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Title: Understanding the structure and structural degradation mechanisms in high-voltage lithium-ion battery cathode oxides. A review of materials diagnostics

Abstract

Materials diagnostic techniques are the principal tools used in the development of low-cost, high-performance electrodes for next-generation lithium-based energy storage technologies. Also, this review highlights the importance of materials diagnostic techniques in unraveling the structure and the structural degradation mechanisms in high-voltage, high-capacity oxides that have the potential to be implemented in high-energy-density lithium-ion batteries for transportation that can use renewable energy and is less-polluting than today. The rise in CO2 concentration in the earth’s atmosphere due to the use of petroleum products in vehicles and the dramatic increase in the cost of gasoline demand the replacement of current internal combustion engines in our vehicles with environmentally friendly, carbon free systems. Therefore, vehicles powered fully/partially by electricity are being introduced into today’s transportation fleet. As power requirements in all-electric vehicles become more demanding, lithium-ion battery (LiB) technology is now the potential candidate to provide higher energy density. Moreover, discovery of layered high-voltage lithium-manganese–rich (HV-LMR) oxides has provided a new direction toward developing high-energy-density LiBs because of their ability to deliver high capacity (~250 mA h/g) and to be operated at high operating voltage (~4.7 V). Unfortunately, practical use of HV-LMR electrodes is not viable because of structural changes in themore » host oxide during operation that can lead to fundamental and practical issues. This article provides the current understanding on the structure and structural degradation pathways in HV-LMR oxides, and manifests the importance of different materials diagnostic tools to unraveling the key mechanism(s). Furthermore, the fundamental insights reported, might become the tools to manipulate the chemical and/or structural aspects of HV-LMR oxides for low cost, high-energy-density LiB applications.« less

Authors:
 [1];  [1];  [1];  [1];  [1]
+ Show Author Affiliations
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1236575
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
MRS Energy & Sustainability
Additional Journal Information:
Journal Volume: 2; Journal ID: ISSN 2329-2237
Publisher:
Materials Research Society
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Mohanty, Debasish, Li, Jianlin, Nagpure, Shrikant C, Wood, III, David L, and Daniel, Claus. Understanding the structure and structural degradation mechanisms in high-voltage lithium-ion battery cathode oxides. A review of materials diagnostics. United States: N. p., 2015. Web. doi:10.1557/mre.2015.16.
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Mohanty, Debasish, Li, Jianlin, Nagpure, Shrikant C, Wood, III, David L, & Daniel, Claus. Understanding the structure and structural degradation mechanisms in high-voltage lithium-ion battery cathode oxides. A review of materials diagnostics. United States. https://doi.org/10.1557/mre.2015.16
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Mohanty, Debasish, Li, Jianlin, Nagpure, Shrikant C, Wood, III, David L, and Daniel, Claus. Mon . "Understanding the structure and structural degradation mechanisms in high-voltage lithium-ion battery cathode oxides. A review of materials diagnostics". United States. https://doi.org/10.1557/mre.2015.16. https://www.osti.gov/servlets/purl/1236575.
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@article{osti_1236575,
title = {Understanding the structure and structural degradation mechanisms in high-voltage lithium-ion battery cathode oxides. A review of materials diagnostics},
author = {Mohanty, Debasish and Li, Jianlin and Nagpure, Shrikant C and Wood, III, David L and Daniel, Claus},
abstractNote = {Materials diagnostic techniques are the principal tools used in the development of low-cost, high-performance electrodes for next-generation lithium-based energy storage technologies. Also, this review highlights the importance of materials diagnostic techniques in unraveling the structure and the structural degradation mechanisms in high-voltage, high-capacity oxides that have the potential to be implemented in high-energy-density lithium-ion batteries for transportation that can use renewable energy and is less-polluting than today. The rise in CO2 concentration in the earth’s atmosphere due to the use of petroleum products in vehicles and the dramatic increase in the cost of gasoline demand the replacement of current internal combustion engines in our vehicles with environmentally friendly, carbon free systems. Therefore, vehicles powered fully/partially by electricity are being introduced into today’s transportation fleet. As power requirements in all-electric vehicles become more demanding, lithium-ion battery (LiB) technology is now the potential candidate to provide higher energy density. Moreover, discovery of layered high-voltage lithium-manganese–rich (HV-LMR) oxides has provided a new direction toward developing high-energy-density LiBs because of their ability to deliver high capacity (~250 mA h/g) and to be operated at high operating voltage (~4.7 V). Unfortunately, practical use of HV-LMR electrodes is not viable because of structural changes in the host oxide during operation that can lead to fundamental and practical issues. This article provides the current understanding on the structure and structural degradation pathways in HV-LMR oxides, and manifests the importance of different materials diagnostic tools to unraveling the key mechanism(s). Furthermore, the fundamental insights reported, might become the tools to manipulate the chemical and/or structural aspects of HV-LMR oxides for low cost, high-energy-density LiB applications.},
doi = {10.1557/mre.2015.16},
journal = {MRS Energy & Sustainability},
number = ,
volume = 2,
place = {United States},
year = {2015},
month = {12}
}
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    High-Performance Li-Rich Layered Transition Metal Oxide Cathode Materials for Li-Ion Batteries
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    Modification of Ni-Rich FCG NMC and NCA Cathodes by Atomic Layer Deposition: Preventing Surface Phase Transitions for High-Voltage Lithium-Ion Batteries
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    • Mohanty, Debasish; Dahlberg, Kevin; King, David M.
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    Extracting maximum capacity from Ni-rich Li[Ni 0.95 Co 0.025 Mn 0.025 ]O 2 cathodes for high-energy-density lithium-ion batteries
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    • Yoon, Chong S.; Ryu, Hoon-Hee; Park, Geon-Tae
    • Journal of Materials Chemistry A, Vol. 6, Issue 9
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    Energy storage through intercalation reactions: electrodes for rechargeable batteries
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    • Massé, Robert C.; Liu, Chaofeng; Li, Yanwei
    • National Science Review, Vol. 4, Issue 1
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