Catalyst synthesis and evaluation using an integrated atomic layer deposition synthesis–catalysis testing tool
Abstract
An integrated atomic layer deposition-catalysis (I-ALD-CAT) tool was developed, combining an ALD manifold with a plug-flow reactor system for the synthesis of supported catalytic materials by ALD and immediate evaluation of catalyst reactivity using gas-phase probe reactions. The I-ALD-CAT system can deliver gaseous reagents comprised of 12 different metal ALD precursors, 4 oxidizing or reducing agents, and 4 catalytic reaction feeds to either of the two plug-flow reactors. The system can employ reactor pressures and temperatures in the range of 10-3 to 1 bar and 300–1000 K, respectively. Furthermore, the instrument is also equipped with a gas chromatograph and a mass spectrometer unit for the detection and quantification of volatile species from ALD and catalytic reactions. In this report, we demonstrate the use of the I-ALD-CAT tool for the ALD of platinum active sites and Al2O3 overcoats, and evaluation of catalyst propylene hydrogenation activity.
- Authors:
-
- Argonne National Lab. (ANL), Lemont, IL (United States)
- Argonne National Lab. (ANL), Lemont, IL (United States); Univ. of Illinois, Chicago, IL (United States)
- Arradiance Inc., Sudbury, MA (United States)
- Argonne National Lab. (ANL), Lemont, IL (United States); Illinois Inst. of Technology, Chicago, IL (United States)
- Argonne National Lab. (ANL), Lemont, IL (United States); Northwestern Univ., Evanston, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division
- OSTI Identifier:
- 1391821
- Alternate Identifier(s):
- OSTI ID: 1229634
- Grant/Contract Number:
- AC02-06CH11357; AC-02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Review of Scientific Instruments
- Additional Journal Information:
- Journal Volume: 86; Journal Issue: 8; Journal ID: ISSN 0034-6748
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 47 OTHER INSTRUMENTATION
Citation Formats
Camacho-Bunquin, Jeffrey, Shou, Heng, Aich, Payoli, Beaulieu, David R., Klotzsch, Helmut, Bachman, Stephen, Marshall, Christopher L., Hock, Adam, and Stair, Peter. Catalyst synthesis and evaluation using an integrated atomic layer deposition synthesis–catalysis testing tool. United States: N. p., 2015.
Web. doi:10.1063/1.4928614.
Camacho-Bunquin, Jeffrey, Shou, Heng, Aich, Payoli, Beaulieu, David R., Klotzsch, Helmut, Bachman, Stephen, Marshall, Christopher L., Hock, Adam, & Stair, Peter. Catalyst synthesis and evaluation using an integrated atomic layer deposition synthesis–catalysis testing tool. United States. https://doi.org/10.1063/1.4928614
Camacho-Bunquin, Jeffrey, Shou, Heng, Aich, Payoli, Beaulieu, David R., Klotzsch, Helmut, Bachman, Stephen, Marshall, Christopher L., Hock, Adam, and Stair, Peter. Mon .
"Catalyst synthesis and evaluation using an integrated atomic layer deposition synthesis–catalysis testing tool". United States. https://doi.org/10.1063/1.4928614. https://www.osti.gov/servlets/purl/1391821.
@article{osti_1391821,
title = {Catalyst synthesis and evaluation using an integrated atomic layer deposition synthesis–catalysis testing tool},
author = {Camacho-Bunquin, Jeffrey and Shou, Heng and Aich, Payoli and Beaulieu, David R. and Klotzsch, Helmut and Bachman, Stephen and Marshall, Christopher L. and Hock, Adam and Stair, Peter},
abstractNote = {An integrated atomic layer deposition-catalysis (I-ALD-CAT) tool was developed, combining an ALD manifold with a plug-flow reactor system for the synthesis of supported catalytic materials by ALD and immediate evaluation of catalyst reactivity using gas-phase probe reactions. The I-ALD-CAT system can deliver gaseous reagents comprised of 12 different metal ALD precursors, 4 oxidizing or reducing agents, and 4 catalytic reaction feeds to either of the two plug-flow reactors. The system can employ reactor pressures and temperatures in the range of 10-3 to 1 bar and 300–1000 K, respectively. Furthermore, the instrument is also equipped with a gas chromatograph and a mass spectrometer unit for the detection and quantification of volatile species from ALD and catalytic reactions. In this report, we demonstrate the use of the I-ALD-CAT tool for the ALD of platinum active sites and Al2O3 overcoats, and evaluation of catalyst propylene hydrogenation activity.},
doi = {10.1063/1.4928614},
journal = {Review of Scientific Instruments},
number = 8,
volume = 86,
place = {United States},
year = {Mon Aug 24 00:00:00 EDT 2015},
month = {Mon Aug 24 00:00:00 EDT 2015}
}
Web of Science
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