Rates of mineral dissolution under CO2 storage conditions

Black, Jay R.; Carroll, Susan A.; Haese, Ralf R.

doi:10.1016/j.chemgeo.2014.09.020

Title: Rates of mineral dissolution under CO₂ storage conditions

Abstract

Evaluating the potential of a sedimentary basin reservoir to securely store CO₂ benefits from a comprehensive understanding of the geochemical reactions that take place once CO₂ is injected into a formation. In particular, models that predict the transport and reaction of CO₂ within a reservoir require a definition of the types of reactions affected by enhanced levels of CO₂ and how the kinetics of these reactions will affect a heterogeneous mineralogy and formation waters within a reservoir over time. In this review we evaluate rate models used to describe mineral dissolution kinetics and compare the range in values reported for the kinetic parameters used to describe the reactivity of various minerals relevant to mainly siliciclastic reservoirs. Parameters that have a significant impact on model results include the reactive surface area of a mineral, the apparent activation energies used to extrapolate reaction rates to the temperatures of potential storage reservoirs (c. 50–125 °C) and the in-situ pH of formation waters with elevated concentrations of dissolved CO₂. The variation in reported values for these parameters can lead to predicted rates that span many orders of magnitude for a given mineral. Despite these uncertainties recent success with geochemical models has been made bymore »« less

Authors:

Black, Jay R. ^[1]; Carroll, Susan A. ^[2]; Haese, Ralf R. ^[1]

Cooperative Research Centre for Greenhouse Gas Technologies (Australia); Univ. of Melbourne (Australia)
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

Publication Date:: Wed Apr 01 00:00:00 EDT 2015

Research Org.:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Org.:: USDOE Office of Fossil Energy (FE); USDOE Office of Fossil Energy and Carbon Management (FECM)

OSTI Identifier:: 1812142

Alternate Identifier(s):: OSTI ID: 1249673

Report Number(s):: LLNL-JRNL-700437
Journal ID: ISSN 0009-2541; 828508

Grant/Contract Number:: AC52-07NA27344

Resource Type:: Accepted Manuscript

Journal Name:: Chemical Geology

Additional Journal Information:: Journal Volume: 399; Journal Issue: N/A; Journal ID: ISSN 0009-2541

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 58 GEOSCIENCES; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Mineral dissolution rates; Geochemical modelling; CO₂ storage

Citation Formats


                    Black, Jay R., Carroll, Susan A., and Haese, Ralf R. Rates of mineral dissolution under CO2 storage conditions.  United States: N. p., 2015. 
Web.  doi:10.1016/j.chemgeo.2014.09.020.

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                    Black, Jay R., Carroll, Susan A., & Haese, Ralf R. Rates of mineral dissolution under CO2 storage conditions.  United States.  https://doi.org/10.1016/j.chemgeo.2014.09.020

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                    Black, Jay R., Carroll, Susan A., and Haese, Ralf R. Wed .  
"Rates of mineral dissolution under CO2 storage conditions".  United States.  https://doi.org/10.1016/j.chemgeo.2014.09.020.  https://www.osti.gov/servlets/purl/1812142.

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@article{osti_1812142,

  title        = {Rates of mineral dissolution under CO2 storage conditions},

  author       = {Black, Jay R. and Carroll, Susan A. and Haese, Ralf R.},

  abstractNote = {Evaluating the potential of a sedimentary basin reservoir to securely store CO2 benefits from a comprehensive understanding of the geochemical reactions that take place once CO2 is injected into a formation. In particular, models that predict the transport and reaction of CO2 within a reservoir require a definition of the types of reactions affected by enhanced levels of CO2 and how the kinetics of these reactions will affect a heterogeneous mineralogy and formation waters within a reservoir over time. In this review we evaluate rate models used to describe mineral dissolution kinetics and compare the range in values reported for the kinetic parameters used to describe the reactivity of various minerals relevant to mainly siliciclastic reservoirs. Parameters that have a significant impact on model results include the reactive surface area of a mineral, the apparent activation energies used to extrapolate reaction rates to the temperatures of potential storage reservoirs (c. 50–125 °C) and the in-situ pH of formation waters with elevated concentrations of dissolved CO2. The variation in reported values for these parameters can lead to predicted rates that span many orders of magnitude for a given mineral. Despite these uncertainties recent success with geochemical models has been made by applying a Monte Carlo approach to optimise the kinetic parameters for minerals where robust thermodynamic and kinetic data do not exist.},

