PIM-1 as a Solution-Processable “Molecular Basket” for CO 2 Capture from Dilute Sources
Abstract
Here, rising atmospheric CO2 levels have triggered recent research into the science of amine materials supported on hard, porous materials such as mesoporous silica or alumina. While such materials can give high CO2 uptakes and good sorption kinetics, they are difficult to utilize in practical applications due to difficulty in contacting large volumes of CO2-laden gases with powder materials without significant pressure drops or sorbent attrition. Here, we describe a simple approach based on the impregnation of a permanently microporous polymer, PIM-1, with poly(ethylene imine) (PEI), removing the need for use of the hard oxide. PEI/PIM-1 composites demonstrate comparable performance to more traditionally studied oxide sorbents, with the benefit that PIM-1 is soluble in common solvents, making it eminently more viable for processing into morphologies that can facilitate heat and mass transfer and fabrication into low pressure drop contactors. In addition to adsorption studies performed on a variety of PEI/PIM-1 architectures, spin diffusion NMR studies were performed to suggest that PEI is well-dispersed within the PIM-1, allowing for rapid CO2 adsorption.
- Authors:
-
- School of Chemical & Biomolecular Engineering and ‡School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332, United States
- Publication Date:
- Research Org.:
- Georgia Institute of Technology, Atlanta, GA (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1228285
- Alternate Identifier(s):
- OSTI ID: 1436497
- Grant/Contract Number:
- SC0012577
- Resource Type:
- Published Article
- Journal Name:
- ACS Macro Letters
- Additional Journal Information:
- Journal Name: ACS Macro Letters Journal Volume: 4 Journal Issue: 12; Journal ID: ISSN 2161-1653
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Pang, Simon H., Jue, Melinda L., Leisen, Johannes, Jones, Christopher W., and Lively, Ryan P. PIM-1 as a Solution-Processable “Molecular Basket” for CO 2 Capture from Dilute Sources. United States: N. p., 2015.
Web. doi:10.1021/acsmacrolett.5b00775.
Pang, Simon H., Jue, Melinda L., Leisen, Johannes, Jones, Christopher W., & Lively, Ryan P. PIM-1 as a Solution-Processable “Molecular Basket” for CO 2 Capture from Dilute Sources. United States. https://doi.org/10.1021/acsmacrolett.5b00775
Pang, Simon H., Jue, Melinda L., Leisen, Johannes, Jones, Christopher W., and Lively, Ryan P. Mon .
"PIM-1 as a Solution-Processable “Molecular Basket” for CO 2 Capture from Dilute Sources". United States. https://doi.org/10.1021/acsmacrolett.5b00775.
@article{osti_1228285,
title = {PIM-1 as a Solution-Processable “Molecular Basket” for CO 2 Capture from Dilute Sources},
author = {Pang, Simon H. and Jue, Melinda L. and Leisen, Johannes and Jones, Christopher W. and Lively, Ryan P.},
abstractNote = {Here, rising atmospheric CO2 levels have triggered recent research into the science of amine materials supported on hard, porous materials such as mesoporous silica or alumina. While such materials can give high CO2 uptakes and good sorption kinetics, they are difficult to utilize in practical applications due to difficulty in contacting large volumes of CO2-laden gases with powder materials without significant pressure drops or sorbent attrition. Here, we describe a simple approach based on the impregnation of a permanently microporous polymer, PIM-1, with poly(ethylene imine) (PEI), removing the need for use of the hard oxide. PEI/PIM-1 composites demonstrate comparable performance to more traditionally studied oxide sorbents, with the benefit that PIM-1 is soluble in common solvents, making it eminently more viable for processing into morphologies that can facilitate heat and mass transfer and fabrication into low pressure drop contactors. In addition to adsorption studies performed on a variety of PEI/PIM-1 architectures, spin diffusion NMR studies were performed to suggest that PEI is well-dispersed within the PIM-1, allowing for rapid CO2 adsorption.},
doi = {10.1021/acsmacrolett.5b00775},
journal = {ACS Macro Letters},
number = 12,
volume = 4,
place = {United States},
year = {Mon Dec 07 00:00:00 EST 2015},
month = {Mon Dec 07 00:00:00 EST 2015}
}
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Works referenced in this record:
Gas sorption and permeation in PIM-1
journal, April 2013
- Li, Pei; Chung, T. S.; Paul, D. R.
- Journal of Membrane Science, Vol. 432
Polymer of Intrinsic Microporosity Incorporating Thioamide Functionality: Preparation and Gas Transport Properties
journal, August 2011
- Mason, Christopher R.; Maynard-Atem, Louise; Al-Harbi, Nasser M.
