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Title: Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries

Fluorinated carbonate solvents are pursued as liquid electrolytes for high-voltage Li-ion batteries. We report aggregation of [Li +(FEC) 3] n polymer species from fluoroethylene carbonate containing electrolytes and scrutinized the causes for this behavior.
Authors:
 [1] ;  [2] ;  [3] ;  [3] ;  [3]
  1. Argonne National Lab. (ANL), Argonne, IL (United States); Northwestern Univ., Evanston, IL (United States)
  2. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
  3. Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Report Number(s):
SAND-2016-1267J
Journal ID: ISSN 1463-9076; PPCPFQ; 619516
Grant/Contract Number:
AC04-94AL85000; SC0001160; AC02-06CH11357
Type:
Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics. PCCP (Print); Journal Volume: 18; Journal Issue: 16; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Research Org:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org:
USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE
OSTI Identifier:
1249078

Malliakas, Christos D., Leung, Kevin, Pupek, Krzysztof Z., Shkrob, Ilya A., and Abraham, Daniel P.. Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries. United States: N. p., Web. doi:10.1039/c6cp01157h.
Malliakas, Christos D., Leung, Kevin, Pupek, Krzysztof Z., Shkrob, Ilya A., & Abraham, Daniel P.. Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries. United States. doi:10.1039/c6cp01157h.
Malliakas, Christos D., Leung, Kevin, Pupek, Krzysztof Z., Shkrob, Ilya A., and Abraham, Daniel P.. 2016. "Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries". United States. doi:10.1039/c6cp01157h. https://www.osti.gov/servlets/purl/1249078.
@article{osti_1249078,
title = {Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries},
author = {Malliakas, Christos D. and Leung, Kevin and Pupek, Krzysztof Z. and Shkrob, Ilya A. and Abraham, Daniel P.},
abstractNote = {Fluorinated carbonate solvents are pursued as liquid electrolytes for high-voltage Li-ion batteries. We report aggregation of [Li+(FEC)3]n polymer species from fluoroethylene carbonate containing electrolytes and scrutinized the causes for this behavior.},
doi = {10.1039/c6cp01157h},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
number = 16,
volume = 18,
place = {United States},
year = {2016},
month = {3}
}

Works referenced in this record:

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004