Dynamic fluxionality and enhanced CO adsorption in the presence of coadsorbed H2O on free gold cluster cations

Xing, Xiaopeng; Li, Xi; Yoon, Bokwon; Landman, Uzi; Parks, Joel H.

doi:10.1016/j.ijms.2014.07.006

Title: Dynamic fluxionality and enhanced CO adsorption in the presence of coadsorbed H2O on free gold cluster cations

Authors:: Xing, Xiaopeng; Li, Xi; Yoon, Bokwon; Landman, Uzi; Parks, Joel H.

Publication Date:: Sun Feb 01 00:00:00 EST 2015

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1244089

Grant/Contract Number:: FG02-061ER45921; FG05-86ER45234

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: International Journal of Mass Spectrometry

Additional Journal Information:: Journal Name: International Journal of Mass Spectrometry Journal Volume: 377 Journal Issue: C; Journal ID: ISSN 1387-3806

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Xing, Xiaopeng, Li, Xi, Yoon, Bokwon, Landman, Uzi, and Parks, Joel H. Dynamic fluxionality and enhanced CO adsorption in the presence of coadsorbed H2O on free gold cluster cations.  Netherlands: N. p., 2015. 
Web.  doi:10.1016/j.ijms.2014.07.006.

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                    Xing, Xiaopeng, Li, Xi, Yoon, Bokwon, Landman, Uzi, & Parks, Joel H. Dynamic fluxionality and enhanced CO adsorption in the presence of coadsorbed H2O on free gold cluster cations.  Netherlands.  https://doi.org/10.1016/j.ijms.2014.07.006

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                    Xing, Xiaopeng, Li, Xi, Yoon, Bokwon, Landman, Uzi, and Parks, Joel H. Sun .  
"Dynamic fluxionality and enhanced CO adsorption in the presence of coadsorbed H2O on free gold cluster cations".  Netherlands.  https://doi.org/10.1016/j.ijms.2014.07.006.

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@article{osti_1244089,

  title        = {Dynamic fluxionality and enhanced CO adsorption in the presence of coadsorbed H2O on free gold cluster cations},

  author       = {Xing, Xiaopeng and Li, Xi and Yoon, Bokwon and Landman, Uzi and Parks, Joel H.},

  abstractNote = {},

  doi          = {10.1016/j.ijms.2014.07.006},

  journal      = {International Journal of Mass Spectrometry},

  number       = C,

  volume       = 377,

  place        = {Netherlands},

  year         = {Sun Feb 01 00:00:00 EST 2015},

  month        = {Sun Feb 01 00:00:00 EST 2015}

}

Copy to clipboard

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https://doi.org/10.1016/j.ijms.2014.07.006

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Title: Dynamic fluxionality and enhanced CO adsorption in the presence of coadsorbed H2O on free gold cluster cations

Citation Formats

Moisture Effect on CO Oxidation over Au/TiO2 Catalyst journal, July 2001

Materials by numbers: Computations as tools of discovery journal, May 2005

Generalized Gradient Approximation Made Simple journal, October 1996

Supported Magnetic Nanoclusters: Soft Landing of Pd Clusters on a MgO Surface journal, October 2002

Gold catalysts prepared by coprecipitation for low-temperature oxidation of hydrogen and of carbon monoxide journal, February 1989

A grid-based Bader analysis algorithm without lattice bias journal, January 2009

Gold Cluster Carbonyls: Saturated Adsorption of CO on Gold Cluster Cations, Vibrational Spectroscopy, and Implications for Their Structures journal, June 2005

Chemisorption-induced Structural Changes and Transition from Chemisorption to Physisorption in Au 6 (CO) n − ( n = 4−9) journal, July 2008

Catalytic Oxidation of Carbon Monoxide on Monodispersed Platinum Clusters: Each Atom Counts journal, April 1999

The Effects of Water on CO Oxidation over TiO2 Supported Au Catalysts journal, November 2009

Further considerations on the thermodynamics of chemical equilibria and reaction rates journal, January 1936

A density functional theory study of the dissociation of H2 on gold clusters: Importance of fluxionality and ensemble effects journal, October 2006

Gold—an introductory perspective journal, January 2008

Resonance Ejection Ion Trap Mass Spectrometry and Nonlinear Field Contributions: The Effect of Scan Direction on Mass Resolution journal, March 1994

Hydrogen-Promoted Oxygen Activation by Free Gold Cluster Cations journal, July 2009

