Waste tire derived carbon-polymer composite paper as pseudocapacitive electrode with long cycle life
Abstract
Recycling hazardous wastes to produce value-added products is becoming essential for the sustainable progress of our society. Herein, highly porous carbon (1625 m2/g–1) is synthesized using waste tires as the precursor and used as supercapacitor electrode. The narrow pore size distribution (PSD) and high surface area led to a good charge storage capacity, especially when used as a three-dimensional nanoscaffold to polymerize polyaniline (PANI/TC). The composite film was highly flexible, conductive and exhibited a capacitance of 480 F/g–1 at 1 mV/s–1 with excellent capacitance retention up to 98% after 10,000 charge/discharge cycles. The high capacitance and long cycle life were ascribed to the short diffusional paths, uniform PANI coating and tight confinement of the PANI in the inner pores of the tire-derived carbon via - interactions, which minimized the degradation of the PANI upon cycling. Here, we anticipate that the same strategy can be applied to deposit other pseudocapacitive materials with low-cost TC to achieve even higher electrochemical performance and longer cycle life, a key challenge for redox active polymers.
- Authors:
-
- Drexel Univ., Philadelphia, PA (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1245349
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemSusChem
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 21; Journal ID: ISSN 1864-5631
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 54 ENVIRONMENTAL SCIENCES
Citation Formats
Boota, M., Paranthaman, Mariappan Parans, Naskar, Amit K., Gogotsi, Yury, Li, Yunchao, and Akato, Kokouvi. Waste tire derived carbon-polymer composite paper as pseudocapacitive electrode with long cycle life. United States: N. p., 2015.
Web. doi:10.1002/cssc.201500866.
Boota, M., Paranthaman, Mariappan Parans, Naskar, Amit K., Gogotsi, Yury, Li, Yunchao, & Akato, Kokouvi. Waste tire derived carbon-polymer composite paper as pseudocapacitive electrode with long cycle life. United States. https://doi.org/10.1002/cssc.201500866
Boota, M., Paranthaman, Mariappan Parans, Naskar, Amit K., Gogotsi, Yury, Li, Yunchao, and Akato, Kokouvi. Fri .
"Waste tire derived carbon-polymer composite paper as pseudocapacitive electrode with long cycle life". United States. https://doi.org/10.1002/cssc.201500866. https://www.osti.gov/servlets/purl/1245349.
@article{osti_1245349,
title = {Waste tire derived carbon-polymer composite paper as pseudocapacitive electrode with long cycle life},
author = {Boota, M. and Paranthaman, Mariappan Parans and Naskar, Amit K. and Gogotsi, Yury and Li, Yunchao and Akato, Kokouvi},
abstractNote = {Recycling hazardous wastes to produce value-added products is becoming essential for the sustainable progress of our society. Herein, highly porous carbon (1625 m2/g–1) is synthesized using waste tires as the precursor and used as supercapacitor electrode. The narrow pore size distribution (PSD) and high surface area led to a good charge storage capacity, especially when used as a three-dimensional nanoscaffold to polymerize polyaniline (PANI/TC). The composite film was highly flexible, conductive and exhibited a capacitance of 480 F/g–1 at 1 mV/s–1 with excellent capacitance retention up to 98% after 10,000 charge/discharge cycles. The high capacitance and long cycle life were ascribed to the short diffusional paths, uniform PANI coating and tight confinement of the PANI in the inner pores of the tire-derived carbon via - interactions, which minimized the degradation of the PANI upon cycling. Here, we anticipate that the same strategy can be applied to deposit other pseudocapacitive materials with low-cost TC to achieve even higher electrochemical performance and longer cycle life, a key challenge for redox active polymers.},
doi = {10.1002/cssc.201500866},
journal = {ChemSusChem},
number = 21,
volume = 8,
place = {United States},
year = {Fri Sep 25 00:00:00 EDT 2015},
month = {Fri Sep 25 00:00:00 EDT 2015}
}
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