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Title: Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries

Abstract

We prepared antiperovskite Li 3OCl superionic conductor films via pulsed laser deposition using a composite target. A significantly enhanced ionic conductivity of 2.0 × 10 -4 S cm -1 at room temperature is achieved, and this value is more than two orders of magnitude higher than that of its bulk counterpart. Moreover, the applicability of Li 3OCl as a solid electrolyte for Li-ion batteries is demonstrated.

Authors:
 [1];  [2];  [1];  [2];  [2];  [3];  [1];  [1];  [2];  [1]
+ Show Author Affiliations
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  2. Univ. of Nevada, Las Vegas, NV (United States)
  3. Univ. at Buffalo, NY (United States)
Publication Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of Nevada, Las Vegas, NV (United States)
Sponsoring Org.:
USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1240619
Alternate Identifier(s):
OSTI ID: 1332394
Report Number(s):
LA-UR-15-26439
Journal ID: ISSN 2198-3844
Grant/Contract Number:  
AC52-06NA25396; NA0001982
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Science
Additional Journal Information:
Journal Name: Advanced Science; Journal ID: ISSN 2198-3844
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; antiperovskite phase; solid-state batteries; superionic conductor; sustainable chemistry; thin films

Citation Formats

Lü, Xujie, Howard, John W., Chen, Aiping, Zhu, Jinlong, Li, Shuai, Wu, Gang, Dowden, Paul, Xu, Hongwu, Zhao, Yusheng, and Jia, Quanxi. Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries. United States: N. p., 2016. Web. doi:10.1002/advs.201500359.
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Lü, Xujie, Howard, John W., Chen, Aiping, Zhu, Jinlong, Li, Shuai, Wu, Gang, Dowden, Paul, Xu, Hongwu, Zhao, Yusheng, & Jia, Quanxi. Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries. United States. doi:10.1002/advs.201500359.
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Lü, Xujie, Howard, John W., Chen, Aiping, Zhu, Jinlong, Li, Shuai, Wu, Gang, Dowden, Paul, Xu, Hongwu, Zhao, Yusheng, and Jia, Quanxi. Tue . "Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries". United States. doi:10.1002/advs.201500359. https://www.osti.gov/servlets/purl/1240619.
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@article{osti_1240619,
title = {Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries},
author = {Lü, Xujie and Howard, John W. and Chen, Aiping and Zhu, Jinlong and Li, Shuai and Wu, Gang and Dowden, Paul and Xu, Hongwu and Zhao, Yusheng and Jia, Quanxi},
abstractNote = {We prepared antiperovskite Li3OCl superionic conductor films via pulsed laser deposition using a composite target. A significantly enhanced ionic conductivity of 2.0 × 10-4 S cm-1 at room temperature is achieved, and this value is more than two orders of magnitude higher than that of its bulk counterpart. Moreover, the applicability of Li3OCl as a solid electrolyte for Li-ion batteries is demonstrated.},
doi = {10.1002/advs.201500359},
journal = {Advanced Science},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {2}
}
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Journal Article:
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Publisher's Version of Record
DOI:  10.1002/advs.201500359
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    Works referencing / citing this record:

    Chemistry Design Towards a Stable Sulfide-Based Superionic Conductor Li 4 Cu 8 Ge 3 S 12
    journal, April 2019

    • Wang, Yingqi; Lü, Xujie; Zheng, Chong
    • Angewandte Chemie International Edition, Vol. 58, Issue 23
    • DOI: 10.1002/anie.201901739
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