Magnetic Ordering in Sr3YCo4O10+x

Kishida, Takayoshi; Kapetanakis, Myron D.; Yan, Jiaqiang; Sales, Brian C.; Pantelides, Sokrates T.; Pennycook, Stephen J.; Chisholm, Matthew F.

doi:10.1038/srep19762

Title: Magnetic Ordering in Sr₃YCo₄O_10+x

Abstract

Transition-metal oxides often exhibit complex magnetic behavior due to the strong interplay between atomic-structure, electronic and magnetic degrees of freedom. Cobaltates, especially, exhibit complex behavior because of cobalt's ability to adopt various valence and spin state configurations. The case of the oxygen-deficient perovskite Sr3YCo4O10+x (SYCO) has attracted considerable attention because of persisting uncertainties about its structure and the origin of the observed room temperature ferromagnetism. Here we report a combined investigation of SYCO using aberration-corrected scanning transmission electron microscopy and density functional theory calculations. Guided by theoretical results on Co-O distances projected on different planes, the atomic-scale images of several different orientations, especially of the fully oxygenated planes, allow the unambiguous extraction of the underlying structure. The calculated magnetic properties of the new structure are in excellent agreement with the experimental data.

Authors:

Kishida, Takayoshi ^[1]; Kapetanakis, Myron D. ^[2]; Yan, Jiaqiang ^[3]; Sales, Brian C. ^[3]; Pantelides, Sokrates T. ^[2]; Pennycook, Stephen J. ^[4]; Chisholm, Matthew F. ^[3]

Asahi Kasei Corporation, Fuji, Shizuoka (Japan). Department of Technology Group, Analysis & Simulation Center
Vanderbilt Univ., Nashville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
National University of Singapore, (Singapore). Department of Materials Science and Engineering

Publication Date:: Thu Jan 28 00:00:00 EST 2016

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Vanderbilt Univ., Nashville, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1239752

Alternate Identifier(s):: OSTI ID: 1597737

Grant/Contract Number:: AC05-00OR22725; FG02- 09ER46554; AC02-05CH11231; FG02-09ER46554

Resource Type:: Accepted Manuscript

Journal Name:: Scientific Reports

Additional Journal Information:: Journal Volume: 6; Journal ID: ISSN 2045-2322

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Kishida, Takayoshi, Kapetanakis, Myron D., Yan, Jiaqiang, Sales, Brian C., Pantelides, Sokrates T., Pennycook, Stephen J., and Chisholm, Matthew F. Magnetic Ordering in Sr3YCo4O10+x.  United States: N. p., 2016. 
Web.  doi:10.1038/srep19762.

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                    Kishida, Takayoshi, Kapetanakis, Myron D., Yan, Jiaqiang, Sales, Brian C., Pantelides, Sokrates T., Pennycook, Stephen J., & Chisholm, Matthew F. Magnetic Ordering in Sr3YCo4O10+x.  United States.  https://doi.org/10.1038/srep19762

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                    Kishida, Takayoshi, Kapetanakis, Myron D., Yan, Jiaqiang, Sales, Brian C., Pantelides, Sokrates T., Pennycook, Stephen J., and Chisholm, Matthew F. Thu .  
"Magnetic Ordering in Sr3YCo4O10+x".  United States.  https://doi.org/10.1038/srep19762.  https://www.osti.gov/servlets/purl/1239752.

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@article{osti_1239752,

  title        = {Magnetic Ordering in Sr3YCo4O10+x},

  author       = {Kishida, Takayoshi and Kapetanakis, Myron D. and Yan, Jiaqiang and Sales, Brian C. and Pantelides, Sokrates T. and Pennycook, Stephen J. and Chisholm, Matthew F.},

  abstractNote = {Transition-metal oxides often exhibit complex magnetic behavior due to the strong interplay between atomic-structure, electronic and magnetic degrees of freedom. Cobaltates, especially, exhibit complex behavior because of cobalt's ability to adopt various valence and spin state configurations. The case of the oxygen-deficient perovskite Sr3YCo4O10+x (SYCO) has attracted considerable attention because of persisting uncertainties about its structure and the origin of the observed room temperature ferromagnetism. Here we report a combined investigation of SYCO using aberration-corrected scanning transmission electron microscopy and density functional theory calculations. Guided by theoretical results on Co-O distances projected on different planes, the atomic-scale images of several different orientations, especially of the fully oxygenated planes, allow the unambiguous extraction of the underlying structure. The calculated magnetic properties of the new structure are in excellent agreement with the experimental data.},

  doi          = {10.1038/srep19762},

  journal      = {Scientific Reports},

  number       = ,

  volume       = 6,

  place        = {United States},

  year         = {Thu Jan 28 00:00:00 EST 2016},

  month        = {Thu Jan 28 00:00:00 EST 2016}

}

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Works referenced in this record:

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Enhanced light element imaging in atomic resolution scanning transmission electron microscopy
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Works referencing / citing this record:

Spin states of Co ³⁺ ions in Sr _0.75 Y _0.25 CoO _2.625 system induced by Jahn-Teller distortion: a density-functional study
journal, August 2018

Muhammady, Shibghatullah; Sutjahja, Inge Magdalena
Materials Research Express, Vol. 5, Issue 9
DOI: 10.1088/2053-1591/aad4e0

