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Title: New type of Weyl semimetal with quadratic double Weyl fermions

Abstract

Weyl semimetals have attracted worldwide attention due to their wide range of exotic properties predicted in theories. The experimental realization had remained elusive for a long time despite much effort. Very recently, the first Weyl semimetal has been discovered in an inversion-breaking, stoichiometric solid TaAs. So far, the TaAs class remains the only Weyl semimetal available in real materials. To facilitate the transition of Weyl semimetals from the realm of purely theoretical interest to the realm of experimental studies and device applications, it is of crucial importance to identify other robust candidates that are experimentally feasible to be realized. In this paper, we propose such a Weyl semimetal candidate in an inversion-breaking, stoichiometric compound strontium silicide, SrSi2, with many new and novel properties that are distinct from TaAs. Here, we show that SrSi2 is a Weyl semimetal even without spin-orbit coupling and that, after the inclusion of spin-orbit coupling, two Weyl fermions stick together forming an exotic double Weyl fermion with quadratic dispersions and a higher chiral charge of ±2. Moreover, we find that the Weyl nodes with opposite charges are located at different energies due to the absence of mirror symmetry in SrSi2, paving the way for the realizationmore » of the chiral magnetic effect. Finally, our systematic results not only identify a much-needed robust Weyl semimetal candidate but also open the door to new topological Weyl physics that is not possible in TaAs« less

Authors:
 [1];  [2];  [2];  [1];  [1];  [3];  [4];  [2];  [2];  [2];  [2];  [2];  [5];  [6];  [7];  [1];  [2]
  1. Centre for Advanced 2D Materials and Graphene Research Centre, National University of Singapore, Singapore 117546,, Department of Physics, National University of Singapore, Singapore 117542,
  2. Joseph Henry Laboratory, Department of Physics, Princeton University, Princeton, NJ 08544,
  3. Joseph Henry Laboratory, Department of Physics, Princeton University, Princeton, NJ 08544,, Department of Physics, National Tsing Hua University, Hsinchu 30013, Taiwan,, Laboratory for Topological Quantum Matter and Spectroscopy (B7), Department of Physics, Princeton University, Princeton, NJ 08544,
  4. Centre for Advanced 2D Materials and Graphene Research Centre, National University of Singapore, Singapore 117546,, Department of Physics, National University of Singapore, Singapore 117542,, Department of Physics, Northeastern University, Boston, MA 02115,
  5. Department of Physics, National Tsing Hua University, Hsinchu 30013, Taiwan,, Institute of Physics, Academia Sinica, Taipei 11529, Taiwan,
  6. Department of Physics, Northeastern University, Boston, MA 02115,
  7. Princeton Center for Theoretical Science, Princeton University, Princeton, NJ 08544
Publication Date:
Research Org.:
Princeton Univ., NJ (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1236659
Alternate Identifier(s):
OSTI ID: 1347702
Grant/Contract Number:  
FG-02-05ER46200; FG02-05ER46200; FG02-07ER46352; AC02-05CH11231
Resource Type:
Published Article
Journal Name:
Proceedings of the National Academy of Sciences of the United States of America
Additional Journal Information:
Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Volume: 113 Journal Issue: 5; Journal ID: ISSN 0027-8424
Publisher:
Proceedings of the National Academy of Sciences
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS; Fermi arc; Weyl fermion; chiral magnetic effect; topological insulator

