[NiIII(OMe)]-mediated reductive activation of CO2 affording a Ni(κ1-OCO) complex
Abstract
Here, carbon dioxide is expected to be employed as an inexpensive and potential feedstock of C1 sources for the mass production of valuable chemicals and fuel. Versatile chemical transformations of CO2, i.e. insertion of CO2 producing bicarbonate/acetate/formate, cleavage of CO2 yielding μ-CO/μ-oxo transition-metal complexes, and electrocatalytic reduction of CO2 affording CO/HCOOH/CH3OH/CH4/C2H4/oxalate were well documented. Herein, we report a novel pathway for the reductive activation of CO2 by the [NiIII(OMe)(P(C6H3-3-SiMe3-2-S)3)]– complex, yielding the [NiIII(κ1-OCO˙–)(P(C6H3-3-SiMe3-2-S)3)]– complex. The formation of this unusual NiIII(κ1-OCO˙–) complex was characterized by single-crystal X-ray diffraction, EPR, IR, SQUID, Ni/S K-edge X-ray absorption spectroscopy, and Ni valence-to-core X-ray emission spectroscopy. The inertness of the analogous complexes [NiIII(SPh)], [NiII(CO)], and [NiII(N2H4)] toward CO2, in contrast, demonstrates that the ionic [NiIII(OMe)] core attracts the binding of weak σ-donor CO2 and triggers the subsequent reduction of CO2 by the nucleophilic [OMe]– in the immediate vicinity. This metal–ligand cooperative activation of CO2 may open a novel pathway promoting the subsequent incorporation of CO2 in the buildup of functionalized products.
- Authors:
-
- National Tsing Hua Univ., Hsinchu (Taiwan)
- Chung Yuan Christian Univ., Taoyuan (Taiwan)
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- National Taiwan Normal Univ., Taipei (Taiwan)
- National Synchrotron Radiation Research Center, Hsinchu (Taiwan)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1251399
- Grant/Contract Number:
- AC02-76SF00515
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Volume: 1021; Journal Issue: C; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Chiou, Tzung -Wen, Tseng, Yen -Ming, Lu, Tsai -Te, Weng, Tsu -Chien, Sokaras, Dimosthenes, Ho, Wei -Chieh, Kuo, Ting -Shen, Jang, Ling -Yun, Lee, Jyh -Fu, and Liaw, Wen -Feng. [NiIII(OMe)]-mediated reductive activation of CO2 affording a Ni(κ1-OCO) complex. United States: N. p., 2016.
Web. doi:10.1039/C5SC04652A.
Chiou, Tzung -Wen, Tseng, Yen -Ming, Lu, Tsai -Te, Weng, Tsu -Chien, Sokaras, Dimosthenes, Ho, Wei -Chieh, Kuo, Ting -Shen, Jang, Ling -Yun, Lee, Jyh -Fu, & Liaw, Wen -Feng. [NiIII(OMe)]-mediated reductive activation of CO2 affording a Ni(κ1-OCO) complex. United States. doi:10.1039/C5SC04652A.
Chiou, Tzung -Wen, Tseng, Yen -Ming, Lu, Tsai -Te, Weng, Tsu -Chien, Sokaras, Dimosthenes, Ho, Wei -Chieh, Kuo, Ting -Shen, Jang, Ling -Yun, Lee, Jyh -Fu, and Liaw, Wen -Feng. Wed .
"[NiIII(OMe)]-mediated reductive activation of CO2 affording a Ni(κ1-OCO) complex". United States. doi:10.1039/C5SC04652A. https://www.osti.gov/servlets/purl/1251399.
