Evidence of covalent synergy in silicon–sulfur–graphene yielding highly efficient and long-life lithium-ion batteries
Abstract
Silicon has the potential to revolutionize the energy storage capacities of lithium-ion batteries to meet the ever increasing power demands of next generation technologies. To avoid the operational stability problems of silicon-based anodes, we propose synergistic physicochemical alteration of electrode structures during their design. This capitalizes on covalent interaction of Si nanoparticles with sulfur-doped graphene and with cyclized polyacrylonitrile to provide a robust nanoarchitecture. This hierarchical structure stabilized the solid electrolyte interphase leading to superior reversible capacity of over 1,000 mAh g-1 for 2,275 cycles at 2 A g-1. Furthermore, the nanoarchitectured design lowered the contact of the electrolyte to the electrode leading to not only high coulombic efficiency of 99.9% but also maintaining high stability even with high electrode loading associated with 3.4 mAh cm-2. As a result, the excellent performance combined with the simplistic, scalable and non-hazardous approach render the process as a very promising candidate for Li-ion battery technology.
- Authors:
-
[1];
[1];
- Univ. of Waterloo, Waterloo, ON (Canada)
- General Motors Global Research and Development Center, Warren, MI (United States)
- Publication Date:
- Research Org.:
- General Motors Global Research and Development Center, Warren, MI (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- OSTI Identifier:
- 1239317
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 6; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; chemical sciences; materials science; nanotechnology
Citation Formats
Hassan, Fathy M., Batmaz, Rasim, Li, Jingde, Wang, Xiaolei, Xiao, Xingcheng, Yu, Aiping, and Chen, Zhongwei. Evidence of covalent synergy in silicon–sulfur–graphene yielding highly efficient and long-life lithium-ion batteries. United States: N. p., 2015.
Web. doi:10.1038/ncomms9597.
Hassan, Fathy M., Batmaz, Rasim, Li, Jingde, Wang, Xiaolei, Xiao, Xingcheng, Yu, Aiping, & Chen, Zhongwei. Evidence of covalent synergy in silicon–sulfur–graphene yielding highly efficient and long-life lithium-ion batteries. United States. https://doi.org/10.1038/ncomms9597
Hassan, Fathy M., Batmaz, Rasim, Li, Jingde, Wang, Xiaolei, Xiao, Xingcheng, Yu, Aiping, and Chen, Zhongwei. Mon .
"Evidence of covalent synergy in silicon–sulfur–graphene yielding highly efficient and long-life lithium-ion batteries". United States. https://doi.org/10.1038/ncomms9597. https://www.osti.gov/servlets/purl/1239317.
@article{osti_1239317,
title = {Evidence of covalent synergy in silicon–sulfur–graphene yielding highly efficient and long-life lithium-ion batteries},
author = {Hassan, Fathy M. and Batmaz, Rasim and Li, Jingde and Wang, Xiaolei and Xiao, Xingcheng and Yu, Aiping and Chen, Zhongwei},
abstractNote = {Silicon has the potential to revolutionize the energy storage capacities of lithium-ion batteries to meet the ever increasing power demands of next generation technologies. To avoid the operational stability problems of silicon-based anodes, we propose synergistic physicochemical alteration of electrode structures during their design. This capitalizes on covalent interaction of Si nanoparticles with sulfur-doped graphene and with cyclized polyacrylonitrile to provide a robust nanoarchitecture. This hierarchical structure stabilized the solid electrolyte interphase leading to superior reversible capacity of over 1,000 mAh g-1 for 2,275 cycles at 2 A g-1. Furthermore, the nanoarchitectured design lowered the contact of the electrolyte to the electrode leading to not only high coulombic efficiency of 99.9% but also maintaining high stability even with high electrode loading associated with 3.4 mAh cm-2. As a result, the excellent performance combined with the simplistic, scalable and non-hazardous approach render the process as a very promising candidate for Li-ion battery technology.},
doi = {10.1038/ncomms9597},
journal = {Nature Communications},
number = ,
volume = 6,
place = {United States},
year = {Mon Oct 26 00:00:00 EDT 2015},
month = {Mon Oct 26 00:00:00 EDT 2015}
}
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Multifunctional Nano-Architecting of Si Electrode for High-Performance Lithium-Ion Battery Anode
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- Journal of The Electrochemical Society, Vol. 166, Issue 13
Caging tin oxide in three-dimensional graphene networks for superior volumetric lithium storage
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Supremely elastic gel polymer electrolyte enables a reliable electrode structure for silicon-based anodes
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