Scalable fabrication of efficient organolead trihalide perovskite solar cells with doctor-bladed active layers
Abstract
Organolead trihalide perovskites (OTPs) are nature abundant materials with prospects as future low-cost renewable energy sources boosted by the solution process capability of these materials. Here we report the fabrication of efficient OTP devices by a simple, high throughput and low-cost doctor-blade coating process which can be compatible with the roll-to-roll fabrication process for the large scale production of perovskite solar cell panels. The formulation of appropriate precursor inks by removing impurities is shown to be critical in the formation of continuous, pin-hole free and phase-pure perovskite films on large area substrates, which is assisted by a high deposition temperature to guide the nucleation and grain growth process. The domain size reached 80–250 μm in 1.5–2 μm thick bladed films. By controlling the stoichiometry and thickness of the OTP films, highest device efficiencies of 12.8% and 15.1% are achieved in the devices fabricated on poly(3,4-ethylenedioxythiophene) polystyrene sulfonate and cross-linked N4,N4'-bis(4-(6-((3-ethyloxetan-3-yl)methoxy)hexyl)phenyl)–N4,N4'-diphenylbiphenyl-4,4'-diamine covered ITO substrates. Furthermore, the carrier diffusion length in doctor-bladed OTP films is beyond 3.5 μm which is significantly larger than in the spin-coated films, due to the formation of crystalline grains with a very large size by the doctor-blade coating method.
- Authors:
-
- Univ. of Nebraska, Lincoln, NE (United States)
- Publication Date:
- Research Org.:
- Univ. of Nebraska, Lincoln, NE (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1237999
- Grant/Contract Number:
- EE0006709
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Energy & Environmental Science
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 5; Journal ID: ISSN 1754-5692
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Deng, Yehao, Peng, Edwin, Shao, Yuchuan, Xiao, Zhengguo, Dong, Qingfeng, and Huang, Jinsong. Scalable fabrication of efficient organolead trihalide perovskite solar cells with doctor-bladed active layers. United States: N. p., 2015.
Web. doi:10.1039/C4EE03907F.
Deng, Yehao, Peng, Edwin, Shao, Yuchuan, Xiao, Zhengguo, Dong, Qingfeng, & Huang, Jinsong. Scalable fabrication of efficient organolead trihalide perovskite solar cells with doctor-bladed active layers. United States. https://doi.org/10.1039/C4EE03907F
Deng, Yehao, Peng, Edwin, Shao, Yuchuan, Xiao, Zhengguo, Dong, Qingfeng, and Huang, Jinsong. Wed .
"Scalable fabrication of efficient organolead trihalide perovskite solar cells with doctor-bladed active layers". United States. https://doi.org/10.1039/C4EE03907F. https://www.osti.gov/servlets/purl/1237999.
@article{osti_1237999,
title = {Scalable fabrication of efficient organolead trihalide perovskite solar cells with doctor-bladed active layers},
author = {Deng, Yehao and Peng, Edwin and Shao, Yuchuan and Xiao, Zhengguo and Dong, Qingfeng and Huang, Jinsong},
abstractNote = {Organolead trihalide perovskites (OTPs) are nature abundant materials with prospects as future low-cost renewable energy sources boosted by the solution process capability of these materials. Here we report the fabrication of efficient OTP devices by a simple, high throughput and low-cost doctor-blade coating process which can be compatible with the roll-to-roll fabrication process for the large scale production of perovskite solar cell panels. The formulation of appropriate precursor inks by removing impurities is shown to be critical in the formation of continuous, pin-hole free and phase-pure perovskite films on large area substrates, which is assisted by a high deposition temperature to guide the nucleation and grain growth process. The domain size reached 80–250 μm in 1.5–2 μm thick bladed films. By controlling the stoichiometry and thickness of the OTP films, highest device efficiencies of 12.8% and 15.1% are achieved in the devices fabricated on poly(3,4-ethylenedioxythiophene) polystyrene sulfonate and cross-linked N4,N4'-bis(4-(6-((3-ethyloxetan-3-yl)methoxy)hexyl)phenyl)–N4,N4'-diphenylbiphenyl-4,4'-diamine covered ITO substrates. Furthermore, the carrier diffusion length in doctor-bladed OTP films is beyond 3.5 μm which is significantly larger than in the spin-coated films, due to the formation of crystalline grains with a very large size by the doctor-blade coating method.},
doi = {10.1039/C4EE03907F},
journal = {Energy & Environmental Science},
number = 5,
volume = 8,
place = {United States},
year = {Wed Mar 25 00:00:00 EDT 2015},
month = {Wed Mar 25 00:00:00 EDT 2015}
}
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Controlling Apparent Coordinated Solvent Number in the Perovskite Intermediate Phase Film for Developing Large‐Area Perovskite Solar Modules
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Metal Halide Perovskites: From Crystal Formations to Light-Emitting-Diode Applications
