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Title: Understanding the structure and structural degradation mechanisms in high-voltage lithium-ion battery cathode oxides. A review of materials diagnostics

Abstract

Materials diagnostic techniques are the principal tools used in the development of low-cost, high-performance electrodes for next-generation lithium-based energy storage technologies. Also, this review highlights the importance of materials diagnostic techniques in unraveling the structure and the structural degradation mechanisms in high-voltage, high-capacity oxides that have the potential to be implemented in high-energy-density lithium-ion batteries for transportation that can use renewable energy and is less-polluting than today. The rise in CO2 concentration in the earth’s atmosphere due to the use of petroleum products in vehicles and the dramatic increase in the cost of gasoline demand the replacement of current internal combustion engines in our vehicles with environmentally friendly, carbon free systems. Therefore, vehicles powered fully/partially by electricity are being introduced into today’s transportation fleet. As power requirements in all-electric vehicles become more demanding, lithium-ion battery (LiB) technology is now the potential candidate to provide higher energy density. Moreover, discovery of layered high-voltage lithium-manganese–rich (HV-LMR) oxides has provided a new direction toward developing high-energy-density LiBs because of their ability to deliver high capacity (~250 mA h/g) and to be operated at high operating voltage (~4.7 V). Unfortunately, practical use of HV-LMR electrodes is not viable because of structural changes in themore » host oxide during operation that can lead to fundamental and practical issues. This article provides the current understanding on the structure and structural degradation pathways in HV-LMR oxides, and manifests the importance of different materials diagnostic tools to unraveling the key mechanism(s). Furthermore, the fundamental insights reported, might become the tools to manipulate the chemical and/or structural aspects of HV-LMR oxides for low cost, high-energy-density LiB applications.« less

Authors:
 [1];  [1];  [1];  [1];  [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1236575
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
MRS Energy & Sustainability
Additional Journal Information:
Journal Volume: 2; Journal ID: ISSN 2329-2237
Publisher:
Materials Research Society
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Mohanty, Debasish, Li, Jianlin, Nagpure, Shrikant C, Wood, III, David L, and Daniel, Claus. Understanding the structure and structural degradation mechanisms in high-voltage lithium-ion battery cathode oxides. A review of materials diagnostics. United States: N. p., 2015. Web. https://doi.org/10.1557/mre.2015.16.
Mohanty, Debasish, Li, Jianlin, Nagpure, Shrikant C, Wood, III, David L, & Daniel, Claus. Understanding the structure and structural degradation mechanisms in high-voltage lithium-ion battery cathode oxides. A review of materials diagnostics. United States. https://doi.org/10.1557/mre.2015.16
Mohanty, Debasish, Li, Jianlin, Nagpure, Shrikant C, Wood, III, David L, and Daniel, Claus. Mon . "Understanding the structure and structural degradation mechanisms in high-voltage lithium-ion battery cathode oxides. A review of materials diagnostics". United States. https://doi.org/10.1557/mre.2015.16. https://www.osti.gov/servlets/purl/1236575.
@article{osti_1236575,
title = {Understanding the structure and structural degradation mechanisms in high-voltage lithium-ion battery cathode oxides. A review of materials diagnostics},
author = {Mohanty, Debasish and Li, Jianlin and Nagpure, Shrikant C and Wood, III, David L and Daniel, Claus},
abstractNote = {Materials diagnostic techniques are the principal tools used in the development of low-cost, high-performance electrodes for next-generation lithium-based energy storage technologies. Also, this review highlights the importance of materials diagnostic techniques in unraveling the structure and the structural degradation mechanisms in high-voltage, high-capacity oxides that have the potential to be implemented in high-energy-density lithium-ion batteries for transportation that can use renewable energy and is less-polluting than today. The rise in CO2 concentration in the earth’s atmosphere due to the use of petroleum products in vehicles and the dramatic increase in the cost of gasoline demand the replacement of current internal combustion engines in our vehicles with environmentally friendly, carbon free systems. Therefore, vehicles powered fully/partially by electricity are being introduced into today’s transportation fleet. As power requirements in all-electric vehicles become more demanding, lithium-ion battery (LiB) technology is now the potential candidate to provide higher energy density. Moreover, discovery of layered high-voltage lithium-manganese–rich (HV-LMR) oxides has provided a new direction toward developing high-energy-density LiBs because of their ability to deliver high capacity (~250 mA h/g) and to be operated at high operating voltage (~4.7 V). Unfortunately, practical use of HV-LMR electrodes is not viable because of structural changes in the host oxide during operation that can lead to fundamental and practical issues. This article provides the current understanding on the structure and structural degradation pathways in HV-LMR oxides, and manifests the importance of different materials diagnostic tools to unraveling the key mechanism(s). Furthermore, the fundamental insights reported, might become the tools to manipulate the chemical and/or structural aspects of HV-LMR oxides for low cost, high-energy-density LiB applications.},
doi = {10.1557/mre.2015.16},
journal = {MRS Energy & Sustainability},
number = ,
volume = 2,
place = {United States},
year = {2015},
month = {12}
}

