Unexpected ligand lability in condition of water oxidation catalysis

Yan, Lifen; Zong, Ruifa; Pushkar, Yulia

doi:10.1016/j.jcat.2015.07.018

Title: Unexpected ligand lability in condition of water oxidation catalysis

Authors:: Yan, Lifen; Zong, Ruifa; Pushkar, Yulia

Publication Date:: Thu Oct 01 00:00:00 EDT 2015

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1244601

Grant/Contract Number:: FG02-10ER16184

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Catalysis

Additional Journal Information:: Journal Name: Journal of Catalysis Journal Volume: 330 Journal Issue: C; Journal ID: ISSN 0021-9517

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Citation Formats


                    Yan, Lifen, Zong, Ruifa, and Pushkar, Yulia. Unexpected ligand lability in condition of water oxidation catalysis.  United States: N. p., 2015. 
Web.  doi:10.1016/j.jcat.2015.07.018.

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                    Yan, Lifen, Zong, Ruifa, & Pushkar, Yulia. Unexpected ligand lability in condition of water oxidation catalysis.  United States.  https://doi.org/10.1016/j.jcat.2015.07.018

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                    Yan, Lifen, Zong, Ruifa, and Pushkar, Yulia. Thu .  
"Unexpected ligand lability in condition of water oxidation catalysis".  United States.  https://doi.org/10.1016/j.jcat.2015.07.018.

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@article{osti_1244601,

  title        = {Unexpected ligand lability in condition of water oxidation catalysis},

  author       = {Yan, Lifen and Zong, Ruifa and Pushkar, Yulia},

  abstractNote = {},

  doi          = {10.1016/j.jcat.2015.07.018},

  journal      = {Journal of Catalysis},

  number       = C,

  volume       = 330,

  place        = {United States},

  year         = {Thu Oct 01 00:00:00 EDT 2015},

  month        = {Thu Oct 01 00:00:00 EDT 2015}

}

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https://doi.org/10.1016/j.jcat.2015.07.018

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Works referenced in this record:

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Title: Unexpected ligand lability in condition of water oxidation catalysis

Citation Formats

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal, June 2005

Electronic Modification of the [Ru II (tpy)(bpy)(OH 2 )] 2+ Scaffold: Effects on Catalytic Water Oxidation journal, November 2010

Synthesis, Structure, and Redox and Catalytic Properties of a New Family of Ruthenium Complexes Containing the Tridentate bpea Ligand journal, August 2001

Visible light-driven water oxidation catalyzed by mononuclear ruthenium complexes journal, October 2013

Homogeneous Catalysis in Supercritical Fluids: Hydrogenation of Supercritical Carbon Dioxide to Formic Acid, Alkyl Formates, and Formamides journal, January 1996

Mono- and Bis-(2,2'-bipyridine) and -(1,10-phenanthroline) Chelates of Ruthenium and Osmium. II. Bischelates of Bivalent and Tervalent Ruthenium journal, January 1963

Mononuclear Ruthenium(II) Complexes That Catalyze Water Oxidation journal, December 2008

Clear Evidence Showing the Robustness of a Highly Active Oxygen-evolving Mononuclear Ruthenium Complex with an Aqua Ligand journal, February 2009

A fast metal–metal bonded water oxidation catalyst journal, June 2014

A stable ruthenium(V) oxo complex. X-Ray crystal structure and oxidising properties of tetra-n-propylammonium bis-2-hydroxy-2-ethylbutyrato(oxo)-ruthenate(V) journal, January 1989

Experimental demonstration of radicaloid character in a RuV=O intermediate in catalytic water oxidation journal, February 2013

Effects of a Proximal Base on Water Oxidation and Proton Reduction Catalyzed by Geometric Isomers of [Ru(tpy)(pynap)(OH2)]2+ journal, November 2011

A Self-Improved Water-Oxidation Catalyst: Is One Site Really Enough? journal, November 2013

Sodium Periodate as a Primary Oxidant for Water-Oxidation Catalysts journal, May 2012

A Ru(II) Bis-terpyridine-like Complex that Catalyzes Water Oxidation: The Influence of Steric Strain journal, August 2013

Concerted O atom-proton transfer in the O--O bond forming step in water oxidation journal, April 2010

Mechanism of Water Oxidation by Single-Site Ruthenium Complex Catalysts journal, February 2010

Role of ligands in catalytic water oxidation by mononuclear ruthenium complexes journal, December 2015

Chlorine K-Edge X-ray Absorption Spectroscopy as a Probe of Chlorine−Manganese Bonding: Model Systems with Relevance to the Oxygen Evolving Complex in Photosystem II † journal, May 1997

Spectroscopic Analysis of Catalytic Water Oxidation by [Ru II (bpy)(tpy)H 2 O] 2+ Suggests That Ru V ═O Is Not a Rate-Limiting Intermediate journal, August 2014

Isolated Seven-Coordinate Ru(IV) Dimer Complex with [HOHOH] − Bridging Ligand as an Intermediate for Catalytic Water Oxidation journal, August 2009