  doi          = {10.1016/j.chemgeo.2014.09.020},

  journal      = {Chemical Geology},

  number       = N/A,

  volume       = 399,

  place        = {United States},

  year         = {Wed Apr 01 00:00:00 EDT 2015},

  month        = {Wed Apr 01 00:00:00 EDT 2015}

}

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An experimental study of dolomite dissolution rates at 80 °C as a function of chemical affinity and solution composition
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Gautelier, Maud; Schott, Jacques; Oelkers, Eric H.
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Dissolution of insulating oxide materials at the molecular scale
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Ohlin, C. André; Villa, Eric M.; Rustad, James R.
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Kinetics of gibbsite dissolution under low ionic strength conditions
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Ganor, Jiwchar; Mogollón, Jose Luis; Lasaga, Antonio C.
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Effects of carbon dioxide on mineral weathering rates at earth surface conditions
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Hangx, Suzanne J. T.; Spiers, Christopher J.
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Nagy, K. L.; Blum, A. E.; Lasaga, A. C.
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Hamer, M.; Graham, R. C.; Amrhein, C.
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Hellevang, H.; Declercq, J.; Aagaard, P.
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Shao, Hongbo; Ray, Jessica R.; Jun, Young-Shin
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Metz, Volker; Raanan, Hadas; Pieper, Heike
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Schott, J.; Pokrovsky, O. S.; Oelkers, E. H.
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Monin, J. C.; Barth, D.; Perrut, M.
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Feldspar dissolution at 25°C and pH 3: Reaction stoichiometry and the effect of cations
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Stillings, Lisa L.; Brantley, Susan L.
Geochimica et Cosmochimica Acta, Vol. 59, Issue 8
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Experimental evaluation of interactions in supercritical CO2/water/rock minerals system under geologic CO2 sequestration conditions
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Acker, James G.; Bricker, Owen P.
Geochimica et Cosmochimica Acta, Vol. 56, Issue 8
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Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 243, Issue 866
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Marty, Nicolas C. M.; Cama, Jordi; Sato, Tsutomu
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Adsorption of Gases in Multimolecular Layers
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Brunauer, Stephen; Emmett, P. H.; Teller, Edward
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Morse, J. W.; Casey, W. H.
American Journal of Science, Vol. 288, Issue 6
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Works referencing / citing this record:

Potential for Mineral Carbonation of CO2 in Pleistocene Basaltic Rocks in Volos Region (Central Greece)
journal, October 2019

Koukouzas, Nikolaos; Koutsovitis, Petros; Tyrologou, Pavlos
Minerals, Vol. 9, Issue 10
DOI: 10.3390/min9100627

Potential of $$\hbox {CO}_{2}$$CO2 based geothermal energy extraction from hot sedimentary and dry rock reservoirs, and enabling carbon geo-sequestration
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Singh, Mrityunjay; Tangirala, Sri Kalyan; Chaudhuri, Abhijit
Geomechanics and Geophysics for Geo-Energy and Geo-Resources, Vol. 6, Issue 1
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Geochemical effects of cement mineral variations on water–rock–CO ₂ interactions in a sandstone reservoir as an experiment and modeling study
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Liu, Ning; Cheng, Jianmei
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A review of geochemical–mechanical impacts in geological carbon storage reservoirs
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Martínez-González, José Ángel; Navarro-Ruiz, Javier; Rimola, Albert
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Multiscale Computational Simulation of Amorphous Silicates’ Structural, Dielectric, and Vibrational Spectroscopic Properties
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Martínez-González, José; Navarro-Ruiz, Javier; Rimola, Albert
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Title: Rates of mineral dissolution under CO2 storage conditions

Abstract

Citation Formats

Carbon dioxide mediated dissolution of Ca-feldspar: implications for silicate weathering journal, February 2000

A model for single-phase PVTx properties of CO2–CH4–C2H6–N2–H2O–NaCl fluid mixtures from 273 to 1273K and from 1 to 5000bar journal, August 2010

