Conceptual process design and techno-economic assessment of ex situ catalytic fast pyrolysis of biomass: A fixed bed reactor implementation scenario for future feasibility
Abstract
Ex situ catalytic fast pyrolysis of biomass is a promising route for the production of fungible liquid biofuels. There is significant ongoing research on the design and development of catalysts for this process. However, there are a limited number of studies investigating process configurations and their effects on biorefinery economics. Herein we present a conceptual process design with techno-economic assessment; it includes the production of upgraded bio-oil via fixed bed ex situ catalytic fast pyrolysis followed by final hydroprocessing to hydrocarbon fuel blendstocks. This study builds upon previous work using fluidized bed systems, as detailed in a recent design report led by the National Renewable Energy Laboratory (NREL/TP-5100-62455); overall yields are assumed to be similar, and are based on enabling future feasibility. Assuming similar yields provides a basis for easy comparison and for studying the impacts of areas of focus in this study, namely, fixed bed reactor configurations and their catalyst development requirements, and the impacts of an inline hot gas filter. A comparison with the fluidized bed system shows that there is potential for higher capital costs and lower catalyst costs in the fixed bed system, leading to comparable overall costs. The key catalyst requirement is to enable themore »
- Authors:
-
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- DWH Process Consulting, Centennial, CO (United States)
- Publication Date:
- Research Org.:
- National Renewable Energy Laboratory (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Bioenergy Technologies Office (BETO)
- OSTI Identifier:
- 1235666
- Report Number(s):
- NREL/JA-5100-64796
Journal ID: ISSN 1022-5528
- Grant/Contract Number:
- AC36-08GO28308
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Topics in Catalysis
- Additional Journal Information:
- Journal Volume: 59; Journal Issue: 1; Related Information: Topics in Catalysis; Journal ID: ISSN 1022-5528
- Publisher:
- Springer
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 09 BIOMASS FUELS; 59 BASIC BIOLOGICAL SCIENCES; ex situ catalytic fast pyrolysis; biofuel; process design; techno-economic assessment; fixed bed reactor; vapor phase upgrading; Aspen Plus
Citation Formats
Dutta, Abhijit, Schaidle, Joshua A., Humbird, David, Baddour, Frederick G., and Sahir, Asad. Conceptual process design and techno-economic assessment of ex situ catalytic fast pyrolysis of biomass: A fixed bed reactor implementation scenario for future feasibility. United States: N. p., 2015.
Web. doi:10.1007/s11244-015-0500-z.
Dutta, Abhijit, Schaidle, Joshua A., Humbird, David, Baddour, Frederick G., & Sahir, Asad. Conceptual process design and techno-economic assessment of ex situ catalytic fast pyrolysis of biomass: A fixed bed reactor implementation scenario for future feasibility. United States. https://doi.org/10.1007/s11244-015-0500-z
Dutta, Abhijit, Schaidle, Joshua A., Humbird, David, Baddour, Frederick G., and Sahir, Asad. Tue .
"Conceptual process design and techno-economic assessment of ex situ catalytic fast pyrolysis of biomass: A fixed bed reactor implementation scenario for future feasibility". United States. https://doi.org/10.1007/s11244-015-0500-z. https://www.osti.gov/servlets/purl/1235666.
