Ultrathin nanosheets of CrSiTe3. A semiconducting two-dimensional ferromagnetic material

Lin, Ming -Wei; Zhung, Houlong L.; Yan, Jiaqiang; Ward, Thomas Zac; Puretzky, Alexander A.; Rouleau, Christopher M.; Gai, Zheng; Liang, Liangbo; Meunier, Vincent; Ganesh, Panchapakesan; Kent, Paul R. C.; Sumpter, Bobby G.; Mandrus, David G.; Geohegan, David B.; Xiao, Kai

doi:10.1039/C5TC03463A

Title: Ultrathin nanosheets of CrSiTe₃. A semiconducting two-dimensional ferromagnetic material

Journal Article · 26 November 2015 · Journal of Materials Chemistry C

DOI: https://doi.org/10.1039/C5TC03463A · OSTI ID:1237632

Lin, Ming -Wei ^[1]; Zhung, Houlong L. ^[1]; Yan, Jiaqiang ^[2]; Ward, Thomas Zac ^[1]; Puretzky, Alexander A. ^[1]; Rouleau, Christopher M. ^[1]; Gai, Zheng ^[1]; Liang, Liangbo ^[3]; Meunier, Vincent ^[4]; Ganesh, Panchapakesan ^[1]; Kent, Paul R. C. ^[1]; Sumpter, Bobby G. ^[1]; Mandrus, David G. ^[2]; Geohegan, David B. ^[1]; Xiao, Kai ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Rensselaer Polytechnic Institute (RPI), Troy, NY (United States)
Rensselaer Polytechnic Institute (RPI), Troy, NY (United States)

Finite range ferromagnetism and antiferromagnetism in two-dimensional (2D) systems within an isotropic Heisenberg model at non-zero temperature were originally proposed to be impossible. However, recent theoretical studies using an Ising model have recently shown that 2D magnetic crystals can exhibit magnetism. Experimental verification of existing 2D magnetic crystals in this system has remained elusive. In this work we for the first time exfoliate the CrSiTe₃, a bulk ferromagnetic semiconductor, to mono- and few-layer 2D crystals onto a Si/SiO₂ substrate. The Raman spectra show the good stability and high quality of the exfoliated flakes, consistent with the computed phonon spectra of 2D CrSiTe₃, giving a strong evidence for the existence of 2D CrSiTe₃ crystals. When the thickness of the CrSiTe₃ crystals is reduced to few-layers, we observed a clear change in resistivity at 80~120 K, consistent with the theoretical calculations on the Curie temperature (Tc) of ~80 K for the magnetic ordering of 2D CrSiTe₃ crystals. As a result, the ferromagnetic mono- and few-layer 2D CrSiTe₃ indicated here should enable numerous applications in nano-spintronics.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1237632

Journal Information:: Journal of Materials Chemistry C, Journal Name: Journal of Materials Chemistry C Journal Issue: 2 Vol. 4; ISSN JMCCCX; ISSN 2050-7526

