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Title: Communication: The simplified generalized entropy theory of glass-formation in polymer melts

Authors:
 [1]
  1. James Franck Institute and Department of Chemistry, University of Chicago, Chicago, Illinois 60615, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1229570
Grant/Contract Number:  
SC0008631
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
The Journal of Chemical Physics
Additional Journal Information:
Journal Name: The Journal of Chemical Physics Journal Volume: 143 Journal Issue: 5; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics
Country of Publication:
United States
Language:
English

Citation Formats

Freed, Karl F. Communication: The simplified generalized entropy theory of glass-formation in polymer melts. United States: N. p., 2015. Web. doi:10.1063/1.4927766.
Freed, Karl F. Communication: The simplified generalized entropy theory of glass-formation in polymer melts. United States. https://doi.org/10.1063/1.4927766
Freed, Karl F. Tue . "Communication: The simplified generalized entropy theory of glass-formation in polymer melts". United States. https://doi.org/10.1063/1.4927766.
@article{osti_1229570,
title = {Communication: The simplified generalized entropy theory of glass-formation in polymer melts},
author = {Freed, Karl F.},
abstractNote = {},
doi = {10.1063/1.4927766},
journal = {The Journal of Chemical Physics},
number = 5,
volume = 143,
place = {United States},
year = {Tue Aug 04 00:00:00 EDT 2015},
month = {Tue Aug 04 00:00:00 EDT 2015}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1063/1.4927766

Citation Metrics:
Cited by: 3 works
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Works referenced in this record:

Lattice Cluster Theory of Multicomponent Polymer Systems: Chain Semiflexibility and Specific Interactions
book, January 2007


Lattice models of polymer solutions: Monomers occupying several lattice sites
journal, December 1987

  • Nemirovsky, A. M.; Bawendi, M. G.; Freed, Karl F.
  • The Journal of Chemical Physics, Vol. 87, Issue 12
  • DOI: 10.1063/1.453320

Lattice cluster theory for dense, thin polymer films
journal, April 2015

  • Freed, Karl F.
  • The Journal of Chemical Physics, Vol. 142, Issue 13
  • DOI: 10.1063/1.4916383

Rheology of the Lower Critical Ordering Transition
journal, July 1995

  • Karis, T. E.; Russell, T. P.; Gallot, Y.
  • Macromolecules, Vol. 28, Issue 4
  • DOI: 10.1021/ma00108a047

Advances in the generalized entropy theory of glass-formation in polymer melts
journal, December 2014

  • Dudowicz, Jacek; Douglas, Jack F.; Freed, Karl F.
  • The Journal of Chemical Physics, Vol. 141, Issue 23
  • DOI: 10.1063/1.4903842

Two glass transitions in miscible polymer blends?
journal, June 2014

  • Dudowicz, Jacek; Douglas, Jack F.; Freed, Karl F.
  • The Journal of Chemical Physics, Vol. 140, Issue 24
  • DOI: 10.1063/1.4884123

Extension of lattice cluster theory to strongly interacting, self-assembling polymeric systems
journal, February 2009

  • Freed, Karl F.
  • The Journal of Chemical Physics, Vol. 130, Issue 6
  • DOI: 10.1063/1.3078516

Fragility of Glass-Forming Polymer Liquids
journal, November 2005

  • Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 45
  • DOI: 10.1021/jp053693k

Influence of Cohesive Energy and Chain Stiffness on Polymer Glass Formation
journal, September 2014

  • Xu, Wen-Sheng; Freed, Karl F.
  • Macromolecules, Vol. 47, Issue 19
  • DOI: 10.1021/ma501581u

Structure and Dynamics of Poly( n -decyl methacrylate) below and above the Glass Transition
journal, October 1998

  • Floudas, G.; Štepánek, P.
  • Macromolecules, Vol. 31, Issue 20
  • DOI: 10.1021/ma9804601

Communication: Towards first principles theory of relaxation in supercooled liquids formulated in terms of cooperative motion
journal, October 2014

  • Freed, Karl F.
  • The Journal of Chemical Physics, Vol. 141, Issue 14
  • DOI: 10.1063/1.4897973

Dynamics of glass-forming liquids. V. On the link between molecular dynamics and configurational entropy
journal, June 1998