@article{osti_1251399,
title = {[NiIII(OMe)]-mediated reductive activation of CO2 affording a Ni(κ1-OCO) complex},
author = {Chiou, Tzung -Wen and Tseng, Yen -Ming and Lu, Tsai -Te and Weng, Tsu -Chien and Sokaras, Dimosthenes and Ho, Wei -Chieh and Kuo, Ting -Shen and Jang, Ling -Yun and Lee, Jyh -Fu and Liaw, Wen -Feng},
abstractNote = {Here, carbon dioxide is expected to be employed as an inexpensive and potential feedstock of C1 sources for the mass production of valuable chemicals and fuel. Versatile chemical transformations of CO2, i.e. insertion of CO2 producing bicarbonate/acetate/formate, cleavage of CO2 yielding μ-CO/μ-oxo transition-metal complexes, and electrocatalytic reduction of CO2 affording CO/HCOOH/CH3OH/CH4/C2H4/oxalate were well documented. Herein, we report a novel pathway for the reductive activation of CO2 by the [NiIII(OMe)(P(C6H3-3-SiMe3-2-S)3)]– complex, yielding the [NiIII(κ1-OCO˙–)(P(C6H3-3-SiMe3-2-S)3)]– complex. The formation of this unusual NiIII(κ1-OCO˙–) complex was characterized by single-crystal X-ray diffraction, EPR, IR, SQUID, Ni/S K-edge X-ray absorption spectroscopy, and Ni valence-to-core X-ray emission spectroscopy. The inertness of the analogous complexes [NiIII(SPh)], [NiII(CO)], and [NiII(N2H4)] toward CO2, in contrast, demonstrates that the ionic [NiIII(OMe)] core attracts the binding of weak σ-donor CO2 and triggers the subsequent reduction of CO2 by the nucleophilic [OMe]– in the immediate vicinity. This metal–ligand cooperative activation of CO2 may open a novel pathway promoting the subsequent incorporation of CO2 in the buildup of functionalized products.},
doi = {10.1039/C5SC04652A},
journal = {Chemical Science},
number = C,
volume = 1021,
place = {United States},
year = {2016},
month = {2}
}
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Works referenced in this record:
Mononuclear Nickel(III) Complexes [Ni III (OR)(P(C 6 H 3 -3-SiMe 3 -2-S) 3 )] − (R = Me, Ph) Containing the Terminal Alkoxide Ligand: Relevance to the Nickel Site of Oxidized-Form [NiFe] Hydrogenases
journal, September 2008
- Chiou, Tzung-Wen; Liaw, Wen-Feng
- Inorganic Chemistry, Vol. 47, Issue 17
Iron-Catalyzed Reduction of CO 2 into Methylene: Formation of C–N, C–O, and C–C Bonds
journal, July 2015
- Jin, Guanghua; Werncke, C. Gunnar; Escudié, Yannick
- Journal of the American Chemical Society, Vol. 137, Issue 30
Phosphinite-Ni(0) Mediated Formation of a Phosphide-Ni(II)-OCOOMe Species via Uncommon Metal–Ligand Cooperation
journal, March 2015
- Kim, Yeong-Eun; Oh, Seohee; Kim, Seji
- Journal of the American Chemical Society, Vol. 137, Issue 13
Electrocatalytic CO2 Conversion to Oxalate by a Copper Complex
journal, January 2010
- Angamuthu, R.; Byers, P.; Lutz, M.
- Science, Vol. 327, Issue 5963
A Germanium(II) Hydride as an Effective Reagent for Hydrogermylation Reactions
journal, January 2009
- Jana, Anukul; Ghoshal, Debajyoti; Roesky, Herbert W.
- Journal of the American Chemical Society, Vol. 131, Issue 3
New nickel–carbon dioxide complex: synthesis, properties, and crystallographic characterization of (carbon dioxide)-bis(tricyclohexylphosphine)nickel
journal, January 1975
- Aresta, Michele; Nobile, C. Francesco; Albano, Vincenzo G.
- J. Chem. Soc., Chem. Commun., Vol. 0, Issue 15
Structure, Function, and Mechanism of the Nickel Metalloenzymes, CO Dehydrogenase, and Acetyl-CoA Synthase
journal, February 2014
- Can, Mehmet; Armstrong, Fraser A.; Ragsdale, Stephen W.
