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Title: Photoinduced Bimolecular Electron Transfer from Cyano Anions in Ionic Liquids

Abstract

Ionic liquids with electron-donating anions are used to investigate rates and mechanisms of photoinduced bimolecular electron transfer to the photoexcited acceptor 9,10-dicyanoanthracene (9,10-DCNA). The set of five cyano anion ILs studied comprises the 1-ethyl-3-methylimidazolium cation paired with each of these five anions: selenocyanate, thiocyanate, dicyanamide, tricyanomethanide, and tetracyano-borate. Measurements with these anions dilute in acetonitrile and 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)-amide show that the selenocyanate and tricyanomethanide anions are strong quenchers of the 9,10-DCNA fluorescence, thiocyanate is a moderately strong quencher, dicyanamide is a weak quencher, and no quenching is observed for tetracyanoborate. Quenching rates are obtained from both time-resolved fluorescence transients and time-integrated spectra. Finally, application of a Smoluchowski diffusion-and-reaction model showed that the complex kinetics observed can be fit using only two adjustable parameters, D and V0, where D is the relative diffusion coefficient between donor and acceptor and V0 is the value of the electronic coupling at donor-acceptor contact.

Authors:
 [1];  [1];  [2];  [1]
+ Show Author Affiliations
  1. Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Road, Piscataway, New Jersey 08854, United States
  2. Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, United States
Publication Date:
Research Org.:
Rutgers Univ., Piscataway, NJ (United States); Pennsylvania State Univ., University Park, PA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1248414
Alternate Identifier(s):
OSTI ID: 1434921
Grant/Contract Number:  
SC0001780; SC0008640
Resource Type:
Published Article
Journal Name:
Journal of Physical Chemistry. B
Additional Journal Information:
Journal Name: Journal of Physical Chemistry. B Journal Volume: 119 Journal Issue: 46; Journal ID: ISSN 1520-6106
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Wu, Boning, Liang, Min, Maroncelli, Mark, and Castner, Jr., Edward W. Photoinduced Bimolecular Electron Transfer from Cyano Anions in Ionic Liquids. United States: N. p., 2015. Web. doi:10.1021/acs.jpcb.5b09216.
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Wu, Boning, Liang, Min, Maroncelli, Mark, & Castner, Jr., Edward W. Photoinduced Bimolecular Electron Transfer from Cyano Anions in Ionic Liquids. United States. https://doi.org/10.1021/acs.jpcb.5b09216
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Wu, Boning, Liang, Min, Maroncelli, Mark, and Castner, Jr., Edward W. Mon . "Photoinduced Bimolecular Electron Transfer from Cyano Anions in Ionic Liquids". United States. https://doi.org/10.1021/acs.jpcb.5b09216.
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@article{osti_1248414,
title = {Photoinduced Bimolecular Electron Transfer from Cyano Anions in Ionic Liquids},
author = {Wu, Boning and Liang, Min and Maroncelli, Mark and Castner, Jr., Edward W.},
abstractNote = {Ionic liquids with electron-donating anions are used to investigate rates and mechanisms of photoinduced bimolecular electron transfer to the photoexcited acceptor 9,10-dicyanoanthracene (9,10-DCNA). The set of five cyano anion ILs studied comprises the 1-ethyl-3-methylimidazolium cation paired with each of these five anions: selenocyanate, thiocyanate, dicyanamide, tricyanomethanide, and tetracyano-borate. Measurements with these anions dilute in acetonitrile and 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)-amide show that the selenocyanate and tricyanomethanide anions are strong quenchers of the 9,10-DCNA fluorescence, thiocyanate is a moderately strong quencher, dicyanamide is a weak quencher, and no quenching is observed for tetracyanoborate. Quenching rates are obtained from both time-resolved fluorescence transients and time-integrated spectra. Finally, application of a Smoluchowski diffusion-and-reaction model showed that the complex kinetics observed can be fit using only two adjustable parameters, D and V0, where D is the relative diffusion coefficient between donor and acceptor and V0 is the value of the electronic coupling at donor-acceptor contact.},
doi = {10.1021/acs.jpcb.5b09216},
journal = {Journal of Physical Chemistry. B},
number = 46,
volume = 119,
place = {United States},
year = {Mon Nov 09 00:00:00 EST 2015},
month = {Mon Nov 09 00:00:00 EST 2015}
}
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https://doi.org/10.1021/acs.jpcb.5b09216
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Works referenced in this record:

