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Title: A Direct Mechanism of Ultrafast Intramolecular Singlet Fission in Pentacene Dimers

Authors:
 [1];  [2];  [2];  [2];  [1];  [2];  [2];  [2];  [3];  [2];  [1]
  1. Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853, United States
  2. Department of Chemistry, Columbia University, New York, New York 10027, United States
  3. Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, United States
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1251272
Alternate Identifier(s):
OSTI ID: 1303026
Report Number(s):
BNL-112540-2016-JA
Journal ID: ISSN 2374-7943
Grant/Contract Number:  
SC0014563; SC00112704
Resource Type:
Published Article
Journal Name:
ACS Central Science
Additional Journal Information:
Journal Name: ACS Central Science Journal Volume: 2 Journal Issue: 5; Journal ID: ISSN 2374-7943
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Center for Functional Nanomaterials

Citation Formats

Fuemmeler, Eric G., Sanders, Samuel N., Pun, Andrew B., Kumarasamy, Elango, Zeng, Tao, Miyata, Kiyoshi, Steigerwald, Michael L., Zhu, X. -Y., Sfeir, Matthew Y., Campos, Luis M., and Ananth, Nandini. A Direct Mechanism of Ultrafast Intramolecular Singlet Fission in Pentacene Dimers. United States: N. p., 2016. Web. doi:10.1021/acscentsci.6b00063.
Fuemmeler, Eric G., Sanders, Samuel N., Pun, Andrew B., Kumarasamy, Elango, Zeng, Tao, Miyata, Kiyoshi, Steigerwald, Michael L., Zhu, X. -Y., Sfeir, Matthew Y., Campos, Luis M., & Ananth, Nandini. A Direct Mechanism of Ultrafast Intramolecular Singlet Fission in Pentacene Dimers. United States. doi:10.1021/acscentsci.6b00063.
Fuemmeler, Eric G., Sanders, Samuel N., Pun, Andrew B., Kumarasamy, Elango, Zeng, Tao, Miyata, Kiyoshi, Steigerwald, Michael L., Zhu, X. -Y., Sfeir, Matthew Y., Campos, Luis M., and Ananth, Nandini. Thu . "A Direct Mechanism of Ultrafast Intramolecular Singlet Fission in Pentacene Dimers". United States. doi:10.1021/acscentsci.6b00063.
@article{osti_1251272,
title = {A Direct Mechanism of Ultrafast Intramolecular Singlet Fission in Pentacene Dimers},
author = {Fuemmeler, Eric G. and Sanders, Samuel N. and Pun, Andrew B. and Kumarasamy, Elango and Zeng, Tao and Miyata, Kiyoshi and Steigerwald, Michael L. and Zhu, X. -Y. and Sfeir, Matthew Y. and Campos, Luis M. and Ananth, Nandini},
abstractNote = {},
doi = {10.1021/acscentsci.6b00063},
journal = {ACS Central Science},
number = 5,
volume = 2,
place = {United States},
year = {2016},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1021/acscentsci.6b00063

Citation Metrics:
Cited by: 28 works
Citation information provided by
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Works referencing / citing this record:

Conformational Planarization versus Singlet Fission: Distinct Excited-State Dynamics of Cyclooctatetraene-Fused Acene Dimers
journal, March 2018

  • Yamakado, Takuya; Takahashi, Shota; Watanabe, Kazuya
  • Angewandte Chemie International Edition, Vol. 57, Issue 19
  • DOI: 10.1002/anie.201802185

Vibronically coherent ultrafast triplet-pair formation and subsequent thermally activated dissociation control efficient endothermic singlet fission
journal, September 2017

  • Stern, Hannah L.; Cheminal, Alexandre; Yost, Shane R.
  • Nature Chemistry, Vol. 9, Issue 12
  • DOI: 10.1038/nchem.2856

Unified model for singlet fission within a non-conjugated covalent pentacene dimer
journal, May 2017

  • Basel, Bettina S.; Zirzlmeier, Johannes; Hetzer, Constantin
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15171

Unraveling structural dynamics in isoenergetic excited S 1 and multi-excitonic 1 (TT) states of 9,10-bis(phenylethynyl)anthracene (BPEA) in solution via ultrafast Raman loss spectroscopy
journal, January 2019

  • Jana, Sanjib; Yapamanu, Adithya Lakshmanna; Umapathy, Siva
  • Physical Chemistry Chemical Physics, Vol. 21, Issue 26
  • DOI: 10.1039/c8cp06658b

Davydov splitting and singlet fission in excitonically coupled pentacene dimers
journal, January 2019

  • Basel, Bettina Sabine; Hetzer, Constantin; Zirzlmeier, Johannes
  • Chemical Science, Vol. 10, Issue 13
  • DOI: 10.1039/c9sc00384c

Conformational Planarization versus Singlet Fission: Distinct Excited-State Dynamics of Cyclooctatetraene-Fused Acene Dimers
journal, March 2018

  • Yamakado, Takuya; Takahashi, Shota; Watanabe, Kazuya
  • Angewandte Chemie International Edition, Vol. 57, Issue 19
  • DOI: 10.1002/anie.201802185

Vibronically coherent ultrafast triplet-pair formation and subsequent thermally activated dissociation control efficient endothermic singlet fission
journal, September 2017

  • Stern, Hannah L.; Cheminal, Alexandre; Yost, Shane R.
  • Nature Chemistry, Vol. 9, Issue 12
  • DOI: 10.1038/nchem.2856

Unified model for singlet fission within a non-conjugated covalent pentacene dimer
journal, May 2017

  • Basel, Bettina S.; Zirzlmeier, Johannes; Hetzer, Constantin
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15171

Unraveling structural dynamics in isoenergetic excited S 1 and multi-excitonic 1 (TT) states of 9,10-bis(phenylethynyl)anthracene (BPEA) in solution via ultrafast Raman loss spectroscopy
journal, January 2019

  • Jana, Sanjib; Yapamanu, Adithya Lakshmanna; Umapathy, Siva
  • Physical Chemistry Chemical Physics, Vol. 21, Issue 26
  • DOI: 10.1039/c8cp06658b

Davydov splitting and singlet fission in excitonically coupled pentacene dimers
journal, January 2019

  • Basel, Bettina Sabine; Hetzer, Constantin; Zirzlmeier, Johannes
  • Chemical Science, Vol. 10, Issue 13
  • DOI: 10.1039/c9sc00384c