  • Richert, R.; Angell, C. A.
  • The Journal of Chemical Physics, Vol. 108, Issue 21
  • DOI: 10.1063/1.476348

The relationship of dynamical heterogeneity to the Adam-Gibbs and random first-order transition theories of glass formation
journal, March 2013

  • Starr, Francis W.; Douglas, Jack F.; Sastry, Srikanth
  • The Journal of Chemical Physics, Vol. 138, Issue 12
  • DOI: 10.1063/1.4790138

Stringlike Cooperative Motion in a Supercooled Liquid
journal, March 1998


Concentration fluctuations in miscible polymer blends: Influence of temperature and chain rigidity
journal, May 2014

  • Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F.
  • The Journal of Chemical Physics, Vol. 140, Issue 19
  • DOI: 10.1063/1.4875345

The Glass Transition Temperature of Polymer Melts
journal, November 2005

  • Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 45
  • DOI: 10.1021/jp0523266

Entropy theory of polymer glass formation revisited. I. General formulation
journal, February 2006

  • Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F.
  • The Journal of Chemical Physics, Vol. 124, Issue 6
  • DOI: 10.1063/1.2166391

The meaning of the “universal” WLF parameters of glass-forming polymer liquids
journal, January 2015

  • Dudowicz, Jacek; Douglas, Jack F.; Freed, Karl F.
  • The Journal of Chemical Physics, Vol. 142, Issue 1
  • DOI: 10.1063/1.4905216

The Descent into Glass Formation in Polymer Fluids
journal, March 2011

  • Freed, Karl F.
  • Accounts of Chemical Research, Vol. 44, Issue 3
  • DOI: 10.1021/ar100122w

Influence of Monomer Molecular Structure on the Miscibility of Polymer Blends
book, January 2005

  • Freed, Karl F.; Dudowicz, Jacek
  • Phase Behaviour of Polymer Blends
  • DOI: 10.1007/b135883

Direct computation of characteristic temperatures and relaxation times for glass-forming polymer liquids
journal, September 2005

  • Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F.
  • The Journal of Chemical Physics, Vol. 123, Issue 11
  • DOI: 10.1063/1.2035087

Does equilibrium polymerization describe the dynamic heterogeneity of glass-forming liquids?
journal, October 2006

  • Douglas, Jack F.; Dudowicz, Jacek; Freed, Karl F.
  • The Journal of Chemical Physics, Vol. 125, Issue 14
  • DOI: 10.1063/1.2356863

Influence of molecular weight and degree of crosslinking on the specific volume and glass temperature of polymers
journal, February 1955


String model for the dynamics of glass-forming liquids
journal, May 2014

  • Pazmiño Betancourt, Beatriz A.; Douglas, Jack F.; Starr, Francis W.
  • The Journal of Chemical Physics, Vol. 140, Issue 20
  • DOI: 10.1063/1.4878502

On the Temperature Dependence of Cooperative Relaxation Properties in Glass‐Forming Liquids
journal, July 1965

  • Adam, Gerold; Gibbs, Julian H.
  • The Journal of Chemical Physics, Vol. 43, Issue 1
  • DOI: 10.1063/1.1696442

A lower critical ordering transition in a diblock copolymer melt
journal, April 1994

  • Russell, T. P.; Karis, T. E.; Gallot, Y.
  • Nature, Vol. 368, Issue 6473
  • DOI: 10.1038/368729a0

Application of the entropy theory of glass formation to poly(α-olefins)
journal, September 2009

  • Stukalin, Evgeny B.; Douglas, Jack F.; Freed, Karl F.
  • The Journal of Chemical Physics, Vol. 131, Issue 11
  • DOI: 10.1063/1.3216109

Lattice cluster theory for polymer melts with specific interactions
journal, July 2014

  • Xu, Wen-Sheng; Freed, Karl F.
  • The Journal of Chemical Physics, Vol. 141, Issue 4
  • DOI: 10.1063/1.4890959

Generalized Entropy Theory of Glass Formation in Polymer Melts with Specific Interactions
journal, March 2015


Nature of the Glass Transition and the Glassy State
journal, March 1958

  • Gibbs, Julian H.; DiMarzio, Edmund A.
  • The Journal of Chemical Physics, Vol. 28, Issue 3
  • DOI: 10.1063/1.1744141