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Title: Defects Engineered Monolayer MoS2 for Improved Hydrogen Evolution Reaction

Abstract

MoS2 is a promising, low-cost material for electrochemical hydrogen production due to its high activity and stability during the reaction. Our work represents an easy method to increase the hydrogen production in electrochemical reaction of MoS2 via defect engineering, and helps to understand the catalytic properties of MoS2.

Authors:
 [1];  [2];  [3];  [1];  [1];  [3];  [4];  [1];  [5]
+ Show Author Affiliations
  1. Rice Univ., Houston, TX (United States). Department of Materials Science and NanoEngineering
  2. Rice Univ., Houston, TX (United States). Department of Chemistry
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division; Vanderbilt Univ., Nashville, TN (United States). Department of Physics and Astronomy
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
  5. Rice Univ., Houston, TX (United States). Department of Materials Science and NanoEngineering; Rice Univ., Houston, TX (United States). Department of Chemistry
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1240562
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Nano Letters
Additional Journal Information:
Journal Volume: 16; Journal Issue: 2; Journal ID: ISSN 1530-6984
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY; Monolayer MoS2; hydrogen evolution reaction; defects; oxygen plasma; hydrogen treatment

Citation Formats

Ye, Gonglan, Gong, Yongji, Lin, Junhao, Li, Bo, He, Yongmin, Pantelides, Sokrates T., Zhou, Wu, Vajtai, Robert, and Ajayan, Pulickel M. Defects Engineered Monolayer MoS2 for Improved Hydrogen Evolution Reaction. United States: N. p., 2016. Web. doi:10.1021/acs.nanolett.5b04331.
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Ye, Gonglan, Gong, Yongji, Lin, Junhao, Li, Bo, He, Yongmin, Pantelides, Sokrates T., Zhou, Wu, Vajtai, Robert, & Ajayan, Pulickel M. Defects Engineered Monolayer MoS2 for Improved Hydrogen Evolution Reaction. United States. https://doi.org/10.1021/acs.nanolett.5b04331
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Ye, Gonglan, Gong, Yongji, Lin, Junhao, Li, Bo, He, Yongmin, Pantelides, Sokrates T., Zhou, Wu, Vajtai, Robert, and Ajayan, Pulickel M. Wed . "Defects Engineered Monolayer MoS2 for Improved Hydrogen Evolution Reaction". United States. https://doi.org/10.1021/acs.nanolett.5b04331. https://www.osti.gov/servlets/purl/1240562.
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@article{osti_1240562,
title = {Defects Engineered Monolayer MoS2 for Improved Hydrogen Evolution Reaction},
author = {Ye, Gonglan and Gong, Yongji and Lin, Junhao and Li, Bo and He, Yongmin and Pantelides, Sokrates T. and Zhou, Wu and Vajtai, Robert and Ajayan, Pulickel M.},
abstractNote = {MoS2 is a promising, low-cost material for electrochemical hydrogen production due to its high activity and stability during the reaction. Our work represents an easy method to increase the hydrogen production in electrochemical reaction of MoS2 via defect engineering, and helps to understand the catalytic properties of MoS2.},
doi = {10.1021/acs.nanolett.5b04331},
journal = {Nano Letters},
number = 2,
volume = 16,
place = {United States},
year = {Wed Jan 13 00:00:00 EST 2016},
month = {Wed Jan 13 00:00:00 EST 2016}
}
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https://doi.org/10.1021/acs.nanolett.5b04331
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    journal, March 2018

    • Anjum, Mohsin Ali Raza; Jeong, Hu Young; Lee, Min Hee
    • Advanced Materials, Vol. 30, Issue 20
    • DOI: 10.1002/adma.201707105

    In-situ visualization of hydrogen evolution sites on helium ion treated molybdenum dichalcogenides under reaction conditions
    journal, July 2019

    • Mitterreiter, Elmar; Liang, Yunchang; Golibrzuch, Matthias
    • npj 2D Materials and Applications, Vol. 3, Issue 1
    • DOI: 10.1038/s41699-019-0107-5

    Oxygen Vacancies in ZnO Nanosheets Enhance CO 2 Electrochemical Reduction to CO
    journal, April 2018

    • Geng, Zhigang; Kong, Xiangdong; Chen, Weiwei
    • Angewandte Chemie, Vol. 130, Issue 21
    • DOI: 10.1002/ange.201711255