Heterogeneity in a room-temperature ionic liquid: Persistent local environments and the red-edge effect
journal, January 2006

  • Hu, Z.; Margulis, C. J.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 4
  • DOI: 10.1073/pnas.0507364103

Bimolecular Electron Transfer in Ionic Liquids: Are Reaction Rates Anomalously High?
journal, January 2012

  • Liang, Min; Kaintz, Anne; Baker, Gary A.
  • The Journal of Physical Chemistry B, Vol. 116, Issue 4
  • DOI: 10.1021/jp210892c

Ionic-liquid materials for the electrochemical challenges of the future
journal, July 2009

  • Armand, Michel; Endres, Frank; MacFarlane, Douglas R.
  • Nature Materials, Vol. 8, Issue 8, p. 621-629
  • DOI: 10.1038/nmat2448

Outer-sphere electron transfer in polar solvents
journal, July 1980

On the Theory of Oxidation‐Reduction Reactions Involving Electron Transfer. I
journal, May 1956

  • Marcus, R. A.
  • The Journal of Chemical Physics, Vol. 24, Issue 5
  • DOI: 10.1063/1.1742723

Electrostatic Free Energy and Other Properties of States Having Nonequilibrium Polarization. I
journal, May 1956

  • Marcus, R. A.
  • The Journal of Chemical Physics, Vol. 24, Issue 5
  • DOI: 10.1063/1.1742724

Electrochemical Characterization of 1-Ethyl-3-methylimidazolium Thiocyanate and Measurement of Triiodide Diffusion Coefficients in Blends of two Ionic Liquids
journal, January 2008

Adiabatic Electron Transfer in a Room-Temperature Ionic Liquid: Reaction Dynamics and Kinetics
journal, October 2009

  • Shim, Youngseon; Kim, Hyung J.
  • The Journal of Physical Chemistry B, Vol. 113, Issue 39
  • DOI: 10.1021/jp9065407

Electron transfers in chemistry and biology
journal, August 1985

  • Marcus, R. A.; Sutin, Norman
  • Biochimica et Biophysica Acta (BBA) - Reviews on Bioenergetics, Vol. 811, Issue 3
  • DOI: 10.1016/0304-4173(85)90014-X

Time-Dependent Rate Coefficients for Diffusion-Influenced Reactions with Centrosymmetric Potentials
journal, March 2005

  • Dudko, Olga K.; Szabo, Attila
  • The Journal of Physical Chemistry B, Vol. 109, Issue 12
  • DOI: 10.1021/jp044433q

Viscosity of (C2–C14) 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide ionic liquids in an extended temperature range
journal, February 2011

  • Tariq, Mohammad; Carvalho, Pedro J.; Coutinho, João A. P.
  • Fluid Phase Equilibria, Vol. 301, Issue 1
  • DOI: 10.1016/j.fluid.2010.10.018

Free Energy of Nonequilibrium Polarization Systems. II. Homogeneous and Electrode Systems
journal, April 1963

  • Marcus, R. A.
  • The Journal of Chemical Physics, Vol. 38, Issue 8
  • DOI: 10.1063/1.1733886

1-Ethyl-3-methylimidazolium Based Ionic Liquids Containing Cyano Groups:  Synthesis, Characterization, and Crystal Structure
journal, February 2004

  • Yoshida, Yukihiro; Muroi, Koji; Otsuka, Akihiro
  • Inorganic Chemistry, Vol. 43, Issue 4
  • DOI: 10.1021/ic035045q

Ionic Liquids at Electrified Interfaces
journal, March 2014

  • Fedorov, Maxim V.; Kornyshev, Alexei A.
  • Chemical Reviews, Vol. 114, Issue 5
  • DOI: 10.1021/cr400374x

Computer simulation studies of electron transfer parameters for cyanoanthracene/N,N-dimethylaniline solutions
journal, March 2003

  • Scherer, P. O. J.; Tachiya, M.
  • The Journal of Chemical Physics, Vol. 118, Issue 9
  • DOI: 10.1063/1.1541617

