Low temperature, non-stoichiometric oxygen-isotope exchange coupled to Fe(II)–goethite interactions

Frierdich, Andrew J.; Beard, Brian L.; Rosso, Kevin M.; Scherer, Michelle M.; Spicuzza, Michael J.; Valley, John W.; Johnson, Clark M.

doi:10.1016/j.gca.2015.03.029

Title: Low temperature, non-stoichiometric oxygen-isotope exchange coupled to Fe(II)–goethite interactions

Authors:: Frierdich, Andrew J.; Beard, Brian L.; Rosso, Kevin M.; Scherer, Michelle M.; Spicuzza, Michael J.; Valley, John W.; Johnson, Clark M.

Publication Date:: Wed Jul 01 00:00:00 EDT 2015

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1251924

Grant/Contract Number:: FG02-93ER14389

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Geochimica et Cosmochimica Acta

Additional Journal Information:: Journal Name: Geochimica et Cosmochimica Acta Journal Volume: 160 Journal Issue: C; Journal ID: ISSN 0016-7037

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Citation Formats


                    Frierdich, Andrew J., Beard, Brian L., Rosso, Kevin M., Scherer, Michelle M., Spicuzza, Michael J., Valley, John W., and Johnson, Clark M. Low temperature, non-stoichiometric oxygen-isotope exchange coupled to Fe(II)–goethite interactions.  United States: N. p., 2015. 
Web.  doi:10.1016/j.gca.2015.03.029.

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                    Frierdich, Andrew J., Beard, Brian L., Rosso, Kevin M., Scherer, Michelle M., Spicuzza, Michael J., Valley, John W., & Johnson, Clark M. Low temperature, non-stoichiometric oxygen-isotope exchange coupled to Fe(II)–goethite interactions.  United States.  https://doi.org/10.1016/j.gca.2015.03.029

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                    Frierdich, Andrew J., Beard, Brian L., Rosso, Kevin M., Scherer, Michelle M., Spicuzza, Michael J., Valley, John W., and Johnson, Clark M. Wed .  
"Low temperature, non-stoichiometric oxygen-isotope exchange coupled to Fe(II)–goethite interactions".  United States.  https://doi.org/10.1016/j.gca.2015.03.029.

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@article{osti_1251924,

  title        = {Low temperature, non-stoichiometric oxygen-isotope exchange coupled to Fe(II)–goethite interactions},

  author       = {Frierdich, Andrew J. and Beard, Brian L. and Rosso, Kevin M. and Scherer, Michelle M. and Spicuzza, Michael J. and Valley, John W. and Johnson, Clark M.},

  abstractNote = {},

  doi          = {10.1016/j.gca.2015.03.029},

  journal      = {Geochimica et Cosmochimica Acta},

  number       = C,

  volume       = 160,

  place        = {United States},

  year         = {Wed Jul 01 00:00:00 EDT 2015},

  month        = {Wed Jul 01 00:00:00 EDT 2015}

}

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Works referenced in this record:

Iron isotope fractionation during microbial reduction of iron: The importance of adsorption
journal, January 2004

Icopini, G. A.; Anbar, A. D.; Ruebush, S. S.
Geology, Vol. 32, Issue 3
DOI: 10.1130/G20184.1

Paleocene–Eocene climatic variation in western North America: Evidence from the δ18O of pedogenic hematite
journal, September 1999

Bao, Huiming; Koch, Paul L.; Rumble, Douglas
Geological Society of America Bulletin, Vol. 111, Issue 9
DOI: 10.1130/0016-7606(1999)111<1405:PECVIW>2.3.CO;2

Oxygen isotope salt effects at high pressure and high temperature and the calibration of oxygen isotope geothermometers
journal, September 2003

Hu, Guixing; Clayton, Robert N.
Geochimica et Cosmochimica Acta, Vol. 67, Issue 17
DOI: 10.1016/S0016-7037(02)01319-4

Ferrozine---a new spectrophotometric reagent for iron
journal, June 1970

Stookey, Lawrence L.
Analytical Chemistry, Vol. 42, Issue 7, p. 779-781
DOI: 10.1021/ac60289a016

A view of reactions at mineral surfaces from the aqueous phase
journal, June 2001

Casey, W. H.
Mineralogical Magazine, Vol. 65, Issue 3
DOI: 10.1180/002646101300119439

Tracking human travel using stable oxygen and hydrogen isotope analyses of hair and urine
journal, January 2007

O'Brien, Diane M.; Wooller, Matthew J.
Rapid Communications in Mass Spectrometry, Vol. 21, Issue 15
DOI: 10.1002/rcm.3108

Aqueous Aluminum Polynuclear Complexes and Nanoclusters: A Review
journal, January 2001

Casey, W. H.; Phillips, B. L.; Furrer, G.
Reviews in Mineralogy and Geochemistry, Vol. 44, Issue 1
DOI: 10.2138/rmg.2001.44.05

Fe isotope exchange between Fe(II)aq and nanoparticulate mackinawite (FeSm) during nanoparticle growth
journal, November 2010

Guilbaud, Romain; Butler, Ian B.; Ellam, Rob M.
Earth and Planetary Science Letters, Vol. 300, Issue 1-2
DOI: 10.1016/j.epsl.2010.10.004

