Tunable morphologies of indium tin oxide nanostructures using nanocellulose templates
Abstract
Metal oxide nanostructures have emerged as an important family of materials for various device applications. The performance is highly dependent on the morphology of the metal oxide nanostructures. Here we report a completely green approach to prepare indium tin oxide (ITO) nanoparticles using only water and cellulose nanofibril (CNF) in addition to the ITO precursor. Surface hydroxyl groups of the CNFs allow for efficient conjugation of ITO precursors (e.g., metal ions) in aqueous solution. The resulting CNF film allows for controllable spatial arrangement of metal oxide precursors, which results in tunable particle morphology (e.g., nanowires, nanospheres, and octahedral nanoparticles). These ITO nanoparticles can also form conductive and transparent ITO films. This study opens a new perspective on developing metal oxide nanostructures.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Laboratory Directed Research and Development (LDRD) Program; USDA
- OSTI Identifier:
- 1244181
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- RSC Advances
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 125; Journal ID: ISSN 2046-2069
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY
Citation Formats
Aytug, Tolga, Meyer III, Harry M., Ozcan, Soydan, Lu, Yuan, and Poole II, Joseph E.. Tunable morphologies of indium tin oxide nanostructures using nanocellulose templates. United States: N. p., 2015.
Web. doi:10.1039/C5RA23054C.
Aytug, Tolga, Meyer III, Harry M., Ozcan, Soydan, Lu, Yuan, & Poole II, Joseph E.. Tunable morphologies of indium tin oxide nanostructures using nanocellulose templates. United States. https://doi.org/10.1039/C5RA23054C
Aytug, Tolga, Meyer III, Harry M., Ozcan, Soydan, Lu, Yuan, and Poole II, Joseph E.. Mon .
"Tunable morphologies of indium tin oxide nanostructures using nanocellulose templates". United States. https://doi.org/10.1039/C5RA23054C. https://www.osti.gov/servlets/purl/1244181.
@article{osti_1244181,
title = {Tunable morphologies of indium tin oxide nanostructures using nanocellulose templates},
author = {Aytug, Tolga and Meyer III, Harry M. and Ozcan, Soydan and Lu, Yuan and Poole II, Joseph E.},
abstractNote = {Metal oxide nanostructures have emerged as an important family of materials for various device applications. The performance is highly dependent on the morphology of the metal oxide nanostructures. Here we report a completely green approach to prepare indium tin oxide (ITO) nanoparticles using only water and cellulose nanofibril (CNF) in addition to the ITO precursor. Surface hydroxyl groups of the CNFs allow for efficient conjugation of ITO precursors (e.g., metal ions) in aqueous solution. The resulting CNF film allows for controllable spatial arrangement of metal oxide precursors, which results in tunable particle morphology (e.g., nanowires, nanospheres, and octahedral nanoparticles). These ITO nanoparticles can also form conductive and transparent ITO films. This study opens a new perspective on developing metal oxide nanostructures.},
doi = {10.1039/C5RA23054C},
journal = {RSC Advances},
number = 125,
volume = 5,
place = {United States},
year = {Mon Nov 30 00:00:00 EST 2015},
month = {Mon Nov 30 00:00:00 EST 2015}
}
Web of Science
Works referenced in this record:
Nonaqueous Sol–Gel Routes to Metal Oxide Nanoparticles
journal, September 2007
- Niederberger, Markus
- Accounts of Chemical Research, Vol. 40, Issue 9
The Future Prospects of Microbial Cellulose in Biomedical Applications
journal, January 2007
- Czaja, Wojciech K.; Young, David J.; Kawecki, Marek
- Biomacromolecules, Vol. 8, Issue 1
Embedded indium-tin-oxide nanoelectrodes for efficiency and lifetime enhancement of polymer-based solar cells
journal, April 2010
- Yu, Peichen; Chang, Chia-Hua; Su, Ming-Shin
- Applied Physics Letters, Vol. 96, Issue 15
Seed Layer-Assisted Chemical Bath Deposition of CuO Films on ITO-Coated Glass Substrates with Tunable Crystallinity and Morphology
journal, April 2014
- Zhu, Changqiong; Panzer, Matthew J.