Chemical and Mechanical Properties of Wellbore Cement Altered by CO 2 -Rich Brine Using a Multianalytical Approach journal, January 2013

Onset of convection in a gravitationally unstable diffusive boundary layer in porous media journal, February 2006

Coupling of geochemical reactions and convective mixing in the long-term geological storage of carbon dioxide journal, April 2007

CO2-induced dissolution of low permeability carbonates. Part II: Numerical modeling of experiments journal, December 2013

Changes in reservoir heterogeneity and quality as a response to high partial pressures of CO2 in a gas reservoir, New Zealand journal, December 2013

CO2-induced dissolution of low permeability carbonates. Part I: Characterization and experiments journal, December 2013

The dissolution kinetics of quartz as a function of pH and time at 70°C journal, January 1988

The effect of aluminum, pH, and chemical affinity on the rates of aluminosilicate dissolution reactions journal, May 1994

Solubility trapping in formation water as dominant CO2 sink in natural gas fields journal, April 2009

The effect of pH and temperature on kaolinite dissolution rate under acidic conditions journal, November 2002

Surface Chemistry and Dissolution Kinetics of Divalent Metal Carbonates journal, February 2002

Upscaling geochemical reaction rates using pore-scale network modeling journal, September 2006

Can Dawsonite Permanently Trap CO 2 ? journal, November 2005

Numerical simulation of CO2 disposal by mineral trapping in deep aquifers journal, June 2004

Dependence of labradorite dissolution kinetics on CO2(aq), Al(aq), and temperature journal, April 2005

Effects of mineral composition and heterogeneity on the reservoir quality evolution with CO 2 intrusion journal, March 2014

Bridging the gap between laboratory measurements and field estimations of silicate weathering using simple calculations journal, February 2007

The dissolution rates of dawsonite at pH 0.9 to 5 and temperatures of 22, 60 and 77°C journal, October 2010

Mineral sequestration of carbon dioxide in a sandstone–shale system journal, April 2005

Reactive transport modelling of the impact of CO2 injection on the clayey cap rock at Sleipner (North Sea) journal, April 2005

Kinetics of acid dissolution of an orthochlorite mineral journal, December 1967

Dissolution kinetics of calcite, dolomite and magnesite at 25 °C and 0 to 50 atm pCO2 journal, April 2005

Vertically averaged approaches for CO 2 migration with solubility trapping : VERTICALLY AVERAGED APPROACHES FOR CO journal, May 2011

Forsterite dissolution and magnesite precipitation at conditions relevant for deep saline aquifer storage and sequestration of carbon dioxide journal, April 2005

The kinetics of silica-water reactions journal, November 1980

Kaolinite dissolution at 25 degrees , 60 degrees , and 80 degrees C journal, September 1990

Experimental study of K-feldspar dissolution rates as a function of chemical affinity at 150°C and pH 9 journal, November 1994

Kinetic modelling of CO2–water–rock interactions journal, July 2013

The solubilities of calcite, aragonite and vaterite in CO2-H2O solutions between 0 and 90°C, and an evaluation of the aqueous model for the system CaCO3-CO2-H2O journal, June 1982

A thermodynamic model for calculating methane solubility, density and gas phase composition of methane-bearing aqueous fluids from 273 to 523K and from 1 to 2000bar journal, July 2006

An experimental study of illite dissolution kinetics as a function of ph from 1.4 to 12.4 and temperature from 5 to 50°C journal, October 2003

The Pretty Hill Formation as a natural analogue for CO 2 storage: An investigation of mineralogical and isotopic changes associated with sandstones exposed to low, intermediate and high CO 2 concentrations over geological time journal, April 2015

Aquifer-on-a-Chip: understanding pore-scale salt precipitation dynamics during CO2 sequestration journal, January 2013

Dissolution and precipitation kinetics of gibbsite at 80°C and pH 3: The dependence on solution saturation state journal, August 1992

An X-ray absorption study of the dissolution of siderite at 300 bar between 50 °C and 100 °C journal, February 2009

Sulphide oxidation and carbonate dissolution as a source of CO2 over geological timescales journal, March 2014

Role of surface speciation in the low-temperature dissolution of minerals journal, February 1988

The effect of time on the weathering of silicate minerals: why do weathering rates differ in the laboratory and field? journal, December 2003