Connecting Observations of Hematite (α-Fe ₂ O ₃ ) Growth Catalyzed by Fe(II)
journal, January 2010

Rosso, Kevin M.; Yanina, Svetlana V.; Gorski, Christopher A.
Environmental Science & Technology, Vol. 44, Issue 1
DOI: 10.1021/es901882a

Experimental hydrogen isotope studies III: Diffusion of hydrogen in hydrous minerals, and stable isotope exchange in metamorphic rocks
journal, May 1981

Graham, Colin M.
Contributions to Mineralogy and Petrology, Vol. 76, Issue 2
DOI: 10.1007/BF00371961

Oxygen isotopes in an oolitic ironstone and the determination of goethite δ18O values by selective dissolution of impurities: The 5M NaOH method
journal, September 1991

Yapp, Crayton J.
Geochimica et Cosmochimica Acta, Vol. 55, Issue 9
DOI: 10.1016/0016-7037(91)90378-I

Isotopic exchange in mineral-fluid systems. I. Theoretical evaluation of oxygen isotopic exchange accompanying surface reactions and diffusion
journal, October 1983

Cole, David R.; Ohmoto, Hiroshi; Lasaga, Antonio C.
Geochimica et Cosmochimica Acta, Vol. 47, Issue 10
DOI: 10.1016/0016-7037(83)90018-2

Oxygen isotopic composition of ferric oxides from recent soil, hydrologic, and marine environments
journal, July 2000

Bao, Huiming; Koch, Paul L.; Thiemens, Mark H.
Geochimica et Cosmochimica Acta, Vol. 64, Issue 13
DOI: 10.1016/S0016-7037(00)00351-3

Redox potential measurements and Mössbauer spectrometry of FeII adsorbed onto FeIII (oxyhydr)oxides
journal, October 2005

Silvester, Ewen; Charlet, Laurent; Tournassat, Christophe
Geochimica et Cosmochimica Acta, Vol. 69, Issue 20
DOI: 10.1016/j.gca.2005.06.013

Stable Fe isotope fractionations produced by aqueous Fe(II)-hematite surface interactions
journal, August 2010

Wu, Lingling; Beard, Brian L.; Roden, Eric E.
Geochimica et Cosmochimica Acta, Vol. 74, Issue 15
DOI: 10.1016/j.gca.2010.04.060

Oxygen isotope records of goethite from ferricrete deposits indicate regionally varying holocene climate change in the Rocky Mountain region, U.S.A.
journal, January 2004

Sjostrom, Derek J.; Hren, Michael T.; Chamberlain, C. Page
Quaternary Research, Vol. 61, Issue 1
DOI: 10.1016/j.yqres.2003.08.008

Application of Fe isotopes to tracing the geochemical and biological cycling of Fe
journal, April 2003

Beard, Brian L.; Johnson, Clark M.; Skulan, Joseph L.
Chemical Geology, Vol. 195, Issue 1-4
DOI: 10.1016/S0009-2541(02)00390-X

Water Structure and Hydrogen Bonding at Goethite/Water Interfaces: Implications for Proton Affinities
journal, February 2012

Boily, Jean-François
The Journal of Physical Chemistry C, Vol. 116, Issue 7
DOI: 10.1021/jp2110456

Iron isotope fractionation between aqueous ferrous iron and goethite
journal, June 2010

Beard, Brian L.; Handler, Robert M.; Scherer, Michelle M.
Earth and Planetary Science Letters, Vol. 295, Issue 1-2
DOI: 10.1016/j.epsl.2010.04.006

Linked Reactivity at Mineral-Water Interfaces Through Bulk Crystal Conduction
journal, March 2008

Yanina, S. V.; Rosso, K. M.
Science, Vol. 320, Issue 5873
DOI: 10.1126/science.1154833

Oxygen isotopes in synthetic goethite and a model for the apparent pH dependence of goethite–water 18O/16O fractionation
journal, March 2007

Yapp, Crayton J.
Geochimica et Cosmochimica Acta, Vol. 71, Issue 5
DOI: 10.1016/j.gca.2006.11.029

Oxygen and hydrogen isotope variations among goethites (α-FeOOH) and the determination of paleotemperatures
journal, February 1987

Yapp, Crayton J.
Geochimica et Cosmochimica Acta, Vol. 51, Issue 2
DOI: 10.1016/0016-7037(87)90247-X

In situ study of the goethite-hematite phase transformation by real time synchrotron powder diffraction
journal, June 1999

Gualtieri, Alessandro F.; Venturelli, Paolo
American Mineralogist, Vol. 84, Issue 5-6
DOI: 10.2138/am-1999-5-624

Determination of the Fe(II)aq–magnetite equilibrium iron isotope fractionation factor using the three-isotope method and a multi-direction approach to equilibrium
journal, April 2014

Frierdich, Andrew J.; Beard, Brian L.; Scherer, Michelle M.
Earth and Planetary Science Letters, Vol. 391
DOI: 10.1016/j.epsl.2014.01.032

An iron isotope signature related to electron transfer between aqueous ferrous iron and goethite
journal, May 2008

Jang, Je-Hun; Mathur, Ryan; Liermann, Laura J.
Chemical Geology, Vol. 250, Issue 1-4
DOI: 10.1016/j.chemgeo.2008.02.002