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Works referenced in this record:

Understanding the Rate Capability of High-Energy-Density Li-Rich Layered Li 1.2 Ni 0.15 Co 0.1 Mn 0.55 O 2 Cathode Materials
journal, December 2013


Analytical electron microscopy of Li1.2Co0.4Mn0.4O2 for lithium-ion batteries
journal, February 2011


Lithium Batteries and Cathode Materials
journal, October 2004

  • Whittingham, M. Stanley
  • Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302
  • DOI: 10.1021/cr020731c

Smart design of lithium-rich layered oxide cathode compositions with suppressed voltage decay
journal, January 2014

  • Lee, Eun-Sung; Manthiram, Arumugam
  • Journal of Materials Chemistry A, Vol. 2, Issue 11
  • DOI: 10.1039/c3ta14975g

Cation Ordering in Layered O3 Li[Ni x Li 1/3 - 2 x /3 Mn 2/ 3 - x /3 ]O 2 (0 ≤ x1 / 2 ) Compounds
journal, May 2005

  • Meng, Y. S.; Ceder, G.; Grey, C. P.
  • Chemistry of Materials, Vol. 17, Issue 9
  • DOI: 10.1021/cm047779m

Facet-Dependent Disorder in Pristine High-Voltage Lithium–Manganese-Rich Cathode Material
journal, November 2014

  • Dixit, Hemant; Zhou, Wu; Idrobo, Juan-Carlos
  • ACS Nano, Vol. 8, Issue 12
  • DOI: 10.1021/nn505740v

EELS analysis of cation valence states and oxygen vacancies in magnetic oxides
journal, October 2000


What can we learn about battery materials from their magnetic properties?
journal, January 2011

  • Chernova, Natasha A.; Nolis, Gene M.; Omenya, Fredrick O.
  • Journal of Materials Chemistry, Vol. 21, Issue 27
  • DOI: 10.1039/c1jm00024a

Study of Mn Dissolution from LiMn[sub 2]O[sub 4] Spinel Electrodes Using Rotating Ring-Disk Collection Experiments
journal, January 2003

  • Wang, Li-Fang; Ou, Chin-Ching; Striebel, Kathryn A.
  • Journal of The Electrochemical Society, Vol. 150, Issue 7
  • DOI: 10.1149/1.1577543

Electrochemical Characterization of Lithium and Manganese Rich Composite Material for Lithium Ion Batteries
journal, January 2013

  • Lu, Wenquan; Wu, Qingliu; Dees, Dennis W.
  • Journal of The Electrochemical Society, Vol. 160, Issue 6
  • DOI: 10.1149/2.134306jes

Materials processing for lithium-ion batteries
journal, March 2011


Materials Challenges and Opportunities of Lithium Ion Batteries
journal, January 2011

  • Manthiram, Arumugam
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 3
  • DOI: 10.1021/jz1015422

Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries
journal, March 2005

  • Thackeray, Michael M.; Johnson, Christopher S.; Vaughey, John T.
  • Journal of Materials Chemistry, Vol. 15, Issue 23, p. 2257-2267
  • DOI: 10.1039/b417616m

Structural transformation of a lithium-rich Li1.2Co0.1Mn0.55Ni0.15O2 cathode during high voltage cycling resolved by in situ X-ray diffraction
journal, May 2013


Structural evolution and the capacity fade mechanism upon long-term cycling in Li-rich cathode material
journal, January 2012