- Chemical Reviews, Vol. 114, Issue 8
Formation of a nickel carbon dioxide adduct and its transformation mediated by a Lewis acid
journal, January 2014
- Kim, Yeong-Eun; Kim, Jin; Lee, Yunho
- Chem. Commun., Vol. 50, Issue 78
Fe(I)-Mediated Reductive Cleavage and Coupling of CO 2 : An Fe II (μ-O,μ-CO)Fe II Core
journal, January 2007
- Lu, Connie C.; Saouma, Caroline T.; Day, Michael W.
- Journal of the American Chemical Society, Vol. 129, Issue 1
Formation of CO 2 - Radical Ions When CO 2 is Adsorbed on Irradiated Magnesium Oxide
journal, July 1965
- Lunsford, Jack H.; Jayne, John P.
- The Journal of Physical Chemistry, Vol. 69, Issue 7
Reactions of CO 2 and CS 2 with 1,2-Bis(di- tert -butylphosphino)ethane Complexes of Nickel(0) and Nickel(I)
journal, November 2010
- Anderson, John S.; Iluc, Vlad M.; Hillhouse, Gregory L.
- Inorganic Chemistry, Vol. 49, Issue 21
Electronic spectoscopy of isoelectronic molecules. II. Linear triatomic groupings containing sixteen valence electrons
journal, February 1971
- McGlynn, Sean P.; Rabalais, John W.; McDonald, Jimmie R.
- Chemical Reviews, Vol. 71, Issue 1
Carbon Dioxide Activation at the Ni,Fe-Cluster of Anaerobic Carbon Monoxide Dehydrogenase
journal, November 2007
- Jeoung, J. -H.; Dobbek, H.
- Science, Vol. 318, Issue 5855
Carbon Dioxide Activation with Sterically Pressured Mid- and High-Valent Uranium Complexes
journal, September 2008
- Bart, Suzanne C.; Anthon, Christian; Heinemann, Frank W.
- Journal of the American Chemical Society, Vol. 130, Issue 37
Mononuclear Nickel(III) and Nickel(II) Thiolate Complexes with Intramolecular S−H Proton Interacting with Both Sulfur and Nickel: Relevance to the [NiFe]/[NiFeSe] Hydrogenases
journal, July 2004
- Lee, Chien-Ming; Chen, Chien-Hong; Ke, Shyue-Chu
- Journal of the American Chemical Society, Vol. 126, Issue 27
How the [NiFe 4 S 4 ] Cluster of CO Dehydrogenase Activates CO 2 and NCO −
journal, April 2015
- Fesseler, Jochen; Jeoung, Jae-Hun; Dobbek, Holger
- Angewandte Chemie International Edition, Vol. 54, Issue 29
Ligand K-edge X-ray absorption spectroscopy: covalency of ligand–metal bonds
journal, January 2005
- Solomon, Edward I.; Hedman, Britt; Hodgson, Keith O.
- Coordination Chemistry Reviews, Vol. 249, Issue 1-2
Catalysis of the electrochemical reduction of carbon dioxide
journal, January 2013
- Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel
- Chem. Soc. Rev., Vol. 42, Issue 6
Oxygen-Atom Transfer from Carbon Dioxide to a Fischer Carbene at (PNP)Ir
journal, May 2008
- Whited, Matthew T.; Grubbs, Robert H.
- Journal of the American Chemical Society, Vol. 130, Issue 18
Carbon Dioxide Reduction and Carbon Monoxide Activation Employing a Reactive Uranium(III) Complex
journal, August 2005
- Castro-Rodriguez, Ingrid; Meyer, Karsten
- Journal of the American Chemical Society, Vol. 127, Issue 32
Utilisation of CO2 as a chemical feedstock: opportunities and challenges
journal, January 2007
- Aresta, Michele; Dibenedetto, Angela
- Dalton Transactions, Issue 28
Addition of CO 2 to Alkyl Iron Complexes, Fe(PP) 2 Me 2
journal, May 2008
- Allen, Olivia R.; Dalgarno, Scott J.; Field, Leslie D.