@article{osti_1235666,
title = {Conceptual process design and techno-economic assessment of ex situ catalytic fast pyrolysis of biomass: A fixed bed reactor implementation scenario for future feasibility},
author = {Dutta, Abhijit and Schaidle, Joshua A. and Humbird, David and Baddour, Frederick G. and Sahir, Asad},
abstractNote = {Ex situ catalytic fast pyrolysis of biomass is a promising route for the production of fungible liquid biofuels. There is significant ongoing research on the design and development of catalysts for this process. However, there are a limited number of studies investigating process configurations and their effects on biorefinery economics. Herein we present a conceptual process design with techno-economic assessment; it includes the production of upgraded bio-oil via fixed bed ex situ catalytic fast pyrolysis followed by final hydroprocessing to hydrocarbon fuel blendstocks. This study builds upon previous work using fluidized bed systems, as detailed in a recent design report led by the National Renewable Energy Laboratory (NREL/TP-5100-62455); overall yields are assumed to be similar, and are based on enabling future feasibility. Assuming similar yields provides a basis for easy comparison and for studying the impacts of areas of focus in this study, namely, fixed bed reactor configurations and their catalyst development requirements, and the impacts of an inline hot gas filter. A comparison with the fluidized bed system shows that there is potential for higher capital costs and lower catalyst costs in the fixed bed system, leading to comparable overall costs. The key catalyst requirement is to enable the effective transformation of highly oxygenated biomass into hydrocarbons products with properties suitable for blending into current fuels. Potential catalyst materials are discussed, along with their suitability for deoxygenation, hydrogenation and C–C coupling chemistry. This chemistry is necessary during pyrolysis vapor upgrading for improved bio-oil quality, which enables efficient downstream hydroprocessing; C–C coupling helps increase the proportion of diesel/jet fuel range product. One potential benefit of fixed bed upgrading over fluidized bed upgrading is catalyst flexibility, providing greater control over chemistry and product composition. Since this study is based on future projections, the impacts of uncertainties in the underlying assumptions are quantified via sensitivity analysis. As a result, this analysis indicates that catalyst researchers should prioritize by: carbon efficiency > catalyst cost > catalyst lifetime, after initially testing for basic operational feasibility.},
doi = {10.1007/s11244-015-0500-z},
journal = {Topics in Catalysis},
number = 1,
volume = 59,
place = {United States},
year = {Tue Oct 06 00:00:00 EDT 2015},
month = {Tue Oct 06 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
Selective Hydrodeoxygenation of Biomass-Derived Oxygenates to Unsaturated Hydrocarbons using Molybdenum Carbide Catalysts
journal, April 2013
- Ren, Hui; Yu, Weiting; Salciccioli, Michael
- ChemSusChem, Vol. 6, Issue 5
Recent advances in heterogeneous catalysts for bio-oil upgrading via “ex situ catalytic fast pyrolysis”: catalyst development through the study of model compounds
journal, January 2014
- Ruddy, Daniel A.; Schaidle, Joshua A.; Ferrell III, Jack R.
- Green Chem., Vol. 16, Issue 2
Vapor phase hydrodeoxygenation of furfural to 2-methylfuran on molybdenum carbide catalysts
journal, January 2014
- Lee, Wen-Sheng; Wang, Zhenshu; Zheng, Weiqing
- Catalysis Science & Technology, Vol. 4, Issue 8
Catalytic hydrodeoxygenation
journal, June 2000
- Furimsky, Edward
- Applied Catalysis A: General, Vol. 199, Issue 2, p. 147-190
Historical Developments in Hydroprocessing Bio-oils
journal, May 2007
- Elliott, Douglas C.
- Energy & Fuels, Vol. 21, Issue 3, p. 1792-1815
Bio-oil Stabilization and Upgrading by Hot Gas Filtration
journal, May 2013
- Baldwin, Robert M.; Feik, Calvin J.
- Energy & Fuels, Vol. 27, Issue 6
Acetone condensation and selective hydrogenation to MIBK on Pd and Pt hydrotalcite-derived MgAl mixed oxide catalysts
journal, November 2005
- Nikolopoulos, A. A.; Jang, B. W. -L.; Spivey, J. J.
- Applied Catalysis A: General, Vol. 296, Issue 1
Insights into the catalytic activity and surface modification of MoO 3 during the hydrodeoxygenation of lignin-derived model compounds into aromatic hydrocarbons under low hydrogen pressures
journal, January 2014
- Prasomsri, Teerawit; Shetty, Manish; Murugappan, Karthick
- Energy Environ. Sci., Vol. 7, Issue 8
Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review
journal, May 2006
- Mohan, Dinesh; Pittman,, Charles U.; Steele, Philip H.