  • Song, Bohang; Liu, Zongwen; Lai, Man On
  • Physical Chemistry Chemical Physics, Vol. 14, Issue 37
  • DOI: 10.1039/c2cp42068f

Solid-Solution Oxides for Storage-Battery Electrodes
journal, January 1980

  • Goodenough, J. B.; Mizushima, K.; Takeda, T.
  • Japanese Journal of Applied Physics, Vol. 19, Issue S3
  • DOI: 10.7567/jjaps.19s3.305

Relationship between non-stoichiometry and physical properties in LiNiO2
journal, May 1995


Recent progress in cathode materials research for advanced lithium ion batteries
journal, May 2012

  • Xu, Bo; Qian, Danna; Wang, Ziying
  • Materials Science and Engineering: R: Reports, Vol. 73, Issue 5-6
  • DOI: 10.1016/j.mser.2012.05.003

Electrochemistry and Structural Chemistry of LiNiO[sub 2] (R3m) for 4 Volt Secondary Lithium Cells
journal, January 1993

  • Ohzuku, Tsutomu
  • Journal of The Electrochemical Society, Vol. 140, Issue 7
  • DOI: 10.1149/1.2220730

Electrochemical Properties of Low Temperature Crystallized LiCoO[sub 2]
journal, January 1997

  • Garcia, B.
  • Journal of The Electrochemical Society, Vol. 144, Issue 4
  • DOI: 10.1149/1.1837569

Understanding Long-Term Cycling Performance of Li 1.2 Ni 0.15 Mn 0.55 Co 0.1 O 2 –Graphite Lithium-Ion Cells
journal, January 2013

  • Li, Y.; Bettge, M.; Polzin, B.
  • Journal of The Electrochemical Society, Vol. 160, Issue 5
  • DOI: 10.1149/2.002305jes

Voltage Fade of Layered Oxides: Its Measurement and Impact on Energy Density
journal, January 2013

  • Bettge, Martin; Li, Yan; Gallagher, Kevin
  • Journal of The Electrochemical Society, Vol. 160, Issue 11
  • DOI: 10.1149/2.034311jes

Comparative Issues of Cathode Materials for Li-Ion Batteries
journal, March 2014


Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries
journal, April 1997

  • Padhi, A. K.
  • Journal of The Electrochemical Society, Vol. 144, Issue 4, p. 1188-1194
  • DOI: 10.1149/1.1837571

Layered Lithium Insertion Material of LiNi 1/2 Mn 1/2 O 2 : A Possible Alternative to LiCoO 2 for Advanced Lithium-Ion Batteries
journal, August 2001

  • Ohzuku, Tsutomu; Makimura, Yoshinari
  • Chemistry Letters, Vol. 30, Issue 8
  • DOI: 10.1246/cl.2001.744

Prospects for reducing the processing cost of lithium ion batteries
journal, February 2015


High-capacity lithium insertion materials of lithium nickel manganese oxides for advanced lithium-ion batteries: toward rechargeable capacity more than 300 mA h g−1
journal, January 2011

  • Ohzuku, Tsutomu; Nagayama, Masatoshi; Tsuji, Kyoji
  • Journal of Materials Chemistry, Vol. 21, Issue 27
  • DOI: 10.1039/c0jm04325g

Correlating hysteresis and voltage fade in lithium- and manganese-rich layered transition-metal oxide electrodes
journal, August 2013

  • Gallagher, Kevin G.; Croy, Jason R.; Balasubramanian, Mahalingam
  • Electrochemistry Communications, Vol. 33
  • DOI: 10.1016/j.elecom.2013.04.022

Non-destructive evaluation of slot-die-coated lithium secondary battery electrodes by in-line laser caliper and IR thermography methods
journal, January 2014

  • Mohanty, Debasish; Li, Jianlin; Born, Rachael
  • Anal. Methods, Vol. 6, Issue 3
  • DOI: 10.1039/c3ay41140k

Effect of Ru substitution on the first charge–discharge cycle of lithium-rich layered oxides
journal, January 2015

  • Knight, James C.; Nandakumar, Pat; Kan, Wang Hay
  • Journal of Materials Chemistry A, Vol. 3, Issue 5
  • DOI: 10.1039/c4ta05178e

Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries
journal, February 2006

  • Kang, Kisuk; Shirley Meng, Ying; Breger, Julien
  • Science, Vol. 311, Issue 5763, p. 977-980
  • DOI: 10.1126/science.1122152

Operando X-ray Absorption Study of the Redox Processes Involved upon Cycling of the Li-Rich Layered Oxide Li 1.20 Mn 0.54 Co 0.13 Ni 0.13 O 2 in Li Ion Batteries
journal, March 2014

  • Koga, H.; Croguennec, L.; Ménétrier, M.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 11
  • DOI: 10.1021/jp412197z

Electrical Energy Storage and Intercalation Chemistry
journal, June 1976


In situ investigations of a Li-rich Mn–Ni layered oxide for Li-ion batteries
journal, January 2012

  • Simonin, Loïc; Colin, Jean-François; Ranieri, Vincent
  • Journal of Materials Chemistry, Vol. 22, Issue 22
  • DOI: 10.1039/c2jm31205k

Effect of Morphology and Manganese Valence on the Voltage Fade and Capacity Retention of Li[Li 2/12 Ni 3/12 Mn 7/12 ]O 2
journal, October 2014

  • Verde, Michael G.; Liu, Haodong; Carroll, Kyler J.
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 21
  • DOI: 10.1021/am504701s

Recent progress in high-voltage lithium ion batteries
journal, September 2013


Mitigation of Layered to Spinel Conversion of a Li-Rich Layered Metal Oxide Cathode Material for Li-Ion Batteries
journal, December 2013

  • Ates, Mehmet Nurullah; Jia, Qingying; Shah, Ankita
  • Journal of The Electrochemical Society, Vol. 161, Issue 3
  • DOI: 10.1149/2.040403jes

Diffraction analysis of the lithium battery cathode material Li 1.2 Mn 0.4 Ni 0.3 Co 0.1 O 2
journal, November 2007


Changes in the Crystal Structure and Electrochemical Properties of Li[sub x]Ni[sub 0.5]Mn[sub 0.5]O[sub 2] during Electrochemical Cycling to High Voltages
journal, January 2007

  • Yabuuchi, Naoaki; Kumar, Sundeep; Li, Hayley H.
  • Journal of The Electrochemical Society, Vol. 154, Issue 6
  • DOI: 10.1149/1.2724734

Status, Opportunities, and Challenges of Electrochemical Energy Storage
journal, January 2013


Nanoscale Phase Separation, Cation Ordering, and Surface Chemistry in Pristine Li 1.2 Ni 0.2 Mn 0.6 O 2 for Li-Ion Batteries
journal, May 2013

  • Gu, Meng; Genc, Arda; Belharouak, Ilias
  • Chemistry of Materials, Vol. 25, Issue 11
  • DOI: 10.1021/cm4009392

K + -Doped Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 : A Novel Cathode Material with an Enhanced Cycling Stability for Lithium-Ion Batteries
journal, June 2014

  • Li, Qi; Li, Guangshe; Fu, Chaochao
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 13
  • DOI: 10.1021/am5017649

The use of neutron scattering in the study of ceramics
journal, November 2004


Synthesis, Characterization and Electrochemistry of Lithium Battery Electrodes: x Li 2 MnO 3 ·(1 − x )LiMn 0.333 Ni 0.333 Co 0.333 O 2 (0 ≤ x ≤ 0.7)
journal, October 2008

  • Johnson, Christopher S.; Li, Naichao; Lefief, Christina
  • Chemistry of Materials, Vol. 20, Issue 19
  • DOI: 10.1021/cm801245r

Correlating cation ordering and voltage fade in a lithium–manganese-rich lithium-ion battery cathode oxide: a joint magnetic susceptibility and TEM study
journal, January 2013

  • Mohanty, Debasish; Sefat, Athena S.; Li, Jianlin
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 44
  • DOI: 10.1039/c3cp53658k

In situ X-ray diffraction study of the lithium excess layered oxide compound Li[Li0.2Ni0.2Mn0.6]O2 during electrochemical cycling
journal, January 2012


Formation of the Spinel Phase in the Layered Composite Cathode Used in Li-Ion Batteries
journal, December 2012

