Real-time monitoring of room-temperature ionic liquid purity through optical diode-based sensing

Wheeler, Jeffrey L.; Dreyer, Christopher B.; Poshusta, Joe; Martin, Jerry L.; Porter, Jason M.

doi:10.1016/j.snb.2015.05.097

Title: Real-time monitoring of room-temperature ionic liquid purity through optical diode-based sensing

Authors:

Wheeler, Jeffrey L.;

; Poshusta, Joe; Martin, Jerry L.; Porter, Jason M.

Publication Date:: Tue Dec 01 00:00:00 EST 2015

Sponsoring Org.:: USDOE Office of Electricity (OE)

OSTI Identifier:: 1253657

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Sensors and Actuators. B, Chemical

Additional Journal Information:: Journal Name: Sensors and Actuators. B, Chemical Journal Volume: 220 Journal Issue: C; Journal ID: ISSN 0925-4005

Publisher:: Elsevier

Country of Publication:: Switzerland

Language:: English

Citation Formats


                    Wheeler, Jeffrey L., Dreyer, Christopher B., Poshusta, Joe, Martin, Jerry L., and Porter, Jason M. Real-time monitoring of room-temperature ionic liquid purity through optical diode-based sensing.  Switzerland: N. p., 2015. 
Web.  doi:10.1016/j.snb.2015.05.097.

Copy to clipboard


                    Wheeler, Jeffrey L., Dreyer, Christopher B., Poshusta, Joe, Martin, Jerry L., & Porter, Jason M. Real-time monitoring of room-temperature ionic liquid purity through optical diode-based sensing.  Switzerland.  https://doi.org/10.1016/j.snb.2015.05.097

Copy to clipboard


                    Wheeler, Jeffrey L., Dreyer, Christopher B., Poshusta, Joe, Martin, Jerry L., and Porter, Jason M. Tue .  
"Real-time monitoring of room-temperature ionic liquid purity through optical diode-based sensing".  Switzerland.  https://doi.org/10.1016/j.snb.2015.05.097.

Copy to clipboard


                    
@article{osti_1253657,

  title        = {Real-time monitoring of room-temperature ionic liquid purity through optical diode-based sensing},

  author       = {Wheeler, Jeffrey L. and Dreyer, Christopher B. and Poshusta, Joe and Martin, Jerry L. and Porter, Jason M.},

  abstractNote = {},

  doi          = {10.1016/j.snb.2015.05.097},

  journal      = {Sensors and Actuators. B, Chemical},

  number       = C,

  volume       = 220,

  place        = {Switzerland},

  year         = {Tue Dec 01 00:00:00 EST 2015},

  month        = {Tue Dec 01 00:00:00 EST 2015}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1016/j.snb.2015.05.097

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 4 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

N-Methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide (PP13–TFSI) – novel electrolyte base for Li battery
journal, July 2003

Sakaebe, Hikari; Matsumoto, Hajime
Electrochemistry Communications, Vol. 5, Issue 7
DOI: 10.1016/S1388-2481(03)00137-1

Monolithic integration of poly(dimethylsiloxane) waveguides and microfluidics for on-chip absorbance measurements
journal, September 2008

Kee, Jack Sheng; Poenar, Daniel Puiu; Neuzil, Pavel
Sensors and Actuators B: Chemical, Vol. 134, Issue 2
DOI: 10.1016/j.snb.2008.05.040

Optical measurements of impurities in room-temperature ionic liquids
journal, January 2014

Porter, Jason M.; Dreyer, Christopher B.; Bicknase, David
Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 133
DOI: 10.1016/j.jqsrt.2013.08.015

Ionic-liquid materials for the electrochemical challenges of the future
journal, July 2009

Armand, Michel; Endres, Frank; MacFarlane, Douglas R.
Nature Materials, Vol. 8, Issue 8, p. 621-629
DOI: 10.1038/nmat2448

Synthesis of ionic liquids in micro-reactors—a process intensification study
journal, January 2007

Waterkamp, Daniel A.; Heiland, Michael; Schlüter, Michael
Green Chemistry, Vol. 9, Issue 10
DOI: 10.1039/b616882e

Simple and multi-configurational flow-cell detector for UV–vis spectroelectrochemical measurements in commercial instruments
journal, September 2013

León, L.; Maraver, J. J.; Carbajo, J.
Sensors and Actuators B: Chemical, Vol. 186
DOI: 10.1016/j.snb.2013.06.024

Effect of Water on the Electrochemical Window and Potential Limits of Room-Temperature Ionic Liquids
journal, December 2008