The effect of pH on kaolinite dissolution rates and on activation energy journal, March 1995

CO2-H2O mixtures in the geological sequestration of CO2. II. Partitioning in chloride brines at 12–100°C and up to 600 bar journal, July 2005

Development of scaling parameters to describe CO2–rock interactions within Weyburn-Midale carbonate flow units journal, June 2013

The CO2QUALSTORE guideline for selection, characterisation and qualification of sites and projects for geological storage of CO2 journal, July 2011

Limitations for brine acidification due to SO2 co-injection in geologic carbon sequestration journal, May 2010

Siderite dissolution kinetics in acidic aqueous solutions from 25 to 100 °C and 0 to 50 atm pCO2 journal, July 2009

On the potential of CO2–water–rock interactions for CO2 storage using a modified kinetic model journal, July 2011

The dissolution of biotite and chlorite at 25°C in the near-neutral pH region journal, February 1996

Dissolution kinetics of kaolinite in acidic aqueous solutions at 25°C journal, September 1992

Forsterite Dissolution in Saline Water at Elevated Temperature and High CO 2 Pressure journal, June 2012

The kinetics of the dissolution of chlorite as a function of pH and at 25°C journal, April 2005

Kinetics of chlorite dissolution at elevated temperatures and CO2 conditions journal, June 2013

Variation of Crystal Dissolution Rate Based on a Dissolution Stepwave Model journal, March 2001

Surface roughness of minerals and implications for dissolution studies journal, April 1992

The dependence of dissolution rates on grain size for some fresh and weathered feldspars journal, November 1992

Degradation of Well Cement by CO 2 under Geologic Sequestration Conditions journal, July 2007

Etch pit coalescence, surface area, and overall mineral dissolution rates journal, November 2005

Effect of pH and organic ligands on the kinetics of smectite dissolution at 25°C journal, September 2006

The effect of partial pressure of carbon dioxide on anorthite dissolution. journal, January 1999

Predicting CO2–water interfacial tension under pressure and temperature conditions of geologic CO2 storage journal, March 2012

Chlorite dissolution in the acid ph-range: a combined microscopic and macroscopic approach journal, April 2003

Change in surface area and dissolution rates during hornblende dissolution at pH 4.0 journal, April 1993

Surface reactions during the early stages of weathering of albite journal, August 1992

Dissolution kinetics of fosteritic olivine at 90–150°C including effects of the presence of CO2 journal, September 2006

The kinetics of chlorite dissolution journal, March 2007

CO2-H2O mixtures in the geological sequestration of CO2. I. Assessment and calculation of mutual solubilities from 12 to 100°C and up to 600 bar journal, August 2003

Smectite dissolution kinetics at 80°C and pH 8.8 journal, August 2000

A New Equation of State for Carbon Dioxide Covering the Fluid Region from the Triple‐Point Temperature to 1100 K at Pressures up to 800 MPa journal, November 1996

The role of reaction affinity and secondary minerals in regulating chemical weathering rates at the Santa Cruz Soil Chronosequence, California journal, May 2009

Calcite, dolomite and magnesite dissolution kinetics in aqueous solutions at acid to circumneutral pH, 25 to 150 °C and 1 to 55 atm pCO2: New constraints on CO2 sequestration in sedimentary basins journal, July 2009

Relation between the dissolution rates of single minerals and reservoir rocks in acidified pore waters journal, August 2011

Numerical modeling of injection and mineral trapping of CO2 with H2S and SO2 in a sandstone formation journal, August 2007

Metastable structures and isotope exchange reactions in polyoxometalate ions provide a molecular view of oxide dissolution journal, January 2012

Simple mechanistic models for inhibition of a dissolution reaction journal, April 1998

An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar journal, February 2003

Experimental study of anorthite dissolution and the relative mechanism of feldspar hydrolysis journal, December 1995

Dissolution kinetics as a function of the Gibbs free energy of reaction: An experimental study based on albite feldspar journal, January 2006

Title: Rates of mineral dissolution under CO₂ storage conditions

Carbon dioxide mediated dissolution of Ca-feldspar: implications for silicate weathering
journal, February 2000

A model for single-phase PVTx properties of CO2–CH4–C2H6–N2–H2O–NaCl fluid mixtures from 273 to 1273K and from 1 to 5000bar
journal, August 2010