Fe Electron Transfer and Atom Exchange in Goethite: Influence of Al-Substitution and Anion Sorption
journal, September 2012

Latta, Drew E.; Bachman, Jonathan E.; Scherer, Michelle M.
Environmental Science & Technology, Vol. 46, Issue 19
DOI: 10.1021/es302094a

Goethite nanoparticle aggregation: effects of buffers, metal ions, and 4-chloronitrobenzene reduction
journal, January 2014

Stemig, Amanda M.; Do, Tram Anh; Yuwono, Virany M.
Environ. Sci.: Nano, Vol. 1, Issue 5
DOI: 10.1039/C3EN00063J

18O-Water exchange in photosystem II: Substrate binding and intermediates of the water splitting cycle
journal, February 2008

Hillier, W.; Wydrzynski, T.
Coordination Chemistry Reviews, Vol. 252, Issue 3-4
DOI: 10.1016/j.ccr.2007.09.004

Proton-promoted dissolution of α-FeOOH nanorods and microrods: Size dependence, anion effects (carbonate and phosphate), aggregation and surface adsorption
journal, November 2012

Rubasinghege, Gayan; Kyei, Patrick K.; Scherer, Michelle M.
Journal of Colloid and Interface Science, Vol. 385, Issue 1
DOI: 10.1016/j.jcis.2012.06.049

The effects of metamorphism on O and Fe isotope compositions in the Biwabik Iron Formation, northern Minnesota
journal, September 2007

Hyslop, Elizabeth Valaas; Valley, John W.; Johnson, Clark M.
Contributions to Mineralogy and Petrology, Vol. 155, Issue 3
DOI: 10.1007/s00410-007-0244-2

Climatic implications of surface domains in arrays of δD and δ18O from hydroxyl minerals: goethite as an example
journal, June 2000

Yapp, Crayton J.
Geochimica et Cosmochimica Acta, Vol. 64, Issue 12
DOI: 10.1016/S0016-7037(00)00347-1

Unraveling climatic changes from intraprofile variation in oxygen and hydrogen isotopic composition of goethite and kaolinite in laterites: an integrated study from Yaou, French Guiana
journal, February 2000

Girard, Jean-Pierre; Freyssinet, Philippe; Chazot, Gilles
Geochimica et Cosmochimica Acta, Vol. 64, Issue 3
DOI: 10.1016/S0016-7037(99)00299-9

Oxygen-Isotope Fractionations in Systems Containing Dolomite
journal, March 1966

Northrop, David A.; Clayton, Robert N.
The Journal of Geology, Vol. 74, Issue 2
DOI: 10.1086/627153

Fast transformation of iron oxyhydroxides by the catalytic action of aqueous Fe(II)
journal, August 2005

Pedersen, Hanne D.; Postma, Dieke; Jakobsen, Rasmus
Geochimica et Cosmochimica Acta, Vol. 69, Issue 16
DOI: 10.1016/j.gca.2005.03.016

Oxygen isotope fractionation in ferric oxide-water systems: low temperature synthesis
journal, March 1999

Bao, Huiming; Koch, Paul L.
Geochimica et Cosmochimica Acta, Vol. 63, Issue 5
DOI: 10.1016/S0016-7037(99)00005-8

Iron isotope fractionation between aqueous Fe(II) and goethite revisited: New insights based on a multi-direction approach to equilibrium and isotopic exchange rate modification
journal, August 2014

Frierdich, Andrew J.; Beard, Brian L.; Reddy, Thiruchelvi R.
Geochimica et Cosmochimica Acta, Vol. 139
DOI: 10.1016/j.gca.2014.05.001

Stable Iron Isotope Fractionation Between Aqueous Fe(II) and Hydrous Ferric Oxide
journal, March 2011

Wu, Lingling; Beard, Brian L.; Roden, Eric E.
Environmental Science & Technology, Vol. 45, Issue 5
DOI: 10.1021/es103171x

18O/16O and D/H in goethite from a North American Oxisol of the Early Eocene climatic optimum
journal, December 2008

Yapp, Crayton J.
Geochimica et Cosmochimica Acta, Vol. 72, Issue 23
DOI: 10.1016/j.gca.2008.09.002

Rates of Water Exchange on the [Fe ₄ (OH) ₂ (hpdta) ₂ (H ₂ O) ₄ ] ⁰ Molecule and Its Implications for Geochemistry
journal, June 2012

Panasci, Adele F.; Ohlin, C. André; Harley, Stephen J.
Inorganic Chemistry, Vol. 51, Issue 12
DOI: 10.1021/ic300370q

Ligand Substitution Reactions at Inorganic Centers ^†
journal, June 2005

Richens, David T.
Chemical Reviews, Vol. 105, Issue 6
DOI: 10.1021/cr030705u

Stable isotope and Rare Earth Element evidence for recent ironstone pods within the Archean Barberton greenstone belt, South Africa
journal, March 2006

Hren, Michael T.; Lowe, Donald R.; Tice, Michael M.
Geochimica et Cosmochimica Acta, Vol. 70, Issue 6
DOI: 10.1016/j.gca.2005.11.016