    Theoretical investigation of various aspects of two dimensional holey boroxine, B 3 O 3
    journal, January 2019

    • Ullah, Saif; Denis, Pablo A.; Sato, Fernando
    • RSC Advances, Vol. 9, Issue 64
    • DOI: 10.1039/c9ra07338h

    Quick Optical Identification of the Defect Formation in Monolayer WSe2 for Growth Optimization
    journal, August 2019

    Regulating p-block metals in perovskite nanodots for efficient electrocatalytic water oxidation
    journal, October 2017

    Wafer-scale synthesis of ultrathin CoO nanosheets with enhanced electrochemical catalytic properties
    journal, January 2017

    • Wang, Fei; Yu, Yanhao; Yin, Xin
    • Journal of Materials Chemistry A, Vol. 5, Issue 19
    • DOI: 10.1039/c7ta01857f

    Colloidally synthesized defect-rich $$\hbox {MoSe}_{2}$$ MoSe 2 nanosheets for superior catalytic activity
    journal, March 2019

    • Hassan, Md Samim; Jana, Atanu; Gahlawat, Soniya
    • Bulletin of Materials Science, Vol. 42, Issue 2
    • DOI: 10.1007/s12034-019-1774-8

    An Efficient and Extremely Stable Photocatalytic PtSe 2 /FTO Thin Film for Water Splitting
    journal, September 2019

    Dual-Functional N Dopants in Edges and Basal Plane of MoS 2 Nanosheets Toward Efficient and Durable Hydrogen Evolution
    journal, December 2016

    • Xiao, Wen; Liu, Peitao; Zhang, Jingyan
    • Advanced Energy Materials, Vol. 7, Issue 7
    • DOI: 10.1002/aenm.201602086

    Hierarchical Nanoboxes Composed of Co 9 S 8 −MoS 2 Nanosheets as Efficient Electrocatalysts for the Hydrogen Evolution Reaction
    journal, January 2018

    • Ganesan, Vinoth; Lim, Sunghyun; Kim, Jinkwon
    • Chemistry - An Asian Journal, Vol. 13, Issue 4
    • DOI: 10.1002/asia.201701536

    Phase engineering of a multiphasic 1T/2H MoS 2 catalyst for highly efficient hydrogen evolution
    journal, January 2017

    • Wang, Dezhi; Zhang, Xiangyong; Bao, Siyuan
    • Journal of Materials Chemistry A, Vol. 5, Issue 6
    • DOI: 10.1039/c6ta09409k

    Enhancing potassium-ion battery performance by defect and interlayer engineering
    journal, January 2019

    • Xu, Yang; Bahmani, Farzaneh; Zhou, Min
    • Nanoscale Horizons, Vol. 4, Issue 1
    • DOI: 10.1039/c8nh00305j

    Confined Catalysis: Progress and Prospects in Energy Conversion
    journal, September 2019

    • Shifa, Tofik Ahmed; Vomiero, Alberto
    • Advanced Energy Materials, Vol. 9, Issue 40
    • DOI: 10.1002/aenm.201902307

    Activating MoS 2 basal planes for hydrogen evolution through direct CVD morphology control
    journal, January 2019

    • Dong, Lianqing; Guo, Shaoqiang; Wang, Yuyan
    • Journal of Materials Chemistry A, Vol. 7, Issue 48
    • DOI: 10.1039/c9ta08738a

    Promoting the electroreduction of CO 2 with oxygen vacancies on a plasma-activated SnO x /carbon foam monolithic electrode
    journal, January 2020

    • Li, Hongqiang; Xiao, Nan; Wang, Yuwei
    • Journal of Materials Chemistry A, Vol. 8, Issue 4
    • DOI: 10.1039/c9ta12401b

    Tuning the electronic and magnetic properties of MoS 2 nanotubes with vacancy defects
    journal, January 2019

    • Yang, Yanmei; Liu, Yang; Man, Baoyuan
    • RSC Advances, Vol. 9, Issue 30
    • DOI: 10.1039/c8ra08981g

    Vertically conductive MoS 2 pyramids with a high density of active edge sites for efficient hydrogen evolution
    journal, January 2020

    • Zhou, Qingwei; Su, Shaoqiang; Cheng, Pengfei
    • Journal of Materials Chemistry C, Vol. 8, Issue 9
    • DOI: 10.1039/c9tc05872a