- Energy & Fuels, Vol. 20, Issue 3, p. 848-889
Fundamentals of Industrial Catalytic Processes
book, January 2005
- Bartholomew, Calvin H.; Farrauto, Robert J.
- John Wiley & Sons, Inc.
Kinetics and Mechanism of Ketonization of Acetic Acid on Ru/TiO2 Catalyst
journal, November 2013
- Pham, Tu N.; Shi, Dachuan; Resasco, Daniel E.
- Topics in Catalysis, Vol. 57, Issue 6-9
Selective catalytic hydroalkylation and deoxygenation of substituted phenols to bicycloalkanes
journal, April 2012
- Zhao, Chen; Camaioni, Donald M.; Lercher, Johannes A.
- Journal of Catalysis, Vol. 288
Direct catalytic upgrading of biomass pyrolysis vapors by a dual function Ru/TiO 2 catalyst
journal, February 2013
- Wan, Shaolong; Pham, Trung; Zhang, Sarah
- AIChE Journal, Vol. 59, Issue 7
Theoretical Investigation of the Reaction Mechanism of the Guaiacol Hydrogenation over a Pt(111) Catalyst
journal, March 2015
- Lu, Jianmin; Behtash, Sina; Mamun, Osman
- ACS Catalysis, Vol. 5, Issue 4
Cascade Reactions for the Continuous and Selective Production of Isobutene from Bioderived Acetic Acid Over Zinc-Zirconia Catalysts
journal, October 2014
- Crisci, Anthony J.; Dou, Herui; Prasomsri, Teerawit
- ACS Catalysis, Vol. 4, Issue 11
Renewable fuels via catalytic hydrodeoxygenation
journal, April 2011
- Choudhary, T. V.; Phillips, C. B.
- Applied Catalysis A: General, Vol. 397, Issue 1-2, p. 1-12
Studies of the synthesis of transition metal phosphides and their activity in the hydrodeoxygenation of a biofuel model compound
journal, October 2012
- Bui, Phuong; Cecilia, Juan Antonio; Oyama, S. Ted.
- Journal of Catalysis, Vol. 294
Progress in catalytic naphtha reforming process: A review
journal, September 2013
- Rahimpour, Mohammad Reza; Jafari, Mitra; Iranshahi, Davood
- Applied Energy, Vol. 109
Field-to-Fuel Performance Testing of Lignocellulosic Feedstocks: An Integrated Study of the Fast Pyrolysis–Hydrotreating Pathway
journal, April 2015
- Howe, Daniel; Westover, Tyler; Carpenter, Daniel
- Energy & Fuels, Vol. 29, Issue 5
Catalytic upgrading of biomass pyrolysis vapors using transition metal-modified ZSM-5 zeolite
journal, October 2012
- Iliopoulou, E. F.; Stefanidis, S. D.; Kalogiannis, K. G.
- Applied Catalysis B: Environmental, Vol. 127
Selective vapor-phase hydrodeoxygenation of anisole to benzene on molybdenum carbide catalysts
journal, November 2014
- Lee, Wen-Sheng; Wang, Zhenshu; Wu, Ryan J.
- Journal of Catalysis, Vol. 319
Recent Advances in Hydrotreating of Pyrolysis Bio-Oil and Its Oxygen-Containing Model Compounds
journal, April 2013
- Wang, Huamin; Male, Jonathan; Wang, Yong
- ACS Catalysis, Vol. 3, Issue 5
Catalytic upgrading pyrolysis vapors of Jatropha waste using metal promoted ZSM-5 catalysts: An analytical PY-GC/MS
journal, May 2014
- Vichaphund, Supawan; Aht-ong, Duangdao; Sricharoenchaikul, Viboon
- Renewable Energy, Vol. 65
Alkali Metal Poisoning of a CeO 2 –WO 3 Catalyst Used in the Selective Catalytic Reduction of NO x with NH 3 : an Experimental and Theoretical Study
journal, February 2012
- Peng, Yue; Li, Junhua; Chen, Liang
- Environmental Science & Technology, Vol. 46, Issue 5
Review of fast pyrolysis of biomass and product upgrading
journal, March 2012
- Bridgwater, A. V.