Isotopic evidence for Holocene climate change in the northern Rockies from a goethite-rich ferricrete chronosequence
journal, May 2000

Poage, Michael A.; Sjostrom, Derek J.; Goldberg, Judd
Chemical Geology, Vol. 166, Issue 3-4
DOI: 10.1016/S0009-2541(99)00220-X

Size-Driven Structural and Thermodynamic Complexity in Iron Oxides
journal, March 2008

Navrotsky, A.; Mazeina, L.; Majzlan, J.
Science, Vol. 319, Issue 5870
DOI: 10.1126/science.1148614

UWG-2, a garnet standard for oxygen isotope ratios: Strategies for high precision and accuracy with laser heating
journal, December 1995

Valley, John W.; Kitchen, Nami; Kohn, Matthew J.
Geochimica et Cosmochimica Acta, Vol. 59, Issue 24
DOI: 10.1016/0016-7037(95)00386-X

Oxygen isotope fractionation between hydroxide minerals and water
journal, February 1998

Zheng, Yong-Fei
Physics and Chemistry of Minerals, Vol. 25, Issue 3
DOI: 10.1007/s002690050105

Oxygen isotope study of Cayenne duricrust paleosurfaces: implications for past climate and laterization processes over French Guiana
journal, November 2002

Girard, Jean-Pierre; Freyssinet, Philippe; Morillon, Anne-Claire
Chemical Geology, Vol. 191, Issue 4
DOI: 10.1016/S0009-2541(02)00130-4

Stable isotope ratios of tap water in the contiguous United States: STABLE ISOTOPE RATIOS OF TAP WATER
journal, March 2007

Bowen, Gabriel J.; Ehleringer, James R.; Chesson, Lesley A.
Water Resources Research, Vol. 43, Issue 3
DOI: 10.1029/2006WR005186

Iron isotope fractionation and atom exchange during sorption of ferrous iron to mineral surfaces
journal, April 2009

Mikutta, Christian; Wiederhold, Jan G.; Cirpka, Olaf A.
Geochimica et Cosmochimica Acta, Vol. 73, Issue 7
DOI: 10.1016/j.gca.2009.01.014

Kinetic theory of oxygen isotopic exchange between minerals and water
journal, May 1987

Criss, R. E.; Gregory, R. T.; Taylor, H. P.
Geochimica et Cosmochimica Acta, Vol. 51, Issue 5
DOI: 10.1016/0016-7037(87)90203-1

High-pressure oxygen-17 NMR evidence for a gradual mechanistic changeover from Ia to Id for water exchange on divalent octahedral metal ions going from manganese(II) to nickel(II)
journal, December 1980

Ducommun, Yves; Newman, Kenneth E.; Merbach, Andre E.
Inorganic Chemistry, Vol. 19, Issue 12
DOI: 10.1021/ic50214a025

Inhibition of Trace Element Release During Fe(II)-Activated Recrystallization of Al-, Cr-, and Sn-Substituted Goethite and Hematite
journal, September 2012

Frierdich, Andrew J.; Scherer, Michelle M.; Bachman, Jonathan E.
Environmental Science & Technology, Vol. 46, Issue 18
DOI: 10.1021/es302137d

Contrasting behavior of oxygen and iron isotopes in banded iron formations revealed by in situ isotopic analysis
journal, December 2013

Li, Weiqiang; Huberty, Jason M.; Beard, Brian L.
Earth and Planetary Science Letters, Vol. 384
DOI: 10.1016/j.epsl.2013.10.014

Fe(II)-Catalyzed Recrystallization of Goethite Revisited
journal, September 2014

Handler, Robert M.; Frierdich, Andrew J.; Johnson, Clark M.
Environmental Science & Technology, Vol. 48, Issue 19
DOI: 10.1021/es503084u

Laser oxygen isotope analysis of weathering goethite from the lateritic profile of Yaou, French Guiana: paleoweathering and paleoclimatic implications
journal, March 1997

Girard, Jean-Pierre; Razanadranorosoa, Doris; Freyssinet, Philippe
Applied Geochemistry, Vol. 12, Issue 2
DOI: 10.1016/S0883-2927(96)00062-5

Modeling of iron diffusion in the iron oxides magnetite and hematite with variable stoichiometry
journal, January 2011

Hallström, Samuel; Höglund, Lars; Ågren, John
Acta Materialia, Vol. 59, Issue 1
DOI: 10.1016/j.actamat.2010.08.032

The flux of oxygen from the basal surface of gibbsite (α-Al(OH)3) at equilibrium
journal, September 2004

Rosenqvist, Jörgen; Casey, William H.
Geochimica et Cosmochimica Acta, Vol. 68, Issue 17
DOI: 10.1016/j.gca.2004.02.022

Rusty Relics of Earth History: Iron(III) Oxides, Isotopes, and Surficial Environments
journal, May 2001

Yapp, Crayton
Annual Review of Earth and Planetary Sciences, Vol. 29, Issue 1
DOI: 10.1146/annurev.earth.29.1.165

Paleoenvironment and the oxygen isotope geochemistry of ironstone of the Upper Ordovician Neda Formation, Wisconsin, USA
journal, May 1993

Yapp, Crayton J.
Geochimica et Cosmochimica Acta, Vol. 57, Issue 10
DOI: 10.1016/0016-7037(93)90572-E

