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Title: Irradiation-enhanced α' precipitation in model FeCrAl alloys

Abstract

We have irradiated the model FeCrAl alloys with varying compositions (Fe(10–18)Cr(10–6)Al at.%) with a neutron at ~ 320 to damage levels of ~ 7 displacements per atom (dpa) to investigate the compositional influence on the formation of irradiation-induced Cr-rich α' precipitates using atom probe tomography. In all alloys, significant number densities of these precipitates were observed. Cluster compositions were investigated and it was found that the average cluster Cr content ranged between 51.1 and 62.5 at.% dependent on initial compositions. Furthermore, this is significantly lower than the Cr-content of α' in binary FeCr alloys. As a result, significant partitioning of the Al from the α' precipitates was also observed.

Authors:
 [1];  [2];  [1];  [1];  [3];  [1];  [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Wisconsin, Madison, WI (United States)
  3. Univ. of Wisconsin, Madison, WI (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Nuclear Energy (NE); USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1238750
Alternate Identifier(s):
OSTI ID: 1337414
Grant/Contract Number:  
AC05-00OR22725; AC07-051D14517
Resource Type:
Accepted Manuscript
Journal Name:
Scripta Materialia
Additional Journal Information:
Journal Volume: 116; Journal Issue: C; Journal ID: ISSN 1359-6462
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; APT; FeCrAl; alpha prime; neutron irradiation

Citation Formats

Edmondson, Philip D., Briggs, Samuel A., Yamamoto, Yukinori, Howard, Richard H., Sridharan, Kumar, Terrani, Kurt A., and Field, Kevin G. Irradiation-enhanced α' precipitation in model FeCrAl alloys. United States: N. p., 2016. Web. doi:10.1016/j.scriptamat.2016.02.002.
Edmondson, Philip D., Briggs, Samuel A., Yamamoto, Yukinori, Howard, Richard H., Sridharan, Kumar, Terrani, Kurt A., & Field, Kevin G. Irradiation-enhanced α' precipitation in model FeCrAl alloys. United States. https://doi.org/10.1016/j.scriptamat.2016.02.002
Edmondson, Philip D., Briggs, Samuel A., Yamamoto, Yukinori, Howard, Richard H., Sridharan, Kumar, Terrani, Kurt A., and Field, Kevin G. Wed . "Irradiation-enhanced α' precipitation in model FeCrAl alloys". United States. https://doi.org/10.1016/j.scriptamat.2016.02.002. https://www.osti.gov/servlets/purl/1238750.
@article{osti_1238750,
title = {Irradiation-enhanced α' precipitation in model FeCrAl alloys},
author = {Edmondson, Philip D. and Briggs, Samuel A. and Yamamoto, Yukinori and Howard, Richard H. and Sridharan, Kumar and Terrani, Kurt A. and Field, Kevin G.},
abstractNote = {We have irradiated the model FeCrAl alloys with varying compositions (Fe(10–18)Cr(10–6)Al at.%) with a neutron at ~ 320 to damage levels of ~ 7 displacements per atom (dpa) to investigate the compositional influence on the formation of irradiation-induced Cr-rich α' precipitates using atom probe tomography. In all alloys, significant number densities of these precipitates were observed. Cluster compositions were investigated and it was found that the average cluster Cr content ranged between 51.1 and 62.5 at.% dependent on initial compositions. Furthermore, this is significantly lower than the Cr-content of α' in binary FeCr alloys. As a result, significant partitioning of the Al from the α' precipitates was also observed.},
doi = {10.1016/j.scriptamat.2016.02.002},
journal = {Scripta Materialia},
number = C,
volume = 116,
place = {United States},
year = {Wed Feb 17 00:00:00 EST 2016},
month = {Wed Feb 17 00:00:00 EST 2016}
}

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Works referenced in this record:

Materials challenges in nuclear energy
journal, February 2013


Radiation tolerance of neutron-irradiated model Fe–Cr–Al alloys
journal, October 2015


High temperature oxidation of fuel cladding candidate materials in steam–hydrogen environments
journal, September 2013


Development and property evaluation of nuclear grade wrought FeCrAl fuel cladding for light water reactors
journal, December 2015


Microstructural stability of Fe–Cr–Al alloys at 450–550 °C
journal, February 2015


Neutronic analysis of candidate accident-tolerant cladding concepts in pressurized water reactors
journal, January 2015


Dislocation loops and bubbles in oxide dispersion strengthened ferritic steel after helium implantation under stress
journal, January 2008


Void-swelling in irons and ferritic steels
journal, November 1979


Microstructural changes in a neutron-irradiated Fe–15 at.%Cr alloy
journal, November 2014

  • Bachhav, Mukesh; Robert Odette, G.; Marquis, Emmanuelle A.
  • Journal of Nuclear Materials, Vol. 454, Issue 1-3
  • DOI: 10.1016/j.jnucmat.2014.08.026

α′ precipitation in neutron-irradiated Fe–Cr alloys
journal, March 2014


Phase separation kinetics in a Fe–Cr–Al alloy
journal, July 2012


Influence of recrystallization on phase separation kinetics of oxide dispersion strengthened Fe–Cr–Al alloy
journal, March 2012


Mapping of 475°C embrittlement in ferritic Fe–Cr–Al alloys
journal, November 2010


Precipitation in iron–chromium–aluminium alloys
journal, June 1984


LAMDA: Irradiated-Materials Microscopy at Oak Ridge National Laboratory
journal, August 2015

  • Parish, Chad M.; Kiran Kumar, N. A. P.; Snead, Lance L.
  • Microscopy and Microanalysis, Vol. 21, Issue S3
  • DOI: 10.1017/S1431927615005814

Atom probe specimen preparation with a dual beam SEM/FIB miller
journal, September 2007


A sensitivity analysis of the maximum separation method for the characterisation of solute clusters
journal, May 2011


A SANS investigation of the irradiation-enhanced α–α′ phases separation in 7–12 Cr martensitic steels
journal, February 2003


Works referencing / citing this record:

Vacancy and interstitial atom evolution with the separation of the nanoscale phase in Fe–Cr alloys: phase-field simulations
journal, January 2020

  • Yan, Zhengwei; Shi, Shujing; Li, Yongsheng
  • Physical Chemistry Chemical Physics, Vol. 22, Issue 6
  • DOI: 10.1039/c9cp06247e

α′ formation kinetics and radiation induced segregation in neutron irradiated 14YWT nanostructured ferritic alloys
journal, June 2019


Influence of Al Addition Strategy on the Microstructure of a Low‐Cr Oxide Dispersion‐Strengthened Ferritic Steel
journal, December 2019

  • Xu, Shuai; Zhou, Zhangjian; Long, Fei
  • Advanced Engineering Materials, Vol. 22, Issue 4
  • DOI: 10.1002/adem.201900879