    Recent Progress on Irradiation-Induced Defect Engineering of Two-Dimensional 2H-MoS2 Few Layers
    journal, February 2019

    • Zhao, Guang-Yi; Deng, Hua; Tyree, Nathaniel
    • Applied Sciences, Vol. 9, Issue 4
    • DOI: 10.3390/app9040678

    Engineering two-dimensional metal oxides via surface functionalization for biological applications
    journal, January 2020

    • Ren, Baiyu; Wang, Yichao; Ou, Jian Zhen
    • Journal of Materials Chemistry B, Vol. 8, Issue 6
    • DOI: 10.1039/c9tb02423a

    Alloy Foam‐Derived Ni 0.86 Fe 2.14 O 4 Hexagonal Plates as an Efficient Electrochemical Catalyst for the Oxygen Evolution Reaction
    journal, January 2020

    Probing the active sites of newly predicted stable Janus scandium dichalcogenides for photocatalytic water-splitting
    journal, January 2019

    • Yang, Xiaoyong; Banerjee, Amitava; Ahuja, Rajeev
    • Catalysis Science & Technology, Vol. 9, Issue 18
    • DOI: 10.1039/c9cy01014a

    Substrate screening effects on the quasiparticle band gap and defect charge transition levels in MoS 2
    journal, August 2018

    Solution-phase phosphorus substitution for enhanced oxygen evolution reaction in Cu 2 WS 4
    journal, January 2019

    • Novak, Travis G.; Prakash, Om; Tiwari, Anand P.
    • RSC Advances, Vol. 9, Issue 1
    • DOI: 10.1039/c8ra09261c

    Nanocatalysts for hydrogen evolution reactions
    journal, January 2018

    • Ojha, Kasinath; Saha, Soumen; Dagar, Preeti
    • Physical Chemistry Chemical Physics, Vol. 20, Issue 10
    • DOI: 10.1039/c7cp06316d

    Photoemission spectroscopy study of structural defects in molybdenum disulfide (MoS 2 ) grown by chemical vapor deposition (CVD)
    journal, January 2019

    • Syari’ati, Ali; Kumar, Sumit; Zahid, Amara
    • Chemical Communications, Vol. 55, Issue 70
    • DOI: 10.1039/c9cc01577a

    Enhancing the electrocatalytic activity of 2H-WS 2 for hydrogen evolution via defect engineering
    journal, January 2019

    • Wu, Longfei; van Hoof, Arno J. F.; Dzade, Nelson Y.
    • Physical Chemistry Chemical Physics, Vol. 21, Issue 11
    • DOI: 10.1039/c9cp00722a

    WS 2 Nanosheets with Highly‐Enhanced Electrochemical Activity by Facile Control of Sulfur Vacancies
    journal, May 2019

    State-of-the-Art Advances and Perspectives for Electrocatalysis
    book, January 2020

    • Ramohlola, Kabelo E.; Hato, Mpitloane J.; Monama, Gobeng R.
    • Methods for Electrocatalysis: Advanced Materials and Allied Applications, p. 311-352
    • DOI: 10.1007/978-3-030-27161-9_13

    Direct deposition of MoSe 2 nanocrystals onto conducting substrates: towards ultra-efficient electrocatalysts for hydrogen evolution
    journal, January 2017

    • Damien, Dijo; Anil, Athira; Chatterjee, Dipanwita
    • Journal of Materials Chemistry A, Vol. 5, Issue 26
    • DOI: 10.1039/c6ta09645j

    Structural Engineering of 2D Nanomaterials for Energy Storage and Catalysis
    journal, February 2018

    Synergetic Exfoliation and Lateral Size Engineering of MoS 2 for Enhanced Photocatalytic Hydrogen Generation
    journal, March 2018

    Structurally Deformed MoS 2 for Electrochemically Stable, Thermally Resistant, and Highly Efficient Hydrogen Evolution Reaction
    journal, October 2017

    Heterostructure engineering of Co-doped MoS 2 coupled with Mo 2 CT x MXene for enhanced hydrogen evolution in alkaline media
    journal, January 2019

    • Liang, Junmei; Ding, Chaoying; Liu, Jiapeng
    • Nanoscale, Vol. 11, Issue 22
    • DOI: 10.1039/c9nr02085c