High-pressure oxygen-17 Fourier transform nuclear magnetic resonance spectroscopy. Mechanism of water exchange on iron(III) in acidic aqueous solution
journal, December 1981

Swaddle, Thomas W.; Merbach, Andre E.
Inorganic Chemistry, Vol. 20, Issue 12
DOI: 10.1021/ic50226a036

Effect of Solution and Solid-Phase Conditions on the Fe(II)-Accelerated Transformation of Ferrihydrite to Lepidocrocite and Goethite
journal, April 2014

Boland, Daniel D.; Collins, Richard N.; Miller, Christopher J.
Environmental Science & Technology, Vol. 48, Issue 10
DOI: 10.1021/es4043275

Interpreting nanoscale size-effects in aggregated Fe-oxide suspensions: Reaction of Fe(II) with Goethite
journal, March 2008

Cwiertny, David M.; Handler, Robert M.; Schaefer, Michael V.
Geochimica et Cosmochimica Acta, Vol. 72, Issue 5
DOI: 10.1016/j.gca.2007.12.018

Atom Exchange between Aqueous Fe(II) and Goethite: An Fe Isotope Tracer Study
journal, February 2009

Handler, Robert M.; Beard, Brian L.; Johnson, Clark M.
Environmental Science & Technology, Vol. 43, Issue 4
DOI: 10.1021/es802402m

Oxygen isotopes in iron (III) oxides
journal, July 1990

Yapp, Crayton J.
Chemical Geology, Vol. 85, Issue 3-4
DOI: 10.1016/0009-2541(90)90010-5

Paleoenvironmental interpretations of oxygen isotope ratios in oolitic ironstones
journal, July 1998

Yapp, Crayton J.
Geochimica et Cosmochimica Acta, Vol. 62, Issue 14
DOI: 10.1016/S0016-7037(98)00164-1

Oxygen isotope effects associated with substitution of Al for Fe in synthetic goethite: Some experimental evidence and the criterion of oxygen yield
journal, November 2012

Yapp, Crayton J.
Geochimica et Cosmochimica Acta, Vol. 97
DOI: 10.1016/j.gca.2012.09.007

Rates of Ligand Exchange between >Fe ^III −OH ₂ Functional Groups on a Nanometer-Sized Aqueous Cluster and Bulk Solution
journal, August 2007

Balogh, Edina; Todea, Ana Maria; Müller, Achim
Inorganic Chemistry, Vol. 46, Issue 17
DOI: 10.1021/ic7009308

Hydrated goethite (α-FeOOH) (100) interface structure: Ordered water and surface functional groups
journal, April 2010

Ghose, Sanjit K.; Waychunas, Glenn A.; Trainor, Thomas P.
Geochimica et Cosmochimica Acta, Vol. 74, Issue 7
DOI: 10.1016/j.gca.2009.12.015

Exchange and fractionation of Mg isotopes between epsomite and saturated MgSO4 solution
journal, April 2011

Li, Weiqiang; Beard, Brian L.; Johnson, Clark M.
Geochimica et Cosmochimica Acta, Vol. 75, Issue 7
DOI: 10.1016/j.gca.2011.01.023

Spectroscopic Evidence for Fe(II)−Fe(III) Electron Transfer at the Iron Oxide−Water Interface
journal, September 2004

Williams, Aaron G. B.; Scherer, Michelle M.
Environmental Science & Technology, Vol. 38, Issue 18
DOI: 10.1021/es049373g

The determination of labile Fe in ferrihydrite by ascorbic acid extraction: Methodology, dissolution kinetics and loss of solubility with age and de-watering
journal, November 2010

Raiswell, Rob; Vu, Hong Phuc; Brinza, Loredana
Chemical Geology, Vol. 278, Issue 1-2
DOI: 10.1016/j.chemgeo.2010.09.002

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Title: Low temperature, non-stoichiometric oxygen-isotope exchange coupled to Fe(II)–goethite interactions

Citation Formats

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Fe isotope exchange between Fe(II)aq and nanoparticulate mackinawite (FeSm) during nanoparticle growth journal, November 2010

Connecting Observations of Hematite (α-Fe 2 O 3 ) Growth Catalyzed by Fe(II) journal, January 2010

Experimental hydrogen isotope studies III: Diffusion of hydrogen in hydrous minerals, and stable isotope exchange in metamorphic rocks journal, May 1981

Oxygen isotopes in an oolitic ironstone and the determination of goethite δ18O values by selective dissolution of impurities: The 5M NaOH method journal, September 1991

Isotopic exchange in mineral-fluid systems. I. Theoretical evaluation of oxygen isotopic exchange accompanying surface reactions and diffusion journal, October 1983

Oxygen isotopic composition of ferric oxides from recent soil, hydrologic, and marine environments journal, July 2000

Redox potential measurements and Mössbauer spectrometry of FeII adsorbed onto FeIII (oxyhydr)oxides journal, October 2005

Stable Fe isotope fractionations produced by aqueous Fe(II)-hematite surface interactions journal, August 2010

Oxygen isotope records of goethite from ferricrete deposits indicate regionally varying holocene climate change in the Rocky Mountain region, U.S.A. journal, January 2004