  • Gu, Meng; Belharouak, Ilias; Zheng, Jianming
  • ACS Nano, Vol. 7, Issue 1
  • DOI: 10.1021/nn305065u

Layered Lithium Insertion Material of LiCo 1/3 Ni 1/3 Mn 1/3 O 2 for Lithium-Ion Batteries
journal, July 2001

  • Ohzuku, Tsutomu; Makimura, Yoshinari
  • Chemistry Letters, Vol. 30, Issue 7
  • DOI: 10.1246/cl.2001.642

Reversible anionic redox chemistry in high-capacity layered-oxide electrodes
journal, July 2013

  • Sathiya, M.; Rousse, G.; Ramesha, K.
  • Nature Materials, Vol. 12, Issue 9
  • DOI: 10.1038/nmat3699

Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] for Lithium-Ion Batteries
journal, January 2001

  • Lu, Zhonghua; MacNeil, D. D.; Dahn, J. R.
  • Electrochemical and Solid-State Letters, Vol. 4, Issue 11
  • DOI: 10.1149/1.1407994

NMR Studies of Cathode Materials for Lithium-Ion Rechargeable Batteries
journal, October 2004

  • Grey, Clare P.; Dupré, Nicolas
  • Chemical Reviews, Vol. 104, Issue 10
  • DOI: 10.1021/cr020734p

Continuous activation of Li2MnO3 component upon cycling in Li1.167Ni0.233Co0.100Mn0.467Mo0.033O2 cathode material for lithium ion batteries
journal, January 2013

  • Yu, Seung-Ho; Yoon, Taeho; Mun, Junyoung
  • Journal of Materials Chemistry A, Vol. 1, Issue 8
  • DOI: 10.1039/c2ta00309k

Long-Range and Local Structure in the Layered Oxide Li 1.2 Co 0.4 Mn 0.4 O 2
journal, April 2011

  • Bareño, J.; Balasubramanian, M.; Kang, S. H.
  • Chemistry of Materials, Vol. 23, Issue 8
  • DOI: 10.1021/cm200250a

Correlation Between Oxygen Vacancy, Microstrain, and Cation Distribution in Lithium-Excess Layered Oxides During the First Electrochemical Cycle
journal, April 2013

  • Fell, Christopher R.; Qian, Danna; Carroll, Kyler J.
  • Chemistry of Materials, Vol. 25, Issue 9
  • DOI: 10.1021/cm4000119

Identifying surface structural changes in layered Li-excess nickel manganese oxides in high voltage lithium ion batteries: A joint experimental and theoretical study
journal, January 2011

  • Xu, Bo; Fell, Christopher R.; Chi, Miaofang
  • Energy & Environmental Science, Vol. 4, Issue 6
  • DOI: 10.1039/c1ee01131f

Origin of voltage decay in high-capacity layered oxide electrodes
journal, December 2014

  • Sathiya, M.; Abakumov, A. M.; Foix, D.
  • Nature Materials, Vol. 14, Issue 2
  • DOI: 10.1038/nmat4137

Structure and electrochemistry of lithium cobalt oxide synthesised at 400°C
journal, March 1992

  • Gummow, R. J.; Thackeray, M. M.; David, W. I. F.
  • Materials Research Bulletin, Vol. 27, Issue 3, p. 327-337
  • DOI: 10.1016/0025-5408(92)90062-5

Direct In situ Observation of Li 2 O Evolution on Li-Rich High-Capacity Cathode Material, Li[Ni x Li (1–2 x )/3 Mn (2– x )/3 ]O 2 (0 ≤ x ≤0.5)
journal, January 2014

  • Hy, Sunny; Felix, Felix; Rick, John
  • Journal of the American Chemical Society, Vol. 136, Issue 3
  • DOI: 10.1021/ja410137s

Powering the Planet
journal, October 2007


Opportunities and challenges for a sustainable energy future
journal, August 2012

  • Chu, Steven; Majumdar, Arun
  • Nature, Vol. 488, Issue 7411, p. 294-303
  • DOI: 10.1038/nature11475

Direct Atomic-Resolution Observation of Two Phases in the Li 1.2 Mn 0.567 Ni 0.166 Co 0.067 O 2 Cathode Material for Lithium-Ion Batteries
journal, April 2013