Citation Formats

Huang, Shin-Ming, Xu, Su-Yang, Belopolski, Ilya, Lee, Chi-Cheng, Chang, Guoqing, Chang, Tay-Rong, Wang, BaoKai, Alidoust, Nasser, Bian, Guang, Neupane, Madhab, Sanchez, Daniel, Zheng, Hao, Jeng, Horng-Tay, Bansil, Arun, Neupert, Titus, Lin, Hsin, and Hasan, M. Zahid. New type of Weyl semimetal with quadratic double Weyl fermions. United States: N. p., 2016. Web. doi:10.1073/pnas.1514581113.
Huang, Shin-Ming, Xu, Su-Yang, Belopolski, Ilya, Lee, Chi-Cheng, Chang, Guoqing, Chang, Tay-Rong, Wang, BaoKai, Alidoust, Nasser, Bian, Guang, Neupane, Madhab, Sanchez, Daniel, Zheng, Hao, Jeng, Horng-Tay, Bansil, Arun, Neupert, Titus, Lin, Hsin, & Hasan, M. Zahid. New type of Weyl semimetal with quadratic double Weyl fermions. United States. https://doi.org/10.1073/pnas.1514581113
Huang, Shin-Ming, Xu, Su-Yang, Belopolski, Ilya, Lee, Chi-Cheng, Chang, Guoqing, Chang, Tay-Rong, Wang, BaoKai, Alidoust, Nasser, Bian, Guang, Neupane, Madhab, Sanchez, Daniel, Zheng, Hao, Jeng, Horng-Tay, Bansil, Arun, Neupert, Titus, Lin, Hsin, and Hasan, M. Zahid. Tue . "New type of Weyl semimetal with quadratic double Weyl fermions". United States. https://doi.org/10.1073/pnas.1514581113.
@article{osti_1236659,
title = {New type of Weyl semimetal with quadratic double Weyl fermions},
author = {Huang, Shin-Ming and Xu, Su-Yang and Belopolski, Ilya and Lee, Chi-Cheng and Chang, Guoqing and Chang, Tay-Rong and Wang, BaoKai and Alidoust, Nasser and Bian, Guang and Neupane, Madhab and Sanchez, Daniel and Zheng, Hao and Jeng, Horng-Tay and Bansil, Arun and Neupert, Titus and Lin, Hsin and Hasan, M. Zahid},
abstractNote = {Weyl semimetals have attracted worldwide attention due to their wide range of exotic properties predicted in theories. The experimental realization had remained elusive for a long time despite much effort. Very recently, the first Weyl semimetal has been discovered in an inversion-breaking, stoichiometric solid TaAs. So far, the TaAs class remains the only Weyl semimetal available in real materials. To facilitate the transition of Weyl semimetals from the realm of purely theoretical interest to the realm of experimental studies and device applications, it is of crucial importance to identify other robust candidates that are experimentally feasible to be realized. In this paper, we propose such a Weyl semimetal candidate in an inversion-breaking, stoichiometric compound strontium silicide, SrSi2, with many new and novel properties that are distinct from TaAs. Here, we show that SrSi2 is a Weyl semimetal even without spin-orbit coupling and that, after the inclusion of spin-orbit coupling, two Weyl fermions stick together forming an exotic double Weyl fermion with quadratic dispersions and a higher chiral charge of ±2. Moreover, we find that the Weyl nodes with opposite charges are located at different energies due to the absence of mirror symmetry in SrSi2, paving the way for the realization of the chiral magnetic effect. Finally, our systematic results not only identify a much-needed robust Weyl semimetal candidate but also open the door to new topological Weyl physics that is not possible in TaAs},
doi = {10.1073/pnas.1514581113},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 5,
volume = 113,
place = {United States},
year = {Tue Jan 19 00:00:00 EST 2016},
month = {Tue Jan 19 00:00:00 EST 2016}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1073/pnas.1514581113

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Works referenced in this record:

Electrical properties of alkaline earth disilicides and digermanides
journal, May 1974


Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Topological insulators and superconductors
journal, October 2011


The structure of SrSI 2 : a crystal of class O (432)
journal, August 1972

  • Pringle, G. E.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 28, Issue 8
  • DOI: 10.1107/S0567740872006053

Weyl electrons kiss
journal, May 2011


Hybrid functionals based on a screened Coulomb potential
journal, May 2003

  • Heyd, Jochen; Scuseria, Gustavo E.; Ernzerhof, Matthias
  • The Journal of Chemical Physics, Vol. 118, Issue 18
  • DOI: 10.1063/1.1564060

Three-dimensional Dirac semimetal and quantum transport in Cd 3 As 2
journal, September 2013


Band structure of cadmium arsenide at room temperature
journal, April 1977


Observation of Fermi arc surface states in a topological metal
journal, December 2014


Discovery of a Weyl fermion state with Fermi arcs in niobium arsenide
journal, August 2015

  • Xu, Su-Yang; Alidoust, Nasser; Belopolski, Ilya
  • Nature Physics, Vol. 11, Issue 9
  • DOI: 10.1038/nphys3437

Consequences of a condensed matter realization of Lorentz-violating QED in Weyl semi-metals
journal, August 2012


Helical Fermi arcs and surface states in time-reversal invariant Weyl semimetals
journal, June 2013


Quantum Spin Hall Effect and Topological Phase Transition in HgTe Quantum Wells
journal, December 2006

  • Bernevig, B. A.; Hughes, T. L.; Zhang, S.-C.
  • Science, Vol. 314, Issue 5806, p. 1757-1761
  • DOI: 10.1126/science.1133734

False-positive and false-negative assignments of topological insulators in density functional theory and hybrids
journal, July 2011


Weyl semimetal with broken time reversal and inversion symmetries
journal, April 2012


Chern Semimetal and the Quantized Anomalous Hall Effect in HgCr 2 Se 4
journal, October 2011


Experimental discovery of a topological Weyl semimetal state in TaP
journal, November 2015

  • Xu, Su-Yang; Belopolski, Ilya; Sanchez, Daniel S.
  • Science Advances, Vol. 1, Issue 10
  • DOI: 10.1126/sciadv.1501092

Transformation of three-dimensional three-connected silicon nets in SrSi2
journal, March 1978


Topological response in Weyl semimetals and the chiral anomaly
journal, September 2012


Non-Fermi-Liquid and Topological States with Strong Spin-Orbit Coupling
journal, November 2013