Application of Fe isotopes to tracing the geochemical and biological cycling of Fe journal, April 2003

Water Structure and Hydrogen Bonding at Goethite/Water Interfaces: Implications for Proton Affinities journal, February 2012

Iron isotope fractionation between aqueous ferrous iron and goethite journal, June 2010

Linked Reactivity at Mineral-Water Interfaces Through Bulk Crystal Conduction journal, March 2008

Oxygen isotopes in synthetic goethite and a model for the apparent pH dependence of goethite–water 18O/16O fractionation journal, March 2007

Oxygen and hydrogen isotope variations among goethites (α-FeOOH) and the determination of paleotemperatures journal, February 1987

In situ study of the goethite-hematite phase transformation by real time synchrotron powder diffraction journal, June 1999

Determination of the Fe(II)aq–magnetite equilibrium iron isotope fractionation factor using the three-isotope method and a multi-direction approach to equilibrium journal, April 2014

An iron isotope signature related to electron transfer between aqueous ferrous iron and goethite journal, May 2008

Fe Electron Transfer and Atom Exchange in Goethite: Influence of Al-Substitution and Anion Sorption journal, September 2012

Goethite nanoparticle aggregation: effects of buffers, metal ions, and 4-chloronitrobenzene reduction journal, January 2014

18O-Water exchange in photosystem II: Substrate binding and intermediates of the water splitting cycle journal, February 2008

Proton-promoted dissolution of α-FeOOH nanorods and microrods: Size dependence, anion effects (carbonate and phosphate), aggregation and surface adsorption journal, November 2012

The effects of metamorphism on O and Fe isotope compositions in the Biwabik Iron Formation, northern Minnesota journal, September 2007

Climatic implications of surface domains in arrays of δD and δ18O from hydroxyl minerals: goethite as an example journal, June 2000

Unraveling climatic changes from intraprofile variation in oxygen and hydrogen isotopic composition of goethite and kaolinite in laterites: an integrated study from Yaou, French Guiana journal, February 2000

Oxygen-Isotope Fractionations in Systems Containing Dolomite journal, March 1966

Fast transformation of iron oxyhydroxides by the catalytic action of aqueous Fe(II) journal, August 2005

Oxygen isotope fractionation in ferric oxide-water systems: low temperature synthesis journal, March 1999

Iron isotope fractionation between aqueous Fe(II) and goethite revisited: New insights based on a multi-direction approach to equilibrium and isotopic exchange rate modification journal, August 2014

Stable Iron Isotope Fractionation Between Aqueous Fe(II) and Hydrous Ferric Oxide journal, March 2011

18O/16O and D/H in goethite from a North American Oxisol of the Early Eocene climatic optimum journal, December 2008

Rates of Water Exchange on the [Fe 4 (OH) 2 (hpdta) 2 (H 2 O) 4 ] 0 Molecule and Its Implications for Geochemistry journal, June 2012

Ligand Substitution Reactions at Inorganic Centers † journal, June 2005

Stable isotope and Rare Earth Element evidence for recent ironstone pods within the Archean Barberton greenstone belt, South Africa journal, March 2006

Isotopic evidence for Holocene climate change in the northern Rockies from a goethite-rich ferricrete chronosequence journal, May 2000

Size-Driven Structural and Thermodynamic Complexity in Iron Oxides journal, March 2008

UWG-2, a garnet standard for oxygen isotope ratios: Strategies for high precision and accuracy with laser heating journal, December 1995

Oxygen isotope fractionation between hydroxide minerals and water journal, February 1998

Oxygen isotope study of Cayenne duricrust paleosurfaces: implications for past climate and laterization processes over French Guiana journal, November 2002

Stable isotope ratios of tap water in the contiguous United States: STABLE ISOTOPE RATIOS OF TAP WATER journal, March 2007

Iron isotope fractionation and atom exchange during sorption of ferrous iron to mineral surfaces journal, April 2009

Kinetic theory of oxygen isotopic exchange between minerals and water journal, May 1987

High-pressure oxygen-17 NMR evidence for a gradual mechanistic changeover from Ia to Id for water exchange on divalent octahedral metal ions going from manganese(II) to nickel(II) journal, December 1980

Inhibition of Trace Element Release During Fe(II)-Activated Recrystallization of Al-, Cr-, and Sn-Substituted Goethite and Hematite journal, September 2012

Contrasting behavior of oxygen and iron isotopes in banded iron formations revealed by in situ isotopic analysis journal, December 2013

Fe(II)-Catalyzed Recrystallization of Goethite Revisited journal, September 2014

Laser oxygen isotope analysis of weathering goethite from the lateritic profile of Yaou, French Guiana: paleoweathering and paleoclimatic implications journal, March 1997

Modeling of iron diffusion in the iron oxides magnetite and hematite with variable stoichiometry journal, January 2011

The flux of oxygen from the basal surface of gibbsite (α-Al(OH)3) at equilibrium journal, September 2004

Rusty Relics of Earth History: Iron(III) Oxides, Isotopes, and Surficial Environments journal, May 2001

Paleoenvironment and the oxygen isotope geochemistry of ironstone of the Upper Ordovician Neda Formation, Wisconsin, USA journal, May 1993