    Direct Synthesis of Large-Area 2D Mo 2 C on In Situ Grown Graphene
    journal, July 2017

    • Geng, Dechao; Zhao, Xiaoxu; Chen, Zhongxin
    • Advanced Materials, Vol. 29, Issue 35
    • DOI: 10.1002/adma.201700072

    Composite electrocatalyst MoxW1-xS2 nanosheets on carbon fiber paper for highly efficient hydrogen evolution reaction
    journal, June 2018

    • Yang, Qiangbin; He, Yi; Zou, Changjun
    • Journal of Solid State Electrochemistry, Vol. 22, Issue 10
    • DOI: 10.1007/s10008-018-3991-2

    A bifunctional electrode engineered by sulfur vacancies for efficient electrocatalysis
    journal, January 2019

    Emerging two-dimensional nanomaterials for electrochemical hydrogen evolution
    journal, January 2017

    • Chen, Yunxu; Yang, Kena; Jiang, Bei
    • Journal of Materials Chemistry A, Vol. 5, Issue 18
    • DOI: 10.1039/c7ta00816c

    Highly Periodic Metal Dichalcogenide Nanostructures with Complex Shapes, High Resolution, and High Aspect Ratios
    journal, October 2017

    • Jang, Sungwoo; Kim, Seon Joon; Koh, Hyeong-Jun
    • Advanced Functional Materials, Vol. 27, Issue 46
    • DOI: 10.1002/adfm.201703842

    Graphene Nanoarchitectonics: Recent Advances in Graphene‐Based Electrocatalysts for Hydrogen Evolution Reaction
    journal, September 2019

    Design, synthesis, and energy-related applications of metal sulfides
    journal, January 2016

    • Liu, Yongchang; Li, Yang; Kang, Hongyan
    • Materials Horizons, Vol. 3, Issue 5
    • DOI: 10.1039/c6mh00075d

    Theoretical investigation on the hydrogen evolution reaction mechanism at MoS 2 heterostructures: the essential role of the 1T/2H phase interface
    journal, January 2020

    • Zhang, Tian; Zhu, Houyu; Guo, Chen
    • Catalysis Science & Technology, Vol. 10, Issue 2
    • DOI: 10.1039/c9cy01901d

    Nanostructured Metal Chalcogenides for Energy Storage and Electrocatalysis
    journal, August 2017

    • Zhang, Yu; Zhou, Qian; Zhu, Jixin
    • Advanced Functional Materials, Vol. 27, Issue 35
    • DOI: 10.1002/adfm.201702317

    Oxygen Evolution Reaction on 2D Ferromagnetic Fe 3 GeTe 2 : Boosting the Reactivity by the Self‐Reduction of Surface Hydroxyl
    journal, August 2019

    • Zhao, Yinghe; Gu, Jinxing; Chen, Zhongfang
    • Advanced Functional Materials, Vol. 29, Issue 44
    • DOI: 10.1002/adfm.201904782

    Template‐Assisted Synthesis of Metallic 1T′‐Sn 0.3 W 0.7 S 2 Nanosheets for Hydrogen Evolution Reaction
    journal, November 2019

    • Shao, Gonglei; Xue, Xiong‐Xiong; Wu, Binbin
    • Advanced Functional Materials, Vol. 30, Issue 5
    • DOI: 10.1002/adfm.201906069

    Unveiling Active Sites for the Hydrogen Evolution Reaction on Monolayer MoS 2
    journal, September 2017

    Nanoarchitectonics for Transition‐Metal‐Sulfide‐Based Electrocatalysts for Water Splitting
    journal, February 2019

    Probing the Electronic Properties of Monolayer MoS 2 via Interaction with Molecular Hydrogen
    journal, December 2018

    • Rezende, Natália P.; Cadore, Alisson R.; Gadelha, Andreij C.
    • Advanced Electronic Materials, Vol. 5, Issue 2
    • DOI: 10.1002/aelm.201800591

    Engineered MoSe 2 -Based Heterostructures for Efficient Electrochemical Hydrogen Evolution Reaction
    journal, February 2018

    • Najafi, Leyla; Bellani, Sebastiano; Oropesa-Nuñez, Reinier
    • Advanced Energy Materials, Vol. 8, Issue 16
    • DOI: 10.1002/aenm.201703212

    Metallic Twin Boundaries Boost the Hydrogen Evolution Reaction on the Basal Plane of Molybdenum Selenotellurides
    journal, April 2018

