Contrasting the Material Chemistry of Cu 2 ZnSnSe 4 and Cu 2 ZnSnS (4– x ) Se x

Aguiar, Jeffery A.; Patel, Maulik; Aoki, Toshihiro; Wozny, Sarah; Al‐Jassim, Mowafak

doi:10.1002/advs.201500320

Title: Contrasting the Material Chemistry of Cu ₂ ZnSnSe ₄ and Cu ₂ ZnSnS _(4– _x ₎ Se _x

Abstract

Earth-abundant sustainable inorganic thin-film solar cells, independent of precious elements, pivot on a marginal material phase space targeting specific compounds. Advanced materials characterization efforts are necessary to expose the roles of microstructure, chemistry, and interfaces. Here, the earth-abundant solar cell device, Cu₂ZnSnS_(4-x)Se_x, is reported, which shows a high abundance of secondary phases compared to similarly grown Cu₂ZnSnSe₄.

Authors:

Aguiar, Jeffery A. ^[1]; Patel, Maulik ^[2]; Aoki, Toshihiro ^[3]; Wozny, Sarah ^[4]; Al‐Jassim, Mowafak ^[1]

National Renewable Energy Laboratory Golden CO 80401 USA
Department of Materials Science and Engineering University of Tennessee‐Knoxville Knoxville TN 37996 USA
LeRoy Center for Solid State Science Arizona State University Tempe AZ 85281 USA
Advanced Materials Research Institute University of New Orleans New Orleans LA 70148 USA

Publication Date:: Tue Feb 02 00:00:00 EST 2016

Research Org.:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1236657

Alternate Identifier(s):: OSTI ID: 1260053; OSTI ID: 1341090

Report Number(s):: NREL/JA-5K00-66725
Journal ID: ISSN 2198-3844; 1500320

Grant/Contract Number:: AC36-08GO28308

Resource Type:: Published Article

Journal Name:: Advanced Science

Additional Journal Information:: Journal Name: Advanced Science Journal Volume: 3 Journal Issue: 6; Journal ID: ISSN 2198-3844

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Subject:: 14 SOLAR ENERGY; 36 MATERIALS SCIENCE; CZTS; photovoltaics; solar cells; STEM; thin-films

Citation Formats


                    Aguiar, Jeffery A., Patel, Maulik, Aoki, Toshihiro, Wozny, Sarah, and Al‐Jassim, Mowafak. Contrasting the Material Chemistry of Cu 2 ZnSnSe 4 and Cu 2 ZnSnS (4– x ) Se x.  Germany: N. p., 2016. 
Web.  doi:10.1002/advs.201500320.

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                    Aguiar, Jeffery A., Patel, Maulik, Aoki, Toshihiro, Wozny, Sarah, & Al‐Jassim, Mowafak. Contrasting the Material Chemistry of Cu 2 ZnSnSe 4 and Cu 2 ZnSnS (4– x ) Se x.  Germany.  https://doi.org/10.1002/advs.201500320

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                    Aguiar, Jeffery A., Patel, Maulik, Aoki, Toshihiro, Wozny, Sarah, and Al‐Jassim, Mowafak. Tue .  
"Contrasting the Material Chemistry of Cu 2 ZnSnSe 4 and Cu 2 ZnSnS (4– x ) Se x".  Germany.  https://doi.org/10.1002/advs.201500320.

