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Title: Volatile out gassing characteristics of highly filled ethylene vinyl acetate binder materials: Gas phase infra-red spectroscopy

Abstract

Gas phase Infra-red (IR) spectroscopy has been used to investigate volatile out gassing properties of highly filled poly (ethylene-co-vinyl acetate) materials. In these studies, a Scout-ENTM heated gas cell was interfaced to a vacuum FTIR spectrometer, and the quantification of evolved species was achieved through calibration of the gas cell with certified gas standards. The volatile out gassing properties were monitored as a function of time during storage at 75°C under vacuum conditions (< 1mbar). Acetic acid, carbon dioxide and water were identified as the major out gassing products through IR absorption peaks at 1797, 2354 and 3853 cm-1, respectively. We present a comparison of three highly filled poly (ethyleneco- vinyl acetate) resins.

Authors:
 [1];  [1];  [1];  [1];  [1];  [2];  [2];  [3]
+ Show Author Affiliations
  1. Atomic Weapons Establishment (AWE), Reading (United Kingdom)
  2. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
  3. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Publication Date:
Research Org.:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1240063
Report Number(s):
LLNL-JRNL-607741
Journal ID: ISSN 0142-9418
Grant/Contract Number:  
AC52-07NA27344
Resource Type:
Accepted Manuscript
Journal Name:
Polymer Testing
Additional Journal Information:
Journal Volume: 32; Journal Issue: 2; Journal ID: ISSN 0142-9418
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; Volatile Out gassing; Infra-red Spectroscopy; Ageing; Poly (ethylene-co-vinyl acetate)

Citation Formats

Patel, Mogon, Bowditch, Martin, Jones, Ben, Netherton, David, Khan, Niaz, Letant, Sonia, Maxwell, Robert S., and Birdsell, Stephen A. Volatile out gassing characteristics of highly filled ethylene vinyl acetate binder materials: Gas phase infra-red spectroscopy. United States: N. p., 2012. Web. doi:10.1016/j.polymertesting.2012.12.001.
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Patel, Mogon, Bowditch, Martin, Jones, Ben, Netherton, David, Khan, Niaz, Letant, Sonia, Maxwell, Robert S., & Birdsell, Stephen A. Volatile out gassing characteristics of highly filled ethylene vinyl acetate binder materials: Gas phase infra-red spectroscopy. United States. https://doi.org/10.1016/j.polymertesting.2012.12.001
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Patel, Mogon, Bowditch, Martin, Jones, Ben, Netherton, David, Khan, Niaz, Letant, Sonia, Maxwell, Robert S., and Birdsell, Stephen A. Sat . "Volatile out gassing characteristics of highly filled ethylene vinyl acetate binder materials: Gas phase infra-red spectroscopy". United States. https://doi.org/10.1016/j.polymertesting.2012.12.001. https://www.osti.gov/servlets/purl/1240063.
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@article{osti_1240063,
title = {Volatile out gassing characteristics of highly filled ethylene vinyl acetate binder materials: Gas phase infra-red spectroscopy},
author = {Patel, Mogon and Bowditch, Martin and Jones, Ben and Netherton, David and Khan, Niaz and Letant, Sonia and Maxwell, Robert S. and Birdsell, Stephen A.},
abstractNote = {Gas phase Infra-red (IR) spectroscopy has been used to investigate volatile out gassing properties of highly filled poly (ethylene-co-vinyl acetate) materials. In these studies, a Scout-ENTM heated gas cell was interfaced to a vacuum FTIR spectrometer, and the quantification of evolved species was achieved through calibration of the gas cell with certified gas standards. The volatile out gassing properties were monitored as a function of time during storage at 75°C under vacuum conditions (< 1mbar). Acetic acid, carbon dioxide and water were identified as the major out gassing products through IR absorption peaks at 1797, 2354 and 3853 cm-1, respectively. We present a comparison of three highly filled poly (ethyleneco- vinyl acetate) resins.},
doi = {10.1016/j.polymertesting.2012.12.001},
journal = {Polymer Testing},
number = 2,
volume = 32,
place = {United States},
year = {Sat Dec 08 00:00:00 EST 2012},
month = {Sat Dec 08 00:00:00 EST 2012}
}
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Journal Article:
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Publisher's Version of Record
https://doi.org/10.1016/j.polymertesting.2012.12.001
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Works referenced in this record:

Synthesis and thermal behaviour of layered silicate–EVA nanocomposites
journal, February 2001

Aspects of the thermal oxidation, yellowing and stabilisation of ethylene vinyl acetate copolymer
journal, January 2000

Aspects of the thermal oxidation of ethylene vinyl acetate copolymer
journal, May 2000

The thermal degradation of poly(vinyl acetate) and poly(ethylene-co-vinyl acetate), Part I: Experimental study of the degradation mechanism
journal, April 2008

The thermal degradation of polyvinyl acetate. I. Products and reaction mechanism at low temperatures
journal, January 1952

Surface modifications on eva treated with sulphuric acid
journal, June 2003

  • Martínez-García, Asunción; Sánchez-Reche, Ana; Martín-Martínez, José Miguel
  • The Journal of Adhesion, Vol. 79, Issue 6
  • DOI: 10.1080/00218460309541

Mathematics of Adsorption. IV. Effect of Intraparticle Diffusion in Agitated Static Systems
journal, January 1952

  • Edeskuty, Fred J.; Amundson, Neal R.
  • The Journal of Physical Chemistry, Vol. 56, Issue 1
  • DOI: 10.1021/j150493a029
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