Experimental design, operation, and results of a 4 kW high temperature steam electrolysis experiment
Abstract
High temperature steam electrolysis (HTSE) is a promising technology for large-scale hydrogen production. However, research on HTSE performance above the kW level is limited. This paper presents the results of 4 kW HTSE long-term test completed in a multi-kW test facility recently developed at the Idaho National Laboratory (INL). The 4 kW HTSE unit included two solid oxide electrolysis stacks operating in parallel, each of which included 40 electrode-supported planar cells. A current density of 0.41 A/cm2 was used for the long-term operation, resulting in a hydrogen production rate about 25 slpm. A demonstration of 920 hours stable operation was achieved. The paper also includes detailed descriptions of the piping layout, steam generation and delivery system, test fixture, heat recuperation system, hot zone, instrumentation, and operating conditions. As a result, this successful demonstration of multi-kW scale HTSE unit will help to advance the technology toward near-term commercialization.
- Authors:
-
- Old Dominion Univ., Norfolk, VA (United States)
- Idaho National Lab. (INL), Idaho Falls, ID (United States)
- Materials and Systems Research, Inc., Salt Lake City, UT (United States)
- Publication Date:
- Research Org.:
- Idaho National Lab. (INL), Idaho Falls, ID (United States)
- Sponsoring Org.:
- USDOE Office of Nuclear Energy (NE)
- OSTI Identifier:
- 1245831
- Alternate Identifier(s):
- OSTI ID: 1250138
- Report Number(s):
- INL/JOU-15-34249
Journal ID: ISSN 0378-7753; PII: S0378775315301488
- Grant/Contract Number:
- AC07-05ID14517
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Power Sources
- Additional Journal Information:
- Journal Volume: 297; Journal Issue: C; Journal ID: ISSN 0378-7753
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 08 HYDROGEN; 21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS; high temperature steam electrolysis; solid oxide electrolysis cell; hydrogen production; multi-kW test
Citation Formats
Zhang, Xiaoyu, O'Brien, James E., Tao, Greg, Zhou, Can, and Housley, Gregory K. Experimental design, operation, and results of a 4 kW high temperature steam electrolysis experiment. United States: N. p., 2015.
Web. doi:10.1016/j.jpowsour.2015.07.098.
Zhang, Xiaoyu, O'Brien, James E., Tao, Greg, Zhou, Can, & Housley, Gregory K. Experimental design, operation, and results of a 4 kW high temperature steam electrolysis experiment. United States. https://doi.org/10.1016/j.jpowsour.2015.07.098
Zhang, Xiaoyu, O'Brien, James E., Tao, Greg, Zhou, Can, and Housley, Gregory K. Thu .
"Experimental design, operation, and results of a 4 kW high temperature steam electrolysis experiment". United States. https://doi.org/10.1016/j.jpowsour.2015.07.098. https://www.osti.gov/servlets/purl/1245831.
@article{osti_1245831,
title = {Experimental design, operation, and results of a 4 kW high temperature steam electrolysis experiment},
author = {Zhang, Xiaoyu and O'Brien, James E. and Tao, Greg and Zhou, Can and Housley, Gregory K.},
abstractNote = {High temperature steam electrolysis (HTSE) is a promising technology for large-scale hydrogen production. However, research on HTSE performance above the kW level is limited. This paper presents the results of 4 kW HTSE long-term test completed in a multi-kW test facility recently developed at the Idaho National Laboratory (INL). The 4 kW HTSE unit included two solid oxide electrolysis stacks operating in parallel, each of which included 40 electrode-supported planar cells. A current density of 0.41 A/cm2 was used for the long-term operation, resulting in a hydrogen production rate about 25 slpm. A demonstration of 920 hours stable operation was achieved. The paper also includes detailed descriptions of the piping layout, steam generation and delivery system, test fixture, heat recuperation system, hot zone, instrumentation, and operating conditions. As a result, this successful demonstration of multi-kW scale HTSE unit will help to advance the technology toward near-term commercialization.},
doi = {10.1016/j.jpowsour.2015.07.098},
journal = {Journal of Power Sources},
number = C,
volume = 297,
place = {United States},
year = {Thu Aug 06 00:00:00 EDT 2015},
month = {Thu Aug 06 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
Syngas Production via High-Temperature Coelectrolysis of Steam and Carbon Dioxide
journal, November 2008
- Stoots, Carl M.; O’Brien, James E.; Herring, J. Stephen
- Journal of Fuel Cell Science and Technology, Vol. 6, Issue 1
Degradation Issues in Solid Oxide Cells During High Temperature Electrolysis
journal, December 2011
- Sohal, M. S.; O’Brien, J. E.; Stoots, C. M.