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@article{osti_1236657,

  title        = {Contrasting the Material Chemistry of Cu 2 ZnSnSe 4 and Cu 2 ZnSnS (4– x ) Se x},

  author       = {Aguiar, Jeffery A. and Patel, Maulik and Aoki, Toshihiro and Wozny, Sarah and Al‐Jassim, Mowafak},

  abstractNote = {Earth-abundant sustainable inorganic thin-film solar cells, independent of precious elements, pivot on a marginal material phase space targeting specific compounds. Advanced materials characterization efforts are necessary to expose the roles of microstructure, chemistry, and interfaces. Here, the earth-abundant solar cell device, Cu2ZnSnS(4-x)Sex, is reported, which shows a high abundance of secondary phases compared to similarly grown Cu2ZnSnSe4.},

  doi          = {10.1002/advs.201500320},

  journal      = {Advanced Science},

  number       = 6,

  volume       = 3,

  place        = {Germany},

  year         = {Tue Feb 02 00:00:00 EST 2016},

  month        = {Tue Feb 02 00:00:00 EST 2016}

}

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Title: Contrasting the Material Chemistry of Cu 2 ZnSnSe 4 and Cu 2 ZnSnS (4– x ) Se x

Abstract

Citation Formats

Structural aspects of adamantine like multinary chalcogenides journal, May 2007

Device Characteristics of CZTSSe Thin-Film Solar Cells with 12.6% Efficiency journal, November 2013

New world record efficiency for Cu(In,Ga)Se2 thin-film solar cells beyond 20% journal, January 2011

Sulfide Nanocrystal Inks for Dense Cu(In 1− x Ga x )(S 1− y Se y ) 2 Absorber Films and Their Photovoltaic Performance journal, August 2009

The crystal structure of kesterite type compounds: A neutron and X-ray diffraction study journal, June 2011

Earth Abundant Element Cu 2 Zn(Sn 1− x Ge x )S 4 Nanocrystals for Tunable Band Gap Solar Cells: 6.8% Efficient Device Fabrication journal, May 2011

In-depth resolved Raman scattering analysis for the identification of secondary phases: Characterization of Cu2ZnSnS4 layers for solar cell applications journal, May 2011

Development of CZTS-based thin film solar cells journal, February 2009

Synthesis of Cu 2 ZnSnS 4 Nanocrystal Ink and Its Use for Solar Cells journal, August 2009

A neutron diffraction study of the stannite-kesterite solid solution series [A neutron diffraction study of the stannite-kesterite solid solution series] journal, February 2007

Phase equilibria in the Cu2S–ZnS–SnS2 system journal, April 2004

Grain boundary segregation in Fe–Mn–C twinning-induced plasticity steels studied by correlative electron backscatter diffraction and atom probe tomography journal, January 2015

Growth mechanisms of co-evaporated kesterite: a comparison of Cu-rich and Zn-rich composition paths: Growth mechanisms of co-evaporated kesterite journal, January 2013

The nature of electrostatic potential fluctuations in Cu 2 ZnSnS 4 and their role on photovoltaic device performance journal, November 2013

Determination of band gap energy (Eg) of Cu2ZnSnSe4 thin films: On the discrepancies of reported band gap values journal, July 2010

Device characteristics of a 10.1% hydrazine-processed Cu2ZnSn(Se,S)4 solar cell: Characteristics of a 10.1% efficient kesterite solar cell journal, September 2011

Determination of secondary phases in kesterite Cu 2 ZnSnS 4 thin films by x-ray absorption near edge structure analysis journal, December 2011

Fabrication and Electronic Properties of CZTSe Single Crystals journal, January 2015

Kesterites-a challenging material for solar cells: Kesterites-a challenging material for solar cells journal, February 2012

Direct observation of Cu, Zn cation disorder in Cu 2 ZnSnS 4 solar cell absorber material using aberration corrected scanning transmission electron microscopy : Aberration corrected STEM in Cu, Zn cation disorder in CZTS journal, September 2012

Co-evaporated Cu2ZnSnSe4 films and devices journal, June 2012

Automated Analysis of SEM X-Ray Spectral Images: A Powerful New Microanalysis Tool journal, January 2003

Band tailing and efficiency limitation in kesterite solar cells journal, September 2013

Band-gap-graded Cu2ZnSn(S1-x,Sex)4 Solar Cells Fabricated by an Ethanol-based, Particulate Precursor Ink Route journal, October 2013

