Spectroscopic signatures of AA' and AB stacking of chemical vapor deposited bilayer MoS2
Abstract
We report prominent resonance Raman and photoluminescence spectroscopic differences between AA' and AB stacked bilayer molybdenum disulfide (MoS2) grown by chemical vapor deposition. Bilayer MoS2 islands consisting of the two stacking orders were obtained under identical growth conditions. Resonance Moreover, Raman and photoluminescence spectra of AA' and AB stacked bilayer MoS2 were obtained on Au nanopyramid surfaces under strong plasmon resonance. Both resonance Raman and photoluminescence spectra show distinct features indicating clear differences in interlayer interaction between these two phases. Finally, the implication of these findings on device applications based on spin and valley degrees of freedom will be discussed.
- Authors:
-
- Univ. of California, Los Angeles, CA (United States)
- Rice Univ., Houston, TX (United States)
- Southeast Univ., Nanjing (China). School of Energy and Environment; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Innovations for High Performance (IHP), Frankfurt (Germany)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Univ. of California, Los Angeles, CA (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1252727
- Alternate Identifier(s):
- OSTI ID: 1286946
- Grant/Contract Number:
- W-7405-ENG-26; AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Nano
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 12; Journal ID: ISSN 1936-0851
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; molybdenum disulfide; bilayer stacking; Au nanopyramids; photoluminescence; resonance Raman; 36 MATERIALS SCIENCE
Citation Formats
Xia, Ming, Li, Bo, Yin, Kuibo, Capellini, Giovanni, Niu, Gang, Gong, Yongji, Zhou, Wu, Ajayan, Pulickel M., and Xie, Ya -Hong. Spectroscopic signatures of AA' and AB stacking of chemical vapor deposited bilayer MoS2. United States: N. p., 2015.
Web. doi:10.1021/acsnano.5b05474.
Xia, Ming, Li, Bo, Yin, Kuibo, Capellini, Giovanni, Niu, Gang, Gong, Yongji, Zhou, Wu, Ajayan, Pulickel M., & Xie, Ya -Hong. Spectroscopic signatures of AA' and AB stacking of chemical vapor deposited bilayer MoS2. United States. https://doi.org/10.1021/acsnano.5b05474
Xia, Ming, Li, Bo, Yin, Kuibo, Capellini, Giovanni, Niu, Gang, Gong, Yongji, Zhou, Wu, Ajayan, Pulickel M., and Xie, Ya -Hong. Wed .
"Spectroscopic signatures of AA' and AB stacking of chemical vapor deposited bilayer MoS2". United States. https://doi.org/10.1021/acsnano.5b05474. https://www.osti.gov/servlets/purl/1252727.
@article{osti_1252727,
title = {Spectroscopic signatures of AA' and AB stacking of chemical vapor deposited bilayer MoS2},
author = {Xia, Ming and Li, Bo and Yin, Kuibo and Capellini, Giovanni and Niu, Gang and Gong, Yongji and Zhou, Wu and Ajayan, Pulickel M. and Xie, Ya -Hong},
abstractNote = {We report prominent resonance Raman and photoluminescence spectroscopic differences between AA' and AB stacked bilayer molybdenum disulfide (MoS2) grown by chemical vapor deposition. Bilayer MoS2 islands consisting of the two stacking orders were obtained under identical growth conditions. Resonance Moreover, Raman and photoluminescence spectra of AA' and AB stacked bilayer MoS2 were obtained on Au nanopyramid surfaces under strong plasmon resonance. Both resonance Raman and photoluminescence spectra show distinct features indicating clear differences in interlayer interaction between these two phases. Finally, the implication of these findings on device applications based on spin and valley degrees of freedom will be discussed.},
doi = {10.1021/acsnano.5b05474},
journal = {ACS Nano},
number = 12,
volume = 9,
place = {United States},
year = {Wed Nov 04 00:00:00 EST 2015},
month = {Wed Nov 04 00:00:00 EST 2015}
}
Web of Science
Works referenced in this record:
Atomically Thin A New Direct-Gap Semiconductor
journal, September 2010
- Mak, Kin Fai; Lee, Changgu; Hone, James
- Physical Review Letters, Vol. 105, Issue 13, Article No.136805
Photoluminescence from Chemically Exfoliated MoS2
journal, December 2011
- Eda, Goki; Yamaguchi, Hisato; Voiry, Damien
- Nano Letters, Vol. 11, Issue 12, p. 5111-5116
Emerging Photoluminescence in Monolayer MoS2
journal, April 2010
- Splendiani, Andrea; Sun, Liang; Zhang, Yuanbo
- Nano Letters, Vol. 10, Issue 4, p. 1271-1275
Coupled Spin and Valley Physics in Monolayers of and Other Group-VI Dichalcogenides
journal, May 2012
- Xiao, Di; Liu, Gui-Bin; Feng, Wanxiang
- Physical Review Letters, Vol. 108, Issue 19
Giant spin-orbit-induced spin splitting in two-dimensional transition-metal dichalcogenide semiconductors
journal, October 2011
- Zhu, Z. Y.; Cheng, Y. C.; Schwingenschlögl, U.