An Introduction to Quadrupole Ion Trap Mass Spectrometry journal, April 1997

Chemisorption-Induced 2D–3D–2D Structural Transitions in Gold Heptamer: (CO) n Au 7 – ( n = 1–4) journal, August 2011

Composition dependent adsorption of multiple CO molecules on binary silver–gold clusters AgnAum+ (n + m = 5): theory and experiment journal, January 2010

Onset of Catalytic Activity of Gold Clusters on Titania with the Appearance of Nonmetallic Properties journal, September 1998

Bonding Trends and Dimensionality Crossover of Gold Nanoclusters on Metal-Supported MgO Thin Films journal, July 2006

Efficient pseudopotentials for plane-wave calculations journal, January 1991

Control and Manipulation of Gold Nanocatalysis: Effects of Metal Oxide Support Thickness and Composition journal, January 2009

Methane Activation and Catalytic Ethylene Formation on Free Au2+ journal, January 2010

Gold clusters ( Au N , 2 <~ N <~ 1 0 ) and their anions journal, July 2000

Size-Dependent Structural Evolution and Chemical Reactivity of Gold Clusters journal, January 2007

Reactions of small gold cluster cations with propylene, methane, and hydrogen: permissive and competitive coadsorption effects journal, March 2009

Tuning the oxidation of carbon monoxide using nanoassembled model catalysts journal, December 2000

Binding energies of CO on gold cluster cations Aun+ (n=1–65): A radiative association kinetics study journal, March 2005

Charging Effects on Bonding and Catalyzed Oxidation of CO on Au8 Clusters on MgO journal, January 2005

Mechanism of ionic reactions journal, January 1935

Factors in gold nanocatalysis: oxidation of CO in the non-scalable size regime journal, June 2007

Gas-Phase Reactivity of Gold Oxide Cluster Cations with CO journal, June 2008

Structures of small gold cluster cations (Aun+, n<14): Ion mobility measurements versus density functional calculations journal, March 2002

Performance of Au/TiO2 catalyst under ambient conditions journal, February 2002

Probing the Structure of Gas-Phase Metallic Clusters via Ligation Energetics: Sequential Addition of C 2 H 4 to Ag m + ( m = 3−7) journal, July 2005

Fluxionality in the Chemical Reactions of Transition Metal Oxide Clusters: The Role of Metal, Spin State, and the Reactant Molecule journal, June 2012

When Gold Is Not Noble: Catalysis by Nanoparticles journal, April 2003

Water-Enhanced Catalysis of CO Oxidation on Free and Supported Gold Nanoclusters journal, September 2005

Diabatic reactions and primary chemiluminescence journal, January 1935

Reactivity-promoting criterion based on internal vibrational energy redistribution journal, June 2007

Composition dependent selectivity in the coadsorption of H2O and CO on pure and binary silver–gold clusters journal, April 2013

Catalytically Active Gold: From Nanoparticles to Ultrathin Films journal, October 2006

Size-dependent fivefold and icosahedral symmetry in silver clusters journal, August 2005

Vital Role of Moisture in the Catalytic Activity of Supported Gold Nanoparticles journal, April 2004

Electric Field Control of Structure, Dimensionality, and Reactivity of Gold Nanoclusters on Metal-Supported MgO Films journal, February 2008

When Gold Is Not Noble: Nanoscale Gold Catalysts journal, December 1999

Structure of Neutral Molecules and Monoanions of Selected Oxopurines in Aqueous Solutions As Studied by NMR Spectroscopy and Theoretical Calculations journal, March 2011

Structural, Electronic, and Impurity-Doping Effects in Nanoscale Chemistry: Supported Gold Nanoclusters journal, March 2003

Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation journal, September 2008

Moisture Effect on CO Oxidation over Au/TiO2 Catalyst
journal, July 2001

Materials by numbers: Computations as tools of discovery
journal, May 2005

Generalized Gradient Approximation Made Simple
journal, October 1996

Supported Magnetic Nanoclusters: Soft Landing of Pd Clusters on a MgO Surface
journal, October 2002

Gold catalysts prepared by coprecipitation for low-temperature oxidation of hydrogen and of carbon monoxide
journal, February 1989

A grid-based Bader analysis algorithm without lattice bias
journal, January 2009

Gold Cluster Carbonyls: Saturated Adsorption of CO on Gold Cluster Cations, Vibrational Spectroscopy, and Implications for Their Structures
journal, June 2005

Chemisorption-induced Structural Changes and Transition from Chemisorption to Physisorption in Au ₆ (CO) _n ⁻ ( n = 4−9)
journal, July 2008

