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Title: Supramolecular gel-assisted synthesis of double shelled Co@CoO@N-C/C nanoparticles with synergistic electrocatalytic activity for the oxygen reduction reaction

Investigating active, stable, and low-cost materials for the oxygen reduction reaction is one of the key challenges in fuel-cell research. In this work, we describe the formation of N-doped carbon shell coated Co@CoO nanoparticles supported on Vulcan XC-72 carbon materials (Co@CoO@N–C/C) based on a simple supramolecular gel-assisted method. The double-shelled Co@CoO@N–C/C core–shell nanoparticles exhibit superior electrocatalytic activities for the oxygen reduction reaction compared to N-doped carbon and cobalt oxides, demonstrating the synergistic effect of the hybrid nanomaterials. Notably, the Co@CoO@N–C/C nanoparticles give rise to a comparable four-electron selectivity, long-term stability, and high methanol tolerance; all show a multi-fold improvement over the commercial Pt/C catalyst. As a result, the progress is of great importance in exploring advanced non-precious metal-based electrocatalysts for fuel cell applications.
Authors:
 [1] ;  [1] ;  [2] ;  [3] ;  [1] ;  [3] ;  [1]
  1. Huazhong Univ. of Science and Technology, Wuhan (China)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States); Tianjin Univ., Tianjin (People's Republic of China)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., Stony Brook, NY (United States)
Publication Date:
Report Number(s):
BNL-111761-2016-JA
Journal ID: ISSN 2040-3364; NANOHL; KC0403020
Grant/Contract Number:
SC00112704
Type:
Accepted Manuscript
Journal Name:
Nanoscale
Additional Journal Information:
Journal Volume: 106; Journal Issue: 22; Journal ID: ISSN 2040-3364
Publisher:
Royal Society of Chemistry
Research Org:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; oxygen reduction reaction; fuel cell; Center for Functional Nanomaterials
OSTI Identifier:
1237186

Wu, Zexing, Wang, Jie, Han, Lili, Lin, Ruogian, Liu, Hongfang, Xin, Huolin L., and Wang, Deli. Supramolecular gel-assisted synthesis of double shelled Co@CoO@N-C/C nanoparticles with synergistic electrocatalytic activity for the oxygen reduction reaction. United States: N. p., Web. doi:10.1039/C5NR07929B.
Wu, Zexing, Wang, Jie, Han, Lili, Lin, Ruogian, Liu, Hongfang, Xin, Huolin L., & Wang, Deli. Supramolecular gel-assisted synthesis of double shelled Co@CoO@N-C/C nanoparticles with synergistic electrocatalytic activity for the oxygen reduction reaction. United States. doi:10.1039/C5NR07929B.
Wu, Zexing, Wang, Jie, Han, Lili, Lin, Ruogian, Liu, Hongfang, Xin, Huolin L., and Wang, Deli. 2016. "Supramolecular gel-assisted synthesis of double shelled Co@CoO@N-C/C nanoparticles with synergistic electrocatalytic activity for the oxygen reduction reaction". United States. doi:10.1039/C5NR07929B. https://www.osti.gov/servlets/purl/1237186.
@article{osti_1237186,
title = {Supramolecular gel-assisted synthesis of double shelled Co@CoO@N-C/C nanoparticles with synergistic electrocatalytic activity for the oxygen reduction reaction},
author = {Wu, Zexing and Wang, Jie and Han, Lili and Lin, Ruogian and Liu, Hongfang and Xin, Huolin L. and Wang, Deli},
abstractNote = {Investigating active, stable, and low-cost materials for the oxygen reduction reaction is one of the key challenges in fuel-cell research. In this work, we describe the formation of N-doped carbon shell coated Co@CoO nanoparticles supported on Vulcan XC-72 carbon materials (Co@CoO@N–C/C) based on a simple supramolecular gel-assisted method. The double-shelled Co@CoO@N–C/C core–shell nanoparticles exhibit superior electrocatalytic activities for the oxygen reduction reaction compared to N-doped carbon and cobalt oxides, demonstrating the synergistic effect of the hybrid nanomaterials. Notably, the Co@CoO@N–C/C nanoparticles give rise to a comparable four-electron selectivity, long-term stability, and high methanol tolerance; all show a multi-fold improvement over the commercial Pt/C catalyst. As a result, the progress is of great importance in exploring advanced non-precious metal-based electrocatalysts for fuel cell applications.},
doi = {10.1039/C5NR07929B},
journal = {Nanoscale},
number = 22,
volume = 106,
place = {United States},
year = {2016},
month = {1}
}