- Physical Review B, Vol. 84, Issue 15
Valley-dependent spin polarization in bulk MoS2 with broken inversion symmetry
journal, July 2014
- Suzuki, R.; Sakano, M.; Zhang, Y. J.
- Nature Nanotechnology, Vol. 9, Issue 8
Valley polarization in MoS2 monolayers by optical pumping
journal, June 2012
- Zeng, Hualing; Dai, Junfeng; Yao, Wang
- Nature Nanotechnology, Vol. 7, Issue 8
Control of valley polarization in monolayer MoS2 by optical helicity
journal, June 2012
- Mak, Kin Fai; He, Keliang; Shan, Jie
- Nature Nanotechnology, Vol. 7, Issue 8
Stacking effects on the electronic and optical properties of bilayer transition metal dichalcogenides , , , and
journal, February 2014
- He, Jiangang; Hummer, Kerstin; Franchini, Cesare
- Physical Review B, Vol. 89, Issue 7
From Bulk to Monolayer MoS2: Evolution of Raman Scattering
journal, January 2012
- Li, Hong; Zhang, Qing; Yap, Chin Chong Ray
- Advanced Functional Materials, Vol. 22, Issue 7
Electrical tuning of valley magnetic moment through symmetry control in bilayer MoS2
journal, January 2013
- Wu, Sanfeng; Ross, Jason S.; Liu, Gui-Bin
- Nature Physics, Vol. 9, Issue 3
Optical signature of symmetry variations and spin-valley coupling in atomically thin tungsten dichalcogenides
journal, April 2013
- Zeng, Hualing; Liu, Gui-Bin; Dai, Junfeng
- Scientific Reports, Vol. 3, Issue 1
Magnetoelectric effects and valley-controlled spin quantum gates in transition metal dichalcogenide bilayers
journal, June 2013
- Gong, Zhirui; Liu, Gui-Bin; Yu, Hongyi
- Nature Communications, Vol. 4, Issue 1
Spin and pseudospins in layered transition metal dichalcogenides
journal, April 2014
- Xu, Xiaodong; Yao, Wang; Xiao, Di
- Nature Physics, Vol. 10, Issue 5
Vapour phase growth and grain boundary structure of molybdenum disulphide atomic layers
journal, June 2013
- Najmaei, Sina; Liu, Zheng; Zhou, Wu
- Nature Materials, Vol. 12, Issue 8, p. 754-759
Valley and band structure engineering of folded MoS2 bilayers
journal, August 2014
- Jiang, Tao; Liu, Hengrui; Huang, Di
- Nature Nanotechnology, Vol. 9, Issue 10
Tailoring the Electronic Structure in Bilayer Molybdenum Disulfide via Interlayer Twist
journal, June 2014
- van der Zande, Arend M.; Kunstmann, Jens; Chernikov, Alexey
- Nano Letters, Vol. 14, Issue 7
Probing the Interlayer Coupling of Twisted Bilayer MoS 2 Using Photoluminescence Spectroscopy
journal, September 2014
- Huang, Shengxi; Ling, Xi; Liang, Liangbo
- Nano Letters, Vol. 14, Issue 10
Evolution of interlayer coupling in twisted molybdenum disulfide bilayers
journal, September 2014
- Liu, Kaihui; Zhang, Liming; Cao, Ting
- Nature Communications, Vol. 5, Issue 1
Giant Optical Response from Graphene–Plasmonic System
journal, June 2012
- Wang, Pu; Zhang, Wei; Liang, Owen
- ACS Nano, Vol. 6, Issue 7
Ultra-Sensitive Graphene-Plasmonic Hybrid Platform for Label-Free Detection
journal, August 2013
