Synthesis and structural analysis of formamidinate-supported Mg complexes

Tsai, Yi-Ju; Pastor, Michael B.; Lo, Wenfeng; Zhao, Qinliang

doi:10.1016/j.ica.2015.05.005

Title: Synthesis and structural analysis of formamidinate-supported Mg complexes

Authors:: Tsai, Yi-Ju; Pastor, Michael B.; Lo, Wenfeng; Zhao, Qinliang

Publication Date:: Sat Aug 01 00:00:00 EDT 2015

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1244294

Grant/Contract Number:: AC02-06CH11357; AC02-05CH11231

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Inorganica Chimica Acta

Additional Journal Information:: Journal Name: Inorganica Chimica Acta Journal Volume: 434 Journal Issue: C; Journal ID: ISSN 0020-1693

Publisher:: Elsevier

Country of Publication:: Switzerland

Language:: English

Citation Formats


                    Tsai, Yi-Ju, Pastor, Michael B., Lo, Wenfeng, and Zhao, Qinliang. Synthesis and structural analysis of formamidinate-supported Mg complexes.  Switzerland: N. p., 2015. 
Web.  doi:10.1016/j.ica.2015.05.005.

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                    Tsai, Yi-Ju, Pastor, Michael B., Lo, Wenfeng, & Zhao, Qinliang. Synthesis and structural analysis of formamidinate-supported Mg complexes.  Switzerland.  https://doi.org/10.1016/j.ica.2015.05.005

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                    Tsai, Yi-Ju, Pastor, Michael B., Lo, Wenfeng, and Zhao, Qinliang. Sat .  
"Synthesis and structural analysis of formamidinate-supported Mg complexes".  Switzerland.  https://doi.org/10.1016/j.ica.2015.05.005.

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@article{osti_1244294,

  title        = {Synthesis and structural analysis of formamidinate-supported Mg complexes},

  author       = {Tsai, Yi-Ju and Pastor, Michael B. and Lo, Wenfeng and Zhao, Qinliang},

  abstractNote = {},

  doi          = {10.1016/j.ica.2015.05.005},

  journal      = {Inorganica Chimica Acta},

  number       = C,

  volume       = 434,

  place        = {Switzerland},

  year         = {Sat Aug 01 00:00:00 EDT 2015},

  month        = {Sat Aug 01 00:00:00 EDT 2015}

}

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Title: Synthesis and structural analysis of formamidinate-supported Mg complexes

Citation Formats

Structural and synthetic studies of magnesium and zinc tolylformamidinate complexes journal, June 2002

One-Step Synthesis of [HM 3 (CO) 11 ] - from M 3 (CO) 12 (M = Fe, Ru, Os) via Unusual Hydride Transfer from 1,3,5-Trimethyl-1,3,5-triazacyclohexane journal, September 2003

Yttrium Alkyl and Benzyl Complexes with Amino−Amidinate Monoanionic Ancillary Ligands journal, July 2000

Synthesis and Characterization of Functionalized N,N‘-Diphenylformamidinate Silver(I) Dimers: Solid-State Structures and Solution Properties journal, November 1999

Electrical properties of atomic-layer-deposited La2O3 films using a novel La formamidinate precursor and ozone journal, July 2009

WinGX and ORTEP for Windows : an update journal, July 2012

Substituent and Isomer Effects on Structural, Spectroscopic, and Electrochemical Properties of Dirhodium(III,II) Complexes Containing Four Identical Unsymmetrical Bridging Ligands journal, December 2003

Gold(I) Formamidinate Clusters: The Structure, Luminescence, and Electrochemistry of the Tetranuclear, Base-Free [Au 4 (ArNC(H)NAr) 4 ] journal, September 2003

N-silylated benzamidines: versatile building blocks in main group and coordination chemistry journal, December 1994

Synthesis and structural characterisation of heavy alkaline earth N,N′-bis(aryl)formamidinate complexes journal, January 2006

Principal trends in the chemistry of amidinate complexes of main-group and transition elements journal, May 2006

Catalytic CN bond metathesis of carbodiimides by group 4 and 5 imido complexes supported by guanidinate ligands journal, January 2003

