Topology-generating interfacial pattern formation during liquid metal dealloying
Abstract
Liquid metal dealloying has emerged as a novel technique to produce topologically complex nanoporous and nanocomposite structures with ultra-high interfacial area and other unique properties relevant for diverse material applications. This process is empirically known to require the selective dissolution of one element of a multicomponent solid alloy into a liquid metal to obtain desirable structures. However, how structures form is not known. Here we demonstrate, using mesoscale phase-field modelling and experiments, that nano/microstructural pattern formation during dealloying results from the interplay of (i) interfacial spinodal decomposition, forming compositional domain structures enriched in the immiscible element, and (ii) diffusion-coupled growth of the enriched solid phase and the liquid phase into the alloy. We highlight how those two basic mechanisms interact to yield a rich variety of topologically disconnected and connected structures. Furthermore, we deduce scaling laws governing microstructural length scales and dealloying kinetics.
- Authors:
-
- Northeastern Univ., Boston, MA (United States)
- Johns Hopkins Univ., Baltimore, MD (United States)
- Publication Date:
- Research Org.:
- Northeastern Univ., Boston, MA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1239972
- Grant/Contract Number:
- FG02-07ER46400
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 6; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY; 36 MATERIALS SCIENCE; physical sciences; materials science
Citation Formats
Geslin, Pierre -Antoine, McCue, Ian, Gaskey, Bernard, Erlebacher, Jonah, and Karma, Alain. Topology-generating interfacial pattern formation during liquid metal dealloying. United States: N. p., 2015.
Web. doi:10.1038/ncomms9887.
Geslin, Pierre -Antoine, McCue, Ian, Gaskey, Bernard, Erlebacher, Jonah, & Karma, Alain. Topology-generating interfacial pattern formation during liquid metal dealloying. United States. https://doi.org/10.1038/ncomms9887
Geslin, Pierre -Antoine, McCue, Ian, Gaskey, Bernard, Erlebacher, Jonah, and Karma, Alain. Thu .
"Topology-generating interfacial pattern formation during liquid metal dealloying". United States. https://doi.org/10.1038/ncomms9887. https://www.osti.gov/servlets/purl/1239972.
@article{osti_1239972,
title = {Topology-generating interfacial pattern formation during liquid metal dealloying},
author = {Geslin, Pierre -Antoine and McCue, Ian and Gaskey, Bernard and Erlebacher, Jonah and Karma, Alain},
abstractNote = {Liquid metal dealloying has emerged as a novel technique to produce topologically complex nanoporous and nanocomposite structures with ultra-high interfacial area and other unique properties relevant for diverse material applications. This process is empirically known to require the selective dissolution of one element of a multicomponent solid alloy into a liquid metal to obtain desirable structures. However, how structures form is not known. Here we demonstrate, using mesoscale phase-field modelling and experiments, that nano/microstructural pattern formation during dealloying results from the interplay of (i) interfacial spinodal decomposition, forming compositional domain structures enriched in the immiscible element, and (ii) diffusion-coupled growth of the enriched solid phase and the liquid phase into the alloy. We highlight how those two basic mechanisms interact to yield a rich variety of topologically disconnected and connected structures. Furthermore, we deduce scaling laws governing microstructural length scales and dealloying kinetics.},
doi = {10.1038/ncomms9887},
journal = {Nature Communications},
number = ,
volume = 6,
place = {United States},
year = {2015},
month = {11}
}
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Works referenced in this record:
Evolution of nanoporosity in dealloying
journal, March 2001
- Erlebacher, Jonah; Aziz, Michael J.; Karma, Alain
- Nature, Vol. 410, Issue 6827, p. 450-453
An Atomistic Description of Dealloying
journal, January 2004
- Erlebacher, Jonah
- Journal of The Electrochemical Society, Vol. 151, Issue 10
Hard Materials with Tunable Porosity
journal, August 2009
- Erlebacher, Jonah; Seshadri, Ram
- MRS Bulletin, Vol. 34, Issue 8
Spontaneous evolution of bicontinuous nanostructures in dealloyed Li-based systems
journal, August 2013
- Chen, Qing; Sieradzki, Karl
- Nature Materials, Vol. 12, Issue 12
Magnesium Alloy Precursor Thin Films for Efficient, Practical Fabrication of Nanoporous Metals
journal, November 2013
- Wang, Lei; Briot, Nicolas J.; Swartzentruber, Phillip D.