- Wang, Pu; Liang, Owen; Zhang, Wei
- Advanced Materials, Vol. 25, Issue 35
Vapor Phase Growth and Imaging Stacking Order of Bilayer Molybdenum Disulfide
journal, April 2014
- Yang, Shengxue; Kang, Jun; Yue, Qu
- The Journal of Physical Chemistry C, Vol. 118, Issue 17
Atomically localized plasmon enhancement in monolayer graphene
journal, January 2012
- Zhou, Wu; Lee, Jaekwang; Nanda, Jagjit
- Nature Nanotechnology, Vol. 7, Issue 3
Anomalous Lattice Vibrations of Single- and Few-Layer MoS 2
journal, March 2010
- Lee, Changgu; Yan, Hugen; Brus, Louis E.
- ACS Nano, Vol. 4, Issue 5
Layer-dependent resonant Raman scattering of a few layer MoS 2 : Raman scattering of a few layer MoS
journal, September 2012
- Chakraborty, Biswanath; Matte, H. S. S. Ramakrishna; Sood, A. K.
- Journal of Raman Spectroscopy, Vol. 44, Issue 1
Dispersive Raman Mode of Layered Compound 2H-MoS 2 under the Resonant Condition
journal, February 1984
- Sekine, Tomoyuki; Uchinokura, Kunimitsu; Nakashizu, Tsuneo
- Journal of the Physical Society of Japan, Vol. 53, Issue 2
Resonant Raman scattering at exciton states tuned by pressure and temperature in
journal, May 2010
- Livneh, Tsachi; Sterer, Eran
- Physical Review B, Vol. 81, Issue 19
Multiphonon resonant Raman scattering in MoS 2
journal, March 2014
- Gołasa, K.; Grzeszczyk, M.; Leszczyński, P.
- Applied Physics Letters, Vol. 104, Issue 9
An intelligent background-correction algorithm for highly fluorescent samples in Raman spectroscopy
journal, October 2009
- Zhang, Zhi-Min; Chen, Shan; Liang, Yi-Zeng
- Journal of Raman Spectroscopy, Vol. 41, Issue 6
Tightly bound trions in monolayer MoS2
journal, December 2012
- Mak, Kin Fai; He, Keliang; Lee, Changgu
- Nature Materials, Vol. 12, Issue 3
Anisotropic mean-square displacements (MSD) in single-crystals of 2 H - and 3 R -MoS 2
journal, August 1983
- Schönfeld, B.; Huang, J. J.; Moss, S. C.
- Acta Crystallographica Section B Structural Science, Vol. 39, Issue 4
Binding Energies in Atomic Negative Ions: III
journal, November 1999
- Andersen, T.; Haugen, H. K.; Hotop, H.
- Journal of Physical and Chemical Reference Data, Vol. 28, Issue 6
Band-gap transition induced by interlayer van der Waals interaction in MoS
journal, July 2011
- Han, S. W.; Kwon, Hyuksang; Kim, Seong Keun
- Physical Review B, Vol. 84, Issue 4
Controlled charge trapping by molybdenum disulphide and graphene in ultrathin heterostructured memory devices
journal, March 2013
- Sup Choi, Min; Lee, Gwan-Hyoung; Yu, Young-Jun
- Nature Communications, Vol. 4, Issue 1
High Performance Multilayer MoS2Transistors with Scandium Contacts
journal, December 2012
- Das, Saptarshi; Chen, Hong-Yan; Penumatcha, Ashish Verma
- Nano Letters, Vol. 13, Issue 1, p. 100-105
Electron-hole transport and photovoltaic effect in gated MoS2 Schottky junctions
journal, April 2013
- Fontana, Marcio; Deppe, Tristan; Boyd, Anthony K.
