Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries
Abstract
We prepared antiperovskite Li 3OCl superionic conductor films via pulsed laser deposition using a composite target. A significantly enhanced ionic conductivity of 2.0 × 10 -4 S cm -1 at room temperature is achieved, and this value is more than two orders of magnitude higher than that of its bulk counterpart. Moreover, the applicability of Li 3OCl as a solid electrolyte for Li-ion batteries is demonstrated.
- Authors:
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Univ. of Nevada, Las Vegas, NV (United States)
- Univ. at Buffalo, NY (United States)
- Publication Date:
- Research Org.:
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of Nevada, Las Vegas, NV (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1240619
- Alternate Identifier(s):
- OSTI ID: 1332394
- Report Number(s):
- LA-UR-15-26439
Journal ID: ISSN 2198-3844
- Grant/Contract Number:
- AC52-06NA25396; NA0001982
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Science
- Additional Journal Information:
- Journal Name: Advanced Science; Journal ID: ISSN 2198-3844
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; antiperovskite phase; solid-state batteries; superionic conductor; sustainable chemistry; thin films
Citation Formats
Lü, Xujie, Howard, John W., Chen, Aiping, Zhu, Jinlong, Li, Shuai, Wu, Gang, Dowden, Paul, Xu, Hongwu, Zhao, Yusheng, and Jia, Quanxi. Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries. United States: N. p., 2016.
Web. doi:10.1002/advs.201500359.
Lü, Xujie, Howard, John W., Chen, Aiping, Zhu, Jinlong, Li, Shuai, Wu, Gang, Dowden, Paul, Xu, Hongwu, Zhao, Yusheng, & Jia, Quanxi. Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries. United States. doi:10.1002/advs.201500359.
Lü, Xujie, Howard, John W., Chen, Aiping, Zhu, Jinlong, Li, Shuai, Wu, Gang, Dowden, Paul, Xu, Hongwu, Zhao, Yusheng, and Jia, Quanxi. Tue .
"Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries". United States. doi:10.1002/advs.201500359. https://www.osti.gov/servlets/purl/1240619.
@article{osti_1240619,
title = {Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries},
author = {Lü, Xujie and Howard, John W. and Chen, Aiping and Zhu, Jinlong and Li, Shuai and Wu, Gang and Dowden, Paul and Xu, Hongwu and Zhao, Yusheng and Jia, Quanxi},
abstractNote = {We prepared antiperovskite Li3OCl superionic conductor films via pulsed laser deposition using a composite target. A significantly enhanced ionic conductivity of 2.0 × 10-4 S cm-1 at room temperature is achieved, and this value is more than two orders of magnitude higher than that of its bulk counterpart. Moreover, the applicability of Li3OCl as a solid electrolyte for Li-ion batteries is demonstrated.},
doi = {10.1002/advs.201500359},
journal = {Advanced Science},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {2}
}
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Works referencing / citing this record:
Chemistry Design Towards a Stable Sulfide-Based Superionic Conductor Li 4 Cu 8 Ge 3 S 12
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