    • Kosmala, Tomasz; Coy Diaz, Horacio; Komsa, Hannu-Pekka
    • Advanced Energy Materials, Vol. 8, Issue 20
    • DOI: 10.1002/aenm.201800031

    Doped-MoSe 2 Nanoflakes/3d Metal Oxide-Hydr(Oxy)Oxides Hybrid Catalysts for pH-Universal Electrochemical Hydrogen Evolution Reaction
    journal, August 2018

    • Najafi, Leyla; Bellani, Sebastiano; Oropesa-Nuñez, Reinier
    • Advanced Energy Materials, Vol. 8, Issue 27
    • DOI: 10.1002/aenm.201801764

    Benchmarking the Activity, Stability, and Inherent Electrochemistry of Amorphous Molybdenum Sulfide for Hydrogen Production
    journal, January 2019

    • Escalera-López, Daniel; Lou, Zhiheng; Rees, Neil V.
    • Advanced Energy Materials, Vol. 9, Issue 8
    • DOI: 10.1002/aenm.201802614

    Single Atoms and Clusters Based Nanomaterials for Hydrogen Evolution, Oxygen Evolution Reactions, and Full Water Splitting
    journal, May 2019

    • Sultan, Siraj; Tiwari, Jitendra N.; Singh, Aditya Narayan
    • Advanced Energy Materials, Vol. 9, Issue 22
    • DOI: 10.1002/aenm.201900624

    Activation of MoS 2 Basal Planes for Hydrogen Evolution by Zinc
    journal, January 2019

    Oxygen Vacancies in ZnO Nanosheets Enhance CO 2 Electrochemical Reduction to CO
    journal, April 2018

    • Geng, Zhigang; Kong, Xiangdong; Chen, Weiwei
    • Angewandte Chemie International Edition, Vol. 57, Issue 21
    • DOI: 10.1002/anie.201711255

    Enhanced Raman and photoluminescence response in monolayer MoS 2 due to laser healing of defects: Enhanced Raman and photoluminescence response
    journal, July 2017

    • Bera, Achintya; Muthu, D. V. S.; Sood, A. K.
    • Journal of Raman Spectroscopy, Vol. 49, Issue 1
    • DOI: 10.1002/jrs.5196

    Conductive Molybdenum Sulfide for Efficient Electrocatalytic Hydrogen Evolution
    journal, October 2018

    Extending the Colloidal Transition Metal Dichalcogenide Library to ReS 2 Nanosheets for Application in Gas Sensing and Electrocatalysis
    journal, December 2019

    • Martín‐García, Beatriz; Spirito, Davide; Bellani, Sebastiano
    • Small, Vol. 15, Issue 52
    • DOI: 10.1002/smll.201904670

    Incorporation of active phase in porous MoS2 for enhanced hydrogen evolution reaction
    journal, January 2020

    • Qiao, Wen; Ma, Tiantian; Xu, Xiaoyong
    • Journal of Materials Science: Materials in Electronics, Vol. 31, Issue 5
    • DOI: 10.1007/s10854-020-02959-x

    Hydrogen adsorption engineering by intramolecular proton transfer on 2D nanosheets
    journal, May 2018

    Colloidal synthesis of VSe 2 single-layer nanosheets as novel electrocatalysts for the hydrogen evolution reaction
    journal, January 2016

    • Zhao, Wenwen; Dong, Bohua; Guo, Zenglong
    • Chemical Communications, Vol. 52, Issue 59
    • DOI: 10.1039/c6cc03854a

    Electrocatalysis of layered Group 5 metallic transition metal dichalcogenides (MX 2 , M = V, Nb, and Ta; X = S, Se, and Te)
    journal, January 2016

    • Chia, Xinyi; Ambrosi, Adriano; Lazar, Petr
    • Journal of Materials Chemistry A, Vol. 4, Issue 37
    • DOI: 10.1039/c6ta05110c

    Magnetism in monolayer 1T-MoS 2 and 1T-MoS 2 H tuned by strain
    journal, January 2018

    Computational screening for high-activity MoS 2 monolayer-based catalysts for the oxygen reduction reaction via substitutional doping with transition metal
    journal, January 2017

    • Wang, Zhongxu; Zhao, Jingxiang; Cai, Qinghai
    • Journal of Materials Chemistry A, Vol. 5, Issue 20
    • DOI: 10.1039/c7ta00577f

