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Title: Unexpected formal insertion of CO 2 into the C-Si bonds of a zinc compound

Abstract

Reaction of [κ 2-PR 2C(SiMe 3)Py] 2Zn (R = Ph, 2a; iPr, 2b) with CO 2 affords the products of formal insertion at the C–Si bond, [κ 2-PR 2CC(O)O(SiMe 3)Py] 2Zn (R = Ph, 3a; iPr, 3b). Insertion product 3b was structurally characterized. As a result, the reaction appears to be a stepwise insertion and rearrangement of CO 2 based on kinetic data.

Authors:
 [1];  [2];  [2];  [2];  [2]
  1. Univ. of New Mexico, Albuquerque, NM (United States); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
  2. Univ. of Vermont, Burlington, VT (United States)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
National Science Foundation (NSF)
OSTI Identifier:
1235362
Report Number(s):
SAND-2015-7532J
Journal ID: ISSN 1359-7345; CHCOFS; 603475
Grant/Contract Number:  
AC04-94AL85000
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 51; Journal Issue: 87; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Kemp, Richard A., McGrew, Genette I., Khatri, Pathik A., Geiger, William E., and Waterman, Rory. Unexpected formal insertion of CO2 into the C-Si bonds of a zinc compound. United States: N. p., 2015. Web. doi:10.1039/C5CC06910F.
Kemp, Richard A., McGrew, Genette I., Khatri, Pathik A., Geiger, William E., & Waterman, Rory. Unexpected formal insertion of CO2 into the C-Si bonds of a zinc compound. United States. doi:10.1039/C5CC06910F.
Kemp, Richard A., McGrew, Genette I., Khatri, Pathik A., Geiger, William E., and Waterman, Rory. Tue . "Unexpected formal insertion of CO2 into the C-Si bonds of a zinc compound". United States. doi:10.1039/C5CC06910F. https://www.osti.gov/servlets/purl/1235362.
@article{osti_1235362,
title = {Unexpected formal insertion of CO2 into the C-Si bonds of a zinc compound},
author = {Kemp, Richard A. and McGrew, Genette I. and Khatri, Pathik A. and Geiger, William E. and Waterman, Rory},
abstractNote = {Reaction of [κ2-PR2C(SiMe3)Py]2Zn (R = Ph, 2a; iPr, 2b) with CO2 affords the products of formal insertion at the C–Si bond, [κ2-PR2CC(O)O(SiMe3)Py]2Zn (R = Ph, 3a; iPr, 3b). Insertion product 3b was structurally characterized. As a result, the reaction appears to be a stepwise insertion and rearrangement of CO2 based on kinetic data.},
doi = {10.1039/C5CC06910F},
journal = {ChemComm},
number = 87,
volume = 51,
place = {United States},
year = {2015},
month = {9}
}

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Cited by: 5 works
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Works referencing / citing this record:

CCDC 1418439: Experimental Crystal Structure Determination: FUXLAN : bis(2-((Diphenylphosphoranylidene)(trimethylsilyl)methyl)pyridine)-zinc
dataset, August 2015

  • McGrew, Genette; Khatri, Pathik; Geiger, William
  • Cambridge Structural Database (CSD)
  • DOI: 10.5517/cc1jm038

CCDC 1418440: Experimental Crystal Structure Determination: FUXLER : bis(Trimethylsilyl (diisopropylphosphoranylidene)(pyridin-2-yl)acetate)-zinc
dataset, August 2015

  • McGrew, Genette; Khatri, Pathik; Geiger, William
  • Cambridge Structural Database (CSD)
  • DOI: 10.5517/cc1jm049