Kinetics of gas phase formic acid decomposition on platinum single crystal and polycrystalline surfaces

Detwiler, Michael D.; Milligan, Cory A.; Zemlyanov, Dmitry Y.; Delgass, W. Nicholas; Ribeiro, Fabio H.

doi:10.1016/j.susc.2015.12.021

Title: Kinetics of gas phase formic acid decomposition on platinum single crystal and polycrystalline surfaces

Authors:: Detwiler, Michael D.; Milligan, Cory A.; Zemlyanov, Dmitry Y.; Delgass, W. Nicholas; Ribeiro, Fabio H.

Publication Date:: Wed Jun 01 00:00:00 EDT 2016

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1252066

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Surface Science

Additional Journal Information:: Journal Name: Surface Science Journal Volume: 648 Journal Issue: C; Journal ID: ISSN 0039-6028

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Detwiler, Michael D., Milligan, Cory A., Zemlyanov, Dmitry Y., Delgass, W. Nicholas, and Ribeiro, Fabio H. Kinetics of gas phase formic acid decomposition on platinum single crystal and polycrystalline surfaces.  Netherlands: N. p., 2016. 
Web.  doi:10.1016/j.susc.2015.12.021.

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                    Detwiler, Michael D., Milligan, Cory A., Zemlyanov, Dmitry Y., Delgass, W. Nicholas, & Ribeiro, Fabio H. Kinetics of gas phase formic acid decomposition on platinum single crystal and polycrystalline surfaces.  Netherlands.  https://doi.org/10.1016/j.susc.2015.12.021

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                    Detwiler, Michael D., Milligan, Cory A., Zemlyanov, Dmitry Y., Delgass, W. Nicholas, and Ribeiro, Fabio H. Wed .  
"Kinetics of gas phase formic acid decomposition on platinum single crystal and polycrystalline surfaces".  Netherlands.  https://doi.org/10.1016/j.susc.2015.12.021.

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@article{osti_1252066,

  title        = {Kinetics of gas phase formic acid decomposition on platinum single crystal and polycrystalline surfaces},

  author       = {Detwiler, Michael D. and Milligan, Cory A. and Zemlyanov, Dmitry Y. and Delgass, W. Nicholas and Ribeiro, Fabio H.},

  abstractNote = {},

  doi          = {10.1016/j.susc.2015.12.021},

  journal      = {Surface Science},

  number       = C,

  volume       = 648,

  place        = {Netherlands},

  year         = {Wed Jun 01 00:00:00 EDT 2016},

  month        = {Wed Jun 01 00:00:00 EDT 2016}

}

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https://doi.org/10.1016/j.susc.2015.12.021

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Works referenced in this record:

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journal, August 1928

Coolidge, Albert Sprague
Journal of the American Chemical Society, Vol. 50, Issue 8
DOI: 10.1021/ja01395a015

Production of CO-free H2 from formic acid. A comparative study of the catalytic behavior of Pt metals on a carbon support
journal, April 2011

Solymosi, F.; Koós, Á.; Liliom, N.
Journal of Catalysis, Vol. 279, Issue 1
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Turnover Rate and Reaction Orders for the Complete Oxidation of Methane on a Palladium Foil in Excess Dioxygen
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Monteiro, R. S.; Zemlyanov, D.; Storey, J. M.
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Hagstrom, S.; Lyon, H. B.; Somorjai, G. A.
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Surface structure change of a [Pt ₄ (µ-CH ₃ COO) ₈ ]/SiO ₂ catalyst active for the decomposition of formic acid
journal, January 1995

Chun, Wang-Jae; Tomishige, Keiichi; Hamakado, Mamiko
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Adsorption of formic acid on clean and oxygen covered Pt(111)
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Avery, Neil R.
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Effect of CO on Pt-catalyzed decomposition of formic acid in ultrahigh vacuum
journal, February 1993

Columbia, M. R.; Crabtree, A. M.; Thiel, P. A.
Journal of Electroanalytical Chemistry, Vol. 345, Issue 1-2
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Surface reaction modification: The effect of structured overlayers of sulfur on the kinetics and mechanism of the decomposition of formic acid on Pt(111)
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Abbas, N.; Madix, R. J.
Applications of Surface Science, Vol. 16, Issue 3-4
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Adsorption study of hydrogen on a stepped Pt (997) surface using low energy recoil scattering
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Koeleman, B. J. J.; de Zwart, S. T.; Boers, A. L.
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Formic acid decomposition on Au catalysts: DFT, microkinetic modeling, and reaction kinetics experiments
journal, February 2014

Singh, Suyash; Li, Sha; Carrasquillo-Flores, Ronald
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Energetics of Formic Acid Conversion to Adsorbed Formates on Pt(111) by Transient Calorimetry
journal, February 2014

Silbaugh, Trent L.; Karp, Eric M.; Campbell, Charles T.
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Coupled theoretical and experimental analysis of surface coverage effects in Pt-catalyzed NO and O2 reaction to NO2 on Pt(111)
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Smeltz, A. D.; Getman, R. B.; Schneider, W. F.
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XPS, EM, and Catalytic Studies of the Accumulation of Carbon on Pt Black
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The interaction of CO and Pt(100). II. Energetic and kinetic parameters
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Similar Records