- Organometallics, Vol. 27, Issue 9
Differential Reduction of CO 2 by Molybdenum and Vanadium Nitrogenases
journal, September 2014
- Rebelein, Johannes G.; Hu, Yilin; Ribbe, Markus W.
- Angewandte Chemie International Edition, Vol. 53, Issue 43
Discrimination of Mononuclear and Dinuclear Dinitrosyl Iron Complexes (DNICs) by S K-Edge X-ray Absorption Spectroscopy: Insight into the Electronic Structure and Reactivity of DNICs
journal, June 2011
- Lu, Tsai-Te; Lai, Szu-Hsueh; Li, Ya-Wen
- Inorganic Chemistry, Vol. 50, Issue 12
Efficient Fixation of Carbon Dioxide by Hypervalent Organobismuth Oxide, Hydroxide, and Alkoxide
journal, August 2008
- Yin, Shuang-Feng; Maruyama, Junpei; Yamashita, Takashi
- Angewandte Chemie International Edition, Vol. 47, Issue 35
Tris(pyrazolyl)hydroboratozinc hydroxide complexes as functional models for carbonic anhydrase: on the nature of the bicarbonate intermediate
journal, June 1993
- Looney, Adrian; Han, Runyu; McNeill, Kristopher
- Journal of the American Chemical Society, Vol. 115, Issue 11
Carbon Dioxide Fixation by Binuclear Complexes with Hydrophobic Binding Pockets This work was supported by the Deutsche Forschungsgemeinschaft (Project No. KE 585/3-1). The author thanks Prof. Dr. H. Vahrenkamp for his support of this work.
journal, November 2001
- Kersting, Berthold
- Angewandte Chemie International Edition, Vol. 40, Issue 21
Making Plastics from Carbon Dioxide: Salen Metal Complexes as Catalysts for the Production of Polycarbonates from Epoxides and CO 2
journal, June 2007
- Darensbourg, Donald J.
- Chemical Reviews, Vol. 107, Issue 6
Transformation of Carbon Dioxide
journal, June 2007
- Sakakura, Toshiyasu; Choi, Jun-Chul; Yasuda, Hiroyuki
- Chemical Reviews, Vol. 107, Issue 6
Radical Scavenging of White Tea and Its Flavonoid Constituents by Electron Paramagnetic Resonance (EPR) Spectroscopy
journal, June 2014
- Azman, Nurul A. M.; Peiró, Sara; Fajarí, Lluís
- Journal of Agricultural and Food Chemistry, Vol. 62, Issue 25
A Linear, O-Coordinated 1-CO2 Bound to Uranium
journal, September 2004
- Castro-Rodriguez, I.
- Science, Vol. 305, Issue 5691
The impact of Metal–Ligand Cooperation in Hydrogenation of Carbon Dioxide Catalyzed by Ruthenium PNP Pincer
journal, October 2013
- Filonenko, Georgy A.; Conley, Matthew P.; Copéret, Christophe
- ACS Catalysis, Vol. 3, Issue 11
Reactions of the Terminal Ni II −OH Group in Substitution and Electrophilic Reactions with Carbon Dioxide and Other Substrates: Structural Definition of Binding Modes in an Intramolecular Ni II ···Fe II Bridged Site
journal, April 2010
- Huang, Deguang; Holm, R. H.
- Journal of the American Chemical Society, Vol. 132, Issue 13
Mononuclear Ni(III) Complexes [Ni III (L)(P(C 6 H 3 -3-SiMe 3 -2-S) 3 )] 0/1- (L = Thiolate, Selenolate, CH 2 CN, Cl, PPh 3 ): Relevance to the Nickel Site of [NiFe] Hydrogenases
journal, December 2006
- Lee, Chien-Ming; Chuang, Ya-Lan; Chiang, Chao-Yi
- Inorganic Chemistry, Vol. 45, Issue 26
Recent developments in the activation of carbon dioxide by metal complexes
journal, January 1999
- Yin, Xiaolong; Moss, John R.