- Scientific Reports, Vol. 3, Issue 1
Tuning Electronic Structure of Bilayer MoS 2 by Vertical Electric Field: A First-Principles Investigation
journal, September 2012
- Liu, Qihang; Li, Linze; Li, Yafei
- The Journal of Physical Chemistry C, Vol. 116, Issue 40
Tunable band gaps in bilayer transition-metal dichalcogenides
journal, November 2011
- Ramasubramaniam, Ashwin; Naveh, Doron; Towe, Elias
- Physical Review B, Vol. 84, Issue 20
Experimental Demonstration of Continuous Electronic Structure Tuning via Strain in Atomically Thin MoS 2
journal, May 2013
- He, Keliang; Poole, Charles; Mak, Kin Fai
- Nano Letters, Vol. 13, Issue 6
Bandgap Engineering of Strained Monolayer and Bilayer MoS2
journal, July 2013
- Conley, Hiram J.; Wang, Bin; Ziegler, Jed I.
- Nano Letters, Vol. 13, Issue 8, p. 3626-3630
New Route for Stabilization of 1T-WS 2 and MoS 2 Phases
journal, November 2011
- Enyashin, Andrey N.; Yadgarov, Lena; Houben, Lothar
- The Journal of Physical Chemistry C, Vol. 115, Issue 50
Works referencing / citing this record:
Atomic-Scale Structural Modification of 2D Materials
journal, January 2019
- Xiao, Yao; Zhou, Mengyue; Zeng, Mengqi
- Advanced Science, Vol. 6, Issue 5
Stacking-controllable interlayer coupling and symmetric configuration of multilayered MoS2
journal, February 2018
- Shinde, Sachin M.; Dhakal, Krishna P.; Chen, Xiang
- NPG Asia Materials, Vol. 10, Issue 2
Controllable growth and electrostatic properties of Bernal stacked bilayer MoS 2
journal, September 2016
- Hao, Song; Yang, Bingchu; Gao, Yongli
- Journal of Applied Physics, Vol. 120, Issue 12
Thermally driven homonuclear-stacking phase of MoS 2 through desulfurization
journal, January 2019
- Hwang, Young Hun; Yun, Won Seok; Cha, Gi-Beom
- Nanoscale, Vol. 11, Issue 23
Interface Characterization and Control of 2D Materials and Heterostructures
journal, July 2018
- Liu, Xiaolong; Hersam, Mark C.
- Advanced Materials, Vol. 30, Issue 39
Modeling the vertical growth of van der Waals stacked 2D materials using the diffuse domain method
journal, January 2020
- Guo, Zhenlin; Price, Christopher; Shenoy, Vivek B.
- Modelling and Simulation in Materials Science and Engineering, Vol. 28, Issue 2
Hydrothermal synthesis of two-dimensional MoS2 and its applications
journal, March 2019
- Zhang, Xiaoyan; Ma, Guoqing; Wang, Jun
- Tungsten, Vol. 1, Issue 1
A Review on Applications of Two-Dimensional Materials in Surface-Enhanced Raman Spectroscopy
journal, January 2018
- Xia, Ming
- International Journal of Spectroscopy, Vol. 2018
2D Materials-Coated Plasmonic Structures for SERS Applications
journal, April 2018
- Xia, Ming
- Coatings, Vol. 8, Issue 4
Growth of 2H stacked WSe 2 bilayers on sapphire
journal, January 2019
- Han, Ali; Aljarb, Areej; Liu, Sheng
- Nanoscale Horizons, Vol. 4, Issue 6
Origin of Structural Transformation in Mono- and Bi-Layered Molybdenum Disulfide
journal, May 2016
- Sun, Xiaoli; Wang, Zhiguo; Li, Zhijie
- Scientific Reports, Vol. 6, Issue 1
Distinctive optoelectronic properties of nanostructured bilayers
journal, August 2019
- Mlinar, Vladan
- Physical Review B, Vol. 100, Issue 8
In situ atomic level studies of thermally controlled interlayer stacking shifts in 2D transition metal dichalcogenide bilayers
journal, January 2020
- Zhou, Si; Chen, Jun; Warner, Jamie H.