Catalytic Oxidation of Carbon Monoxide on Monodispersed Platinum Clusters: Each Atom Counts
journal, April 1999

The Effects of Water on CO Oxidation over TiO2 Supported Au Catalysts
journal, November 2009

Further considerations on the thermodynamics of chemical equilibria and reaction rates
journal, January 1936

A density functional theory study of the dissociation of H2 on gold clusters: Importance of fluxionality and ensemble effects
journal, October 2006

Gold—an introductory perspective
journal, January 2008

Resonance Ejection Ion Trap Mass Spectrometry and Nonlinear Field Contributions: The Effect of Scan Direction on Mass Resolution
journal, March 1994

Hydrogen-Promoted Oxygen Activation by Free Gold Cluster Cations
journal, July 2009

An Introduction to Quadrupole Ion Trap Mass Spectrometry
journal, April 1997

Chemisorption-Induced 2D–3D–2D Structural Transitions in Gold Heptamer: (CO) _n Au ₇ ^– ( n = 1–4)
journal, August 2011

Composition dependent adsorption of multiple CO molecules on binary silver–gold clusters AgnAum+ (n + m = 5): theory and experiment
journal, January 2010

Onset of Catalytic Activity of Gold Clusters on Titania with the Appearance of Nonmetallic Properties
journal, September 1998

Bonding Trends and Dimensionality Crossover of Gold Nanoclusters on Metal-Supported MgO Thin Films
journal, July 2006

Efficient pseudopotentials for plane-wave calculations
journal, January 1991

Control and Manipulation of Gold Nanocatalysis: Effects of Metal Oxide Support Thickness and Composition
journal, January 2009

Methane Activation and Catalytic Ethylene Formation on Free Au2+
journal, January 2010

Gold clusters $({Au}_{N},$ $2 <~ N <~ 10)$ and their anions
journal, July 2000

Size-Dependent Structural Evolution and Chemical Reactivity of Gold Clusters
journal, January 2007

Reactions of small gold cluster cations with propylene, methane, and hydrogen: permissive and competitive coadsorption effects
journal, March 2009

Tuning the oxidation of carbon monoxide using nanoassembled model catalysts
journal, December 2000

Binding energies of CO on gold cluster cations Aun+ (n=1–65): A radiative association kinetics study
journal, March 2005

Charging Effects on Bonding and Catalyzed Oxidation of CO on Au₈ Clusters on MgO
journal, January 2005

Mechanism of ionic reactions
journal, January 1935

Factors in gold nanocatalysis: oxidation of CO in the non-scalable size regime
journal, June 2007

Gas-Phase Reactivity of Gold Oxide Cluster Cations with CO
journal, June 2008

Structures of small gold cluster cations (Aun+, n<14): Ion mobility measurements versus density functional calculations
journal, March 2002

Performance of Au/TiO2 catalyst under ambient conditions
journal, February 2002

Probing the Structure of Gas-Phase Metallic Clusters via Ligation Energetics: Sequential Addition of C ₂ H ₄ to Ag _m ⁺ ( m = 3−7)
journal, July 2005

Fluxionality in the Chemical Reactions of Transition Metal Oxide Clusters: The Role of Metal, Spin State, and the Reactant Molecule
journal, June 2012

When Gold Is Not Noble: Catalysis by Nanoparticles
journal, April 2003

Water-Enhanced Catalysis of CO Oxidation on Free and Supported Gold Nanoclusters
journal, September 2005

Diabatic reactions and primary chemiluminescence
journal, January 1935

Reactivity-promoting criterion based on internal vibrational energy redistribution
journal, June 2007

Composition dependent selectivity in the coadsorption of H2O and CO on pure and binary silver–gold clusters
journal, April 2013

Catalytically Active Gold: From Nanoparticles to Ultrathin Films
journal, October 2006

Size-dependent fivefold and icosahedral symmetry in silver clusters
journal, August 2005

Vital Role of Moisture in the Catalytic Activity of Supported Gold Nanoparticles
journal, April 2004

Electric Field Control of Structure, Dimensionality, and Reactivity of Gold Nanoclusters on Metal-Supported MgO Films
journal, February 2008

When Gold Is Not Noble: Nanoscale Gold Catalysts
journal, December 1999

Structure of Neutral Molecules and Monoanions of Selected Oxopurines in Aqueous Solutions As Studied by NMR Spectroscopy and Theoretical Calculations
journal, March 2011

Structural, Electronic, and Impurity-Doping Effects in Nanoscale Chemistry: Supported Gold Nanoclusters
journal, March 2003

Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
journal, September 2008