- Coordination Chemistry Reviews, Vol. 181, Issue 1
Reversible CO 2 binding triggered by metal–ligand cooperation in a rhenium( i ) PNP pincer-type complex and the reaction with dihydrogen
journal, January 2014
- Vogt, Matthias; Nerush, Alexander; Diskin-Posner, Yael
- Chem. Sci., Vol. 5, Issue 5
Organosamarium-Mediated Transformations of CO 2 and COS: Monoinsertion and Disproportionation Reactions and the Reductive Coupling of CO 2 to [O 2 CCO 2 ] 2-
journal, February 1998
- Evans, William J.; Seibel, Christopher A.; Ziller, Joseph W.
- Inorganic Chemistry, Vol. 37, Issue 4
O/C Bond Cleavage of CO 2 by Ni I
journal, March 2008
- Fullmer, Benjamin C.; Fan, Hongjun; Pink, Maren
- Inorganic Chemistry, Vol. 47, Issue 6
The Organometallic Chemistry of Carbon Dioxide
journal, January 1996
- Gibson, Dorothy H.
- Chemical Reviews, Vol. 96, Issue 6
Differential Reduction of CO 2 by Molybdenum and Vanadium Nitrogenases
journal, September 2014
- Rebelein, Johannes G.; Hu, Yilin; Ribbe, Markus W.
- Angewandte Chemie, Vol. 126, Issue 43
Works referencing / citing this record:
CCDC 1435237: Experimental Crystal Structure Determination: QUZWAL : bis(triphenylphosphoranylidene)ammonium (isocyanato)-(2,2',2''-(phosphinetriyl)tris(6-(trimethylsilyl)benzenethiolato))-nickel(iii) tetrahydrofuran solvate
dataset, November 2015
- Chiou, Tzung-Wen; Tseng, Yen-Ming; Lu, Tsai-Te
- Cambridge Structural Database (CSD)
CCDC 1435238: Experimental Crystal Structure Determination: QUZWEP : bis(triphenylphosphoranylidene)ammonium (hydrazine)-(2,2',2''-(phosphinetriyl)tris(6-(trimethylsilyl)benzenethiolato))-nickel tetrahydrofuran solvate
dataset, November 2015
- Chiou, Tzung-Wen; Tseng, Yen-Ming; Lu, Tsai-Te
- Cambridge Structural Database (CSD)
CCDC 785531: Experimental Crystal Structure Determination: QUZVUE : bis(triphenylphosphoranylidene)ammonium (carbon dioxide radical anion)-(2,2',2''-(phosphinetriyl)tris(6-(trimethylsilyl)benzenethiolato))-nickel tetrahydrofuran solvate
dataset, November 2015
- Chiou, Tzung-Wen; Tseng, Yen-Ming; Lu, Tsai-Te
- Cambridge Structural Database (CSD)
Carbon Dioxide Fixation by Binuclear Complexes with Hydrophobic Binding Pockets This work was supported by the Deutsche Forschungsgemeinschaft (Project No. KE 585/3-1). The author thanks Prof. Dr. H. Vahrenkamp for his support of this work.
journal, November 2001
- Kersting, Berthold
- Angewandte Chemie International Edition, Vol. 40, Issue 21
Efficient Fixation of Carbon Dioxide by Hypervalent Organobismuth Oxide, Hydroxide, and Alkoxide
journal, August 2008
- Yin, Shuang-Feng; Maruyama, Junpei; Yamashita, Takashi
- Angewandte Chemie International Edition, Vol. 47, Issue 35
Differential Reduction of CO 2 by Molybdenum and Vanadium Nitrogenases
journal, September 2014
- Rebelein, Johannes G.; Hu, Yilin; Ribbe, Markus W.