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Transition metal (Mn, Co) and zinc formamidinate compounds having the basic beryllium acetate structure, and unique isomeric iron compounds journal, December 1997

X-ray structural characterization of some sterically bulky N-donor and N-alkyl Grignard reagents journal, January 2006

Syntheses and Structures of Magnesium Complexes with Reduced α-Diimine Ligands journal, November 2011

The synthesis and characterization of aluminum, gallium and zinc formamidinates journal, March 2010

Synthesis and structural characterization of metal halide complexes containing N,N′-di(2-methoxyphenyl)formamidine (o-HDMophF) journal, March 2005

Substituent effects in dinuclear paddlewheel compounds: electrochemical and spectroscopic investigations journal, August 1998

Mono- versus Bis-chelate Formation in Triazenide and Amidinate Complexes of Magnesium and Zinc journal, October 2007

Non-cyclopentadienyl ancillaries in organogroup 3 metal chemistry: a fine balance in ligand design journal, November 2002

Monomeric and Dimeric Amidinate Complexes of Magnesium journal, November 2001

The syntheses and structures of some main group complexes of the sterically hindered N,N′-bis(2,6-diisopropylphenyl)-4-toluamidinate ligand journal, January 2005

Bulky guanidinato and amidinato zinc complexes and their comparative stabilities journal, January 2010

Potassium complexes of the ‘super’ formamidine (2,6-Pr2iC6H3)NC(H)NH(2,6-Pr2iC6H3), HDippForm. journal, January 2003

The coordination chemistry of the amidine ligand journal, July 1994

Bulky formamidinate complexes of lithium: the first examples of η2:η1-CN,N′ metal amidinate coordination journal, January 2005

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Synthetic and catalytic intermediates in a magnesium promoted Tishchenko reaction journal, January 2012

Molecular Magnesium(I) Compounds: From Curiosity to Kudos journal, March 2008

Bis(μ-N,N′-η2-N,O-η2-N′,O′-di(o-methoxyphenyl)formamidinato)disilver(I): an interesting coordination geometry for silver(I) and room temperature fluorescence journal, January 1998

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Synthesis and Crystal Structures of Magnesium and Calcium Triazenide Complexes journal, November 1998

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Synthesis, structure, and properties of magnesium complexes containing cyclopentadienyl and amidinate ligand sets journal, October 2003

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journal, June 2002

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journal, September 2003

Yttrium Alkyl and Benzyl Complexes with Amino−Amidinate Monoanionic Ancillary Ligands
journal, July 2000

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journal, November 1999

Electrical properties of atomic-layer-deposited La2O3 films using a novel La formamidinate precursor and ozone
journal, July 2009

WinGX and ORTEP for Windows : an update
journal, July 2012

Substituent and Isomer Effects on Structural, Spectroscopic, and Electrochemical Properties of Dirhodium(III,II) Complexes Containing Four Identical Unsymmetrical Bridging Ligands
journal, December 2003

Gold(I) Formamidinate Clusters: The Structure, Luminescence, and Electrochemistry of the Tetranuclear, Base-Free [Au ₄ (ArNC(H)NAr) ₄ ]
journal, September 2003

N-silylated benzamidines: versatile building blocks in main group and coordination chemistry
journal, December 1994

Synthesis and structural characterisation of heavy alkaline earth N,N′-bis(aryl)formamidinate complexes
journal, January 2006

Principal trends in the chemistry of amidinate complexes of main-group and transition elements
journal, May 2006

Catalytic CN bond metathesis of carbodiimides by group 4 and 5 imido complexes supported by guanidinate ligands
journal, January 2003

Paramagnetic Bis(1,4-di-tert-butyl-1,4-diazabutadiene) Adducts of Lithium, Magnesium, and Zinc
journal, May 1994

Transition metal (Mn, Co) and zinc formamidinate compounds having the basic beryllium acetate structure, and unique isomeric iron compounds
journal, December 1997

X-ray structural characterization of some sterically bulky N-donor and N-alkyl Grignard reagents
journal, January 2006

Syntheses and Structures of Magnesium Complexes with Reduced α-Diimine Ligands
journal, November 2011

