Selective Oxidation of Alcohols Using Photoactive VO@g-C 3 N 4

doi:10.1021/acssuschemeng.5b01163

Title: Selective Oxidation of Alcohols Using Photoactive VO@g-C ₃ N ₄

Article Details
Other Related Research

Authors:

Verma, Sanny ^[1] ; Baig, R. B. Nasir ^[1] ; Nadagouda, Mallikarjuna N. ^[2] ; Varma, Rajender S. ^[1]

Sustainable Technology Division, National Risk Management Research Laboratory, U.S. Environmental Protection Agency, MS 443, Cincinnati, Ohio 45268, United States
WQMB, WSWRD, National Risk Management Research Laboratory, U.S. Environmental Protection Agency, MS 443, Cincinnati, Ohio 45268, United States

Publication Date:: 2015-12-24

Type:: Published Article

Journal Name:: ACS Sustainable Chemistry & Engineering

Additional Journal Information:: Journal Name: ACS Sustainable Chemistry & Engineering Journal Volume: 4 Journal Issue: 3; Journal ID: ISSN 2168-0485

Publisher:: American Chemical Society

Sponsoring Org:: USDOE

Country of Publication:: United States

Language:: English

OSTI Identifier:: 1238208


                    Verma, Sanny, Baig, R. B. Nasir, Nadagouda, Mallikarjuna N., and Varma, Rajender S.. Selective Oxidation of Alcohols Using Photoactive VO@g-C 3 N 4.  United States: N. p.,  
        Web.  doi:10.1021/acssuschemeng.5b01163.

Copy to clipboard


                    Verma, Sanny, Baig, R. B. Nasir, Nadagouda, Mallikarjuna N., & Varma, Rajender S.. Selective Oxidation of Alcohols Using Photoactive VO@g-C 3 N 4.  United States.  doi:10.1021/acssuschemeng.5b01163.

Copy to clipboard


                    Verma, Sanny, Baig, R. B. Nasir, Nadagouda, Mallikarjuna N., and Varma, Rajender S.. 2015.  
        "Selective Oxidation of Alcohols Using Photoactive VO@g-C 3 N 4".  United States.  
        doi:10.1021/acssuschemeng.5b01163.

Copy to clipboard


                    
@article{osti_1238208,

  title        = {Selective Oxidation of Alcohols Using Photoactive VO@g-C 3 N 4},

  author       = {Verma, Sanny and Baig, R. B. Nasir and Nadagouda, Mallikarjuna N. and Varma, Rajender S.},

  abstractNote = {},

  doi          = {10.1021/acssuschemeng.5b01163},

  journal      = {ACS Sustainable Chemistry & Engineering},

  number       = 3,

  volume       = 4,

  place        = {United States},

  year         = {2015},

  month        = {12}

}

Copy to clipboard

Free Publicly Accessible Full Text
Publisher's Version of Record at 10.1021/acssuschemeng.5b01163

Citation Metrics
Cited by: 19works
Citation information provided by
Web of Science

Save / Share this Record
Export Metadata
- Endnote
- RIS
- Excel
- CSV
- XML
Save to My Library
Send to Email

Send to Email

Email address:

Content:

Similar Records

Similar records in DOE PAGES and OSTI.GOV collections:

Polyoxoanion-supported, atomically dispersed transition metals: The catalytic oxidation of cyclohexene with dioxygen by the catalyst precursors ((n-C sub 4 H sub 9 ) sub 4 N) sub 5 Na sub 3 ((1,5-COD)Irter dot P sub 2 W sub 15 Nb sub 3 O sub 62 ), ((n-C sub 4 H sub 9 ) sub 4 N) sub 5 Na sub 3 ((1,5-COD)Rhter dot P sub 2 W sub 15 Nb sub 3 O sub 62 ), and ((n-C sub 4 H sub 9 ) sub 4 N) sub 4. 5 Na sub 2. 5 ((C sub 6 H sub 6 )Ruter dot P sub 2 W sub 15 Nb sub 3 O sub 62 )

Journal Article - in OSTI.gov collection Mizuno, N. ; Lyon, D.K. ; Finke, R.G. March 1991 - Journal of Catalysis; (United States)