- Angewandte Chemie International Edition, Vol. 53, Issue 43
How the [NiFe 4 S 4 ] Cluster of CO Dehydrogenase Activates CO 2 and NCO −
journal, April 2015
- Fesseler, Jochen; Jeoung, Jae-Hun; Dobbek, Holger
- Angewandte Chemie International Edition, Vol. 54, Issue 29
A Biomimetic Nickel Complex with a Reduced CO 2 Ligand Generated by Formate Deprotonation and Its Behaviour towards CO 2
journal, May 2018
- Zimmermann, Philipp; Hoof, Santina; Braun-Cula, Beatrice
- Angewandte Chemie International Edition, Vol. 57, Issue 24
Ligand K-edge X-ray absorption spectroscopy: covalency of ligand–metal bonds
journal, January 2005
- Solomon, Edward I.; Hedman, Britt; Hodgson, Keith O.
- Coordination Chemistry Reviews, Vol. 249, Issue 1-2
Recent developments in the activation of carbon dioxide by metal complexes
journal, January 1999
- Yin, Xiaolong; Moss, John R.
- Coordination Chemistry Reviews, Vol. 181, Issue 1
Transformation of Carbon Dioxide
journal, June 2007
- Sakakura, Toshiyasu; Choi, Jun-Chul; Yasuda, Hiroyuki
- Chemical Reviews, Vol. 107, Issue 6
Making Plastics from Carbon Dioxide: Salen Metal Complexes as Catalysts for the Production of Polycarbonates from Epoxides and CO 2
journal, June 2007
- Darensbourg, Donald J.
- Chemical Reviews, Vol. 107, Issue 6
Structure, Function, and Mechanism of the Nickel Metalloenzymes, CO Dehydrogenase, and Acetyl-CoA Synthase
journal, February 2014
- Can, Mehmet; Armstrong, Fraser A.; Ragsdale, Stephen W.
- Chemical Reviews, Vol. 114, Issue 8
Electronic spectoscopy of isoelectronic molecules. II. Linear triatomic groupings containing sixteen valence electrons
journal, February 1971
- McGlynn, Sean P.; Rabalais, John W.; McDonald, Jimmie R.
- Chemical Reviews, Vol. 71, Issue 1
The Organometallic Chemistry of Carbon Dioxide
journal, January 1996
- Gibson, Dorothy H.
- Chemical Reviews, Vol. 96, Issue 6
The impact of Metal–Ligand Cooperation in Hydrogenation of Carbon Dioxide Catalyzed by Ruthenium PNP Pincer
journal, October 2013
- Filonenko, Georgy A.; Conley, Matthew P.; Copéret, Christophe
- ACS Catalysis, Vol. 3, Issue 11
Mononuclear Ni(III) Complexes [Ni III (L)(P(C 6 H 3 -3-SiMe 3 -2-S) 3 )] 0/1- (L = Thiolate, Selenolate, CH 2 CN, Cl, PPh 3 ): Relevance to the Nickel Site of [NiFe] Hydrogenases
journal, December 2006
- Lee, Chien-Ming; Chuang, Ya-Lan; Chiang, Chao-Yi
- Inorganic Chemistry, Vol. 45, Issue 26
Reactions of CO 2 and CS 2 with 1,2-Bis(di- tert -butylphosphino)ethane Complexes of Nickel(0) and Nickel(I)
journal, November 2010
- Anderson, John S.; Iluc, Vlad M.; Hillhouse, Gregory L.