    Engineering of transition metal dichalcogenide-based 2D nanomaterials through doping for environmental applications
    journal, January 2019

    • Balasubramaniam, Bhuvaneshwari; Singh, Narendra; Kar, Prasenjit
    • Molecular Systems Design & Engineering, Vol. 4, Issue 4
    • DOI: 10.1039/c8me00116b

    Structural and electronic properties of hydrogenated GaBi and InBi honeycomb monolayers with point defects
    journal, January 2018

    • Zhang, Yunzhen; Ye, Han; Yu, Zhongyuan
    • RSC Advances, Vol. 8, Issue 13
    • DOI: 10.1039/c8ra00369f

    Carbon nanotube-induced phase and stability engineering: a strained cobalt-doped WSe 2 /MWNT heterostructure for enhanced hydrogen evolution reaction
    journal, January 2018

    • Zhang, Guoyuan; Zheng, Xiaoli; Xu, Qun
    • Journal of Materials Chemistry A, Vol. 6, Issue 11
    • DOI: 10.1039/c8ta00163d

    Engineering the nanostructure of molybdenum nitride nanodot embedded N-doped porous hollow carbon nanochains for rapid all pH hydrogen evolution
    journal, January 2018

    • Wang, Min-Qiang; Tang, Chun; Ye, Cui
    • Journal of Materials Chemistry A, Vol. 6, Issue 30
    • DOI: 10.1039/c8ta04684k

    Microwave-assisted synthesis of group 5 transition metal dichalcogenide thin films
    journal, January 2018

    • Kwak, Junghyeok; Jung, Sunshin; Lee, Noho
    • Journal of Materials Chemistry C, Vol. 6, Issue 42
    • DOI: 10.1039/c8tc03909g

    Porous aluminum electrodes with 3D channels and zig-zag edges for efficient hydrogen evolution
    journal, January 2019

    • Periasamy, Arun Prakash; Sriram, Pavithra; Chen, Yu-Wen
    • Chemical Communications, Vol. 55, Issue 38
    • DOI: 10.1039/c9cc01667h

    Applications of nano-porous graphene materials – critical review on performance and challenges
    journal, January 2020

    • Guirguis, Albert; Maina, James W.; Zhang, Xiwang
    • Materials Horizons, Vol. 7, Issue 5
    • DOI: 10.1039/c9mh01570a

    Recent advances in two-dimensional materials and their nanocomposites in sustainable energy conversion applications
    journal, January 2019

    • Khan, Karim; Tareen, Ayesha Khan; Aslam, Muhammad
    • Nanoscale, Vol. 11, Issue 45
    • DOI: 10.1039/c9nr05919a

    1% defect enriches MoS 2 quantum dot: catalysis and blue luminescence
    journal, January 2020

    • Tang, Jingmin; Sakamoto, Masanori; Ohta, Haruhisa
    • Nanoscale, Vol. 12, Issue 7
    • DOI: 10.1039/c9nr07612c

    Revealing the nature of active sites in electrocatalysis
    journal, January 2019

    • Garlyyev, Batyr; Fichtner, Johannes; Piqué, Oriol
    • Chemical Science, Vol. 10, Issue 35
    • DOI: 10.1039/c9sc02654a

    Interfacial aspect of ZnTe/In 2 Te 3 heterostructures as an efficient catalyst for the hydrogen evolution reaction
    journal, January 2019

    • Yang, Xiaoyong; Banerjee, Amitava; Xu, Zhitong
    • Journal of Materials Chemistry A, Vol. 7, Issue 48
    • DOI: 10.1039/c9ta09687f

    2D coordination polymers: Design guidelines and materials perspective
    journal, December 2019

    • Tran, Michael; Kline, Katelyn; Qin, Ying
    • Applied Physics Reviews, Vol. 6, Issue 4
    • DOI: 10.1063/1.5110895

    Revealing the microscopic CVD growth mechanism of MoSe 2 and the role of hydrogen gas during the growth procedure
    journal, May 2018

    Single-layer 1 T ′-MoS 2 under electron irradiation from ab initio molecular dynamics
    journal, March 2018

    Recent progress in plasma-assisted synthesis and modification of 2D materials
    journal, April 2018

    Carbon-Based Photocathode Materials for Solar Hydrogen Production
    journal, September 2018