((n-C{sub 4}H{sub 9}){sub 4}N){sub 5}Na{sub 3}((1,5-COD)Ir{center dot}P{sub 2}W{sub 15}Nb{sub 3}O{sub 62}), 1, ((n-C{sub 4}H{sub 9}){sub 4}N){sub 5}Na{sub 3}((1,5-COD)Rh{center dot}P{sub 2}W{sub 15}Nb{sub 3}O{sub 62}), and ((n-C{sub 4}H{sub 9}){sub 4}N){sub 4.5}Na{sub 2.5}((C{sub 6}H{sub 6})Ru{center dot}P{sub 2}W{sub 15}Nb{sub 3}O{sub 62}) have been shown to catalyze the oxygenation of cyclohexene with molecular oxygen. The polyoxoanion-supported iridium (I) complex, 1, shows the highest activity of this group with a turnover frequency of 2.9 h{sup {minus}1} at 38{degree}C in CH{sub 2}Cl{sub 2} (540 total turnovers), which is 100-fold greater than its parent iridium compound, ((1,5-COD)IrCl){sub 2}. Additional experiments using H{sub 2}/O{sub 2} mixtures and H{sub 2}O{submore »« less
Full Text Available
Using design principles to systematically plan the synthesis of hole-conducting transparent oxides: Cu ₃VO ₄ and Ag ₃VO ₄ as a case study

Journal Article Trimarchi, Giancarlo ; Peng, Haowei ; Im, Jino ; ... October 2011 - Physical Review. B. Condensed Matter and Materials Physics

Cited by 26Full Text Available
Metal-free g-C{sub 3}N{sub 4} photocatalyst by sulfuric acid activation for selective aerobic oxidation of benzyl alcohol under visible light

Journal Article - in OSTI.gov collection Zhang, Ligang ; University of Chinese Academy of Sciences, Beijing 100049 ; Liu, Di ; ... November 2014 - Materials Research Bulletin

Highlights: • A novel visible-light-driven acid-modified g-C{sub 3}N{sub 4} was prepared. • The texture, electronic and surface property were tuned by acid modification. • Acid-modified g-C{sub 3}N{sub 4} shows much higher activity for photocatalytic activity. • Acid sites on the surface of g-C{sub 3}N{sub 4} favor efficient charge separation. - Abstract: In this work, modification of graphitic carbon nitride photocatalyst with acid was accomplished with a facile method through reflux in different acidic substances. The g-C{sub 3}N{sub 4}-based material was found to be a metal-free photocatalyst useful for the selective oxidation of benzyl alcohol with dioxygen as the oxidant undermore »« less
Full Text Available
Hydrothermal synthesis and characterization of two- and three-dimensional solids of the oxovanadium(IV)-phosphite system. The structures of [HN(Me)(CH{sub 2}CH{sub 2}){sub 2}N(Me)H]-[(VO){sub 4}(OH){sub 2}(HPO{sub 3}){sub 4}], [H{sub 2}N(CH{sub 2}CH{sub 2}){sub 2}NH{sub 2}][(VO){sub 3}(HPO{sub 3}){sub 4}(H{sub 2}O){sub 2}], and [VO(HPO{sub 3})(H{sub 2}O)]

Journal Article - in OSTI.gov collection Bonavia, G. ; DeBord, J. ; Rose, D. November 1995 - Chemistry of Materials

Hydrothermal reaction of VCl{sub 4} with phosphorous acid H{sub 3}PO{sub 3}, in the presence of organoamines, yields oxovanadium (IV)-phosphite materials: [HN(Me)(CH{sub 2}CH{sub 2}){sub 2}N(Me)H][(VO){sub 4}(OH){sub 2}-(HPO{sub 3}){sub 4}] (1), [H{sub 2}N(CH{sub 2}CH{sub 2}){sub 2}NH{sub 2}][(VO){sub 3}(HPO{sub 3}){sub 4}-(H{sub 2}O){sub 2}] (2), and [VO(HPO{sub 3})H{sub 2}O] (3). The framework structure of 3 is presented. 32 refs., 3 figs.
Full Text Available
Selective CO ₂ reduction to C ₃ and C ₄ oxyhydrocarbons on nickel phosphides at overpotentials as low as 10 mV

Journal Article Calvinho, Karin U. D. ; Laursen, Anders B. ; Yap, Kyra M. K. ; ... January 2018 - Energy & Environmental Science

Bioinspired nickel phosphide electrocatalysts achieve breakthrough efficiency and selectivity for C ₃ and C ₄ products.

Access journal articles and accepted manuscripts resulting from DOE research funding

Title: Selective Oxidation of Alcohols Using Photoactive VO@g-C 3 N 4

Access journal articles and accepted manuscripts
resulting from DOE research funding

Title: Selective Oxidation of Alcohols Using Photoactive VO@g-C ₃ N ₄