- Journal of Fuel Cell Science and Technology, Vol. 9, Issue 1
Life cycle assessment of high temperature electrolysis for hydrogen production via nuclear energy
journal, June 2006
- Utgikar, V.; Thiesen, T.
- International Journal of Hydrogen Energy, Vol. 31, Issue 7
Hydrogen production by high temperature electrolysis of water vapour☆
journal, January 1980
- Doenitz, W.; Schmidberger, R.; Steinheil, E.
- International Journal of Hydrogen Energy, Vol. 5, Issue 1
Concepts and design for scaling up high temperature water vapour electrolysis☆
journal, January 1982
- Doenitz, W.; Schmidberger, R.
- International Journal of Hydrogen Energy, Vol. 7, Issue 4
High-temperature electrolysis of water vapor?status of development and perspectives for application
journal, January 1985
- Donitz, W.
- International Journal of Hydrogen Energy, Vol. 10, Issue 5
Electrochemical high temperature technology for hydrogen production or direct electricity generation☆
journal, January 1988
- Donitz, W.; Dietrich, G.; Erdle, E.
- International Journal of Hydrogen Energy, Vol. 13, Issue 5
Progress in high-temperature electrolysis for hydrogen production using planar SOFC technology
journal, March 2007
- Herring, J. Stephen; O’Brien, James E.; Stoots, Carl M.
- International Journal of Hydrogen Energy, Vol. 32, Issue 4
High-temperature electrolysis for large-scale hydrogen production from nuclear energy – Experimental investigations
journal, May 2010
- Stoots, Carl M.; O'Brien, James E.; Condie, Keith G.
- International Journal of Hydrogen Energy, Vol. 35, Issue 10
Improved durability of SOEC stacks for high temperature electrolysis
journal, January 2013
- Zhang, Xiaoyu; O'Brien, James E.; O'Brien, Robert C.
- International Journal of Hydrogen Energy, Vol. 38, Issue 1
3D CFD model of a multi-cell high-temperature electrolysis stack
journal, May 2009
- Hawkes, Grant; O'Brien, James; Stoots, Carl
- International Journal of Hydrogen Energy, Vol. 34, Issue 9
High Temperature Electrolysis at EIFER, Main Achievements at Cell and Stack Level
journal, January 2012
- Brisse, Annabelle; Schefold, Josef
- Energy Procedia, Vol. 29
Durable SOC stacks for production of hydrogen and synthesis gas by high temperature electrolysis
journal, July 2011
- Ebbesen, Sune Dalgaard; Høgh, Jens; Nielsen, Karsten Agersted
- International Journal of Hydrogen Energy, Vol. 36, Issue 13
Enhanced Performance and Durability of a High Temperature Steam Electrolysis Stack
journal, April 2013
- Mougin, J.; Mansuy, A.; Chatroux, A.
- Fuel Cells, Vol. 13, Issue 4
High Temperature Steam Electrolysis Stack with Enhanced Performance and Durability
journal, January 2012
- Mougin, Julie; Chatroux, A.; Couturier, K.
- Energy Procedia, Vol. 29
Advance in highly efficient hydrogen production by high temperature steam electrolysis
journal, April 2008
- Yu, Bo; Zhang, WenQiang; Chen, Jing
- Science in China Series B: Chemistry, Vol. 51, Issue 4
Status and research of highly efficient hydrogen production through high temperature steam electrolysis at INET
journal, April 2010
- Bo, Yu; Wenqiang, Zhang; Jingming, Xu
- International Journal of Hydrogen Energy, Vol. 35, Issue 7
Achieving high-efficiency hydrogen production using planar solid-oxide electrolysis stacks
journal, July 2014
- Li, Qingshan; Zheng, Yifeng; Guan, Wanbing
- International Journal of Hydrogen Energy, Vol. 39, Issue 21
Investigation of 30-cell solid oxide electrolyzer stack modules for hydrogen production
journal, May 2014
- Zheng, Yifeng; Li, Qingshan; Guan, Wanbin
- Ceramics International, Vol. 40, Issue 4
Hydrogen production performance of 3-cell flat-tubular solid oxide electrolysis stack
journal, January 2012
- Kim, Sun-Dong; Yu, Ji-Haeng; Seo, Doo-Won
- International Journal of Hydrogen Energy, Vol. 37, Issue 1
Electrochemical performance and long-term durability of a 200 W-class solid oxide regenerative fuel cell stack
journal, December 2014
- Hong, Jongsup; Kim, Hyo-Jin; Park, Sun-Young
- International Journal of Hydrogen Energy, Vol. 39, Issue 35
Works referencing / citing this record:
A Detailed Post Mortem Analysis of Solid Oxide Electrolyzer Cells after Long-Term Stack Operation
journal, January 2018
- Frey, Carolin E.; Fang, Qingping; Sebold, Doris
- Journal of The Electrochemical Society, Vol. 165, Issue 5