O’Mahony, Aoife M.; Silvester, Debbie S.; Aldous, Leigh
Journal of Chemical & Engineering Data, Vol. 53, Issue 12
DOI: 10.1021/je800678e

Purification of imidazolium ionic liquids for spectroscopic applications
journal, October 2005

Nockemann, Peter; Binnemans, Koen; Driesen, Kris
Chemical Physics Letters, Vol. 415, Issue 1-3
DOI: 10.1016/j.cplett.2005.08.128

Purity specification methods for ionic liquids
journal, January 2008

Stark, Annegret; Behrend, Peter; Braun, Oliver
Green Chemistry, Vol. 10, Issue 11
DOI: 10.1039/b808532c

The large scale synthesis of pure imidazolium and pyrrolidinium ionic liquids
journal, January 2007

Burrell, Anthony K.; Sesto, Rico E. Del; Baker, Sheila N.
Green Chemistry, Vol. 9, Issue 5
DOI: 10.1039/b615950h

Electronic structures of ionic liquids <mml:math altimg="si12.gif" display="inline" overflow="scroll" xmlns:xocs="http://www.elsevier.com/xml/xocs/dtd" xmlns:xs="http://www.w3.org/2001/XMLSchema" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://www.elsevier.com/xml/ja/dtd" xmlns:ja="http://www.elsevier.com/xml/ja/dtd" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:tb="http://www.elsevier.com/xml/common/table/dtd" xmlns:sb="http://www.elsevier.com/xml/common/struct-bib/dtd" xmlns:ce="http://www.elsevier.com/xml/common/dtd" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:cals="http://www.elsevier.com/xml/common/cals/dtd"><mml:mrow><mml:mo stretchy="false">[</mml:mo><mml:msub><mml:mrow><mml:mtext>C</mml:mtext></mml:mrow><mml:mrow><mml:mi>n</mml:mi></mml:mrow></mml:msub><mml:mtext>mim</mml:mtext><mml:msup><mml:mrow><mml:mo stretchy="false">]</mml:mo></mml:mrow><mml:mrow><mml:mo>+</mml:mo></mml:mrow></mml:msup><mml:msubsup><mml:mrow><mml:mtext>BF</mml:mtext></mml:mrow><mml:mrow><mml:mn>4</mml:mn></mml:mrow><mml:mrow><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math> and <mml:math altimg="si13.gif" display="inline" overflow="scroll" xmlns:xocs="http://www.elsevier.com/xml/xocs/dtd" xmlns:xs="http://www.w3.org/2001/XMLSchema" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://www.elsevier.com/xml/ja/dtd" xmlns:ja="http://www.elsevier.com/xml/ja/dtd" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:tb="http://www.elsevier.com/xml/common/table/dtd" xmlns:sb="http://www.elsevier.com/xml/common/struct-bib/dtd" xmlns:ce="http://www.elsevier.com/xml/common/dtd" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:cals="http://www.elsevier.com/xml/common/cals/dtd"><mml:mrow><mml:mo stretchy="false">[</mml:mo><mml:msub><mml:mrow><mml:mtext>C</mml:mtext></mml:mrow><mml:mrow><mml:mi>n</mml:mi></mml:mrow></mml:msub><mml:mtext>mim</mml:mtext><mml:msup><mml:mrow><mml:mo stretchy="false">]</mml:mo></mml:mrow><mml:mrow><mml:mo>+</mml:mo></mml:mrow></mml:msup><mml:msubsup><mml:mrow><mml:mtext>PF</mml:mtext></mml:mrow><mml:mrow><mml:mn>6</mml:mn></mml:mrow><mml:mrow><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math> studied by ultraviolet photoemission, inverse photoemission, and near-edge X-ray absorption fine structure spectroscopies
journal, April 2008

Nishi, Toshio; Iwahashi, Takashi; Yamane, Hiroyuki
Chemical Physics Letters, Vol. 455, Issue 4-6
DOI: 10.1016/j.cplett.2008.01.049

Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis
journal, August 1999

Welton, Thomas
Chemical Reviews, Vol. 99, Issue 8, p. 2071-2084
DOI: 10.1021/cr980032t

How transparent are the imidazolium ionic liquids? A case study with 1-methyl-3-butylimidazolium hexafluorophosphate, [bmim][PF6]
journal, February 2005

Paul, Aniruddha; Mandal, Prasun Kumar; Samanta, Anunay
Chemical Physics Letters, Vol. 402, Issue 4-6
DOI: 10.1016/j.cplett.2004.12.060

CHEMISTRY: Ionic Liquids--Solvents of the Future?
journal, October 2003

Rogers, R. D.; Seddon, Kenneth R.
Science, Vol. 302, Issue 5646, p. 792-793
DOI: 10.1126/science.1090313