Ferromagnet-antiferromagnet transition in layered perovskites of Sr ₃ YCo ₄ O _10.5 type
journal, November 2018

Troyanchuk, I. O.; Bushinsky, M. V.; Tereshko, N. V.
Materials Research Express, Vol. 6, Issue 2
DOI: 10.1088/2053-1591/aaef21

Room-Temperature Ferromagnetic Sr₃YCo₄O_10+δ and Carbon Black-Reinforced Polyvinylidenefluoride Composites toward High-Performance Electromagnetic Interference Shielding
journal, May 2019

Lalan, Vidhya; Puthiyedath Narayanan, Aparna; Surendran, Kuzhichalil Peethambharan
ACS Omega, Vol. 4, Issue 5
DOI: 10.1021/acsomega.9b00454

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Title: Magnetic Ordering in Sr3YCo4O10+x

Abstract

Citation Formats

Crystal Structure of the Novel Complex Cobalt Oxide Sr 0.7 Y 0.3 CoO 2.62 journal, October 2003

Room-temperature ferromagnetism in Sr 1 − x Y x Co O 3 − δ ( 0.2 ⩽ x ⩽ 0.25 ) journal, September 2005

Correlation of chemical coordination and magnetic ordering in Sr 3 YCo 4 O 10.5 + δ ( δ = 0.02 and 0.26) journal, July 2009

Orbital Ordering of Intermediate-Spin State of Co 3+ in Sr 3 YCo 4 O 10.5 journal, February 2011

Complex room-temperature ferrimagnetism induced by zigzag stripes of oxygen vacancies in Sr 3 YCo 4 O 10 + δ journal, April 2011

Mapping Octahedral Tilts and Polarization Across a Domain Wall in BiFeO 3 from Z-Contrast Scanning Transmission Electron Microscopy Image Atomic Column Shape Analysis journal, October 2010

Visualization of Light Elements at Ultrahigh Resolution by STEM Annular Bright Field Microscopy journal, July 2009

Direct oxygen imaging within a ceramic interface, with some observations upon the dark contrast at the grain boundary journal, March 2011

Robust atomic resolution imaging of light elements using scanning transmission electron microscopy journal, November 2009

Direct imaging of hydrogen-atom columns in a crystal by annular bright-field electron microscopy journal, February 2011

Atomic Structure of Luminescent Centers in High-Efficiency Ce-doped w-AlN Single Crystal journal, January 2014

Enhanced light element imaging in atomic resolution scanning transmission electron microscopy journal, January 2014

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal, July 1996

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal, October 1996

Ab initiomolecular dynamics for liquid metals journal, January 1993

Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study journal, January 1998

Mapping Octahedral Tilts and Polarization Across a Domain Wall in BiFeO 3 from Z-Contrast Scanning Transmission Electron Microscopy Image Atomic Column Shape Analysis journal, October 2010

Neutron Diffraction Study of the Magnetic Properties of the Series of Perovskite-Type Compounds [ ( 1 − x ) La , x Ca ] Mn O 3 journal, October 1955

Spin states of Co 3+ ions in Sr 0.75 Y 0.25 CoO 2.625 system induced by Jahn-Teller distortion: a density-functional study journal, August 2018

Ferromagnet-antiferromagnet transition in layered perovskites of Sr 3 YCo 4 O 10.5 type journal, November 2018

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Title: Magnetic Ordering in Sr₃YCo₄O_10+x

Crystal Structure of the Novel Complex Cobalt Oxide Sr _0.7 Y _0.3 CoO _2.62
journal, October 2003

Room-temperature ferromagnetism in ${Sr}_{1 - x} Y_{x} Co O_{3 - δ}$ $(0.2 ⩽ x ⩽ 0.25)$
journal, September 2005

Correlation of chemical coordination and magnetic ordering in ${Sr}_{3} {YCo}_{4} O_{10.5 + δ}$ ( $δ = 0.02$ and 0.26)
journal, July 2009

Orbital Ordering of Intermediate-Spin State of Co ³⁺ in Sr ₃ YCo ₄ O _10.5
journal, February 2011

Complex room-temperature ferrimagnetism induced by zigzag stripes of oxygen vacancies in ${Sr}_{3} {YCo}_{4} O_{10 + δ}$
journal, April 2011

Mapping Octahedral Tilts and Polarization Across a Domain Wall in BiFeO ₃ from Z-Contrast Scanning Transmission Electron Microscopy Image Atomic Column Shape Analysis
journal, October 2010

Visualization of Light Elements at Ultrahigh Resolution by STEM Annular Bright Field Microscopy
journal, July 2009

Direct oxygen imaging within a ceramic interface, with some observations upon the dark contrast at the grain boundary
journal, March 2011

Robust atomic resolution imaging of light elements using scanning transmission electron microscopy
journal, November 2009

Direct imaging of hydrogen-atom columns in a crystal by annular bright-field electron microscopy
journal, February 2011

Atomic Structure of Luminescent Centers in High-Efficiency Ce-doped w-AlN Single Crystal
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Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
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Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

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journal, January 1993

Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study
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Neutron Diffraction Study of the Magnetic Properties of the Series of Perovskite-Type Compounds $[(1 - x) La, x Ca] Mn O_{3}$
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Spin states of Co ³⁺ ions in Sr _0.75 Y _0.25 CoO _2.625 system induced by Jahn-Teller distortion: a density-functional study
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