Ruthenium-Catalyzed Reactions for Organic Synthesis journal, November 1998

A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II journal, March 2012

Synthesis and properties of the chloro-bridged dimer [(bpy)2RuCl]22+ and its transient 3+ mixed-valence ion journal, August 1978

Diminished photoisomerization of active ruthenium water oxidation catalyst by anchoring to metal oxide electrodes journal, November 2013

Structure and Electronic Configurations of the Intermediates of Water Oxidation in Blue Ruthenium Dimer Catalysis journal, March 2012

Highly efficient and robust molecular water oxidation catalysts based on ruthenium complexes journal, January 2014

Theoretical approaches to x-ray absorption fine structure journal, July 2000

Further Observations on Water Oxidation Catalyzed by Mononuclear Ru(II) Complexes journal, February 2012

The Possible Role of Proton-Coupled Electron Transfer (PCET) in Water Oxidation by Photosystem II journal, July 2007

Bromine K-edge EXAFS studies of bromide binding to bromoperoxidase from Ascophyllum nodosum journal, August 1999

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005

Electronic Modification of the [Ru ^II (tpy)(bpy)(OH ₂ )] ²⁺ Scaffold: Effects on Catalytic Water Oxidation
journal, November 2010

Synthesis, Structure, and Redox and Catalytic Properties of a New Family of Ruthenium Complexes Containing the Tridentate bpea Ligand
journal, August 2001

Visible light-driven water oxidation catalyzed by mononuclear ruthenium complexes
journal, October 2013

Homogeneous Catalysis in Supercritical Fluids: Hydrogenation of Supercritical Carbon Dioxide to Formic Acid, Alkyl Formates, and Formamides
journal, January 1996

Mono- and Bis-(2,2'-bipyridine) and -(1,10-phenanthroline) Chelates of Ruthenium and Osmium. II. Bischelates of Bivalent and Tervalent Ruthenium
journal, January 1963

Mononuclear Ruthenium(II) Complexes That Catalyze Water Oxidation
journal, December 2008

Clear Evidence Showing the Robustness of a Highly Active Oxygen-evolving Mononuclear Ruthenium Complex with an Aqua Ligand
journal, February 2009

A fast metal–metal bonded water oxidation catalyst
journal, June 2014

A stable ruthenium(V) oxo complex. X-Ray crystal structure and oxidising properties of tetra-n-propylammonium bis-2-hydroxy-2-ethylbutyrato(oxo)-ruthenate(V)
journal, January 1989

Experimental demonstration of radicaloid character in a RuV=O intermediate in catalytic water oxidation
journal, February 2013

Effects of a Proximal Base on Water Oxidation and Proton Reduction Catalyzed by Geometric Isomers of [Ru(tpy)(pynap)(OH2)]2+
journal, November 2011

A Self-Improved Water-Oxidation Catalyst: Is One Site Really Enough?
journal, November 2013

Sodium Periodate as a Primary Oxidant for Water-Oxidation Catalysts
journal, May 2012

A Ru(II) Bis-terpyridine-like Complex that Catalyzes Water Oxidation: The Influence of Steric Strain
journal, August 2013

Concerted O atom-proton transfer in the O--O bond forming step in water oxidation
journal, April 2010

Mechanism of Water Oxidation by Single-Site Ruthenium Complex Catalysts
journal, February 2010

Role of ligands in catalytic water oxidation by mononuclear ruthenium complexes
journal, December 2015

Chlorine K-Edge X-ray Absorption Spectroscopy as a Probe of Chlorine−Manganese Bonding: Model Systems with Relevance to the Oxygen Evolving Complex in Photosystem II ^†
journal, May 1997

Spectroscopic Analysis of Catalytic Water Oxidation by [Ru ^II (bpy)(tpy)H ₂ O] ²⁺ Suggests That Ru ^V ═O Is Not a Rate-Limiting Intermediate
journal, August 2014

Isolated Seven-Coordinate Ru(IV) Dimer Complex with [HOHOH] ⁻ Bridging Ligand as an Intermediate for Catalytic Water Oxidation
journal, August 2009

Ruthenium-Catalyzed Reactions for Organic Synthesis
journal, November 1998

A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II
journal, March 2012

Synthesis and properties of the chloro-bridged dimer [(bpy)2RuCl]22+ and its transient 3+ mixed-valence ion
journal, August 1978

Diminished photoisomerization of active ruthenium water oxidation catalyst by anchoring to metal oxide electrodes
journal, November 2013

Structure and Electronic Configurations of the Intermediates of Water Oxidation in Blue Ruthenium Dimer Catalysis
journal, March 2012

Highly efficient and robust molecular water oxidation catalysts based on ruthenium complexes
journal, January 2014

Theoretical approaches to x-ray absorption fine structure
journal, July 2000

Further Observations on Water Oxidation Catalyzed by Mononuclear Ru(II) Complexes
journal, February 2012

The Possible Role of Proton-Coupled Electron Transfer (PCET) in Water Oxidation by Photosystem II
journal, July 2007

Bromine K-edge EXAFS studies of bromide binding to bromoperoxidase from Ascophyllum nodosum
journal, August 1999