How Is Diffusion of Neutral and Charged Tracers Related to the Structure and Dynamics of a Room-Temperature Ionic Liquid? Large Deviations from Stokes–Einstein Behavior Explained
journal, April 2015

  • Araque, Juan C.; Yadav, Sharad K.; Shadeck, Michael
  • The Journal of Physical Chemistry B, Vol. 119, Issue 23
  • DOI: 10.1021/acs.jpcb.5b01093

Dynamic Stokes Shift and Excitation Wavelength Dependent Fluorescence of Dipolar Molecules in Room Temperature Ionic Liquids
journal, July 2006

  • Samanta, Anunay
  • The Journal of Physical Chemistry B, Vol. 110, Issue 28
  • DOI: 10.1021/jp060441q

Photoelectron transfer from excited-state ruthenium(ii) tris(bipyridyl) to methylviologen in an ionic liquid
journal, January 2000

  • Gordon, Charles M.; McLean, Andrew J.
  • Chemical Communications, Issue 15
  • DOI: 10.1039/b003754k

How Does the Ionic Liquid Organizational Landscape Change when Nonpolar Cationic Alkyl Groups Are Replaced by Polar Isoelectronic Diethers?
journal, January 2013

  • Kashyap, Hemant K.; Santos, Cherry S.; Daly, Ryan P.
  • The Journal of Physical Chemistry B, Vol. 117, Issue 4
  • DOI: 10.1021/jp311032p

Electrochemical Reactivity in Room-Temperature Ionic Liquids
journal, July 2008

  • Hapiot, Philippe; Lagrost, Corinne
  • Chemical Reviews, Vol. 108, Issue 7
  • DOI: 10.1021/cr0680686

Theory of diffusion-influenced fluorescence quenching
journal, September 1989

Spurious Observation of the Marcus Inverted Region in Bimolecular Photoinduced Electron Transfer
journal, July 2012

  • Rosspeintner, Arnulf; Koch, Marius; Angulo, Gonzalo
  • Journal of the American Chemical Society, Vol. 134, Issue 28
  • DOI: 10.1021/ja3049095

Physical trends and structural features in organic salts of the thiocyanate anion
journal, October 2002

  • Pringle, Jennifer M.; Golding, Jake; Forsyth, Craig M.
  • Journal of Materials Chemistry, Vol. 12, Issue 12
  • DOI: 10.1039/b208372h

Experimental Evidence of the Relevance of Orientational Correlations in Photoinduced Bimolecular Reactions in Solution
journal, August 2013

  • Angulo, Gonzalo; Cuetos, Alejandro; Rosspeintner, Arnulf
  • The Journal of Physical Chemistry A, Vol. 117, Issue 36
  • DOI: 10.1021/jp407203r

Excitation Wavelength Dependence of the Dynamics of Bimolecular Photoinduced Electron Transfer Reactions
journal, April 2014

  • Letrun, Romain; Vauthey, Eric
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 10
  • DOI: 10.1021/jz500569r

A Study of the Time-Resolved Fluorescence Spectrum and Red Edge Effect of ANF in a Room-Temperature Ionic Liquid
journal, June 2006

  • Hu, Zhonghan; Margulis, Claudio J.
  • The Journal of Physical Chemistry B, Vol. 110, Issue 23
  • DOI: 10.1021/jp061652y

Influence of Diffusion on the Kinetics of Donor−Acceptor Electron Transfer Monitored by the Quenching of Donor Fluorescence
journal, August 2002

  • Gladkikh, V. S.; Burshtein, A. I.; Tavernier, H. L.
  • The Journal of Physical Chemistry A, Vol. 106, Issue 30
  • DOI: 10.1021/jp0207228

Application of 1-ethyl-3-methylimidazolium thiocyanate to the electrolyte of electrochemical double layer capacitors
journal, November 2006

Chemical Dynamics in Condensed Phases
book, April 2006

Electron-Transfer Dynamics for a Donor–Bridge–Acceptor Complex in Ionic Liquids
journal, July 2015

  • DeVine, Jessalyn A.; Labib, Marena; Harries, Megan E.
  • The Journal of Physical Chemistry B, Vol. 119, Issue 34
  • DOI: 10.1021/acs.jpcb.5b03320