The synthesis and characterization of aluminum, gallium and zinc formamidinates
journal, March 2010

Synthesis and structural characterization of metal halide complexes containing N,N′-di(2-methoxyphenyl)formamidine (o-HDMophF)
journal, March 2005

Substituent effects in dinuclear paddlewheel compounds: electrochemical and spectroscopic investigations
journal, August 1998

Mono- versus Bis-chelate Formation in Triazenide and Amidinate Complexes of Magnesium and Zinc
journal, October 2007

Non-cyclopentadienyl ancillaries in organogroup 3 metal chemistry: a fine balance in ligand design
journal, November 2002

Monomeric and Dimeric Amidinate Complexes of Magnesium
journal, November 2001

The syntheses and structures of some main group complexes of the sterically hindered N,N′-bis(2,6-diisopropylphenyl)-4-toluamidinate ligand
journal, January 2005

Bulky guanidinato and amidinato zinc complexes and their comparative stabilities
journal, January 2010

Potassium complexes of the ‘super’ formamidine (2,6-Pr2iC6H3)NC(H)NH(2,6-Pr2iC6H3), HDippForm.
journal, January 2003

The coordination chemistry of the amidine ligand
journal, July 1994

Bulky formamidinate complexes of lithium: the first examples of η2:η1-CN,N′ metal amidinate coordination
journal, January 2005

Structural Studies of N,N′-Di(ortho-fluorophenyl)formamidine Group 1 Metallation
journal, January 2003

Synthetic and catalytic intermediates in a magnesium promoted Tishchenko reaction
journal, January 2012

Molecular Magnesium(I) Compounds: From Curiosity to Kudos
journal, March 2008

Bis(μ-N,N′-η2-N,O-η2-N′,O′-di(o-methoxyphenyl)formamidinato)disilver(I): an interesting coordination geometry for silver(I) and room temperature fluorescence
journal, January 1998

Asymmetric Bis(formamidinate) Group 4 Complexes: Synthesis, Structure and Their Reactivity in the Polymerization of α-Olefins.
journal, June 2014

Monomeric Three- and Four-Coordinate Magnesium Amides
journal, March 1998

Ueber Tautomerie
journal, January 1895

Stable Magnesium(I) Compounds with Mg-Mg Bonds
journal, December 2007

Synthesis and Crystal Structures of Magnesium and Calcium Triazenide Complexes
journal, November 1998

Structural studies of formamidine compounds: from neutral to anionic and cationic species
journal, January 1997

Synthesis, structure, and properties of magnesium complexes containing cyclopentadienyl and amidinate ligand sets
journal, October 2003

Metal (Li, K, SnII and HgII) complexes of the 1,3-diazaallyl [N(R)C(Ph)NC(Ph)CR2]− (R = SiMe3)
journal, January 1998

Ligand control in nuclearity of Zn complexes supported by formamidinates
journal, September 2015

A Convenient Synthesis of N,N'-Disubstituted Formamidines and Acetamidines ¹
journal, April 1963

Factors that Influence π- versus η ² -Coordination of β-Diketiminato Ligands in Magnesium Complexes
journal, May 2004

The Chemistry of β-Diketiminatometal Complexes
journal, September 2002

Synthesis and structural characterisation of some novel lithium and sodium N,N′-di(para-tolyl)formamidinate complexes
journal, January 2002

Solid State Structures and Dynamic Solution Equilibria of Bis(dibenzylamido)magnesium Complexes: Aggregation Dependence on Stoichiometry and Denticity of Donor Solvent
journal, December 1997

Synthesis and Structures of Monomeric Magnesium, Calcium, Strontium, and Barium Amides Involving the N , N -(2,4,6-Trimethylphenyl)(trimethylsilyl)amido Ligand
journal, June 2005

Combined X-ray Diffraction and ¹⁵ N CPMAS NMR Study of Molecular Structure and Proton Order/Disorder Phenomena in Cyclic N , N ‘-Bisarylformamidine Dimers
journal, December 1997

Alkali-metal bis(aryl)formamidinates: a study of coordinative versatility
journal, January 2007