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Title: Giant elastic tunability in strained BiFeO 3 near an electrically induced phase transition

Elastic anomalies are signatures of phase transitions in condensed matters and have traditionally been studied using various techniques spanning from neutron scattering to static mechanical testing. Here, using band-excitation elastic/piezoresponse spectroscopy, we probed sub-MHz elastic dynamics of a tip bias-induced rhombohedral–tetragonal phase transition of strained (001)-BiFeO 3 (rhombohedral) ferroelectric thin films from ~10 3 nm 3 sample volumes. Near this transition, we observed that the Young's modulus intrinsically softens by over 30% coinciding with 2-3 folds enhancement of local piezoresponse. Coupled with phase-field modeling, we also addressed the influence of polarization switching and mesoscopic structural heterogeneities (e.g., domain walls) on the kinetics of this phase transition, thereby providing fresh insights into the morphotropic phase boundary (MPB) in ferroelectrics. Moreover, the giant electrically tunable elastic stiffness and corresponding electromechanical properties observed here suggest potential applications of BiFeO 3 in next-generation frequency-agile electroacoustic devices, based on utilization of the soft modes underlying successive ferroelectric phase transitions.
Authors:
 [1] ;  [2] ;  [2] ;  [3] ;  [3] ;  [2] ;  [2] ;  [2] ;  [2] ;  [2] ;  [2]
  1. Tsinghua Univ., Beijing (China); RIKEN Center for Emergent Matter Science (CEMS), Saitama (Japan)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Pennsylvania State Univ., University Park, PA (United States)
Publication Date:
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 6; Journal Issue: 4; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Research Org:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE
OSTI Identifier:
1244194

Yu, Pu, Vasudevan, Rama K., Tselev, Alexander, Xue, Fei, Chen, Long -Qing, Maksymovych, Petro, Kalinin, Sergei V., Balke, Nina, Li, Q., Cao, Y., and Laanait, N.. Giant elastic tunability in strained BiFeO3 near an electrically induced phase transition. United States: N. p., Web. doi:10.1038/ncomms9985.
Yu, Pu, Vasudevan, Rama K., Tselev, Alexander, Xue, Fei, Chen, Long -Qing, Maksymovych, Petro, Kalinin, Sergei V., Balke, Nina, Li, Q., Cao, Y., & Laanait, N.. Giant elastic tunability in strained BiFeO3 near an electrically induced phase transition. United States. doi:10.1038/ncomms9985.
Yu, Pu, Vasudevan, Rama K., Tselev, Alexander, Xue, Fei, Chen, Long -Qing, Maksymovych, Petro, Kalinin, Sergei V., Balke, Nina, Li, Q., Cao, Y., and Laanait, N.. 2015. "Giant elastic tunability in strained BiFeO3 near an electrically induced phase transition". United States. doi:10.1038/ncomms9985. https://www.osti.gov/servlets/purl/1244194.
@article{osti_1244194,
title = {Giant elastic tunability in strained BiFeO3 near an electrically induced phase transition},
author = {Yu, Pu and Vasudevan, Rama K. and Tselev, Alexander and Xue, Fei and Chen, Long -Qing and Maksymovych, Petro and Kalinin, Sergei V. and Balke, Nina and Li, Q. and Cao, Y. and Laanait, N.},
abstractNote = {Elastic anomalies are signatures of phase transitions in condensed matters and have traditionally been studied using various techniques spanning from neutron scattering to static mechanical testing. Here, using band-excitation elastic/piezoresponse spectroscopy, we probed sub-MHz elastic dynamics of a tip bias-induced rhombohedral–tetragonal phase transition of strained (001)-BiFeO3 (rhombohedral) ferroelectric thin films from ~103 nm3 sample volumes. Near this transition, we observed that the Young's modulus intrinsically softens by over 30% coinciding with 2-3 folds enhancement of local piezoresponse. Coupled with phase-field modeling, we also addressed the influence of polarization switching and mesoscopic structural heterogeneities (e.g., domain walls) on the kinetics of this phase transition, thereby providing fresh insights into the morphotropic phase boundary (MPB) in ferroelectrics. Moreover, the giant electrically tunable elastic stiffness and corresponding electromechanical properties observed here suggest potential applications of BiFeO3 in next-generation frequency-agile electroacoustic devices, based on utilization of the soft modes underlying successive ferroelectric phase transitions.},
doi = {10.1038/ncomms9985},
journal = {Nature Communications},
number = 4,
volume = 6,
place = {United States},
year = {2015},
month = {11}
}

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