Chemical and Mechanical Properties of Wellbore Cement Altered by CO ₂ -Rich Brine Using a Multianalytical Approach
journal, January 2013

Onset of convection in a gravitationally unstable diffusive boundary layer in porous media
journal, February 2006

Coupling of geochemical reactions and convective mixing in the long-term geological storage of carbon dioxide
journal, April 2007

CO2-induced dissolution of low permeability carbonates. Part II: Numerical modeling of experiments
journal, December 2013

Changes in reservoir heterogeneity and quality as a response to high partial pressures of CO2 in a gas reservoir, New Zealand
journal, December 2013

CO2-induced dissolution of low permeability carbonates. Part I: Characterization and experiments
journal, December 2013

The dissolution kinetics of quartz as a function of pH and time at 70°C
journal, January 1988

The effect of aluminum, pH, and chemical affinity on the rates of aluminosilicate dissolution reactions
journal, May 1994

Solubility trapping in formation water as dominant CO2 sink in natural gas fields
journal, April 2009

The effect of pH and temperature on kaolinite dissolution rate under acidic conditions
journal, November 2002

Surface Chemistry and Dissolution Kinetics of Divalent Metal Carbonates
journal, February 2002

Upscaling geochemical reaction rates using pore-scale network modeling
journal, September 2006

Can Dawsonite Permanently Trap CO ₂ ?
journal, November 2005

Numerical simulation of CO2 disposal by mineral trapping in deep aquifers
journal, June 2004

Dependence of labradorite dissolution kinetics on CO2(aq), Al(aq), and temperature
journal, April 2005

Effects of mineral composition and heterogeneity on the reservoir quality evolution with CO ₂ intrusion
journal, March 2014

Bridging the gap between laboratory measurements and field estimations of silicate weathering using simple calculations
journal, February 2007

The dissolution rates of dawsonite at pH 0.9 to 5 and temperatures of 22, 60 and 77°C
journal, October 2010

Mineral sequestration of carbon dioxide in a sandstone–shale system
journal, April 2005

Reactive transport modelling of the impact of CO2 injection on the clayey cap rock at Sleipner (North Sea)
journal, April 2005

Kinetics of acid dissolution of an orthochlorite mineral
journal, December 1967

Dissolution kinetics of calcite, dolomite and magnesite at 25 °C and 0 to 50 atm pCO2
journal, April 2005

Vertically averaged approaches for CO ₂ migration with solubility trapping : VERTICALLY AVERAGED APPROACHES FOR CO
journal, May 2011

Forsterite dissolution and magnesite precipitation at conditions relevant for deep saline aquifer storage and sequestration of carbon dioxide
journal, April 2005

The kinetics of silica-water reactions
journal, November 1980

Kaolinite dissolution at 25 degrees , 60 degrees , and 80 degrees C
journal, September 1990

Experimental study of K-feldspar dissolution rates as a function of chemical affinity at 150°C and pH 9
journal, November 1994

Kinetic modelling of CO2–water–rock interactions
journal, July 2013

The solubilities of calcite, aragonite and vaterite in CO2-H2O solutions between 0 and 90°C, and an evaluation of the aqueous model for the system CaCO3-CO2-H2O
journal, June 1982

A thermodynamic model for calculating methane solubility, density and gas phase composition of methane-bearing aqueous fluids from 273 to 523K and from 1 to 2000bar
journal, July 2006

An experimental study of illite dissolution kinetics as a function of ph from 1.4 to 12.4 and temperature from 5 to 50°C
journal, October 2003

The Pretty Hill Formation as a natural analogue for CO 2 storage: An investigation of mineralogical and isotopic changes associated with sandstones exposed to low, intermediate and high CO 2 concentrations over geological time
journal, April 2015

Aquifer-on-a-Chip: understanding pore-scale salt precipitation dynamics during CO2 sequestration
journal, January 2013

Dissolution and precipitation kinetics of gibbsite at 80°C and pH 3: The dependence on solution saturation state
journal, August 1992

An X-ray absorption study of the dissolution of siderite at 300 bar between 50 °C and 100 °C
journal, February 2009

Sulphide oxidation and carbonate dissolution as a source of CO2 over geological timescales
journal, March 2014