  • Yu, Haijun; Ishikawa, Ryo; So, Yeong-Gi
  • Angewandte Chemie International Edition, Vol. 52, Issue 23
  • DOI: 10.1002/anie.201301236

Higher, Stronger, Better…︁ A Review of 5 Volt Cathode Materials for Advanced Lithium-Ion Batteries
journal, June 2012


Reversible Oxygen Participation to the Redox Processes Revealed for Li 1.20 Mn 0.54 Co 0.13 Ni 0.13 O 2
journal, January 2013

  • Koga, Hideyuki; Croguennec, Laurence; Ménétrier, Michel
  • Journal of The Electrochemical Society, Vol. 160, Issue 6
  • DOI: 10.1149/2.038306jes

First Evidence of Manganese–Nickel Segregation and Densification upon Cycling in Li-Rich Layered Oxides for Lithium Batteries
journal, July 2013

  • Boulineau, Adrien; Simonin, Loïc; Colin, Jean-François
  • Nano Letters, Vol. 13, Issue 8
  • DOI: 10.1021/nl4019275

Formation of Layered–Layered Composites in the Li–Co–Mn Oxide Pseudoternary System during Slow Cooling
journal, March 2013

  • McCalla, E.; Lowartz, C. M.; Brown, C. R.
  • Chemistry of Materials, Vol. 25, Issue 6
  • DOI: 10.1021/cm304002b

Probing the electrode/electrolyte interface in the lithium excess layered oxide Li1.2Ni0.2Mn0.6O2
journal, January 2013

  • Carroll, Kyler J.; Qian, Danna; Fell, Chris
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 26
  • DOI: 10.1039/c3cp51927a

Electrochemical and Structural Properties of xLi2M‘O3 ·(1− x )LiMn0.5Ni0.5O2 Electrodes for Lithium Batteries (M‘ = Ti, Mn, Zr; 0 ≤ x ⩽ 0.3)
journal, May 2004

  • Kim, Jeom-Soo; Johnson, Christopher S.; Vaughey, John T.
  • Chemistry of Materials, Vol. 16, Issue 10, p. 1996-2006
  • DOI: 10.1021/cm0306461

Integrated Materials xLi[sub 2]MnO[sub 3]⋅(1−x)LiMn[sub 1/3]Ni[sub 1/3]Co[sub 1/3]O[sub 2] (x=0.3, 0.5, 0.7) Synthesized
journal, January 2010

  • Amalraj, Francis; Kovacheva, Daniela; Talianker, Michael
  • Journal of The Electrochemical Society, Vol. 157, Issue 10
  • DOI: 10.1149/1.3463782

Suppressed capacity/voltage fading of high-capacity lithium-rich layered materials via the design of heterogeneous distribution in the composition
journal, January 2014

  • Yang, Xiukang; Wang, Di; Yu, Ruizhi
  • Journal of Materials Chemistry A, Vol. 2, Issue 11
  • DOI: 10.1039/c3ta14513a

Li -rich layer-structured cathode materials for high energy Li -ion batteries
journal, August 2014


High-Energy Cathode Materials (Li 2 MnO 3 –LiMO 2 ) for Lithium-Ion Batteries
journal, March 2013

  • Yu, Haijun; Zhou, Haoshen
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 8
  • DOI: 10.1021/jz400032v

Quantifying Hysteresis and Voltage Fade in xLi 2 MnO 3 (1-x)LiMn 0.5 Ni 0.5 O 2 Electrodes as a Function of Li 2 MnO 3 Content
journal, December 2013

  • Croy, Jason R.; Gallagher, Kevin G.; Balasubramanian, Mahalingam
  • Journal of The Electrochemical Society, Vol. 161, Issue 3
  • DOI: 10.1149/2.049403jes

Unraveling the Voltage-Fade Mechanism in High-Energy-Density Lithium-Ion Batteries: Origin of the Tetrahedral Cations for Spinel Conversion
journal, October 2014

  • Mohanty, Debasish; Li, Jianlin; Abraham, Daniel P.
  • Chemistry of Materials, Vol. 26, Issue 21
  • DOI: 10.1021/cm5031415

Electrochemical and Structural Study of the Layered, “Li-Excess” Lithium-Ion Battery Electrode Material Li[Li 1/9 Ni 1/3 Mn 5/9 ]O 2
journal, July 2009