- Chemistry of Materials, Vol. 26, Issue 9
Protein Microarrays on ITO Surfaces by a Direct Covalent Attachment Scheme
journal, July 2002
- Ng, Hou Tee; Fang, Aiping; Huang, Liqun
- Langmuir, Vol. 18, Issue 16
Porous Indium Oxide Nanotubes: Layer-by-Layer Assembly on Carbon-Nanotube Templates and Application for Room-Temperature NH3 Gas Sensors
journal, June 2007
- Du, N.; Zhang, H.; Chen, B. D.
- Advanced Materials, Vol. 19, Issue 12
Indium tin oxide nano-particles through an emulsion technique
journal, August 2002
- Sujatha Devi, P.; Chatterjee, M.; Ganguli, D.
- Materials Letters, Vol. 55, Issue 4
Preparation and Optical Properties of Colloidal, Monodisperse, and Highly Crystalline ITO Nanoparticles
journal, April 2008
- Choi, Sang-Il; Nam, Ki Min; Park, Bo Keun
- Chemistry of Materials, Vol. 20, Issue 8
Templated Nanocrystal-Based Porous TiO2 Films for Next-Generation Electrochemical Capacitors
journal, February 2009
- Brezesinski, Torsten; Wang, John; Polleux, Julien
- Journal of the American Chemical Society, Vol. 131, Issue 5, p. 1802-1809
The effect of substrate temperature on the properties of ITO thin films for OLED applications
journal, November 2006
- Reddy, V. Sivaji; Das, K.; Dhar, A.
- Semiconductor Science and Technology, Vol. 21, Issue 12
Improving lithium–sulphur batteries through spatial control of sulphur species deposition on a hybrid electrode surface
journal, May 2014
- Yao, Hongbin; Zheng, Guangyuan; Hsu, Po-Chun
- Nature Communications, Vol. 5, Issue 1
Cation-Induced Hydrogels of Cellulose Nanofibrils with Tunable Moduli
journal, August 2013
- Dong, Hong; Snyder, James F.; Williams, Kristen S.
- Biomacromolecules, Vol. 14, Issue 9
Microbial cellulose—the natural power to heal wounds
journal, January 2006
- Czaja, W.; Krystynowicz, A.; Bielecki, S.
- Biomaterials, Vol. 27, Issue 2
ITO nanowires and nanoparticles for transparent films
journal, October 2011
- Dattoli, Eric N.; Lu, Wei
- MRS Bulletin, Vol. 36, Issue 10
Transparent conducting oxide semiconductors for transparent electrodes
journal, March 2005
- Minami, Tadatsugu
- Semiconductor Science and Technology, Vol. 20, Issue 4
A Novel Route to Octahedral In 2 O 3 Particles Exhibiting Near Band Emission
journal, January 2005
- Zhang, Wu; Huang, Zhen; Li, Ting
- Chemistry Letters, Vol. 34, Issue 1
Microfibrillated cellulose and new nanocomposite materials: a review
journal, February 2010
- Siró, István; Plackett, David
- Cellulose, Vol. 17, Issue 3
Unusually High Performance Photovoltaic Cell Based on a [60]Fullerene Metal Cluster−Porphyrin Dyad SAM on an ITO Electrode
journal, March 2005
- Cho, Youn-Jaung; Ahn, Tae Kyu; Song, Hyunjoon
- Journal of the American Chemical Society, Vol. 127, Issue 8
Three-Color, Tunable, Organic Light-Emitting Devices
journal, June 1997
- Shen, Z.
- Science, Vol. 276, Issue 5321
High-yield synthesis of single crystalline tin-doped indium oxide octahedrons via a low-temperature, catalyst-free process
journal, June 2006
- Wei, Ming; Zhi, Dan; MacManus-Driscoll, Judith L.
