1,3-benzazaphospholide ytterbium( iii ) complexes
journal, January 2019

  • Ying, Huacheng; Gong, Mingzhu; Pi, Chengfu
  • Dalton Transactions, Vol. 48, Issue 8
  • DOI: 10.1039/c8dt04768e

Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity
journal, May 2018

  • Joost, Maximilian; Nava, Matthew; Transue, Wesley J.
  • Proceedings of the National Academy of Sciences, Vol. 115, Issue 23
  • DOI: 10.1073/pnas.1804035115