Dielectric Relaxation and Solvation Dynamics in a Prototypical Ionic Liquid + Dipolar Protic Liquid Mixture: 1-Butyl-3-Methylimidazolium Tetrafluoroborate + Water
journal, June 2013

  • Zhang, Xin-Xing; Liang, Min; Hunger, Johannes
  • The Journal of Physical Chemistry B, Vol. 117, Issue 49
  • DOI: 10.1021/jp4043528

Ionic Liquids in Electrochemical Devices and Processes: Managing Interfacial Electrochemistry
journal, November 2007

  • MacFarlane, Douglas R.; Forsyth, Maria; Howlett, Patrick C.
  • Accounts of Chemical Research, Vol. 40, Issue 11
  • DOI: 10.1021/ar7000952

Interactions between water and 1-butyl-1-methylpyrrolidinium ionic liquids
journal, August 2015

  • Fadeeva, Tatiana A.; Husson, Pascale; DeVine, Jessalyn A.
  • The Journal of Chemical Physics, Vol. 143, Issue 6
  • DOI: 10.1063/1.4928065

Molecular volumes and the Stokes-Einstein equation
journal, April 1970

  • Edward, John T.
  • Journal of Chemical Education, Vol. 47, Issue 4
  • DOI: 10.1021/ed047p261

Solvent-Controlled Intramolecular Electron Transfer in Ionic Liquids
journal, May 2011

  • Li, Xiang; Liang, Min; Chakraborty, Anjan
  • The Journal of Physical Chemistry B, Vol. 115, Issue 20
  • DOI: 10.1021/jp200339e

Exact calculation of the solvation energy of a pair of ions in polar media within the framework of the dielectric continuum model
journal, November 1998

  • Miyazaki, Kunimasa; Tachiya, M.
  • The Journal of Chemical Physics, Vol. 109, Issue 17
  • DOI: 10.1063/1.477364

A Comparison of Electron-Transfer Dynamics in Ionic Liquids and Neutral Solvents
journal, February 2012

  • Lee, Heather Y.; Issa, Joseph B.; Isied, Stephan S.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 8
  • DOI: 10.1021/jp208852r

A Comparative Electrochemical Study of Diffusion in Room Temperature Ionic Liquid Solvents versus Acetonitrile
journal, March 2005

  • Evans, Russell G.; Klymenko, Oleksiy V.; Price, Paul D.
  • ChemPhysChem, Vol. 6, Issue 3
  • DOI: 10.1002/cphc.200400549

High-Pressure Testing of Heterogeneous Charge Transfer in a Room-Temperature Ionic Liquid:  Evidence for Solvent Dynamic Control
journal, March 2008

  • Dolidze, Tina D.; Khoshtariya, Dimitri E.; Illner, Peter
  • The Journal of Physical Chemistry B, Vol. 112, Issue 10
  • DOI: 10.1021/jp077734j

Controlling the Outcome of Electron Transfer Reactions in Ionic Liquids
journal, September 2009

  • Annapureddy, Harsha V. R.; Margulis, Claudio J.
  • The Journal of Physical Chemistry B, Vol. 113, Issue 35
  • DOI: 10.1021/jp905144n

Bimolecular Photoinduced Electron Transfer in Imidazolium-Based Room-Temperature Ionic Liquids Is Not Faster than in Conventional Solvents
journal, February 2012

  • Koch, Marius; Rosspeintner, Arnulf; Angulo, Gonzalo
  • Journal of the American Chemical Society, Vol. 134, Issue 8
  • DOI: 10.1021/ja208265x

Communication: Unusual structure and transport in ionic liquid-hexane mixtures
journal, March 2015

  • Liang, Min; Khatun, Sufia; Castner, Edward W.
  • The Journal of Chemical Physics, Vol. 142, Issue 12
  • DOI: 10.1063/1.4916388

Lifetimes of Radical Anions of Dicyanoanthracene, Phenazine, and Anthraquinone in the Excited State from the Selective Electron-Transfer Quenching
journal, January 1996

  • Fujita, Morifumi; Ishida, Akito; Majima, Tetsuro
  • The Journal of Physical Chemistry, Vol. 100, Issue 13
  • DOI: 10.1021/jp953203w

