DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Biofuels production from hydrothermal decarboxylation of oleic acid and soybean oil over Ni-based transition metal carbides supported on Al-SBA-15

Authors:
; ;
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1250091
Grant/Contract Number:  
DEFG36-05GO85005
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Applied Catalysis. A, General
Additional Journal Information:
Journal Name: Applied Catalysis. A, General Journal Volume: 498 Journal Issue: C; Journal ID: ISSN 0926-860X
Publisher:
Elsevier
Country of Publication:
Netherlands
Language:
English

Citation Formats

Al Alwan, Basem, Salley, Steven O., and Ng, K. Y. Simon. Biofuels production from hydrothermal decarboxylation of oleic acid and soybean oil over Ni-based transition metal carbides supported on Al-SBA-15. Netherlands: N. p., 2015. Web. doi:10.1016/j.apcata.2015.03.012.
Al Alwan, Basem, Salley, Steven O., & Ng, K. Y. Simon. Biofuels production from hydrothermal decarboxylation of oleic acid and soybean oil over Ni-based transition metal carbides supported on Al-SBA-15. Netherlands. https://doi.org/10.1016/j.apcata.2015.03.012
Al Alwan, Basem, Salley, Steven O., and Ng, K. Y. Simon. Mon . "Biofuels production from hydrothermal decarboxylation of oleic acid and soybean oil over Ni-based transition metal carbides supported on Al-SBA-15". Netherlands. https://doi.org/10.1016/j.apcata.2015.03.012.
@article{osti_1250091,
title = {Biofuels production from hydrothermal decarboxylation of oleic acid and soybean oil over Ni-based transition metal carbides supported on Al-SBA-15},
author = {Al Alwan, Basem and Salley, Steven O. and Ng, K. Y. Simon},
abstractNote = {},
doi = {10.1016/j.apcata.2015.03.012},
journal = {Applied Catalysis. A, General},
number = C,
volume = 498,
place = {Netherlands},
year = {Mon Jun 01 00:00:00 EDT 2015},
month = {Mon Jun 01 00:00:00 EDT 2015}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1016/j.apcata.2015.03.012

Citation Metrics:
Cited by: 37 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Biodiesel production from oleaginous microorganisms
journal, January 2009


Stabilizing Catalytic Pathways via Redundancy: Selective Reduction of Microalgae Oil to Alkanes
journal, May 2012

  • Peng, Baoxiang; Yuan, Xiaoguo; Zhao, Chen
  • Journal of the American Chemical Society, Vol. 134, Issue 22
  • DOI: 10.1021/ja302436q

Catalytic deoxygenation of fatty acids and their derivatives to hydrocarbon fuels via decarboxylation/decarbonylation
journal, March 2012

  • Santillan-Jimenez, Eduardo; Crocker, Mark
  • Journal of Chemical Technology & Biotechnology, Vol. 87, Issue 8
  • DOI: 10.1002/jctb.3775

Revisiting the hydrogenation of sunflower oil over a Ni catalyst
journal, September 2007

  • Fernández, María B.; Tonetto, Gabriela M.; Crapiste, Guillermo H.
  • Journal of Food Engineering, Vol. 82, Issue 2
  • DOI: 10.1016/j.jfoodeng.2007.02.010

Activated Carbons for Hydrothermal Decarboxylation of Fatty Acids
journal, February 2011

  • Fu, Jie; Shi, Fan; Thompson, L. T.
  • ACS Catalysis, Vol. 1, Issue 3
  • DOI: 10.1021/cs1001306

Synthesis of δ-stearolactone from oleic acid
journal, March 2000

  • Cermak, Steven C.; Isbell, Terry A.
  • Journal of the American Oil Chemists' Society, Vol. 77, Issue 3
  • DOI: 10.1007/s11746-000-0040-6

Thermal hydrolysis of vegetable oils and fats. 1. Reaction kinetics
journal, May 1988

  • Patil, T. A.; Butala, D. N.; Raghunathan, T. S.
  • Industrial & Engineering Chemistry Research, Vol. 27, Issue 5
  • DOI: 10.1021/ie00077a001

Renewable Diesel Production from the Hydrotreating of Rapeseed Oil with Pt/Zeolite and NiMo/Al2O3 Catalysts
journal, March 2011

