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Title: Large cross section for super energy transfer from hyperthermal atoms to ambient molecules

Authors:
; ; ;
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1249748
Grant/Contract Number:  
DEFG 02-86ER 134584
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Physical Review A
Additional Journal Information:
Journal Name: Physical Review A Journal Volume: 93 Journal Issue: 4; Journal ID: ISSN 2469-9926
Publisher:
American Physical Society
Country of Publication:
United States
Language:
English

Citation Formats

Ma, Jianqiang, Wilhelm, Michael J., Smith, Jonathan M., and Dai, Hai-Lung. Large cross section for super energy transfer from hyperthermal atoms to ambient molecules. United States: N. p., 2016. Web. doi:10.1103/PhysRevA.93.040702.
Ma, Jianqiang, Wilhelm, Michael J., Smith, Jonathan M., & Dai, Hai-Lung. Large cross section for super energy transfer from hyperthermal atoms to ambient molecules. United States. https://doi.org/10.1103/PhysRevA.93.040702
Ma, Jianqiang, Wilhelm, Michael J., Smith, Jonathan M., and Dai, Hai-Lung. Tue . "Large cross section for super energy transfer from hyperthermal atoms to ambient molecules". United States. https://doi.org/10.1103/PhysRevA.93.040702.
@article{osti_1249748,
title = {Large cross section for super energy transfer from hyperthermal atoms to ambient molecules},
author = {Ma, Jianqiang and Wilhelm, Michael J. and Smith, Jonathan M. and Dai, Hai-Lung},
abstractNote = {},
doi = {10.1103/PhysRevA.93.040702},
journal = {Physical Review A},
number = 4,
volume = 93,
place = {United States},
year = {2016},
month = {4}
}

Works referenced in this record:

Photolysis (193 nm) of SO 2 : Nascent Product Energy Distribution Examined through IR Emission
journal, December 2011

  • Ma, Jianqiang; Wilhelm, Michael J.; Smith, Jonathan M.
  • The Journal of Physical Chemistry A, Vol. 116, Issue 1
  • DOI: 10.1021/jp2061943

Strong combination-band IR emission from highly vibrationally excited acetylene
journal, January 2010

  • Nikow, Matthew; Wilhelm, Michael J.; Smith, Jonathan M.
  • Physical Chemistry Chemical Physics, Vol. 12, Issue 12
  • DOI: 10.1039/b918211j

Time-Resolved IR Chemiluminescence from Reactive Collisions between Hydrogen Atoms and SO2
journal, June 1995

  • Morris, Vernon R.; Han, Ke-Li; Jackson, William M.
  • The Journal of Physical Chemistry, Vol. 99, Issue 25
  • DOI: 10.1021/j100025a007

Potential-energy surface of H·SO2
journal, January 1997

  • Qi, Jian-Xin; Deng, Wei-Qiao; Han, Ke-Li
  • Journal of the Chemical Society, Faraday Transactions, Vol. 93, Issue 1
  • DOI: 10.1039/a603116a

Collisional activation of cyclobutene by hexafluorobenzene: A chemical probe for highly energetic collisions in reactive systems
journal, January 1989

  • Morgulis, Julie M.; Sapers, Steven S.; Steel, Colin
  • The Journal of Chemical Physics, Vol. 90, Issue 2
  • DOI: 10.1063/1.456118

Shock Tube Kinetic Study for the Reaction of H Atoms with SO 2 : Comparison between Experiments and Theory
journal, October 2004

  • Murakami, Yoshinori; Onishi, Shouichi; Fujii, Nobuyuki
  • The Journal of Physical Chemistry A, Vol. 108, Issue 40
  • DOI: 10.1021/jp0403700

Vibrational Modes of the Vinyl and Deuterated Vinyl Radicals
journal, August 2009

  • Nikow, Matthew; Wilhelm, Michael J.; Dai, Hai-Lung
  • The Journal of Physical Chemistry A, Vol. 113, Issue 31
  • DOI: 10.1021/jp809735e

