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Title: Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries

Abstract

We prepared antiperovskite Li 3OCl superionic conductor films via pulsed laser deposition using a composite target. A significantly enhanced ionic conductivity of 2.0 × 10 -4 S cm -1 at room temperature is achieved, and this value is more than two orders of magnitude higher than that of its bulk counterpart. Moreover, the applicability of Li 3OCl as a solid electrolyte for Li-ion batteries is demonstrated.

Authors:
 [1];  [2];  [1];  [2];  [2];  [3];  [1];  [1];  [2];  [1]
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  2. Univ. of Nevada, Las Vegas, NV (United States)
  3. Univ. at Buffalo, NY (United States)
Publication Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of Nevada, Las Vegas, NV (United States)
Sponsoring Org.:
USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1240619
Alternate Identifier(s):
OSTI ID: 1332394
Report Number(s):
LA-UR-15-26439
Journal ID: ISSN 2198-3844
Grant/Contract Number:  
AC52-06NA25396; NA0001982
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Science
Additional Journal Information:
Journal Name: Advanced Science; Journal ID: ISSN 2198-3844
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; antiperovskite phase; solid-state batteries; superionic conductor; sustainable chemistry; thin films

Citation Formats

Lü, Xujie, Howard, John W., Chen, Aiping, Zhu, Jinlong, Li, Shuai, Wu, Gang, Dowden, Paul, Xu, Hongwu, Zhao, Yusheng, and Jia, Quanxi. Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries. United States: N. p., 2016. Web. doi:10.1002/advs.201500359.
Lü, Xujie, Howard, John W., Chen, Aiping, Zhu, Jinlong, Li, Shuai, Wu, Gang, Dowden, Paul, Xu, Hongwu, Zhao, Yusheng, & Jia, Quanxi. Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries. United States. doi:10.1002/advs.201500359.
Lü, Xujie, Howard, John W., Chen, Aiping, Zhu, Jinlong, Li, Shuai, Wu, Gang, Dowden, Paul, Xu, Hongwu, Zhao, Yusheng, and Jia, Quanxi. Tue . "Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries". United States. doi:10.1002/advs.201500359. https://www.osti.gov/servlets/purl/1240619.
@article{osti_1240619,
title = {Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries},
author = {Lü, Xujie and Howard, John W. and Chen, Aiping and Zhu, Jinlong and Li, Shuai and Wu, Gang and Dowden, Paul and Xu, Hongwu and Zhao, Yusheng and Jia, Quanxi},
abstractNote = {We prepared antiperovskite Li3OCl superionic conductor films via pulsed laser deposition using a composite target. A significantly enhanced ionic conductivity of 2.0 × 10-4 S cm-1 at room temperature is achieved, and this value is more than two orders of magnitude higher than that of its bulk counterpart. Moreover, the applicability of Li3OCl as a solid electrolyte for Li-ion batteries is demonstrated.},
doi = {10.1002/advs.201500359},
journal = {Advanced Science},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {2}
}

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Cited by: 14 works
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    Works referencing / citing this record:

    Chemistry Design Towards a Stable Sulfide-Based Superionic Conductor Li 4 Cu 8 Ge 3 S 12
    journal, April 2019

    • Wang, Yingqi; Lü, Xujie; Zheng, Chong
    • Angewandte Chemie International Edition, Vol. 58, Issue 23
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