  • Sotelo-Boyás, Rogelio; Liu, Yanyong; Minowa, Tomoaki
  • Industrial & Engineering Chemistry Research, Vol. 50, Issue 5, p. 2791-2799
  • DOI: 10.1021/ie100824d

Investigation of the Morphology of the Mesoporous SBA-16 and SBA-15 Materials
journal, May 2006

  • Stevens, Wesley J. J.; Lebeau, Kurt; Mertens, Myrjam
  • The Journal of Physical Chemistry B, Vol. 110, Issue 18
  • DOI: 10.1021/jp0548725

Two-Step Preparation for Catalyst-Free Biodiesel Fuel Production: Hydrolysis and Methyl Esterification
journal, January 2004


Mechanism of Fat Splitting
journal, April 1949

  • Lascaray, Lucio
  • Industrial & Engineering Chemistry, Vol. 41, Issue 4
  • DOI: 10.1021/ie50472a025

Study of the Temperature-Programmed Reaction Synthesis of Early Transition Metal Carbide and Nitride Catalyst Materials from Oxide Precursors
journal, January 2000

  • Claridge, John B.; York, Andrew P. E.; Brungs, Attila J.
  • Chemistry of Materials, Vol. 12, Issue 1, p. 132-142
  • DOI: 10.1021/cm9911060

Catalytic Activities of NiMo Carbide Supported on SiO2 for the Hydrodeoxygenation of Ethyl Benzoate, Acetone, and Acetaldehyde
journal, March 2010

  • Zhang, Wei; Zhang, Ye; Zhao, Liangfu
  • Energy & Fuels, Vol. 24, Issue 3, p. 2052-2059
  • DOI: 10.1021/ef901222z

Direct conversion of triglycerides to olefins and paraffins over noble metal supported catalysts
journal, March 2011


Heterogeneous Catalytic Deoxygenation of Stearic Acid for Production of Biodiesel
journal, August 2006

  • Snåre, Mathias; Kubičková, Iva; Mäki-Arvela, Päivi
  • Industrial & Engineering Chemistry Research, Vol. 45, Issue 16, p. 5708-5715
  • DOI: 10.1021/ie060334i

Hydrocarbons for diesel fuel via decarboxylation of vegetable oils
journal, October 2005


Deoxygenation of palmitic and stearic acid over supported Pd catalysts: Effect of metal dispersion
journal, February 2009


Decomposition of a long chain saturated fatty acid with some additives in hot compressed water
journal, November 2006


Catalytic reaction pathways in liquid-phase deoxygenation of C18 free fatty acids
journal, February 2010


Glycerol as a Source for Fuels and Chemicals by Low-Temperature Catalytic Processing
journal, June 2006

  • Soares, Ricardo R.; Simonetti, Dante A.; Dumesic, James A.
  • Angewandte Chemie, Vol. 118, Issue 24
  • DOI: 10.1002/ange.200600212

Continuous decarboxylation of lauric acid over Pd/C catalyst
journal, December 2008


Catalytic Hydrothermal Conversion of Triglycerides to Non-ester Biofuels
journal, February 2010

  • Li, Lixiong; Coppola, Edward; Rine, Jeffrey
  • Energy & Fuels, Vol. 24, Issue 2
  • DOI: 10.1021/ef901163a

Hydrogen production by aqueous phase catalytic reforming of glycerine
journal, February 2011


Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water
journal, August 2002

  • Cortright, R. D.; Davda, R. R.; Dumesic, J. A.
  • Nature, Vol. 418, Issue 6901
  • DOI: 10.1038/nature01009

Support effects on hydrotreating of soybean oil over NiMo carbide catalyst
journal, September 2013


Catalytic Deoxygenation of Methyl-Octanoate and Methyl-Stearate on Pt/Al2O3
journal, February 2009


Correlation of Pt–Re surface properties with reaction pathways for the aqueous-phase reforming of glycerol
journal, March 2012


Catalytic deoxygenation of unsaturated renewable feedstocks for production of diesel fuel hydrocarbons
journal, May 2008


Influence of water in the deactivation of a sulfided NiMo/γ-Al2O3 catalyst during hydrodeoxygenation
journal, March 1994


Kinetics of catalytic transfer hydrogenation of soybean oil
journal, June 1993


Utilization of vegetable oils as an alternative source for diesel-type fuel: hydrocracking on reduced Ni/SiO2 and sulphided Ni-Mo/γ-Al2O3
journal, June 1989