- Metallurgical and Materials Transactions A, Vol. 45, Issue 1
Achieving finer pores and ligaments in nanoporous palladium–nickel thin films
journal, February 2010
- Li, W. -C.; Balk, T. J.
- Scripta Materialia, Vol. 62, Issue 3
Oxygen reduction in nanoporous metal–ionic liquid composite electrocatalysts
journal, October 2010
- Snyder, J.; Fujita, T.; Chen, M. W.
- Nature Materials, Vol. 9, Issue 11
Atomic origins of the high catalytic activity of nanoporous gold
journal, August 2012
- Fujita, Takeshi; Guan, Pengfei; McKenna, Keith
- Nature Materials, Vol. 11, Issue 9
Surface-chemistry-driven actuation in nanoporous gold
journal, November 2008
- Biener, J.; Wittstock, A.; Zepeda-Ruiz, L. A.
- Nature Materials, Vol. 8, Issue 1
Electrochemical DNA Biosensor Based on Nanoporous Gold Electrode and Multifunctional Encoded DNA−Au Bio Bar Codes
journal, December 2008
- Hu, Kongcheng; Lan, Dongxiao; Li, Xuemei
- Analytical Chemistry, Vol. 80, Issue 23
Toward the Theoretical Capacitance of RuO 2 Reinforced by Highly Conductive Nanoporous Gold
journal, March 2013
- Chen, L. Y.; Hou, Y.; Kang, J. L.
- Advanced Energy Materials, Vol. 3, Issue 7
Are Nanoporous Materials Radiation Resistant?
journal, June 2011
- Bringa, E. M.; Monk, J. D.; Caro, A.
- Nano Letters, Vol. 12, Issue 7
Dealloying by metallic melt
journal, April 2011
- Wada, Takeshi; Yubuta, Kunio; Inoue, Akihisa
- Materials Letters, Vol. 65, Issue 7
Bulk-Nanoporous-Silicon Negative Electrode with Extremely High Cyclability for Lithium-Ion Batteries Prepared Using a Top-Down Process
journal, July 2014
- Wada, Takeshi; Ichitsubo, Tetsu; Yubuta, Kunio
- Nano Letters, Vol. 14, Issue 8
Optimizing niobium dealloying with metallic melt to fabricate porous structure for electrolytic capacitors
journal, February 2015
- Kim, Joung Wook; Tsuda, Masashi; Wada, Takeshi
- Acta Materialia, Vol. 84
Size Effects in the Mechanical Properties of Bulk Bicontinuous Ta/Cu Nanocomposites Made by Liquid Metal Dealloying: Size Effects in the Mechanical Properties of Bulk…
journal, June 2015
- McCue, Ian; Ryan, Stephen; Hemker, Kevin
- Advanced Engineering Materials, Vol. 18, Issue 1
Ultrafine nanoporous gold by low-temperature dealloying and kinetics of nanopore formation
journal, August 2007
- Qian, L. H.; Chen, M. W.
- Applied Physics Letters, Vol. 91, Issue 8
Mechanism of Coarsening and Bubble Formation in High-Genus Nanoporous Metals
journal, June 2011
- Erlebacher, J.
- Physical Review Letters, Vol. 106, Issue 22
Three-dimensional open-cell macroporous iron, chromium and ferritic stainless steel
journal, May 2013
- Wada, Takeshi; Kato, Hidemi
- Scripta Materialia, Vol. 68, Issue 9
Surface Diffusion and Dissolution Kinetics in the Electrolyte–Metal Interface
journal, January 2010
- Policastro, S. A.; Carnahan, J. C.; Zangari, G.
- Journal of The Electrochemical Society, Vol. 157, Issue 10
Nanoporous gold formation by dealloying: A Metropolis Monte Carlo study
journal, June 2013
- Zinchenko, O.; De Raedt, H. A.; Detsi, E.