- Biomass and Bioenergy, Vol. 38, p. 68-94
Effect of metal–support interaction on the selective hydrodeoxygenation of anisole to aromatics over Ni-based catalysts
journal, February 2014
- Yang, Yongxing; Ochoa-Hernández, Cristina; de la Peña O'Shea, Víctor A.
- Applied Catalysis B: Environmental, Vol. 145
Hydrodeoxygenation and coupling of aqueous phenolics over bifunctional zeolite-supported metal catalysts
journal, January 2010
- Hong, Do-Young; Miller, Stephen J.; Agrawal, Pradeep K.
- Chem. Commun., Vol. 46, Issue 7
Sustainable recovery of nickel from spent hydrogenation catalyst: economics, emissions and wastes assessment
journal, March 2011
- Yang, Q. Z.; Qi, G. J.; Low, H. C.
- Journal of Cleaner Production, Vol. 19, Issue 4
Disproportionation and transalkylation of alkylbenzenes over zeolite catalysts
journal, May 1999
- Tsai, T.
- Applied Catalysis A: General, Vol. 181, Issue 2
Role of Keto Intermediates in the Hydrodeoxygenation of Phenol over Pd on Oxophilic Supports
journal, January 2015
- de Souza, Priscilla M.; Rabelo-Neto, Raimundo C.; Borges, Luiz E. P.
- ACS Catalysis, Vol. 5, Issue 2
Vapour-phase C–C coupling reactions of biomass-derived oxygenates over Pd/CeZrOx catalysts
journal, September 2009
- Kunkes, Edward L.; Gürbüz, Elif I.; Dumesic, James A.
- Journal of Catalysis, Vol. 266, Issue 2
A review on ex situ catalytic fast pyrolysis of biomass
journal, August 2014
- Wan, Shaolong; Wang, Yong
- Frontiers of Chemical Science and Engineering, Vol. 8, Issue 3
Ketonization of Carboxylic Acids: Mechanisms, Catalysts, and Implications for Biomass Conversion
journal, October 2013
- Pham, Tu N.; Sooknoi, Tawan; Crossley, Steven P.
- ACS Catalysis, Vol. 3, Issue 11
Hydrotreatment of pyrolysis oils from biomass: reactivity of the various categories of oxygenated compounds and preliminary techno-economical study
journal, May 1996
- Grange, P.; Laurent, E.; Maggi, R.
- Catalysis Today, Vol. 29, Issue 1-4
Review of C-C Coupling Reactions in Biomass Exploitation Processes
journal, December 2010
- F. Iliopoulou, Eleni
- Current Organic Synthesis, Vol. 7, Issue 6
Hydrodeoxygenation of guaiacol as model compound for pyrolysis oil on transition metal phosphide hydroprocessing catalysts
journal, January 2011
- Zhao, H. Y.; Li, D.; Bui, P.
- Applied Catalysis A: General, Vol. 391, Issue 1-2
Gas distribution in shallow packed beds
journal, October 1993
- Porter, Kenneth E.; Ali, Quasim H.; Hassan, Ahmed O.
- Industrial & Engineering Chemistry Research, Vol. 32, Issue 10
Conversion of Guaiacol over Supported Ru Catalysts
journal, June 2013
- Boonyasuwat, Sunya; Omotoso, Taiwo; Resasco, Daniel E.