High-pressure oxygen-17 Fourier transform nuclear magnetic resonance spectroscopy. Mechanism of water exchange on iron(III) in acidic aqueous solution journal, December 1981

Effect of Solution and Solid-Phase Conditions on the Fe(II)-Accelerated Transformation of Ferrihydrite to Lepidocrocite and Goethite journal, April 2014

Interpreting nanoscale size-effects in aggregated Fe-oxide suspensions: Reaction of Fe(II) with Goethite journal, March 2008

Atom Exchange between Aqueous Fe(II) and Goethite: An Fe Isotope Tracer Study journal, February 2009

Oxygen isotopes in iron (III) oxides journal, July 1990

Paleoenvironmental interpretations of oxygen isotope ratios in oolitic ironstones journal, July 1998

Oxygen isotope effects associated with substitution of Al for Fe in synthetic goethite: Some experimental evidence and the criterion of oxygen yield journal, November 2012

Rates of Ligand Exchange between >Fe III −OH 2 Functional Groups on a Nanometer-Sized Aqueous Cluster and Bulk Solution journal, August 2007

Hydrated goethite (α-FeOOH) (100) interface structure: Ordered water and surface functional groups journal, April 2010

Exchange and fractionation of Mg isotopes between epsomite and saturated MgSO4 solution journal, April 2011

Spectroscopic Evidence for Fe(II)−Fe(III) Electron Transfer at the Iron Oxide−Water Interface journal, September 2004

The determination of labile Fe in ferrihydrite by ascorbic acid extraction: Methodology, dissolution kinetics and loss of solubility with age and de-watering journal, November 2010

Iron isotope fractionation during microbial reduction of iron: The importance of adsorption
journal, January 2004

Paleocene–Eocene climatic variation in western North America: Evidence from the δ18O of pedogenic hematite
journal, September 1999

Oxygen isotope salt effects at high pressure and high temperature and the calibration of oxygen isotope geothermometers
journal, September 2003

Ferrozine---a new spectrophotometric reagent for iron
journal, June 1970

A view of reactions at mineral surfaces from the aqueous phase
journal, June 2001

Tracking human travel using stable oxygen and hydrogen isotope analyses of hair and urine
journal, January 2007

Aqueous Aluminum Polynuclear Complexes and Nanoclusters: A Review
journal, January 2001

Fe isotope exchange between Fe(II)aq and nanoparticulate mackinawite (FeSm) during nanoparticle growth
journal, November 2010

Connecting Observations of Hematite (α-Fe ₂ O ₃ ) Growth Catalyzed by Fe(II)
journal, January 2010

Experimental hydrogen isotope studies III: Diffusion of hydrogen in hydrous minerals, and stable isotope exchange in metamorphic rocks
journal, May 1981

Oxygen isotopes in an oolitic ironstone and the determination of goethite δ18O values by selective dissolution of impurities: The 5M NaOH method
journal, September 1991

Isotopic exchange in mineral-fluid systems. I. Theoretical evaluation of oxygen isotopic exchange accompanying surface reactions and diffusion
journal, October 1983

Oxygen isotopic composition of ferric oxides from recent soil, hydrologic, and marine environments
journal, July 2000

Redox potential measurements and Mössbauer spectrometry of FeII adsorbed onto FeIII (oxyhydr)oxides
journal, October 2005

Stable Fe isotope fractionations produced by aqueous Fe(II)-hematite surface interactions
journal, August 2010

Oxygen isotope records of goethite from ferricrete deposits indicate regionally varying holocene climate change in the Rocky Mountain region, U.S.A.
journal, January 2004

Application of Fe isotopes to tracing the geochemical and biological cycling of Fe
journal, April 2003

Water Structure and Hydrogen Bonding at Goethite/Water Interfaces: Implications for Proton Affinities
journal, February 2012

Iron isotope fractionation between aqueous ferrous iron and goethite
journal, June 2010

Linked Reactivity at Mineral-Water Interfaces Through Bulk Crystal Conduction
journal, March 2008

Oxygen isotopes in synthetic goethite and a model for the apparent pH dependence of goethite–water 18O/16O fractionation
journal, March 2007

Oxygen and hydrogen isotope variations among goethites (α-FeOOH) and the determination of paleotemperatures
journal, February 1987

In situ study of the goethite-hematite phase transformation by real time synchrotron powder diffraction
journal, June 1999

Determination of the Fe(II)aq–magnetite equilibrium iron isotope fractionation factor using the three-isotope method and a multi-direction approach to equilibrium
journal, April 2014

An iron isotope signature related to electron transfer between aqueous ferrous iron and goethite
journal, May 2008

Fe Electron Transfer and Atom Exchange in Goethite: Influence of Al-Substitution and Anion Sorption
journal, September 2012

Goethite nanoparticle aggregation: effects of buffers, metal ions, and 4-chloronitrobenzene reduction
journal, January 2014

18O-Water exchange in photosystem II: Substrate binding and intermediates of the water splitting cycle
journal, February 2008

Proton-promoted dissolution of α-FeOOH nanorods and microrods: Size dependence, anion effects (carbonate and phosphate), aggregation and surface adsorption
journal, November 2012

The effects of metamorphism on O and Fe isotope compositions in the Biwabik Iron Formation, northern Minnesota
journal, September 2007