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Spray-cast multilayer perovskite solar cells with an active-area of 1.5 cm2
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UV Degradation and Recovery of Perovskite Solar Cells
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Control of aggregation and dissolution of small molecule hole transport layers via a doping strategy for highly efficient perovskite solar cells
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Recent advances in interfacial engineering of perovskite solar cells
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Editors' Choice—Stability of Unstable Perovskites: Recent Strategies for Making Stable Perovskite Solar Cells
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Surfactant-controlled ink drying enables high-speed deposition of perovskite films for efficient photovoltaic modules
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Molecular doping enabled scalable blading of efficient hole-transport-layer-free perovskite solar cells
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Bilateral alkylamine for suppressing charge recombination and improving stability in blade-coated perovskite solar cells
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Meniscus-assisted solution printing of large-grained perovskite films for high-efficiency solar cells
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Perovskite Solar Cells: Progress and Advancements
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A Review of Perovskite Photovoltaic Materials’ Synthesis and Applications via Chemical Vapor Deposition Method
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Micrometric Wrinkled Patterns Spontaneously Formed on Hydrogel Thin Films via Argon Plasma Exposure
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High-Performance Perovskite Solar Cells with Enhanced Environmental Stability Based on Amphiphile-Modified CH 3 NH 3 PbI 3
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Spray-Cast Multilayer Organometal Perovskite Solar Cells Fabricated in Air
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General Nondestructive Passivation by 4‐Fluoroaniline for Perovskite Solar Cells with Improved Performance and Stability
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Lead Iodide and Perovskite Films Obtained by Iodination of PbS Thin Films
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Gas-solid reaction based over one-micrometer thick stable perovskite films for efficient solar cells and modules
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Recent progressive efforts in perovskite solar cells toward commercialization
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Coated and Printed Perovskites for Photovoltaic Applications
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Flexible Wire-Shaped Perovskite Photodetector via Joule Heating for Improved Crystallization and Performance
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Solution-processed bathocuproine cathode buffer layer towards efficient planar heterojunction perovskite solar cells
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Back-Contact Perovskite Solar Cells
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Composition Engineering in Doctor-Blading of Perovskite Solar Cells
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Drying Dynamics of Solution‐Processed Perovskite Thin‐Film Photovoltaics: In Situ Characterization, Modeling, and Process Control
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Air-Stable, Efficient Mixed-Cation Perovskite Solar Cells with Cu Electrode by Scalable Fabrication of Active Layer
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Processing‐Performance Evolution of Perovskite Solar Cells: From Large Grain Polycrystalline Films to Single Crystals
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Amino-Acid-Induced Preferential Orientation of Perovskite Crystals for Enhancing Interfacial Charge Transfer and Photovoltaic Performance
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Enhancing the Performance of Perovskite Solar Cells by Hybridizing SnS Quantum Dots with CH 3 NH 3 PbI 3
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One‐Step Inkjet Printed Perovskite in Air for Efficient Light Harvesting
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Cations Functionalized Carbon Nano‐Dots Enabling Interfacial Passivation and Crystallization Control for Inverted Perovskite Solar Cells
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Multifunctional asymmetrical molecules for high-performance perovskite and organic solar cells
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Flexible and Transparent Substrates Based on Gold Nanoparticles and TiO2 for in Situ Bioanalysis by Surface-Enhanced Raman Spectroscopy
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Carrier Diffusion in Thin-Film CH3NH3PbI3 Perovskite Measured using Four-Wave Mixing
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