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Magnetic structure and phase stability of the van der Waals bonded ferromagnet Fe 3 − x GeTe 2 May, Andrew F.; Calder, Stuart; Cantoni, Claudia Physical Review B, Vol. 93, Issue 1 https://doi.org/10.1103/physrevb.93.014411	journal	January 2016
Electronic and magnetic properties of single-layer M P X 3 metal phosphorous trichalcogenides Chittari, Bheema Lingam; Park, Youngju; Lee, Dongkyu Physical Review B, Vol. 94, Issue 18 https://doi.org/10.1103/physrevb.94.184428	journal	November 2016
Tricritical behavior of the two-dimensional intrinsically ferromagnetic semiconductor CrGeTe 3 Lin, G. T.; Zhuang, H. L.; Luo, X. Physical Review B, Vol. 95, Issue 24 https://doi.org/10.1103/physrevb.95.245212	journal	June 2017
Critical behavior of quasi-two-dimensional semiconducting ferromagnet Cr 2 Ge 2 Te 6 Liu, Yu; Petrovic, C. Physical Review B, Vol. 96, Issue 5 https://doi.org/10.1103/physrevb.96.054406	journal	August 2017
Critical behavior of the quasi-two-dimensional weak itinerant ferromagnet trigonal chromium telluride Cr 0.62 Te Liu, Yu; Petrovic, C. Physical Review B, Vol. 96, Issue 13 https://doi.org/10.1103/physrevb.96.134410	journal	October 2017
Critical behavior of the van der Waals bonded ferromagnet Fe 3 − x GeTe 2 Liu, Yu; Ivanovski, V. N.; Petrovic, C. Physical Review B, Vol. 96, Issue 14 https://doi.org/10.1103/physrevb.96.144429	journal	October 2017
Three-dimensional magnetic critical behavior in CrI 3 Liu, Yu; Petrovic, C. Physical Review B, Vol. 97, Issue 1 https://doi.org/10.1103/physrevb.97.014420	journal	January 2018
Anisotropic magnetocaloric effect in single crystals of CrI 3 Liu, Yu; Petrovic, C. Physical Review B, Vol. 97, Issue 17 https://doi.org/10.1103/physrevb.97.174418	journal	May 2018
Electronic structure of ferromagnetic semiconductor CrGeTe 3 by angle-resolved photoemission spectroscopy Li, Y. F.; Wang, W.; Guo, W. Physical Review B, Vol. 98, Issue 12 https://doi.org/10.1103/physrevb.98.125127	journal	September 2018
Large magneto-optical effects and magnetic anisotropy energy in two-dimensional Cr 2 Ge 2 Te 6 Fang, Yimei; Wu, Shunqing; Zhu, Zi-Zhong Physical Review B, Vol. 98, Issue 12 https://doi.org/10.1103/physrevb.98.125416	journal	September 2018
Gate-Controllable Magneto-optic Kerr Effect in Layered Collinear Antiferromagnets Sivadas, Nikhil; Okamoto, Satoshi; Xiao, Di Physical Review Letters, Vol. 117, Issue 26 https://doi.org/10.1103/physrevlett.117.267203	journal	December 2016
Magnetic behavior and spin-lattice coupling in cleavable van der Waals layered CrCl 3 crystals McGuire, Michael A.; Clark, Genevieve; Kc, Santosh Physical Review Materials, Vol. 1, Issue 1 https://doi.org/10.1103/physrevmaterials.1.014001	journal	June 2017
Giant tunneling magnetoresistance in spin-filter van der Waals heterostructures Song, Tiancheng; Cai, Xinghan; Tu, Matisse Wei-Yuan Science, Vol. 360, Issue 6394 https://doi.org/10.1126/science.aar4851	journal	May 2018
Ab Initio Study of Optoelectronic and Magnetic Properties of Ternary Chromium Chalcogenides Ong, Marc; Hammouri, Mahmoud; Jishi, Radi A. Advances in Materials Science and Engineering, Vol. 2018 https://doi.org/10.1155/2018/3762451	journal	November 2018
Magnetic Properties of Proton Irradiated Mn3Si2Te6 van der Waals Single Crystals Martinez, L. M.; Saiz, C. L.; Cosio, A. MRS Advances, Vol. 4, Issue 40 https://doi.org/10.1557/adv.2019.260	journal	January 2019
Very large tunneling magnetoresistance in layered magnetic semiconductor CrI3 Wang, Zhe; Gutiérrez-Lezama, Ignacio; Ubrig, Nicolas ETH Zurich https://doi.org/10.3929/ethz-b-000275019	text	January 2018
Gate-controllable magneto-optic Kerr effect in layered collinear antiferromagnets Sivadas, Nikhil; Okamoto, Satoshi; Xiao, Di arXiv https://doi.org/10.48550/arxiv.1607.02156	text	January 2016
Layer-dependent Ferromagnetism in a van der Waals Crystal down to the Monolayer Limit Huang, Bevin; Clark, Genevieve; Navarro-Moratalla, Efren arXiv https://doi.org/10.48550/arxiv.1703.05892	text	January 2017
Giant Tunneling Magnetoresistance in Spin-Filter van der Waals Heterostructures Song, Tiancheng; Cai, Xinghan; Tu, Matisse Wei-Yuan arXiv https://doi.org/10.48550/arxiv.1801.08679	text	January 2018
Hard magnetic properties in nanoflake van der Waals Fe3GeTe2 Tan, Cheng; Lee, Jinhwan; Jung, Soon-Gil arXiv https://doi.org/10.48550/arxiv.1803.02934	text	January 2018
Effect of Coulomb Interactions on the Electronic and Magnetic Properties of Two-Dimensional CrSiTe$_3$ and CrGeTe$_3$ Materials Kang, Sungmo; Kang, Seungjin; Yu, Jaejun arXiv https://doi.org/10.48550/arxiv.1807.10686	text	January 2018
Long Range Intrinsic Ferromagnetism in Two Dimensional Materials and Dissipationless Future Technologies Shabbir, Babar; Nadeem, Muhammad; Dai, Zhigao arXiv https://doi.org/10.48550/arxiv.1810.09053	text	January 2018
Two Dimensional Ferromagnetic Semiconductor: Monolayer CrGeS$_3$ Ren, Yulu; Ge, Yanfeng; Wan, Wenhui arXiv https://doi.org/10.48550/arxiv.1906.07396	text	January 2019

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