    • Bellani, Sebastiano; Antognazza, Maria Rosa; Bonaccorso, Francesco
    • Advanced Materials, Vol. 31, Issue 9
    • DOI: 10.1002/adma.201801446

    Multiscale structural and electronic control of molybdenum disulfide foam for highly efficient hydrogen production
    journal, April 2017

    • Deng, Jiao; Li, Haobo; Wang, Suheng
    • Nature Communications, Vol. 8, Issue 1
    • DOI: 10.1038/ncomms14430

    Electrochemical generation of sulfur vacancies in the basal plane of MoS2 for hydrogen evolution
    journal, April 2017

    • Tsai, Charlie; Li, Hong; Park, Sangwook
    • Nature Communications, Vol. 8, Issue 1
    • DOI: 10.1038/ncomms15113

    Non-equilibrium fractal growth of MoS 2 for electrocatalytic hydrogen evolution
    journal, January 2019

    • Park, Taejin; Bae, Changdeuck; Lee, Hyangsook
    • CrystEngComm, Vol. 21, Issue 3
    • DOI: 10.1039/c8ce01952e

    In situ synthesis of MoS 2 /graphene nanosheets as free-standing and flexible electrode paper for high-efficiency hydrogen evolution reaction
    journal, January 2018

    • Zhang, Xianghui; Zhang, Mingguang; Tian, Yiqun
    • RSC Advances, Vol. 8, Issue 19
    • DOI: 10.1039/c8ra01226a

    Superhydrophobic states of 2D nanomaterials controlled by atomic defects can modulate cell adhesion
    journal, January 2019

    • Jaiswal, Manish K.; Singh, Kanwar Abhay; Lokhande, Giriraj
    • Chemical Communications, Vol. 55, Issue 60
    • DOI: 10.1039/c9cc00547a

    MoC based Mott–Schottky electrocatalyst for boosting the hydrogen evolution reaction performance
    journal, January 2020

    • Ji, Xinyang; Wang, Kaixuan; Zhang, Yao
    • Sustainable Energy & Fuels, Vol. 4, Issue 1
    • DOI: 10.1039/c9se00897g

    Mo 2 C/graphene heterostructures: low temperature chemical vapor deposition on liquid bimetallic Sn–Cu and hydrogen evolution reaction electrocatalytic properties
    journal, January 2019

    • Chaitoglou, Stefanos; Giannakopoulou, Tatiana; Speliotis, Thanassis
    • Nanotechnology, Vol. 30, Issue 12
    • DOI: 10.1088/1361-6528/aaf9e8

    Polypyrrole coated niobium disulfide nanowires as high performance electrocatalysts for hydrogen evolution reaction
    journal, July 2019

    Prevention of Hydrogen Damage Using MoS2 Coating on Iron Surface
    journal, March 2019

    Plasma-Assisted Synthesis and Surface Modification of Electrode Materials for Renewable Energy
    journal, February 2018

    2D Transition Metal Dichalcogenide Thin Films Obtained by Chemical Gas Phase Deposition Techniques
    journal, October 2018

    • Park, Gyu-Hyeon; Nielsch, Kornelius; Thomas, Andy
    • Advanced Materials Interfaces, Vol. 6, Issue 3
    • DOI: 10.1002/admi.201800688

    High‐Resolution Electrochemical Mapping of the Hydrogen Evolution Reaction on Transition‐Metal Dichalcogenide Nanosheets
    journal, January 2020

    • Takahashi, Yasufumi; Kobayashi, Yu; Wang, Ziqian
    • Angewandte Chemie, Vol. 132, Issue 9
    • DOI: 10.1002/ange.201912863

    Activation of MoS 2 Basal Planes for Hydrogen Evolution by Zinc
    journal, January 2019

    • Wu, Wenzhuo; Niu, Chunyao; Wei, Cong
    • Angewandte Chemie International Edition, Vol. 58, Issue 7
    • DOI: 10.1002/anie.201812475

    Defect Engineering of MoS 2 and Its Impacts on Electrocatalytic and Photocatalytic Behavior in Hydrogen Evolution Reactions
    journal, December 2018

    A machine perspective of atomic defects in scanning transmission electron microscopy
    journal, August 2019

    • Dan, Jiadong; Zhao, Xiaoxu; Pennycook, Stephen J.
    • InfoMat, Vol. 1, Issue 3
    • DOI: 10.1002/inf2.12026