  • Jiang, Meng; Key, Baris; Meng, Ying S.
  • Chemistry of Materials, Vol. 21, Issue 13
  • DOI: 10.1021/cm900279u

Corrosion/Fragmentation of Layered Composite Cathode and Related Capacity/Voltage Fading during Cycling Process
journal, July 2013

  • Zheng, Jianming; Gu, Meng; Xiao, Jie
  • Nano Letters, Vol. 13, Issue 8
  • DOI: 10.1021/nl401849t

Synthesis and electrochemistry of spinel LTLiCoO2
journal, July 1993


Layered lithium transition metal oxide cathodes towards high energy lithium-ion batteries
journal, January 2012

  • He, Ping; Yu, Haijun; Li, De
  • Journal of Materials Chemistry, Vol. 22, Issue 9
  • DOI: 10.1039/c2jm14305d

Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

Neutron Diffraction and Magnetic Susceptibility Studies on a High-Voltage Li 1.2 Mn 0.55 Ni 0.15 Co 0.10 O 2 Lithium Ion Battery Cathode: Insight into the Crystal Structure
journal, September 2013

  • Mohanty, Debasish; Huq, Ashfia; Payzant, E. Andrew
  • Chemistry of Materials, Vol. 25, Issue 20
  • DOI: 10.1021/cm402278q

Designing High-Capacity, Lithium-Ion Cathodes Using X-ray Absorption Spectroscopy
journal, December 2011

  • Croy, Jason R.; Balasubramanian, Mahalingam; Kim, Donghan
  • Chemistry of Materials, Vol. 23, Issue 24, p. 5415-5424
  • DOI: 10.1021/cm2026703

Atomic Structure of a Lithium-Rich Layered Oxide Material for Lithium-Ion Batteries: Evidence of a Solid Solution
journal, August 2011

  • Jarvis, Karalee A.; Deng, Zengqiang; Allard, Lawrence F.
  • Chemistry of Materials, Vol. 23, Issue 16
  • DOI: 10.1021/cm200831c

Study of the Lithium-Rich Integrated Compound xLi 2 MnO 3 ·(1-x)LiMO 2 (x around 0.5; M = Mn, Ni, Co; 2:2:1) and Its Electrochemical Activity as Positive Electrode in Lithium Cells
journal, December 2012

  • Amalraj, Francis; Talianker, Michael; Markovsky, Boris
  • Journal of The Electrochemical Society, Vol. 160, Issue 2
  • DOI: 10.1149/2.070302jes

Next-generation lithium-ion batteries: The promise of near-term advancements
journal, May 2014

  • Croy, Jason R.; Abouimrane, Ali; Zhang, Zhengcheng
  • MRS Bulletin, Vol. 39, Issue 5
  • DOI: 10.1557/mrs.2014.84

In situ X-ray absorption spectroscopic study of Li-rich layered cathode material Li[Ni0.17Li0.2Co0.07Mn0.56]O2
journal, August 2011


LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density
journal, June 1980


Non-destructive evaluation of slot-die-coated lithium secondary battery electrodes by in-line laser caliper and IR thermography methods
journal, January 2014

  • Mohanty, Debasish; Li, Jianlin; Born, Rachael
  • Anal. Methods, Vol. 6, Issue 3
  • DOI: 10.1039/C3AY41140K

Cathode materials review
conference, January 2014

  • Daniel, Claus; Mohanty, Debasish; Li, Jianlin
  • REVIEW ON ELECTROCHEMICAL STORAGE MATERIALS AND TECHNOLOGY: Proceedings of the 1st International Freiberg Conference on Electrochemical Storage Materials, AIP Conference Proceedings
  • DOI: 10.1063/1.4878478

Solid-Solution Oxides for Storage-Battery Electrodes
journal, January 1980

  • Goodenough, J. B.; Mizushima, K.; Takeda, T.
  • Japanese Journal of Applied Physics, Vol. 19, Issue S3
  • DOI: 10.7567/JJAPS.19S3.305

Relationship between non-stoichiometry and physical properties in LiNiO2
journal, May 1995


Structure and Binding of Specifically Mutated Neurotensin Fragments on a Silver Substrate: Vibrational Studies
journal, June 2011