Vibrational level structure of highly excited SO 2 in the electronic ground state. II. Vibrational assignment by dispersed fluorescence and stimulated emission pumping spectroscopy
journal, April 1990

  • Yamanouchi, Kaoru; Takeuchi, Shingo; Tsuchiya, Soji
  • The Journal of Chemical Physics, Vol. 92, Issue 7
  • DOI: 10.1063/1.457766

The Roaming Atom: Straying from the Reaction Path in Formaldehyde Decomposition
journal, November 2004


A theoretical study of the H+SO2 reaction
journal, July 1994


Chemical Reaction and Energy Transfer Between Hot H Atoms and CO 2 Molecules
journal, December 2006


Time‐resolved Fourier transform spectroscopy with 0.25 cm −1 spectral and <10 −7 s time resolution in the visible region
journal, June 1992

  • Hartland, Gregory V.; Xie, Wei; Dai, Hai‐Lung
  • Review of Scientific Instruments, Vol. 63, Issue 6
  • DOI: 10.1063/1.1143815

Sulfur Oxyacids and Radicals in the Gas Phase. A Variable-Time Neutralization−Photoexcitation−Reionization Mass Spectrometric and Ab Initio/RRKM Study
journal, December 1997

  • Frank, Aaron J.; Sadílek, Martin; Ferrier, Jordan G.
  • Journal of the American Chemical Society, Vol. 119, Issue 50
  • DOI: 10.1021/ja972602x

Temperature dependence of the reaction of OH with SO
journal, January 2000

  • Blitz, Mark A.; McKee, Kenneth W.; Pilling, Michael J.
  • Proceedings of the Combustion Institute, Vol. 28, Issue 2
  • DOI: 10.1016/S0082-0784(00)80664-5

Hot Atoms Revisited: Laser Photolysis and Product Detection
journal, October 1986


Chemical Activation through Super Energy Transfer Collisions
journal, January 2014

  • Smith, Jonathan M.; Nikow, Matthew; Ma, Jianqiang
  • Journal of the American Chemical Society, Vol. 136, Issue 5
  • DOI: 10.1021/ja4126966

Vibrational excitation through tug-of-war inelastic collisions
journal, July 2008

  • Greaves, Stuart J.; Wrede, Eckart; Goldberg, Noah T.
  • Nature, Vol. 454, Issue 7200
  • DOI: 10.1038/nature07079

Vibrational Energy Transfer
journal, January 1996

  • Flynn, George W.; Parmenter, Charles S.; Wodtke, Alec M.
  • The Journal of Physical Chemistry, Vol. 100, Issue 31
  • DOI: 10.1021/jp953735c

Double many-body expansion potential energy surface for ground state HSO2
journal, January 2005

  • Ballester, M. Y.; Varandas, A. J. C.
  • Physical Chemistry Chemical Physics, Vol. 7, Issue 11
  • DOI: 10.1039/b500990a

Collisional deactivation of highly vibrationally excited NO 2 monitored by time‐resolved Fourier transform infrared emission spectroscopy
journal, May 1994

  • Hartland, Gregory V.; Qin, Dong; Dai, Hai‐Lung
  • The Journal of Chemical Physics, Vol. 100, Issue 10
  • DOI: 10.1063/1.466827

Thermochemistry of the HOSO Radical, a Key Intermediate in Fossil Fuel Combustion
journal, June 2009

  • Wheeler, Steven E.; Schaefer, Henry F.
  • The Journal of Physical Chemistry A, Vol. 113, Issue 24
  • DOI: 10.1021/jp9029387

Vibrational state distributions and absolute excitation efficiencies for T‐V transfer collisions of NO and CO with H atoms produced by excimer laser photolysis
journal, November 1983

  • Wight, Charles A.; Leone, Stephen R.
  • The Journal of Chemical Physics, Vol. 79, Issue 10
  • DOI: 10.1063/1.445628

Dynamics and kinetics of the H+SO2 reaction: A theoretical study
journal, May 2007

  • Ballester, M. Y.; Caridade, P. J. S. B.; Varandas, A. J. C.
  • Chemical Physics Letters, Vol. 439, Issue 4-6
  • DOI: 10.1016/j.cplett.2007.03.112