- Catalysis Letters, Vol. 143, Issue 8
Effective hydrodeoxygenation of biomass-derived oxygenates into unsaturated hydrocarbons by MoO3 using low H2 pressures
journal, January 2013
- Prasomsri, Teerawit; Nimmanwudipong, Tarit; Román-Leshkov, Yuriy
- Energy & Environmental Science, Vol. 6, Issue 6, p. 1732-1738
Upgrading of lignin-derived bio-oils by catalytic hydrodeoxygenation
journal, January 2014
- Saidi, Majid; Samimi, Fereshteh; Karimipourfard, Dornaz
- Energy Environ. Sci., Vol. 7, Issue 1
Aqueous Phase Hydroalkylation and Hydrodeoxygenation of Phenol by Dual Functional Catalysts Comprised of Pd/C and H/La-BEA
journal, November 2012
- Zhao, Chen; Song, Wenji; Lercher, Johannes A.
- ACS Catalysis, Vol. 2, Issue 12
One-step synthesis of methyl isobutyl ketone from acetone and hydrogen over Pd/(Nb2O5/SiO2) catalysts
journal, January 2001
- Chen, Y. Z.; Liaw, B. J.; Tan, H. R.
- Applied Catalysis A: General, Vol. 205, Issue 1-2
Hydrodeoxygenation of model compounds and catalytic systems for pyrolysis bio-oils upgrading
journal, January 2012
- He, Zhong; Wang, Xianqin
- Catalysis for Sustainable Energy, Vol. 1
Performance of a catalytically activated ceramic hot gas filter for catalytic tar removal from biomass gasification gas
journal, May 2009
- Nacken, Manfred; Ma, Lina; Heidenreich, Steffen
- Applied Catalysis B: Environmental, Vol. 88, Issue 3-4
Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels: Fast Pyrolysis and Hydrotreating Bio-oil Pathway
report, November 2013
- Jones, Susanne; Meyer, Pimphan; Snowden-Swan, Lesley
- PNNL--23053
Biomass Feedstock and Conversion Supply System Design and Analysis
report, September 2014
- Jacobson, Jacob J.; Roni, Mohammad S.; Lamers, Patrick
Fundamentals of Industrial Catalytic Processes
book, January 2005
- Bartholomew, Calvin H.; Farrauto, Robert J.
- John Wiley & Sons, Inc.
Cover Picture: Upgrading Pyrolysis Oil over Ni/HZSM-5 by Cascade Reactions (Angew. Chem. Int. Ed. 24/2012)
journal, March 2012
- Zhao, Chen; Lercher, Johannes A.
- Angewandte Chemie International Edition, Vol. 51, Issue 24
Conversion of Guaiacol over Supported Ru Catalysts
journal, June 2013
- Boonyasuwat, Sunya; Omotoso, Taiwo; Resasco, Daniel E.
- Catalysis Letters, Vol. 143, Issue 8
Hydrotreatment of pyrolysis oils from biomass: reactivity of the various categories of oxygenated compounds and preliminary techno-economical study
journal, May 1996
- Grange, P.; Laurent, E.; Maggi, R.
- Catalysis Today, Vol. 29, Issue 1-4
Characterization and upgrading of bio-oils produced by rapid thermal processing
journal, January 1994
- Maggi, Rosanna; Delmon, Bernard
- Biomass and Bioenergy, Vol. 7, Issue 1-6
Review of fast pyrolysis of biomass and product upgrading
journal, March 2012
- Bridgwater, A. V.
- Biomass and Bioenergy, Vol. 38, p. 68-94
Field-to-Fuel Performance Testing of Lignocellulosic Feedstocks: An Integrated Study of the Fast Pyrolysis–Hydrotreating Pathway
journal, April 2015
- Howe, Daniel; Westover, Tyler; Carpenter, Daniel
- Energy & Fuels, Vol. 29, Issue 5
Cascade Reactions for the Continuous and Selective Production of Isobutene from Bioderived Acetic Acid Over Zinc-Zirconia Catalysts
journal, October 2014
- Crisci, Anthony J.; Dou, Herui; Prasomsri, Teerawit
- ACS Catalysis, Vol. 4, Issue 11
Bio-oil Stabilization and Upgrading by Hot Gas Filtration
journal, May 2013
- Baldwin, Robert M.; Feik, Calvin J.