- Journal of Materials Research, Vol. 35, Issue 11
Restoring the intrinsic optical properties of CVD-grown MoS 2 monolayers and their heterostructures
journal, January 2019
- Kojima, Kana; Lim, Hong En; Liu, Zheng
- Nanoscale, Vol. 11, Issue 27
Controlled Vapor Growth and Nonlinear Optical Applications of Large-Area 3R Phase WS 2 and WSe 2 Atomic Layers
journal, January 2019
- Zeng, Zhouxiaosong; Sun, Xingxia; Zhang, Danliang
- Advanced Functional Materials, Vol. 29, Issue 11
Thickness and Stacking Sequence Determination of Exfoliated Dichalcogenides (1T-TaS 2 , 2H-MoS 2 ) Using Scanning Transmission Electron Microscopy
journal, August 2018
- Hovden, Robert; Liu, Pengzi; Schnitzer, Noah
- Microscopy and Microanalysis, Vol. 24, Issue 4
Analysis of photoluminescence behavior of high-quality single-layer MoS2
journal, April 2019
- Xu, Lu; Zhao, Liyun; Wang, Yunsong
- Nano Research, Vol. 12, Issue 7
High-Mobility Multilayered MoS 2 Flakes with Low Contact Resistance Grown by Chemical Vapor Deposition
journal, February 2017
- Zheng, Jingying; Yan, Xingxu; Lu, Zhixing
- Advanced Materials, Vol. 29, Issue 13
High degree of circular polarization in WS2 spiral nanostructures induced by broken symmetry
journal, February 2019
- Barman, Prahalad Kanti; Sarma, Prasad V.; Shaijumon, M. M.
- Scientific Reports, Vol. 9, Issue 1
Carrier dynamics and spin–valley–layer effects in bilayer transition metal dichalcogenides
journal, January 2019
- Ciccarino, Christopher J.; Chakraborty, Chitraleema; Englund, Dirk R.
- Faraday Discussions, Vol. 214
Transition metal dichalcogenides bilayer single crystals by reverse-flow chemical vapor epitaxy
journal, February 2019
- Zhang, Xiumei; Nan, Haiyan; Xiao, Shaoqing
- Nature Communications, Vol. 10, Issue 1
Mapping of Low-Frequency Raman Modes in CVD-Grown Transition Metal Dichalcogenides: Layer Number, Stacking Orientation and Resonant Effects
journal, January 2016
- O’Brien, Maria; McEvoy, Niall; Hanlon, Damien
- Scientific Reports, Vol. 6, Issue 1
Davydov splitting and polytypism in few-layer MoS 2
journal, October 2018
- Na, Woongki; Kim, Kangwon; Lee, Jae-Ung
- 2D Materials, Vol. 6, Issue 1
Atomic-Scale Structural Modification of 2D Materials
journal, January 2019
- Xiao, Yao; Zhou, Mengyue; Zeng, Mengqi
- Advanced Science, Vol. 6, Issue 5
Transition metal dichalcogenides bilayer single crystals by reverse-flow chemical vapor epitaxy
journal, February 2019
- Zhang, Xiumei; Nan, Haiyan; Xiao, Shaoqing
- Nature Communications, Vol. 10, Issue 1
High degree of circular polarization in WS2 spiral nanostructures induced by broken symmetry
journal, February 2019
- Barman, Prahalad Kanti; Sarma, Prasad V.; Shaijumon, M. M.
- Scientific Reports, Vol. 9, Issue 1
Origin of Structural Transformation in Mono- and Bi-Layered Molybdenum Disulfide
journal, May 2016
- Sun, Xiaoli; Wang, Zhiguo; Li, Zhijie
- Scientific Reports, Vol. 6, Issue 1