- Inorganic Chemistry, Vol. 49, Issue 21
Discrimination of Mononuclear and Dinuclear Dinitrosyl Iron Complexes (DNICs) by S K-Edge X-ray Absorption Spectroscopy: Insight into the Electronic Structure and Reactivity of DNICs
journal, June 2011
- Lu, Tsai-Te; Lai, Szu-Hsueh; Li, Ya-Wen
- Inorganic Chemistry, Vol. 50, Issue 12
O/C Bond Cleavage of CO 2 by Ni I
journal, March 2008
- Fullmer, Benjamin C.; Fan, Hongjun; Pink, Maren
- Inorganic Chemistry, Vol. 47, Issue 6
Mononuclear Nickel(III) Complexes [Ni III (OR)(P(C 6 H 3 -3-SiMe 3 -2-S) 3 )] − (R = Me, Ph) Containing the Terminal Alkoxide Ligand: Relevance to the Nickel Site of Oxidized-Form [NiFe] Hydrogenases
journal, September 2008
- Chiou, Tzung-Wen; Liaw, Wen-Feng
- Inorganic Chemistry, Vol. 47, Issue 17
Organosamarium-Mediated Transformations of CO 2 and COS: Monoinsertion and Disproportionation Reactions and the Reductive Coupling of CO 2 to [O 2 CCO 2 ] 2-
journal, February 1998
- Evans, William J.; Seibel, Christopher A.; Ziller, Joseph W.
- Inorganic Chemistry, Vol. 37, Issue 4
Formation of CO 2 - Radical Ions When CO 2 is Adsorbed on Irradiated Magnesium Oxide
journal, July 1965
- Lunsford, Jack H.; Jayne, John P.
- The Journal of Physical Chemistry, Vol. 69, Issue 7
Tris(pyrazolyl)hydroboratozinc hydroxide complexes as functional models for carbonic anhydrase: on the nature of the bicarbonate intermediate
journal, June 1993
- Looney, Adrian; Han, Runyu; McNeill, Kristopher
- Journal of the American Chemical Society, Vol. 115, Issue 11
Mononuclear Nickel(III) and Nickel(II) Thiolate Complexes with Intramolecular S−H Proton Interacting with Both Sulfur and Nickel: Relevance to the [NiFe]/[NiFeSe] Hydrogenases
journal, July 2004
- Lee, Chien-Ming; Chen, Chien-Hong; Ke, Shyue-Chu
- Journal of the American Chemical Society, Vol. 126, Issue 27
Carbon Dioxide Reduction and Carbon Monoxide Activation Employing a Reactive Uranium(III) Complex
journal, August 2005
- Castro-Rodriguez, Ingrid; Meyer, Karsten
- Journal of the American Chemical Society, Vol. 127, Issue 32
Fe(I)-Mediated Reductive Cleavage and Coupling of CO 2 : An Fe II (μ-O,μ-CO)Fe II Core
journal, January 2007
- Lu, Connie C.; Saouma, Caroline T.; Day, Michael W.
- Journal of the American Chemical Society, Vol. 129, Issue 1
Reactions of the Terminal Ni II −OH Group in Substitution and Electrophilic Reactions with Carbon Dioxide and Other Substrates: Structural Definition of Binding Modes in an Intramolecular Ni II ···Fe II Bridged Site
journal, April 2010
- Huang, Deguang; Holm, R. H.
- Journal of the American Chemical Society, Vol. 132, Issue 13
Phosphinite-Ni(0) Mediated Formation of a Phosphide-Ni(II)-OCOOMe Species via Uncommon Metal–Ligand Cooperation
journal, March 2015
- Kim, Yeong-Eun; Oh, Seohee; Kim, Seji
- Journal of the American Chemical Society, Vol. 137, Issue 13
Oxygen-Atom Transfer from Carbon Dioxide to a Fischer Carbene at (PNP)Ir
journal, May 2008
- Whited, Matthew T.; Grubbs, Robert H.
- Journal of the American Chemical Society, Vol. 130, Issue 18
Carbon Dioxide Activation with Sterically Pressured Mid- and High-Valent Uranium Complexes
journal, September 2008
- Bart, Suzanne C.; Anthon, Christian; Heinemann, Frank W.