- Nanotechnology, Vol. 17, Issue 14
Assembly of mesoporous indium tin oxide electrodes from nano-hydroxide building blocks
journal, January 2012
- Liu, Yujing; Štefanić, Goran; Rathouský, Jiří
- Chemical Science, Vol. 3, Issue 7
Direct preparation of anatase TiO2 nanotubes in porous alumina membranes
journal, January 1999
- Imai, Hiroaki; Takei, Yuko; Shimizu, Kazuhiko
- Journal of Materials Chemistry, Vol. 9, Issue 12
Crystallization of Indium Tin Oxide Nanoparticles: From Cooperative Behavior to Individuality
journal, February 2007
- Ba, Jianhua; Feldhoff, Armin; Fattakhova Rohlfing, Dina
- Small, Vol. 3, Issue 2
Progress in Modification of Indium-Tin Oxide/Organic Interfaces for Organic Light-Emitting Diodes
journal, January 2013
- Wu, Qi-Hui
- Critical Reviews in Solid State and Materials Sciences, Vol. 38, Issue 4
Nonaqueous Synthesis of Uniform Indium Tin Oxide Nanocrystals and Their Electrical Conductivity in Dependence of the Tin Oxide Concentration
journal, June 2006
- Ba, Jianhua; Fattakhova Rohlfing, Dina; Feldhoff, Armin
- Chemistry of Materials, Vol. 18, Issue 12
A Facile Solution-Phase Approach to Transparent and Conducting ITO Nanocrystal Assemblies
journal, August 2012
- Lee, Jonghun; Lee, Sunghwan; Li, Guanglai
- Journal of the American Chemical Society, Vol. 134, Issue 32
Inorganic Hollow Nanotube Aerogels by Atomic Layer Deposition onto Native Nanocellulose Templates
journal, February 2011
- Korhonen, Juuso T.; Hiekkataipale, Panu; Malm, Jari
- ACS Nano, Vol. 5, Issue 3
A Surface Sol−Gel Process of TiO 2 and Other Metal Oxide Films with Molecular Precision
journal, June 1997
- Ichinose, Izumi; Senzu, Hiroyuki; Kunitake, Toyoki
- Chemistry of Materials, Vol. 9, Issue 6
Photocatalytic properties of visible-light enabling layered titanium oxide/tin indium oxide films
journal, May 2008
- Wu, K.; Cho, T.
- Applied Catalysis B: Environmental, Vol. 80, Issue 3-4
Effects of temperature on indium tin oxide particles synthesized by co-precipitation
journal, March 2006
- Li, Shitao; Qiao, Xueliang; Chen, Jianguo
- Journal of Crystal Growth, Vol. 289, Issue 1
A room temperature indium tin oxide/quartz crystal microbalance gas sensor for nitric oxide
journal, August 2003
- Hu, Jianqiao; Zhu, Furong; Zhang, Jian
- Sensors and Actuators B: Chemical, Vol. 93, Issue 1-3
Optical Transmittance of Indium Tin Oxide Nanoparticles Prepared by Laser-Induced Fragmentation in Water
journal, June 2006
- Usui, Hiroyuki; Sasaki, Takeshi; Koshizaki, Naoto
- The Journal of Physical Chemistry B, Vol. 110, Issue 26
SnO 2 −In 2 O 3 Nanocomposites as Semiconductor Gas Sensors for CO and NO x Detection
journal, March 2007
- McCue, Justin T.; Ying, Jackie Y.
- Chemistry of Materials, Vol. 19, Issue 5
Low temperature high sensor response nano gas sensor using ITO nanofibers
journal, December 2009
- Xu, Shiyou; Shi, Yong
- Sensors and Actuators B: Chemical, Vol. 143, Issue 1
Atomic Layer Deposition of TiO 2 on Mesoporous nanoITO: Conductive Core–Shell Photoanodes for Dye-Sensitized Solar Cells
journal, May 2014
- Alibabaei, Leila; Farnum, Byron H.; Kalanyan, Berç
- Nano Letters, Vol. 14, Issue 6
Growth and luminescence of zinc-blende-structured ZnSe nanowires by metal-organic chemical vapor deposition
journal, December 2003
- Zhang, X. T.; Liu, Z.; Leung, Y. P.
- Applied Physics Letters, Vol. 83, Issue 26
Cellulose Nanocrystals: Chemistry, Self-Assembly, and Applications
journal, June 2010
- Habibi, Youssef; Lucia, Lucian A.; Rojas, Orlando J.
- Chemical Reviews, Vol. 110, Issue 6
Keimbildung in übersättigten Gebilden
journal, January 1926
- Volmer, M.; Weber, Α.
- Zeitschrift für Physikalische Chemie, Vol. 119U, Issue 1