Climatic implications of surface domains in arrays of δD and δ18O from hydroxyl minerals: goethite as an example
journal, June 2000

Unraveling climatic changes from intraprofile variation in oxygen and hydrogen isotopic composition of goethite and kaolinite in laterites: an integrated study from Yaou, French Guiana
journal, February 2000

Oxygen-Isotope Fractionations in Systems Containing Dolomite
journal, March 1966

Fast transformation of iron oxyhydroxides by the catalytic action of aqueous Fe(II)
journal, August 2005

Oxygen isotope fractionation in ferric oxide-water systems: low temperature synthesis
journal, March 1999

Iron isotope fractionation between aqueous Fe(II) and goethite revisited: New insights based on a multi-direction approach to equilibrium and isotopic exchange rate modification
journal, August 2014

Stable Iron Isotope Fractionation Between Aqueous Fe(II) and Hydrous Ferric Oxide
journal, March 2011

18O/16O and D/H in goethite from a North American Oxisol of the Early Eocene climatic optimum
journal, December 2008

Rates of Water Exchange on the [Fe ₄ (OH) ₂ (hpdta) ₂ (H ₂ O) ₄ ] ⁰ Molecule and Its Implications for Geochemistry
journal, June 2012

Ligand Substitution Reactions at Inorganic Centers ^†
journal, June 2005

Stable isotope and Rare Earth Element evidence for recent ironstone pods within the Archean Barberton greenstone belt, South Africa
journal, March 2006

Isotopic evidence for Holocene climate change in the northern Rockies from a goethite-rich ferricrete chronosequence
journal, May 2000

Size-Driven Structural and Thermodynamic Complexity in Iron Oxides
journal, March 2008

UWG-2, a garnet standard for oxygen isotope ratios: Strategies for high precision and accuracy with laser heating
journal, December 1995

Oxygen isotope fractionation between hydroxide minerals and water
journal, February 1998

Oxygen isotope study of Cayenne duricrust paleosurfaces: implications for past climate and laterization processes over French Guiana
journal, November 2002

Stable isotope ratios of tap water in the contiguous United States: STABLE ISOTOPE RATIOS OF TAP WATER
journal, March 2007

Iron isotope fractionation and atom exchange during sorption of ferrous iron to mineral surfaces
journal, April 2009

Kinetic theory of oxygen isotopic exchange between minerals and water
journal, May 1987

High-pressure oxygen-17 NMR evidence for a gradual mechanistic changeover from Ia to Id for water exchange on divalent octahedral metal ions going from manganese(II) to nickel(II)
journal, December 1980

Inhibition of Trace Element Release During Fe(II)-Activated Recrystallization of Al-, Cr-, and Sn-Substituted Goethite and Hematite
journal, September 2012

Contrasting behavior of oxygen and iron isotopes in banded iron formations revealed by in situ isotopic analysis
journal, December 2013

Fe(II)-Catalyzed Recrystallization of Goethite Revisited
journal, September 2014

Laser oxygen isotope analysis of weathering goethite from the lateritic profile of Yaou, French Guiana: paleoweathering and paleoclimatic implications
journal, March 1997

Modeling of iron diffusion in the iron oxides magnetite and hematite with variable stoichiometry
journal, January 2011

The flux of oxygen from the basal surface of gibbsite (α-Al(OH)3) at equilibrium
journal, September 2004

Rusty Relics of Earth History: Iron(III) Oxides, Isotopes, and Surficial Environments
journal, May 2001

Paleoenvironment and the oxygen isotope geochemistry of ironstone of the Upper Ordovician Neda Formation, Wisconsin, USA
journal, May 1993

High-pressure oxygen-17 Fourier transform nuclear magnetic resonance spectroscopy. Mechanism of water exchange on iron(III) in acidic aqueous solution
journal, December 1981

Effect of Solution and Solid-Phase Conditions on the Fe(II)-Accelerated Transformation of Ferrihydrite to Lepidocrocite and Goethite
journal, April 2014

Interpreting nanoscale size-effects in aggregated Fe-oxide suspensions: Reaction of Fe(II) with Goethite
journal, March 2008

Atom Exchange between Aqueous Fe(II) and Goethite: An Fe Isotope Tracer Study
journal, February 2009

Oxygen isotopes in iron (III) oxides
journal, July 1990

Paleoenvironmental interpretations of oxygen isotope ratios in oolitic ironstones
journal, July 1998

Oxygen isotope effects associated with substitution of Al for Fe in synthetic goethite: Some experimental evidence and the criterion of oxygen yield
journal, November 2012

Rates of Ligand Exchange between >Fe ^III −OH ₂ Functional Groups on a Nanometer-Sized Aqueous Cluster and Bulk Solution
journal, August 2007

Hydrated goethite (α-FeOOH) (100) interface structure: Ordered water and surface functional groups
journal, April 2010

Exchange and fractionation of Mg isotopes between epsomite and saturated MgSO4 solution
journal, April 2011

Spectroscopic Evidence for Fe(II)−Fe(III) Electron Transfer at the Iron Oxide−Water Interface
journal, September 2004

The determination of labile Fe in ferrihydrite by ascorbic acid extraction: Methodology, dissolution kinetics and loss of solubility with age and de-watering
journal, November 2010