Role of surface speciation in the low-temperature dissolution of minerals
journal, February 1988

The effect of time on the weathering of silicate minerals: why do weathering rates differ in the laboratory and field?
journal, December 2003

The effect of pH on kaolinite dissolution rates and on activation energy
journal, March 1995

CO2-H2O mixtures in the geological sequestration of CO2. II. Partitioning in chloride brines at 12–100°C and up to 600 bar
journal, July 2005

Development of scaling parameters to describe CO2–rock interactions within Weyburn-Midale carbonate flow units
journal, June 2013

The CO2QUALSTORE guideline for selection, characterisation and qualification of sites and projects for geological storage of CO2
journal, July 2011

Limitations for brine acidification due to SO2 co-injection in geologic carbon sequestration
journal, May 2010

Siderite dissolution kinetics in acidic aqueous solutions from 25 to 100 °C and 0 to 50 atm pCO2
journal, July 2009

On the potential of CO2–water–rock interactions for CO2 storage using a modified kinetic model
journal, July 2011

The dissolution of biotite and chlorite at 25°C in the near-neutral pH region
journal, February 1996

Dissolution kinetics of kaolinite in acidic aqueous solutions at 25°C
journal, September 1992

Forsterite Dissolution in Saline Water at Elevated Temperature and High CO ₂ Pressure
journal, June 2012

The kinetics of the dissolution of chlorite as a function of pH and at 25°C
journal, April 2005

Kinetics of chlorite dissolution at elevated temperatures and CO2 conditions
journal, June 2013

Variation of Crystal Dissolution Rate Based on a Dissolution Stepwave Model
journal, March 2001

Surface roughness of minerals and implications for dissolution studies
journal, April 1992

The dependence of dissolution rates on grain size for some fresh and weathered feldspars
journal, November 1992

Degradation of Well Cement by CO ₂ under Geologic Sequestration Conditions
journal, July 2007

Etch pit coalescence, surface area, and overall mineral dissolution rates
journal, November 2005

Effect of pH and organic ligands on the kinetics of smectite dissolution at 25°C
journal, September 2006

The effect of partial pressure of carbon dioxide on anorthite dissolution.
journal, January 1999

Predicting CO2–water interfacial tension under pressure and temperature conditions of geologic CO2 storage
journal, March 2012

Chlorite dissolution in the acid ph-range: a combined microscopic and macroscopic approach
journal, April 2003

Change in surface area and dissolution rates during hornblende dissolution at pH 4.0
journal, April 1993

Surface reactions during the early stages of weathering of albite
journal, August 1992

Dissolution kinetics of fosteritic olivine at 90–150°C including effects of the presence of CO2
journal, September 2006

The kinetics of chlorite dissolution
journal, March 2007

CO₂-H₂O mixtures in the geological sequestration of CO₂. I. Assessment and calculation of mutual solubilities from 12 to 100°C and up to 600 bar
journal, August 2003

Smectite dissolution kinetics at 80°C and pH 8.8
journal, August 2000

A New Equation of State for Carbon Dioxide Covering the Fluid Region from the Triple‐Point Temperature to 1100 K at Pressures up to 800 MPa
journal, November 1996

The role of reaction affinity and secondary minerals in regulating chemical weathering rates at the Santa Cruz Soil Chronosequence, California
journal, May 2009

Calcite, dolomite and magnesite dissolution kinetics in aqueous solutions at acid to circumneutral pH, 25 to 150 °C and 1 to 55 atm pCO2: New constraints on CO2 sequestration in sedimentary basins
journal, July 2009

Relation between the dissolution rates of single minerals and reservoir rocks in acidified pore waters
journal, August 2011

Numerical modeling of injection and mineral trapping of CO2 with H2S and SO2 in a sandstone formation
journal, August 2007

Metastable structures and isotope exchange reactions in polyoxometalate ions provide a molecular view of oxide dissolution
journal, January 2012

Simple mechanistic models for inhibition of a dissolution reaction
journal, April 1998

An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar
journal, February 2003

Experimental study of anorthite dissolution and the relative mechanism of feldspar hydrolysis
journal, December 1995

Dissolution kinetics as a function of the Gibbs free energy of reaction: An experimental study based on albite feldspar
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