Solute Diffusion in Ionic Liquids, NMR Measurements and Comparisons to Conventional Solvents
journal, September 2013

  • Kaintz, Anne; Baker, Gary; Benesi, Alan
  • The Journal of Physical Chemistry B, Vol. 117, Issue 39
  • DOI: 10.1021/jp405393d

On the Theory of Electron‐Transfer Reactions. VI. Unified Treatment for Homogeneous and Electrode Reactions
journal, July 1965

  • Marcus, R. A.
  • The Journal of Chemical Physics, Vol. 43, Issue 2
  • DOI: 10.1063/1.1696792

Energy applications of ionic liquids
journal, January 2009

  • Wishart, James F.
  • Energy & Environmental Science, Vol. 2, Issue 9
  • DOI: 10.1039/b906273d

Ionic Liquids: Structure and Photochemical Reactions
journal, May 2011

Solute–solute spatial distribution in hydrogen bonding liquids probed with time-dependent intermolecular electron transfer
journal, January 2001

  • Tavernier, H. L.; Fayer, M. D.
  • The Journal of Chemical Physics, Vol. 114, Issue 10
  • DOI: 10.1063/1.1349705

Solvent as Electron Donor:  Donor/Acceptor Electronic Coupling Is a Dynamical Variable
journal, March 2000

  • Castner, Edward W.; Kennedy, Darcy; Cave, Robert J.
  • The Journal of Physical Chemistry A, Vol. 104, Issue 13
  • DOI: 10.1021/jp9936852

Solubility of CO2 in ionic liquids containing cyanide anions: [c2mim][SCN], [c2mim][N(CN)2], [c2mim][C(CN)3]
journal, April 2014

Morphology and intermolecular dynamics of 1-alkyl-3-methylimidazolium bis{(trifluoromethane)sulfonyl}amide ionic liquids: structural and dynamic evidence of nanoscale segregation
journal, September 2009

Ultrafast Structure and Dynamics in Ionic Liquids: 2D-IR Spectroscopy Probes the Molecular Origin of Viscosity
journal, April 2014

  • Ren, Zhe; Ivanova, Anna S.; Couchot-Vore, Duane
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 9
  • DOI: 10.1021/jz500372f

Photoinduced Intermolecular Electron Transfer in Liquid Solutions
journal, July 2004

  • Saik, V. O.; Goun, A. A.; Nanda, J.
  • The Journal of Physical Chemistry A, Vol. 108, Issue 32
  • DOI: 10.1021/jp049391k

Structure of 1-Alkyl-1-methylpyrrolidinium Bis(trifluoromethylsulfonyl)amide Ionic Liquids with Linear, Branched, and Cyclic Alkyl Groups
journal, July 2013

  • Kashyap, Hemant K.; Santos, Cherry S.; Murthy, N. Sanjeeva
  • The Journal of Physical Chemistry B, Vol. 117, Issue 49
  • DOI: 10.1021/jp403518j

Dynamic solvent effects on outer‐sphere electron transfer
journal, August 1987

  • Rips, Ilya; Jortner, Joshua
  • The Journal of Chemical Physics, Vol. 87, Issue 4
  • DOI: 10.1063/1.453184

On the Coherent Description of Diffusion-Influenced Fluorescence Quenching Experiments II: Early Events
journal, February 2010

  • Angulo, Gonzalo; Kattnig, Daniel R.; Rosspeintner, Arnulf
  • Chemistry - A European Journal, Vol. 16, Issue 7
  • DOI: 10.1002/chem.200901693

Ultrafast Photochemistry in Liquids
journal, April 2013

Comparison of Diffusivity Data Derived from Electrochemical and NMR Investigations of the SeCN¯/(SeCN) 2 /(SeCN) 3 ¯ System in Ionic Liquids
journal, June 2011

  • Solangi, Amber; Bond, Alan M.; Burgar, Iko
  • The Journal of Physical Chemistry B, Vol. 115, Issue 21
  • DOI: 10.1021/jp111977q

Electrochemical Stability of Imidazolium Based Ionic Liquids Containing Cyano Groups in the Anion: A Cyclic Voltammetry, XPS and DFT Study
journal, January 2012