- Macromolecules, Vol. 44, Issue 16
Separation of CO2 from air by temperature-vacuum swing adsorption using diamine-functionalized silica gel
journal, January 2011
- Wurzbacher, Jan Andre; Gebald, Christoph; Steinfeld, Aldo
- Energy & Environmental Science, Vol. 4, Issue 9
Dynamic CO 2 adsorption performance of internally cooled silica-supported poly(ethylenimine) hollow fiber sorbents
journal, September 2014
- Fan, Yanfang; Labreche, Ying; Lively, Ryan P.
- AIChE Journal, Vol. 60, Issue 11
Carbon Dioxide Capture from the Air Using a Polyamine Based Regenerable Solid Adsorbent
journal, December 2011
- Goeppert, Alain; Czaun, Miklos; May, Robert B.
- Journal of the American Chemical Society, Vol. 133, Issue 50, p. 20164-20167
Towards Chiral Microporous Soluble Polymers-Binaphthalene-Based Polyimides: Towards Chiral Microporous Soluble …
journal, January 2011
- Ritter, Nicola; Senkovska, Irena; Kaskel, Stefan
- Macromolecular Rapid Communications, Vol. 32, Issue 5
Atomistic packing model and free volume distribution of a polymer with intrinsic microporosity (PIM-1)
journal, June 2008
- Heuchel, Matthias; Fritsch, Detlev; Budd, Peter M.
- Journal of Membrane Science, Vol. 318, Issue 1-2
Investigation of Porous Silica Supported Mixed-Amine Sorbents for Post-Combustion CO 2 Capture
journal, April 2012
- Fauth, D. J.; Gray, M. L.; Pennline, H. W.
- Energy & Fuels, Vol. 26, Issue 4
Absorption of Carbon Dioxide into Aqueous Blends of Diethanolamine and Methyldiethanolamine
journal, November 2000
- Rinker, Edward B.; Ashour, Sami S.; Sandall, Orville C.
- Industrial & Engineering Chemistry Research, Vol. 39, Issue 11
Preparation and characterization of novel CO2 “molecular basket” adsorbents based on polymer-modified mesoporous molecular sieve MCM-41
journal, August 2003
- Xu, Xiaochun; Song, Chunshan; Andrésen, John M.
- Microporous and Mesoporous Materials, Vol. 62, Issue 1-2
Effect of Nonsolvent Treatments on the Microstructure of PIM-1
journal, August 2015
- Jue, Melinda L.; McKay, Craig S.; McCool, Benjamin A.
- Macromolecules, Vol. 48, Issue 16
Enhanced CO 2 Adsorption over Polymeric Amines Supported on Heteroatom-Incorporated SBA-15 Silica: Impact of Heteroatom Type and Loading on Sorbent Structure and Adsorption Performance
journal, November 2012
- Kuwahara, Yasutaka; Kang, Dun-Yen; Copeland, John R.
- Chemistry - A European Journal, Vol. 18, Issue 52
Aminosilanes Grafted to Basic Alumina as CO 2 Adsorbents-Role of Grafting Conditions on CO 2 Adsorption Properties
journal, September 2014
- Bali, Sumit; Leisen, Johannes; Foo, Guo Shiou
- ChemSusChem, Vol. 7, Issue 11
Novel Polyethylenimine-Modified Mesoporous Molecular Sieve of MCM-41 Type as High-Capacity Adsorbent for CO2 Capture
journal, November 2002
- Xu, Xiaochun; Song, Chunshan; Andresen, John M.
- Energy & Fuels, Vol. 16, Issue 6, p. 1463-1469
Highly Stable Porous Polymer Networks with Exceptionally High Gas-Uptake Capacities
journal, July 2011
- Yuan, Daqiang; Lu, Weigang; Zhao, Dan
- Advanced Materials, Vol. 23, Issue 32
Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic nanoporous materials
journal, January 2004
- Budd, Peter M.; Ghanem, Bader S.; Makhseed, Saad
- Chemical Communications, Issue 2
Polyethylenimine-Impregnated Mesoporous Silica: Effect of Amine Loading and Surface Alkyl Chains on CO 2 Adsorption
journal, October 2011
- Heydari-Gorji, Aliakbar; Belmabkhout, Youssef; Sayari, Abdelhamid
- Langmuir, Vol. 27, Issue 20
Probing the Role of Zr Addition versus Textural Properties in Enhancement of CO 2 Adsorption Performance in Silica/PEI Composite Sorbents
journal, August 2015
- Sakwa-Novak, Miles A.; Holewinski, Adam; Hoyt, Caroline B.