- Computer Physics Communications, Vol. 184, Issue 6
Effect of Precursor Stoichiometry on the Morphology of Nanoporous Platinum Sponges
journal, June 2014
- Supansomboon, Supitcha; Porkovich, Alexander; Dowd, Annette
- ACS Applied Materials & Interfaces, Vol. 6, Issue 12
Thermal Stability of Nanoporous Raney Gold Catalyst
journal, July 2015
- Tai, Matthew; Gentle, Angus; de Silva, Kaludewa
- Metals, Vol. 5, Issue 3
Phase field modeling of electrochemistry. I. Equilibrium
journal, February 2004
- Guyer, J. E.; Boettinger, W. J.; Warren, J. A.
- Physical Review E, Vol. 69, Issue 2
Phase field modeling of electrochemistry. II. Kinetics
journal, February 2004
- Guyer, J. E.; Boettinger, W. J.; Warren, J. A.
- Physical Review E, Vol. 69, Issue 2
Phase-Field Simulation of Solidification
journal, August 2002
- Boettinger, W. J.; Warren, J. A.; Beckermann, C.
- Annual Review of Materials Research, Vol. 32, Issue 1
Growth of 'dizzy dendrites' in a random field of foreign particles
journal, January 2003
- Gránásy, László; Pusztai, Tamás; Warren, James A.
- Nature Materials, Vol. 2, Issue 2
Orientation selection in dendritic evolution
journal, July 2006
- Haxhimali, Tomorr; Karma, Alain; Gonzales, Frédéric
- Nature Materials, Vol. 5, Issue 8
Phase-field models in materials science
journal, July 2009
- Steinbach, Ingo
- Modelling and Simulation in Materials Science and Engineering, Vol. 17, Issue 7
Phase-Field Models for Microstructure Evolution
journal, August 2002
- Chen, Long-Qing
- Annual Review of Materials Research, Vol. 32, Issue 1
Phase-Field Method of Phase Transitions/Domain Structures in Ferroelectric Thin Films: A Review
journal, June 2008
- Chen, Long-Qing
- Journal of the American Ceramic Society, Vol. 91, Issue 6
Solidification microstructures and solid-state parallels: Recent developments, future directions
journal, February 2009
- Asta, M.; Beckermann, C.; Karma, A.
- Acta Materialia, Vol. 57, Issue 4
Kinetics of Crystal Etching Limited by Terrace Dissolution
journal, January 2010
- Snyder, J.; Erlebacher, J.
- Journal of The Electrochemical Society, Vol. 157, Issue 3
Continuous growth model for interface motion during alloy solidification
journal, August 1988
- Aziz, Michael J.; Kaplan, Theodore
- Acta Metallurgica, Vol. 36, Issue 8
Solute trapping and solute drag in a phase-field model of rapid solidification
journal, September 1998
- Ahmad, N. A.; Wheeler, A. A.; Boettinger, W. J.
- Physical Review E, Vol. 58, Issue 3
Spinodal decomposition in ternary systems
journal, October 1971
- Morral, J. E.; Cahn, J. W.
- Acta Metallurgica, Vol. 19, Issue 10
An analysis of clustering and ordering in multicomponent solid solutions—I. Stability criteria
journal, January 1972
- De Fontaine, D.
- Journal of Physics and Chemistry of Solids, Vol. 33, Issue 2
Crystallization microstructure in transparent monotectic alloys
journal, September 1986
- Kaukler, William F.; Frazier, Donald O.
- Nature, Vol. 323, Issue 6083
On The Instability Of Jets
journal, November 1878
- Rayleigh, Lord
- Proceedings of the London Mathematical Society, Vol. s1-10, Issue 1
Shape instabilities of eutectic composites at elevated temperatures
journal, June 1971
- Cline, H. E.
- Acta Metallurgica, Vol. 19, Issue 6
Universality and self-similarity in pinch-off of rods by bulk diffusion
journal, August 2010
- Aagesen, Larry K.; Johnson, Anthony E.; Fife, Julie L.
- Nature Physics, Vol. 6, Issue 10
Diffusion in copper and copper alloys. Part III. Diffusion in systems involving elements of the groups IA, IIA, IIIB, IVB, VB, VIB, and VIIB
journal, January 1975
- Butrymowicz, Daniel B.; Manning, John R.; Read, Michael E.
- Journal of Physical and Chemical Reference Data, Vol. 4, Issue 1
The structures expected in a simple ternary eutectic system: Part II. The Al-Ag-Cu ternary system
journal, August 1980
- Mccartney, D. G.; Jordan, R. M.; Hunt, J. D.