Title: Kinetics of gas phase formic acid decomposition on platinum single crystal and polycrystalline surfaces

Citation Formats

The Vapor Density and some Other Properties of Formic acid journal, August 1928

Production of CO-free H2 from formic acid. A comparative study of the catalytic behavior of Pt metals on a carbon support journal, April 2011

Turnover Rate and Reaction Orders for the Complete Oxidation of Methane on a Palladium Foil in Excess Dioxygen journal, April 2001

Surface Structures on the Clean Platinum (100) Surface journal, September 1965

Surface structure change of a [Pt 4 (µ-CH 3 COO) 8 ]/SiO 2 catalyst active for the decomposition of formic acid journal, January 1995

Adsorption of formic acid on clean and oxygen covered Pt(111) journal, July 1982

Effect of CO on Pt-catalyzed decomposition of formic acid in ultrahigh vacuum journal, February 1993

Surface reaction modification: The effect of structured overlayers of sulfur on the kinetics and mechanism of the decomposition of formic acid on Pt(111) journal, July 1983

Decomposition of acetic acid monomer, acetic acid dimer, and acetic anhydride on Ni(111) journal, August 1984

Atomic subshell photoionization cross sections and asymmetry parameters: 1 ⩽ Z ⩽ 103 journal, January 1985

Adsorption study of hydrogen on a stepped Pt (997) surface using low energy recoil scattering journal, December 1983

Chemisorption of CO on the Pt(111) surface journal, May 1977

Formic acid decomposition on Au catalysts: DFT, microkinetic modeling, and reaction kinetics experiments journal, February 2014

Energetics of Formic Acid Conversion to Adsorbed Formates on Pt(111) by Transient Calorimetry journal, February 2014

Coupled theoretical and experimental analysis of surface coverage effects in Pt-catalyzed NO and O2 reaction to NO2 on Pt(111) journal, July 2008

XPS, EM, and Catalytic Studies of the Accumulation of Carbon on Pt Black journal, January 2001

The interaction of CO and Pt(100). II. Energetic and kinetic parameters journal, June 1983

Trends in Formic Acid Decomposition on Model Transition Metal Surfaces: A Density Functional Theory study journal, November 2014

Hartree-Slater subshell photoionization cross-sections at 1254 and 1487 eV journal, January 1976

Metallic Corner Atoms in Gold Clusters Supported on Rutile Are the Dominant Active Site during Water−Gas Shift Catalysis journal, October 2010

The Vapor Density and some Other Properties of Formic acid
journal, August 1928

Production of CO-free H2 from formic acid. A comparative study of the catalytic behavior of Pt metals on a carbon support
journal, April 2011

Turnover Rate and Reaction Orders for the Complete Oxidation of Methane on a Palladium Foil in Excess Dioxygen
journal, April 2001

Surface Structures on the Clean Platinum (100) Surface
journal, September 1965

Surface structure change of a [Pt ₄ (µ-CH ₃ COO) ₈ ]/SiO ₂ catalyst active for the decomposition of formic acid
journal, January 1995

Adsorption of formic acid on clean and oxygen covered Pt(111)
journal, July 1982

Effect of CO on Pt-catalyzed decomposition of formic acid in ultrahigh vacuum
journal, February 1993

Surface reaction modification: The effect of structured overlayers of sulfur on the kinetics and mechanism of the decomposition of formic acid on Pt(111)
journal, July 1983

Decomposition of acetic acid monomer, acetic acid dimer, and acetic anhydride on Ni(111)
journal, August 1984

Atomic subshell photoionization cross sections and asymmetry parameters: 1 ⩽ Z ⩽ 103
journal, January 1985

Adsorption study of hydrogen on a stepped Pt (997) surface using low energy recoil scattering
journal, December 1983

Chemisorption of CO on the Pt(111) surface
journal, May 1977

Formic acid decomposition on Au catalysts: DFT, microkinetic modeling, and reaction kinetics experiments
journal, February 2014

Energetics of Formic Acid Conversion to Adsorbed Formates on Pt(111) by Transient Calorimetry
journal, February 2014

Coupled theoretical and experimental analysis of surface coverage effects in Pt-catalyzed NO and O2 reaction to NO2 on Pt(111)
journal, July 2008

XPS, EM, and Catalytic Studies of the Accumulation of Carbon on Pt Black
journal, January 2001

The interaction of CO and Pt(100). II. Energetic and kinetic parameters
journal, June 1983

Trends in Formic Acid Decomposition on Model Transition Metal Surfaces: A Density Functional Theory study
journal, November 2014

Hartree-Slater subshell photoionization cross-sections at 1254 and 1487 eV
journal, January 1976

Metallic Corner Atoms in Gold Clusters Supported on Rutile Are the Dominant Active Site during Water−Gas Shift Catalysis
journal, October 2010