- Energy & Fuels, Vol. 27, Issue 6
Review of C-C Coupling Reactions in Biomass Exploitation Processes
journal, December 2010
- F. Iliopoulou, Eleni
- Current Organic Synthesis, Vol. 7, Issue 6
Works referencing / citing this record:
Synthesis of α-MoC 1− x Nanoparticles with a Surface-Modified SBA-15 Hard Template: Determination of Structure-Function Relationships in Acetic Acid Deoxygenation
journal, June 2016
- Baddour, Frederick G.; Nash, Connor P.; Schaidle, Joshua A.
- Angewandte Chemie International Edition, Vol. 55, Issue 31
Pulsed laser ablated zeolite nanoparticles: A novel nano‐catalyst for the synthesis of 1,8‐dioxo‐octahydroxanthene and N ‐aryl‐1,8‐dioxodecahydroacridine with molecular docking validation
journal, December 2019
- Abdelghany, A. M.; Menazea, A. A.; Abd‐El‐Maksoud, Mansoura A.
- Applied Organometallic Chemistry, Vol. 34, Issue 2
Techno‐economic comparative assessment of novel lignin depolymerization routes to bio‐based aromatics
journal, April 2019
- Vural Gursel, Iris; Dijkstra, Jan W.; Huijgen, Wouter J. J.
- Biofuels, Bioproducts and Biorefining, Vol. 13, Issue 4
A comparative techno‐economic assessment of three bio‐oil upgrading routes for aviation biofuel production
journal, July 2019
- Michailos, Stavros; Bridgwater, Anthony
- International Journal of Energy Research
Lowering greenhouse gas (GHG) emissions: techno‐economic analysis of biomass conversion to biofuels and value‐added chemicals
journal, May 2019
- Sharma, Anita; Jakhete, Akshay; Sharma, Abhishek
- Greenhouse Gases: Science and Technology, Vol. 9, Issue 3
Advancing catalytic fast pyrolysis through integrated multiscale modeling and experimentation: Challenges, progress, and perspectives
journal, April 2018
- Ciesielski, Peter N.; Pecha, M. Brennan; Bharadwaj, Vivek S.
- Wiley Interdisciplinary Reviews: Energy and Environment, Vol. 7, Issue 4
Acetic acid hydrodeoxygenation on molybdenum carbide catalysts
journal, January 2018
- Kumar, Anurag; Phadke, Sohan; Bhan, Aditya
- Catalysis Science & Technology, Vol. 8, Issue 11
Synergistic effect of Mo–W carbides on selective hydrodeoxygenation of guaiacol to oxygen-free aromatic hydrocarbons
journal, January 2019
- Tran, Chi-Cong; Han, Yinglei; Garcia-Perez, Manuel
- Catalysis Science & Technology, Vol. 9, Issue 6
Valorization of aqueous waste streams from thermochemical biorefineries
journal, January 2019
- Wilson, A. Nolan; Dutta, Abhijit; Black, Brenna A.
- Green Chemistry, Vol. 21, Issue 15
A review of thermochemical upgrading of pyrolysis bio‐oil: Techno‐economic analysis, life cycle assessment, and technology readiness
journal, November 2019
- Sorunmu, Yetunde; Billen, Pieter; Spatari, Sabrina
- GCB Bioenergy, Vol. 12, Issue 1
Synthesis of α-MoC 1− x Nanoparticles with a Surface-Modified SBA-15 Hard Template: Determination of Structure-Function Relationships in Acetic Acid Deoxygenation
journal, June 2016
- Baddour, Frederick G.; Nash, Connor P.; Schaidle, Joshua A.
- Angewandte Chemie, Vol. 128, Issue 31