    Recent advances in two‐dimensional transition metal dichalcogenides as photoelectrocatalyst for hydrogen evolution reaction
    journal, January 2020

    • Nguyen, Van‐Huy; Nguyen, Thang P.; Le, Thu‐Ha
    • Journal of Chemical Technology & Biotechnology
    • DOI: 10.1002/jctb.6335

    A comparative study of hydrogen evolution reaction on pseudo-monolayer WS 2 and PtS 2 : insights based on the density functional theory
    journal, January 2017

    • Mir, Showkat H.; Chakraborty, Sudip; Wärnå, John
    • Catalysis Science & Technology, Vol. 7, Issue 3
    • DOI: 10.1039/c6cy02426b

    Group 6 transition metal dichalcogenide nanomaterials: synthesis, applications and future perspectives
    journal, January 2018

    • Samadi, Morasae; Sarikhani, Navid; Zirak, Mohammad
    • Nanoscale Horizons, Vol. 3, Issue 2
    • DOI: 10.1039/c7nh00137a

    A sea-change: manganese doped nickel/nickel oxide electrocatalysts for hydrogen generation from seawater
    journal, January 2018

    • Lu, Xunyu; Pan, Jian; Lovell, Emma
    • Energy & Environmental Science, Vol. 11, Issue 7
    • DOI: 10.1039/c8ee00976g

    MoS 2 -supported gold nanoparticle for CO hydrogenation
    journal, September 2017

    • Rawal, Takat B.; Le, Duy; Rahman, Talat S.
    • Journal of Physics: Condensed Matter, Vol. 29, Issue 41
    • DOI: 10.1088/1361-648x/aa8314

    Controllable epitaxial growth of MoSe 2 –MoS 2 lateral heterostructures with tunable electrostatic properties
    journal, October 2018

    Unraveling energy loss processes of low energy heavy ions in 2D materials
    journal, August 2019

    Defects in metal triiodide perovskite materials towards high-performance solar cells: origin, impact, characterization, and engineering
    journal, January 2018

    • Ran, Chenxin; Xu, Jiantie; Gao, Weiyin
    • Chemical Society Reviews, Vol. 47, Issue 12
    • DOI: 10.1039/c7cs00868f

    Efficient Solar Light Harvesting CdS/Co 9 S 8 Hollow Cubes for Z-Scheme Photocatalytic Water Splitting
    journal, February 2017

    Niobium disulphide (NbS$_2$)-based (heterogeneous) electrocatalysts for an efficient hydrogen evolution reaction
    text, January 2020

    Facile Synthesis of Molybdenum Diselenide Layers for High-Performance Hydrogen Evolution Electrocatalysts
    journal, May 2018

    Nitrogen-Plasma-Treated Continuous Monolayer MoS2 for Improving Hydrogen Evolution Reaction
    journal, December 2019

    Multiscale structural and electronic control of molybdenum disulfide foam for highly efficient hydrogen production
    journal, April 2017

    • Deng, Jiao; Li, Haobo; Wang, Suheng
    • Nature Communications, Vol. 8, Issue 1
    • DOI: 10.1038/ncomms14430

    Electrochemical generation of sulfur vacancies in the basal plane of MoS2 for hydrogen evolution
    journal, April 2017

    • Tsai, Charlie; Li, Hong; Park, Sangwook
    • Nature Communications, Vol. 8, Issue 1
    • DOI: 10.1038/ncomms15113

    Regulating p-block metals in perovskite nanodots for efficient electrocatalytic water oxidation
    journal, October 2017

    Boundary activated hydrogen evolution reaction on monolayer MoS2
    journal, March 2019

    Engineering grain boundaries at the 2D limit for the hydrogen evolution reaction
    journal, January 2020

    Hydrogen physisorption based on the dissociative hydrogen chemisorption at the sulphur vacancy of MoS2 surface
    journal, August 2017

    Revealing the nature of active sites in electrocatalysis
    journal, January 2019

    • Garlyyev, Batyr; Fichtner, Johannes; Piqué, Oriol
    • Chemical Science, Vol. 10, Issue 35
    • DOI: 10.1039/c9sc02654a

    Progress in Electrocatalytic Hydrogen Evolution Based on Monolayer Molybdenum Disulfide
    journal, March 2019

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