Topological electronic structure and Weyl semimetal in the TlBiSe 2 class of semiconductors
journal, September 2012


Effets galvanomagnétiques et thermomagnétiques classiques dans l'arséniure de cadmium
journal, January 1967


Adler-Bell-Jackiw anomaly in Weyl semimetals: Application to pyrochlore iridates
journal, June 2012


Weyl semimetal phase in the non-centrosymmetric compound TaAs
journal, August 2015

  • Yang, L. X.; Liu, Z. K.; Sun, Y.
  • Nature Physics, Vol. 11, Issue 9
  • DOI: 10.1038/nphys3425

Energy-band structure of Cd 3 As 2 at low temperatures and the dependence of the direct gap on temperature and pressure
journal, April 1977


Recent developments in transport phenomena in Weyl semimetals
journal, November 2013


Ultrahigh mobility and giant magnetoresistance in the Dirac semimetal Cd3As2
journal, November 2014

  • Liang, Tian; Gibson, Quinn; Ali, Mazhar N.
  • Nature Materials, Vol. 14, Issue 3
  • DOI: 10.1038/nmat4143

Chiral magnetic effect
journal, October 2008


Density response in Weyl metals
journal, June 2014


Some Optical Properties of Thin Evaporated Cd3As2 Films
journal, January 1967


Chiral magnetic effect in a two-band lattice model of Weyl semimetal
journal, March 2015


Prediction of a Weyl semimetal in Hg 1 x y Cd x Mn y Te
journal, February 2014


Revisiting magnetic coupling in transition-metal-benzene complexes with maximally localized Wannier functions
journal, June 2009


Superconductivity of doped Weyl semimetals: Finite-momentum pairing and electronic analog of the 3 He- A phase
journal, December 2012


Observation of Weyl nodes and Fermi arcs in tantalum phosphide
journal, March 2016

  • Xu, N.; Weng, H. M.; Lv, B. Q.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms11006

Electronic structure of alkali-pnictide compounds
journal, March 1992


Elektron und Gravitation. I
journal, May 1929


Colloquium: Topological insulators
journal, November 2010


Observation of a three-dimensional topological Dirac semimetal phase in high-mobility Cd3As2
journal, May 2014

  • Neupane, Madhab; Xu, Su-Yang; Sankar, Raman
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4786

Discovery of a Three-Dimensional Topological Dirac Semimetal, Na3Bi
journal, January 2014


G W study of topological insulators Bi 2 Se 3 , Bi 2 Te 3 , and Sb 2 Te 3 : Beyond the perturbative one-shot approach
journal, July 2013


Topological Mott Insulator in Three-Dimensional Systems with Quadratic Band Touching
journal, September 2014


Observation of a large-gap topological-insulator class with a single Dirac cone on the surface
journal, May 2009

  • Xia, Y.; Qian, D.; Hsieh, D.
  • Nature Physics, Vol. 5, Issue 6, p. 398-402
  • DOI: 10.1038/nphys1274

Weyl Semimetal in a Topological Insulator Multilayer
journal, September 2011


Discovery of a Weyl fermion semimetal and topological Fermi arcs
journal, July 2015


Weyl semimetals from noncentrosymmetric topological insulators
journal, October 2014


Dirac semimetal and topological phase transitions in A 3 Bi ( A = Na , K, Rb)
journal, May 2012


Quantum oscillations from surface Fermi arcs in Weyl and Dirac semimetals
journal, October 2014

  • Potter, Andrew C.; Kimchi, Itamar; Vishwanath, Ashvin
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6161

Infrared optical absorption of Hg 1− x Cd x Te
journal, June 1979

  • Finkman, E.; Nemirovsky, Y.
  • Journal of Applied Physics, Vol. 50, Issue 6
  • DOI: 10.1063/1.326421

Energy Gap in Hg 1− x Cd x Te by Optical Absorption
journal, September 1969


The Adler-Bell-Jackiw anomaly and Weyl fermions in a crystal
journal, November 1983


Magneto-optical conductivity of Weyl semimetals
journal, June 2013


Multi-Weyl Topological Semimetals Stabilized by Point Group Symmetry
journal, June 2012


Experimental Realization of a Three-Dimensional Dirac Semimetal
journal, July 2014


Enhancement of thermoelectric performance driven by Ge substitution in SrSi 2 alloy
journal, July 2013


A stable three-dimensional topological Dirac semimetal Cd3As2
journal, May 2014

  • Liu, Z. K.; Jiang, J.; Zhou, B.
  • Nature Materials, Vol. 13, Issue 7
  • DOI: 10.1038/nmat3990

Topological semimetal and Fermi-arc surface states in the electronic structure of pyrochlore iridates
journal, May 2011


A Weyl Fermion semimetal with surface Fermi arcs in the transition metal monopnictide TaAs class
journal, June 2015

  • Huang, Shin-Ming; Xu, Su-Yang; Belopolski, Ilya
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8373