Quasiclassical trajectory study of fast H-atom collisions with acetylene
journal, June 2012

  • Han, Yong-Chang; Sharma, Amit R.; Bowman, Joel M.
  • The Journal of Chemical Physics, Vol. 136, Issue 21
  • DOI: 10.1063/1.4728069

Chemical Cartography: Finding the Keys to the Kinetic Labyrinth
journal, November 1989


Vibrational energy disposal in reactive and inelastic collisions of H(D)+HCl(DCl) at 1–3 eV
journal, November 1984

  • Wight, Charles A.; Magnotta, Frank; Leone, Stephen R.
  • The Journal of Chemical Physics, Vol. 81, Issue 9
  • DOI: 10.1063/1.448188

Characterization of Reaction Pathways on the Potential Energy Surfaces for H + SO 2 and HS + O 2
journal, December 1999

  • Goumri, A.; Rocha, John-David R.; Laakso, Dianna
  • The Journal of Physical Chemistry A, Vol. 103, Issue 51
  • DOI: 10.1021/jp9924070

Vibrational relaxation in SO2
journal, March 1979


Collisional excitation of CO 2 (01 1 1) by hot hydrogen atoms: Alternating intensities in state‐resolved vibrational, rotational, and translational energy transfer
journal, July 1990

  • Khan, Farooq A.; Kreutz, Thomas G.; O’Neill, James A.
  • The Journal of Chemical Physics, Vol. 93, Issue 1
  • DOI: 10.1063/1.459718

CASPT2 Study of the Potential Energy Surface of the HSO 2 System
journal, March 2011

  • Garrido, Juan D.; Ballester, Maikel Y.; Orozco-González, Yoelvis
  • The Journal of Physical Chemistry A, Vol. 115, Issue 9
  • DOI: 10.1021/jp108460v

Collisional Energy Transfer from Highly Vibrationally Excited Radicals Is Very Efficient
journal, December 2012

  • Wilhelm, Michael J.; Nikow, Matthew; Smith, Jonathan M.
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 1
  • DOI: 10.1021/jz301761e

H+N2O collision dynamics: Branching ratios for T–V energy transfer and the effect of N2O vibrational excitation on the reaction kinetics
journal, September 1997

  • Neil, W. S.; Li, J. -Y.; Sloan, J. J.
  • The Journal of Chemical Physics, Vol. 107, Issue 12
  • DOI: 10.1063/1.474815

Excimer laser photolysis studies of translational‐to‐vibrational energy transfer in collisions of H and D atoms with CO
journal, April 1983

  • Wight, Charles A.; Leone, Stephen R.
  • The Journal of Chemical Physics, Vol. 78, Issue 8
  • DOI: 10.1063/1.445397

Combined Experimental and Master Equation Investigation of the Multiwell Reaction H + SO 2
journal, March 2006

  • Blitz, Mark A.; Hughes, Kevin J.; Pilling, Michael J.
  • The Journal of Physical Chemistry A, Vol. 110, Issue 9
  • DOI: 10.1021/jp054722u

Photodissociation of vinyl cyanide at 193 nm: Nascent product distributions of the molecular elimination channels
journal, January 2009

  • Wilhelm, Michael J.; Nikow, Matthew; Letendre, Laura
  • The Journal of Chemical Physics, Vol. 130, Issue 4
  • DOI: 10.1063/1.3065986

Spectroscopic Detection and Structure of Hydroxidooxidosulfur (HOSO) Radical, An Important Intermediate in the Chemistry of Sulfur-Bearing Compounds
journal, November 2013

  • McCarthy, Michael C.; Lattanzi, Valerio; Martinez, Oscar
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 23
  • DOI: 10.1021/jz4021537

Trajectory Study of Supercollision Relaxation in Highly Vibrationally Excited Pyrazine and CO 2
journal, September 2005

  • Li, Ziman; Sansom, Rebecca; Bonella, Sara
  • The Journal of Physical Chemistry A, Vol. 109, Issue 34
  • DOI: 10.1021/jp0525336