- Langmuir, Vol. 31, Issue 34
Oxidative Stability of Amino Polymer–Alumina Hybrid Adsorbents for Carbon Dioxide Capture
journal, March 2013
- Bali, Sumit; Chen, Thomas T.; Chaikittisilp, Watcharop
- Energy & Fuels, Vol. 27, Issue 3
Thermal, Oxidative and CO 2 Induced Degradation of Primary Amines Used for CO 2 Capture: Effect of Alkyl Linker on Stability
journal, May 2014
- Didas, Stephanie A.; Zhu, Rongshun; Brunelli, Nicholas A.
- The Journal of Physical Chemistry C, Vol. 118, Issue 23
Polyethyleneimine–nano silica composites: a low-cost and promising adsorbent for CO 2 capture
journal, January 2015
- Li, Kaimin; Jiang, Jianguo; Tian, Sicong
- Journal of Materials Chemistry A, Vol. 3, Issue 5
Solution-Processed, Organophilic Membrane Derived from a Polymer of Intrinsic Microporosity
journal, March 2004
- Budd, P. M.; Elabas, E. S.; Ghanem, B. S.
- Advanced Materials, Vol. 16, Issue 5, p. 456-459
Applications of Pore-Expanded Mesoporous Silicas. 3. Triamine Silane Grafting for Enhanced CO 2 Adsorption
journal, April 2006
- Harlick, Peter J. E.; Sayari, Abdelhamid
- Industrial & Engineering Chemistry Research, Vol. 45, Issue 9
Porous, Crystalline, Covalent Organic Frameworks
journal, November 2005
- Côté, Adrien P.; Benin, Annabelle I.; Ockwig, Nathan W.
- Science, Vol. 310, Issue 5751, p. 1166-1170
Thermal stability of polyethylenimine based carbon dioxide adsorbents and its influence on selection of regeneration strategies
journal, December 2008
- Drage, T. C.; Arenillas, A.; Smith, K. M.
- Microporous and Mesoporous Materials, Vol. 116, Issue 1-3
CO2 capture on polyethylenimine-impregnated hydrophobic mesoporous silica: Experimental and kinetic modeling
journal, September 2011
- Heydari-Gorji, Aliakbar; Sayari, Abdelhamid
- Chemical Engineering Journal, Vol. 173, Issue 1
Dramatic Enhancement of CO 2 Uptake by Poly(ethyleneimine) Using Zirconosilicate Supports
journal, June 2012
- Kuwahara, Yasutaka; Kang, Dun-Yen; Copeland, John R.
- Journal of the American Chemical Society, Vol. 134, Issue 26
Amine-Tethered Solid Adsorbents Coupling High Adsorption Capacity and Regenerability for CO2 Capture From Ambient Air
journal, May 2011
- Choi, Sunho; Gray, McMahan L.; Jones, Christopher W.
- ChemSusChem, Vol. 4, Issue 5
Synthesis–Structure–Property Relationships for Hyperbranched Aminosilica CO 2 Adsorbents
journal, December 2009
- Drese, Jeffrey H.; Choi, Sunho; Lively, Ryan P.
- Advanced Functional Materials, Vol. 19, Issue 23
Linking CO 2 Sorption Performance to Polymer Morphology in Aminopolymer/Silica Composites through Neutron Scattering
journal, September 2015
- Holewinski, Adam; Sakwa-Novak, Miles A.; Jones, Christopher W.
- Journal of the American Chemical Society, Vol. 137, Issue 36
Poly(allylamine)–Mesoporous Silica Composite Materials for CO 2 Capture from Simulated Flue Gas or Ambient Air
journal, December 2011
- Chaikittisilp, Watcharop; Khunsupat, Ratayakorn; Chen, Thomas T.
- Industrial & Engineering Chemistry Research, Vol. 50, Issue 24
Poly(amide-imide)/Silica Supported PEI Hollow Fiber Sorbents for Postcombustion CO 2 Capture by RTSA
journal, October 2014
- Labreche, Ying; Fan, Yanfang; Rezaei, Fateme
- ACS Applied Materials & Interfaces, Vol. 6, Issue 21
Gas separation membranes from polymers of intrinsic microporosity
journal, April 2005
- Budd, P.; Msayib, K.; Tattershall, C.
- Journal of Membrane Science, Vol. 251, Issue 1-2
CO2 adsorption on branched polyethyleneimine-impregnated mesoporous silica SBA-15
journal, June 2010
- Sanz, R.; Calleja, G.; Arencibia, A.