- Metallurgical Transactions A, Vol. 11, Issue 8
Large scale phase-field simulations of directional ternary eutectic solidification
journal, July 2015
- Hötzer, Johannes; Jainta, Marcus; Steinmetz, Philipp
- Acta Materialia, Vol. 93
Phase-field model for solidification of ternary alloys coupled with thermodynamic database
journal, March 2003
- Kobayashi, Hiroki; Ode, Machiko; Gyoon Kim, Seong
- Scripta Materialia, Vol. 48, Issue 6
Multicomponent alloy solidification: Phase-field modeling and simulations
journal, April 2005
- Nestler, Britta; Garcke, Harald; Stinner, Björn
- Physical Review E, Vol. 71, Issue 4
Works referencing / citing this record:
Solid State Porous Metal Production: A Review of the Capabilities, Characteristics, and Challenges
journal, January 2018
- Atwater, Mark A.; Guevara, Laura N.; Darling, Kris A.
- Advanced Engineering Materials, Vol. 20, Issue 7
Beating Thermal Coarsening in Nanoporous Materials via High‐Entropy Design
journal, December 2019
- Joo, Soo‐Hyun; Bae, Jae Wung; Park, Won‐Young
- Advanced Materials, Vol. 32, Issue 6
A Trimodal Porous Cobalt‐Based Electrocatalyst for Enhanced Oxygen Evolution
journal, July 2019
- Cao, Zhen; Zhou, Tingting; Chen, Yan‐Li
- Advanced Materials Interfaces, Vol. 6, Issue 17
Challenges to model the role of heterogeneities on the shock response and spall failure of metallic materials at the mesoscales
journal, December 2019
- Dongare, Avinash M.
- Journal of Materials Science, Vol. 55, Issue 8
Nanoporous magnesium
journal, August 2018
- Okulov, Ilya Vladimirovich; Lamaka, Sviatlana V.; Wada, Takeshi
- Nano Research, Vol. 11, Issue 12
Dealloying-based interpenetrating-phase nanocomposites matching the elastic behavior of human bone
journal, February 2017
- Okulov, I. V.; Weissmüller, J.; Markmann, J.
- Scientific Reports, Vol. 7, Issue 1
Bi-continuous pattern formation in thin films via solid-state interfacial dealloying studied by multimodal characterization
journal, January 2019
- Zhao, Chonghang; Kisslinger, Kim; Huang, Xiaojing
- Materials Horizons, Vol. 6, Issue 10
Small-angle X-ray scattering of nanoporous materials
journal, January 2020
- Welborn, Samuel S.; Detsi, Eric
- Nanoscale Horizons, Vol. 5, Issue 1
Local heterogeneity in the mechanical properties of bicontinuous composites made by liquid metal dealloying
journal, December 2016
- McCue, Ian; Gaskey, Bernard; Crawford, Bryan
- Applied Physics Letters, Vol. 109, Issue 23
Microstructural patterns with tunable mechanical anisotropy obtained by simulating anisotropic spinodal decomposition
journal, October 2018
- Vidyasagar, A.; Krödel, S.; Kochmann, D. M.
- Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 474, Issue 2218
Phase-field investigation of the coarsening of porous structures by surface diffusion
journal, August 2019
- Geslin, Pierre-Antoine; Buchet, Mickaël; Wada, Takeshi
- Physical Review Materials, Vol. 3, Issue 8
Evolution of a bicontinuous structure in peritectic melting: The simplest form of dealloying
journal, November 2019
- Hu, Wen-Kai; Shao, Jun-Chao; Wang, Shao-Gang
- Physical Review Materials, Vol. 3, Issue 11
Self-organization of helium precipitates into elongated channels within metal nanolayers
journal, November 2017
- Chen, Di; Li, Nan; Yuryev, Dina
- Science Advances, Vol. 3, Issue 11
Pattern formation during electrochemical and liquid metal dealloying
journal, January 2018
- McCue, Ian; Karma, Alain; Erlebacher, Jonah
- MRS Bulletin, Vol. 43, Issue 1
Dealloying-based interpenetrating-phase nanocomposites matching the elastic behavior of human bone
text, January 2017
- Okulov, Ilya; Weissmüller, Jörg; Markmann, Jürgen
- nature.com