- Journal of the American Chemical Society, Vol. 130, Issue 37
A Germanium(II) Hydride as an Effective Reagent for Hydrogermylation Reactions
journal, January 2009
- Jana, Anukul; Ghoshal, Debajyoti; Roesky, Herbert W.
- Journal of the American Chemical Society, Vol. 131, Issue 3
Iron-Catalyzed Reduction of CO 2 into Methylene: Formation of C–N, C–O, and C–C Bonds
journal, July 2015
- Jin, Guanghua; Werncke, C. Gunnar; Escudié, Yannick
- Journal of the American Chemical Society, Vol. 137, Issue 30
Radical Scavenging of White Tea and Its Flavonoid Constituents by Electron Paramagnetic Resonance (EPR) Spectroscopy
journal, June 2014
- Azman, Nurul A. M.; Peiró, Sara; Fajarí, Lluís
- Journal of Agricultural and Food Chemistry, Vol. 62, Issue 25
Addition of CO 2 to Alkyl Iron Complexes, Fe(PP) 2 Me 2
journal, May 2008
- Allen, Olivia R.; Dalgarno, Scott J.; Field, Leslie D.
- Organometallics, Vol. 27, Issue 9
Utilisation of CO2 as a chemical feedstock: opportunities and challenges
journal, January 2007
- Aresta, Michele; Dibenedetto, Angela
- Dalton Transactions, Issue 28
Catalysis of the electrochemical reduction of carbon dioxide
journal, January 2013
- Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel
- Chem. Soc. Rev., Vol. 42, Issue 6
New nickel–carbon dioxide complex: synthesis, properties, and crystallographic characterization of (carbon dioxide)-bis(tricyclohexylphosphine)nickel
journal, January 1975
- Aresta, Michele; Nobile, C. Francesco; Albano, Vincenzo G.
- J. Chem. Soc., Chem. Commun., Vol. 0, Issue 15
Formation of a nickel carbon dioxide adduct and its transformation mediated by a Lewis acid
journal, January 2014
- Kim, Yeong-Eun; Kim, Jin; Lee, Yunho
- Chem. Commun., Vol. 50, Issue 78
Reversible CO 2 binding triggered by metal–ligand cooperation in a rhenium( i ) PNP pincer-type complex and the reaction with dihydrogen
journal, January 2014
- Vogt, Matthias; Nerush, Alexander; Diskin-Posner, Yael
- Chem. Sci., Vol. 5, Issue 5
A Linear, O-Coordinated 1-CO2 Bound to Uranium
journal, September 2004
- Castro-Rodriguez, I.
- Science, Vol. 305, Issue 5691
Carbon Dioxide Activation at the Ni,Fe-Cluster of Anaerobic Carbon Monoxide Dehydrogenase
journal, November 2007
- Jeoung, J. -H.; Dobbek, H.
- Science, Vol. 318, Issue 5855
Electrocatalytic CO2 Conversion to Oxalate by a Copper Complex
journal, January 2010
- Angamuthu, R.; Byers, P.; Lutz, M.
- Science, Vol. 327, Issue 5963
A Biomimetic Nickel Complex with a Reduced CO 2 Ligand Generated by Formate Deprotonation and Its Behaviour towards CO 2
journal, May 2018
- Zimmermann, Philipp; Hoof, Santina; Braun-Cula, Beatrice
- Angewandte Chemie International Edition, Vol. 57, Issue 24
Ein biomimetischer Nickelkomplex mit einem reduzierten, durch Formiatdeprotonierung erzeugten CO 2 -Liganden und sein Verhalten gegenüber CO 2
journal, May 2018
- Zimmermann, Philipp; Hoof, Santina; Braun-Cula, Beatrice
- Angewandte Chemie, Vol. 130, Issue 24
XANES/EPR Evidence of the Oxidation of Nickel(II) Quinolinylpropioamide and Its Application in Csp 3 −H Functionalization
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