Defect formation and phase stability of Cu 2 ZnSnS 4 photovoltaic material journal, March 2010

The path towards a high-performance solution-processed kesterite solar cell journal, June 2011

Title: Contrasting the Material Chemistry of Cu ₂ ZnSnSe ₄ and Cu ₂ ZnSnS _(4– _x ₎ Se _x

Structural aspects of adamantine like multinary chalcogenides
journal, May 2007

Device Characteristics of CZTSSe Thin-Film Solar Cells with 12.6% Efficiency
journal, November 2013

New world record efficiency for Cu(In,Ga)Se2 thin-film solar cells beyond 20%
journal, January 2011

Sulfide Nanocrystal Inks for Dense Cu(In _{1− x} Ga _x )(S _{1− y} Se _y ) ₂ Absorber Films and Their Photovoltaic Performance
journal, August 2009

The crystal structure of kesterite type compounds: A neutron and X-ray diffraction study
journal, June 2011

Earth Abundant Element Cu ₂ Zn(Sn _{1− x} Ge _x )S ₄ Nanocrystals for Tunable Band Gap Solar Cells: 6.8% Efficient Device Fabrication
journal, May 2011

In-depth resolved Raman scattering analysis for the identification of secondary phases: Characterization of Cu2ZnSnS4 layers for solar cell applications
journal, May 2011

Development of CZTS-based thin film solar cells
journal, February 2009

Synthesis of Cu ₂ ZnSnS ₄ Nanocrystal Ink and Its Use for Solar Cells
journal, August 2009

A neutron diffraction study of the stannite-kesterite solid solution series [A neutron diffraction study of the stannite-kesterite solid solution series]
journal, February 2007

Phase equilibria in the Cu2S–ZnS–SnS2 system
journal, April 2004

Grain boundary segregation in Fe–Mn–C twinning-induced plasticity steels studied by correlative electron backscatter diffraction and atom probe tomography
journal, January 2015

Growth mechanisms of co-evaporated kesterite: a comparison of Cu-rich and Zn-rich composition paths: Growth mechanisms of co-evaporated kesterite
journal, January 2013

The nature of electrostatic potential fluctuations in Cu ₂ ZnSnS ₄ and their role on photovoltaic device performance
journal, November 2013

Determination of band gap energy (Eg) of Cu2ZnSnSe4 thin films: On the discrepancies of reported band gap values
journal, July 2010

Device characteristics of a 10.1% hydrazine-processed Cu2ZnSn(Se,S)4 solar cell: Characteristics of a 10.1% efficient kesterite solar cell
journal, September 2011

Determination of secondary phases in kesterite Cu ₂ ZnSnS ₄ thin films by x-ray absorption near edge structure analysis
journal, December 2011

Fabrication and Electronic Properties of CZTSe Single Crystals
journal, January 2015

Kesterites-a challenging material for solar cells: Kesterites-a challenging material for solar cells
journal, February 2012

Direct observation of Cu, Zn cation disorder in Cu ₂ ZnSnS ₄ solar cell absorber material using aberration corrected scanning transmission electron microscopy : Aberration corrected STEM in Cu, Zn cation disorder in CZTS
journal, September 2012

Co-evaporated Cu2ZnSnSe4 films and devices
journal, June 2012

Automated Analysis of SEM X-Ray Spectral Images: A Powerful New Microanalysis Tool
journal, January 2003

Band tailing and efficiency limitation in kesterite solar cells
journal, September 2013

Band-gap-graded Cu2ZnSn(S1-x,Sex)4 Solar Cells Fabricated by an Ethanol-based, Particulate Precursor Ink Route
journal, October 2013

Defect formation and phase stability of ${Cu}_{2} {ZnSnS}_{4}$ photovoltaic material
journal, March 2010

The path towards a high-performance solution-processed kesterite solar cell
journal, June 2011