  • Weingarth, Daniel; Czekaj, Izabela; Fei, Zhaofu
  • Journal of The Electrochemical Society, Vol. 159, Issue 7
  • DOI: 10.1149/2.001207jes

A Solvent-Free, SeCN - /(SeCN) 3 - Based Ionic Liquid Electrolyte for High-Efficiency Dye-Sensitized Nanocrystalline Solar Cells
journal, June 2004

  • Wang, Peng; Zakeeruddin, Shaik M.; Moser, Jacques-E.
  • Journal of the American Chemical Society, Vol. 126, Issue 23
  • DOI: 10.1021/ja048472r

Low viscosity ionic liquids based on organic salts of the dicyanamide anion
journal, January 2001

  • MacFarlane, Douglas R.; Golding, Jake; Forsyth, Stewart
  • Chemical Communications, Issue 16
  • DOI: 10.1039/b103064g

Ionic Liquids Based on Polynitrile Anions: Hydrophobicity, Low Proton Affinity, and High Radiolytic Resistance Combined
journal, May 2013

  • Shkrob, Ilya A.; Marin, Timothy W.; Wishart, James F.
  • The Journal of Physical Chemistry B, Vol. 117, Issue 23
  • DOI: 10.1021/jp404313g

Fast Calculation of van der Waals Volume as a Sum of Atomic and Bond Contributions and Its Application to Drug Compounds
journal, September 2003

  • Zhao, Yuan H.; Abraham, Michael H.; Zissimos, Andreas M.
  • The Journal of Organic Chemistry, Vol. 68, Issue 19
  • DOI: 10.1021/jo034808o

Diffusion‐controlled electron transfer reactions: Subpicosecond fluorescence measurements of coumarin 1 quenched by aniline and N , N ‐dimethylaniline
journal, October 1995

  • Shannon, Colman F.; Eads, Daniel D.
  • The Journal of Chemical Physics, Vol. 103, Issue 13
  • DOI: 10.1063/1.470557

Physicochemical Properties and Structures of Room Temperature Ionic Liquids. 2. Variation of Alkyl Chain Length in Imidazolium Cation
journal, April 2005

  • Tokuda, Hiroyuki; Hayamizu, Kikuko; Ishii, Kunikazu
  • The Journal of Physical Chemistry B, Vol. 109, Issue 13
  • DOI: 10.1021/jp044626d

Cation/Anion Associations in Ionic Liquids Modulated by Hydration and Ionic Medium
journal, April 2011

  • Hou, Jianbo; Zhang, Zhiyang; Madsen, Louis A.
  • The Journal of Physical Chemistry B, Vol. 115, Issue 16
  • DOI: 10.1021/jp1110899

Complete Solvation Response of Coumarin 153 in Ionic Liquids
journal, August 2012

  • Zhang, Xin-Xing; Liang, Min; Ernsting, Nikolaus P.
  • The Journal of Physical Chemistry B, Vol. 117, Issue 16
  • DOI: 10.1021/jp305430a

Photoinduced intermolecular electron transfer in complex liquids: Experiment and theory
journal, December 2000

  • Tavernier, H. L.; Kalashnikov, M. M.; Fayer, M. D.
  • The Journal of Chemical Physics, Vol. 113, Issue 22
  • DOI: 10.1063/1.1323505

Distance Dependence of Electron Transfer in DNA:  The Role of the Reorganization Energy and Free Energy
journal, December 2000

  • Tavernier, H. L.; Fayer, M. D.
  • The Journal of Physical Chemistry B, Vol. 104, Issue 48
  • DOI: 10.1021/jp001362w

Photoinduced Electron Transfer Reaction in Room Temperature Ionic Liquids:  A Combined Laser Flash Photolysis and Fluorescence Study
journal, March 2007

  • Paul, Aniruddha; Samanta, Anunay
  • The Journal of Physical Chemistry B, Vol. 111, Issue 8
  • DOI: 10.1021/jp067481e

A subpicosecond, subnanosecond and steady‐state study of diffusion‐influenced fluorescence quenching
journal, July 1990

  • Eads, Daniel D.; Dismer, Berit G.; Fleming, Graham R.
  • The Journal of Chemical Physics, Vol. 93, Issue 2
  • DOI: 10.1063/1.459177
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