Ionic liquids: solvent properties and organic reactivity
journal, January 2005

Chiappe, Cinzia; Pieraccini, Daniela
Journal of Physical Organic Chemistry, Vol. 18, Issue 4
DOI: 10.1002/poc.863

Investigating the electrochemical windows of ionic liquids
journal, January 2013

Hayyan, Maan; Mjalli, Farouq S.; Hashim, Mohd Ali
Journal of Industrial and Engineering Chemistry, Vol. 19, Issue 1
DOI: 10.1016/j.jiec.2012.07.011

Air and water stable ionic liquids in physical chemistry
journal, January 2006

Endres, Frank; Zein El Abedin, Sherif
Physical Chemistry Chemical Physics, Vol. 8, Issue 18
DOI: 10.1039/b600519p

IC Determination of Halide Impurities in Ionic Liquids
journal, February 2008

Hao, Fuping; Haddad, Paul R.; Ruther, Thomas
Chromatographia, Vol. 67, Issue 5-6
DOI: 10.1365/s10337-008-0527-4

Optical sensing systems for microfluidic devices: A review
journal, October 2007

Kuswandi, Bambang; Huskens, Jurriaan
Analytica Chimica Acta, Vol. 601, Issue 2, p. 141-155
DOI: 10.1016/j.aca.2007.08.046

Decolorization of Ionic Liquids for Spectroscopy
journal, January 2007

Earle, Martyn J.; Gordon, Charles M.; Plechkova, Natalia V.
Analytical Chemistry, Vol. 79, Issue 2
DOI: 10.1021/ac061481t

Detection limits of chemical sensors: Applications and misapplications
journal, October 2012

Loock, Hans-Peter; Wentzell, Peter D.
Sensors and Actuators B: Chemical, Vol. 173
DOI: 10.1016/j.snb.2012.06.071

Similar Records in DOE PAGES and OSTI.GOV collections:

Current rectification for transport of room-temperature ionic liquids through conical nanopores

Journal Article Jiang, Xikai ; Liu, Ying ; Qiao, Rui - Journal of Physical Chemistry. C

Here, we studied the transport of room-temperature ionic liquids (RTILs) through charged conical nanopores using a Landau-Ginzburg-type continuum model that takes steric effect and strong ion-ion correlations into account. When the surface charge is uniform on the pore wall, weak current rectification is observed. When the charge density near the pore base is removed, the ionic current is greatly suppressed under negative bias voltage while nearly unchanged under positive bias voltage, thereby leading to enhanced current rectification. These predictions agree qualitatively with prior experimental observations, and we elucidated them by analyzing the different components of the ionic current and themore »« less
Cited by 18
https://doi.org/10.1021/acs.jpcc.5b11522

Full Text Available
SU-F-J-44: Development of a Room Laser Based Real-Time Alignment Monitoring System Using An Array of Photodiodes

Journal Article Noh, Y ; Kim, T ; Kang, S ; ... - Medical Physics

Purpose: To develop a real-time alignment monitoring system (RAMS) to compensate for the limitations of the conventional room laser based alignment system, and to verify the feasibility of the RAMS. Methods: The RAMS was composed of a room laser sensing array (RLSA), an analog-todigital converter, and a control PC. In the RLSA, seven photodiodes (each in 1 mm width) are arranged in a pattern that the RAMS provides alignment in 1 mm resolution. It works based on detecting laser light aligned on one of photodiodes. When misaligned, the laser would match with different photodiode(s) giving signal at unexpected location. Thus,more »« less
https://doi.org/10.1118/1.4955952
Time-dependent density functional theory for the charging kinetics of electric double layer containing room-temperature ionic liquids

Journal Article Lian, Cheng ; Univ. of California, Riverside, CA ; Zhao, Shuangliang ; ... - Journal of Chemical Physics

Understanding the charging kinetics of electric double layers is of fundamental importance for the design and development of novel electrochemical devices such as supercapacitors and field-effect transistors. In this paper, we study the dynamic behavior of room-temperature ionic liquids using a classical time-dependent density functional theory that accounts for the molecular excluded volume effects, the electrostatic correlations, and the dispersion forces. While the conventional models predict a monotonic increase of the surface charge with time upon application of an electrode voltage, our results show that dispersion between ions results in a non-monotonic increase of the surface charge with the durationmore »« less
Cited by 37
https://doi.org/10.1063/1.4968037

Full Text Available
Note: Real time optical sensing of alpha-radiation emitting radioactive aerosols based on solid state nuclear track detector

Journal Article Kulkarni, A. ; Bak, M. S., E-mail: tkim@skku.edu, E-mail: moonsoo@skku.edu ; Ha, S. ; ... - Review of Scientific Instruments