  • Podstawka-Proniewicz, Edyta; Kudelski, Andrzej; Kim, Younkyoo
  • The Journal of Physical Chemistry B, Vol. 115, Issue 21
  • DOI: 10.1021/jp201316n

Li -rich layer-structured cathode materials for high energy Li -ion batteries
journal, August 2014


The use of neutron scattering in the study of ceramics
journal, November 2004


Synthesis and electrochemistry of spinel LTLiCoO2
journal, July 1993


Thermal Dehydration of Magnesium Acetate Tetrahydrate: Formation and in Situ Crystallization of Anhydrous Glass
journal, November 2012

  • Koga, Nobuyoshi; Suzuki, Yasumichi; Tatsuoka, Tomoyuki
  • The Journal of Physical Chemistry B, Vol. 116, Issue 49
  • DOI: 10.1021/jp3052517

A Li-Rich Layered Cathode Material with Enhanced Structural Stability and Rate Capability for Li-on Batteries
journal, December 2013

  • Ates, Mehmet Nurullah; Mukerjee, Sanjeev; Abraham, K. M.
  • Journal of The Electrochemical Society, Vol. 161, Issue 3
  • DOI: 10.1149/2.070403jes

EELS analysis of cation valence states and oxygen vacancies in magnetic oxides
journal, October 2000


Effect of Ru substitution on the first charge–discharge cycle of lithium-rich layered oxides
journal, January 2015

  • Knight, James C.; Nandakumar, Pat; Kan, Wang Hay
  • Journal of Materials Chemistry A, Vol. 3, Issue 5
  • DOI: 10.1039/C4TA05178E

    Works referencing / citing this record:

    High-Performance Li-Rich Layered Transition Metal Oxide Cathode Materials for Li-Ion Batteries
    journal, January 2019

    • Redel, Katarzyna; Kulka, Andrzej; Plewa, Anna
    • Journal of The Electrochemical Society, Vol. 166, Issue 3
    • DOI: 10.1149/2.0511903jes

    Li- and Mn-rich layered oxide cathode materials for lithium-ion batteries: a review from fundamentals to research progress and applications
    journal, January 2018

    • Pan, Hongge; Zhang, Shiming; Chen, Jian
    • Molecular Systems Design & Engineering, Vol. 3, Issue 5
    • DOI: 10.1039/c8me00025e

    Editors' Choice—State of Charge Dependent Resistance Build-Up in Li- and Mn-Rich Layered Oxides during Lithium Extraction and Insertion
    journal, January 2019

    • Teufl, Tobias; Pritzl, Daniel; Solchenbach, Sophie
    • Journal of The Electrochemical Society, Vol. 166, Issue 6
    • DOI: 10.1149/2.1131906jes

    Oxygen Release and Surface Degradation of Li- and Mn-Rich Layered Oxides in Variation of the Li 2 MnO 3 Content
    journal, January 2018

    • Teufl, Tobias; Strehle, Benjamin; Müller, Philipp
    • Journal of The Electrochemical Society, Vol. 165, Issue 11
    • DOI: 10.1149/2.0691811jes

    Modification of Ni-Rich FCG NMC and NCA Cathodes by Atomic Layer Deposition: Preventing Surface Phase Transitions for High-Voltage Lithium-Ion Batteries
    journal, May 2016

    • Mohanty, Debasish; Dahlberg, Kevin; King, David M.
    • Scientific Reports, Vol. 6, Issue 1
    • DOI: 10.1038/srep26532

    Extracting maximum capacity from Ni-rich Li[Ni 0.95 Co 0.025 Mn 0.025 ]O 2 cathodes for high-energy-density lithium-ion batteries
    journal, January 2018

    • Yoon, Chong S.; Ryu, Hoon-Hee; Park, Geon-Tae
    • Journal of Materials Chemistry A, Vol. 6, Issue 9
    • DOI: 10.1039/c7ta11346c

    Energy storage through intercalation reactions: electrodes for rechargeable batteries
    journal, December 2016

    • Massé, Robert C.; Liu, Chaofeng; Li, Yanwei
    • National Science Review, Vol. 4, Issue 1
    • DOI: 10.1093/nsr/nww093