Decarboxylation and further transformation of oleic acid over bifunctional, Pt/SAPO-11 catalyst and Pt/chloride Al2O3 catalysts
journal, May 2014

  • Ahmadi, Masoudeh; Macias, Eugenia E.; Jasinski, Jacek B.
  • Journal of Molecular Catalysis A: Chemical, Vol. 386
  • DOI: 10.1016/j.molcata.2014.02.004

Diesel-like Hydrocarbons from Catalytic Deoxygenation of Stearic Acid over Supported Pd Nanoparticles on SBA-15 Catalysts
journal, December 2009


Aqueous phase reforming of glycerol for hydrogen production over Pt–Re supported on carbon
journal, August 2010


Corrosion Behavior of Austenitic and Ferritic Steels in Supercritical Water
journal, March 2008


Effect of Metal Ratio and Preparation Method on Nickel–Tungsten Carbide Catalyst for Hydrocracking of Distillers Dried Grains with Solubles Corn Oil
journal, April 2014

  • Al Alwan, Basem; Sari, Elvan; Salley, Steven O.
  • Industrial & Engineering Chemistry Research, Vol. 53, Issue 17
  • DOI: 10.1021/ie500241b

Production of engine fuels from inedible vegetable oils and fats
journal, July 2010

  • Berenblyum, A. S.; Danyushevsky, V. Ya.; Katsman, E. A.
  • Petroleum Chemistry, Vol. 50, Issue 4
  • DOI: 10.1134/S0965544110040080

Understanding Effect of Wall Structure on the Hydrothermal Stability of Mesostructured Silica SBA-15
journal, April 2005

  • Zhang, Fuqiang; Yan, Yan; Yang, Haifeng
  • The Journal of Physical Chemistry B, Vol. 109, Issue 18
  • DOI: 10.1021/jp044632+

Deoxygenation of dodecanoic acid under inert atmosphere
journal, August 2010


Hydrothermal catalytic processing of saturated and unsaturated fatty acids to hydrocarbons with glycerol for in situ hydrogen production
journal, January 2014

  • Vardon, Derek R.; Sharma, Brajendra K.; Jaramillo, Humberto
  • Green Chemistry, Vol. 16, Issue 3, p. 1507-1520
  • DOI: 10.1039/c3gc41798k

Hydrocracking of DDGS corn oil over transition metal carbides supported on Al-SBA-15: Effect of fractional sum of metal electronegativities
journal, September 2014


The kinetics of the catalytic-transfer hydrogenation of edible oils
journal, December 2000


Catalytic hydrothermal deoxygenation of palmitic acid
journal, January 2010

  • Fu, Jie; Lu, Xiuyang; Savage, Phillip E.
  • Energy & Environmental Science, Vol. 3, Issue 3
  • DOI: 10.1039/b923198f

The role of rhenium in the conversion of glycerol to synthesis gas over carbon supported platinum–rhenium catalysts
journal, November 2008

  • Kunkes, Edward L.; Simonetti, Dante A.; Dumesic, James A.
  • Journal of Catalysis, Vol. 260, Issue 1
  • DOI: 10.1016/j.jcat.2008.09.027

Biodiesel production: a review
journal, October 1999


Production of diesel fuel from renewable feeds: Kinetics of ethyl stearate decarboxylation
journal, November 2007

  • Snåre, M.; Kubičková, I.; Mäki-Arvela, P.
  • Chemical Engineering Journal, Vol. 134, Issue 1-3
  • DOI: 10.1016/j.cej.2007.03.064

Aqueous-phase reforming of oxygenated hydrocarbons over Sn-modified Ni catalysts
journal, February 2004

  • Shabaker, J. W.; Huber, G. W.; Dumesic, J. A.
  • Journal of Catalysis, Vol. 222, Issue 1, p. 180-191
  • DOI: 10.1016/j.jcat.2003.10.022

Hydrolysis of Vegetable Oils in Sub- and Supercritical Water
journal, March 1997

  • Holliday, Russell L.; King, Jerry W.; List, Gary R.
  • Industrial & Engineering Chemistry Research, Vol. 36, Issue 3
  • DOI: 10.1021/ie960668f

An overview of aqueous-phase catalytic processes for production of hydrogen and alkanes in a biorefinery
journal, January 2006