A sensitive radioactive aerosols sensor has been designed and developed. Its design guidance is based on the need for a low operational cost and reliable measurements to provide daily aerosol monitoring. The exposure of diethylene-glycol bis (allylcarbonate) to radiation causes modification of its physico-chemical properties like surface roughness and reflectance. In the present study, optical sensor based on the reflectance measurement has been developed with an aim to monitor real time presence of alpha radioactive aerosols emitted from thorium nitrate hydrate. The results shows that the fabricated sensor can detect 0.0157 kBq to 0.1572 kBq of radio activity by radioactivemore »« less
https://doi.org/10.1063/1.4922463
Real Time and Distributed Temperature Sensing and Quench Detection Via Multi-Functional Fiber Optic Sensors

Technical Report MANJOORAN, NAVIN ; PICKRELL, GARY

Real Time and Distributed Temperature Sensing and Quench Detection Via Multi-Functional Fiber Optic Sensors final report and results discussion.

Similar Records

Title: Real-time monitoring of room-temperature ionic liquid purity through optical diode-based sensing

Citation Formats

N-Methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide (PP13–TFSI) – novel electrolyte base for Li battery journal, July 2003

Monolithic integration of poly(dimethylsiloxane) waveguides and microfluidics for on-chip absorbance measurements journal, September 2008

Optical measurements of impurities in room-temperature ionic liquids journal, January 2014

Ionic-liquid materials for the electrochemical challenges of the future journal, July 2009

Synthesis of ionic liquids in micro-reactors—a process intensification study journal, January 2007

Simple and multi-configurational flow-cell detector for UV–vis spectroelectrochemical measurements in commercial instruments journal, September 2013

Effect of Water on the Electrochemical Window and Potential Limits of Room-Temperature Ionic Liquids journal, December 2008

Purification of imidazolium ionic liquids for spectroscopic applications journal, October 2005

Purity specification methods for ionic liquids journal, January 2008

The large scale synthesis of pure imidazolium and pyrrolidinium ionic liquids journal, January 2007

Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis journal, August 1999

How transparent are the imidazolium ionic liquids? A case study with 1-methyl-3-butylimidazolium hexafluorophosphate, [bmim][PF6] journal, February 2005

CHEMISTRY: Ionic Liquids--Solvents of the Future? journal, October 2003

Ionic liquids: solvent properties and organic reactivity journal, January 2005

Investigating the electrochemical windows of ionic liquids journal, January 2013

Air and water stable ionic liquids in physical chemistry journal, January 2006

IC Determination of Halide Impurities in Ionic Liquids journal, February 2008

Optical sensing systems for microfluidic devices: A review journal, October 2007

Decolorization of Ionic Liquids for Spectroscopy journal, January 2007

Detection limits of chemical sensors: Applications and misapplications journal, October 2012

N-Methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide (PP13–TFSI) – novel electrolyte base for Li battery
journal, July 2003

Monolithic integration of poly(dimethylsiloxane) waveguides and microfluidics for on-chip absorbance measurements
journal, September 2008

Optical measurements of impurities in room-temperature ionic liquids
journal, January 2014

Ionic-liquid materials for the electrochemical challenges of the future
journal, July 2009

Synthesis of ionic liquids in micro-reactors—a process intensification study
journal, January 2007

Simple and multi-configurational flow-cell detector for UV–vis spectroelectrochemical measurements in commercial instruments
journal, September 2013

Effect of Water on the Electrochemical Window and Potential Limits of Room-Temperature Ionic Liquids
journal, December 2008

Purification of imidazolium ionic liquids for spectroscopic applications
journal, October 2005

Purity specification methods for ionic liquids
journal, January 2008

The large scale synthesis of pure imidazolium and pyrrolidinium ionic liquids
journal, January 2007

Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis
journal, August 1999

How transparent are the imidazolium ionic liquids? A case study with 1-methyl-3-butylimidazolium hexafluorophosphate, [bmim][PF6]
journal, February 2005

CHEMISTRY: Ionic Liquids--Solvents of the Future?
journal, October 2003

Ionic liquids: solvent properties and organic reactivity
journal, January 2005

Investigating the electrochemical windows of ionic liquids
journal, January 2013

Air and water stable ionic liquids in physical chemistry
journal, January 2006

IC Determination of Halide Impurities in Ionic Liquids
journal, February 2008

Optical sensing systems for microfluidic devices: A review
journal, October 2007

Decolorization of Ionic Liquids for Spectroscopy
journal, January 2007

Detection limits of chemical sensors: Applications and misapplications
journal, October 2012