- Applied Surface Science, Vol. 256, Issue 17
Evolution of Crystallinity, Chain Mobility, and Crystallite Size during Polymer Crystallization
journal, October 2004
- Leisen, Johannes; Beckham, Haskell W.; Sharaf, Mohammed A.
- Macromolecules, Vol. 37, Issue 21
Adsorptive removal of carbon dioxide using polyethyleneimine-loaded mesoporous silica materials
journal, August 2008
- Son, Won-Jin; Choi, Jung-Sik; Ahn, Wha-Seung
- Microporous and Mesoporous Materials, Vol. 113, Issue 1-3
Application of Amine-Tethered Solid Sorbents for Direct CO 2 Capture from the Ambient Air
journal, March 2011
- Choi, Sunho; Drese, Jeffrey H.; Eisenberger, Peter M.
- Environmental Science & Technology, Vol. 45, Issue 6
Role of Amine Structure on Carbon Dioxide Adsorption from Ultradilute Gas Streams such as Ambient Air
journal, July 2012
- Didas, Stephanie A.; Kulkarni, Ambarish R.; Sholl, David S.
- ChemSusChem, Vol. 5, Issue 10, p. 2058-2064
Mesoporous Alumina-Supported Amines as Potential Steam-Stable Adsorbents for Capturing CO 2 from Simulated Flue Gas and Ambient Air
journal, November 2011
- Chaikittisilp, Watcharop; Kim, Hyung-Ju; Jones, Christopher W.
- Energy & Fuels, Vol. 25, Issue 11
Thermal, Oxidative, and CO 2 -Induced Degradation of Supported Polyethylenimine Adsorbents
journal, May 2012
- Heydari-Gorji, Aliakbar; Sayari, Abdelhamid
- Industrial & Engineering Chemistry Research, Vol. 51, Issue 19
Nanoporous Organic Polymer/Cage Composite Membranes
journal, December 2012
- Bushell, Alexandra F.; Budd, Peter M.; Attfield, Martin P.
- Angewandte Chemie International Edition, Vol. 52, Issue 4
Towards Polymer-Based Hydrogen Storage Materials: Engineering Ultramicroporous Cavities within Polymers of Intrinsic Microporosity
journal, March 2006
- McKeown, Neil B.; Gahnem, Bader; Msayib, Kadhum J.
- Angewandte Chemie International Edition, Vol. 45, Issue 11
Post-spinning infusion of poly(ethyleneimine) into polymer/silica hollow fiber sorbents for carbon dioxide capture
journal, April 2013
- Labreche, Ying; Lively, Ryan P.; Rezaei, Fateme
- Chemical Engineering Journal, Vol. 221
Calibration of 1 H NMR Spin Diffusion Coefficients for Mobile Polymers through Transverse Relaxation Measurements
journal, July 1999
- Mellinger, F.; Wilhelm, M.; Spiess, H. W.
- Macromolecules, Vol. 32, Issue 14
Tuning Cooperativity by Controlling the Linker Length of Silica-Supported Amines in Catalysis and CO 2 Capture
journal, August 2012
- Brunelli, Nicholas A.; Didas, Stephanie A.; Venkatasubbaiah, Krishnan
- Journal of the American Chemical Society, Vol. 134, Issue 34
Direct Capture of Low-Concentration CO 2 on Mesoporous Carbon-Supported Solid Amine Adsorbents at Ambient Temperature
journal, May 2015
- Wang, Jitong; Huang, Haihong; Wang, Mei
- Industrial & Engineering Chemistry Research, Vol. 54, Issue 19
Amine-bearing mesoporous silica for CO2 removal from dry and humid air
journal, June 2010
- Belmabkhout, Youssef; Serna-Guerrero, Rodrigo; Sayari, Abdelhamid
- Chemical Engineering Science, Vol. 65, Issue 11
Porous aromatic frameworks: Synthesis, structure and functions
journal, January 2013
- Ben, Teng; Qiu, Shilun
- CrystEngComm, Vol. 15, Issue 1
CO 2 -Induced Degradation of Amine-Containing Adsorbents: Reaction Products and Pathways
journal, August 2012
- Sayari, Abdelhamid; Heydari-Gorji, Aliakbar; Yang, Yong
- Journal of the American Chemical Society, Vol. 134, Issue 33
CO 2 Capture from the Atmosphere and Simultaneous Concentration Using Zeolites and Amine-Grafted SBA-15
journal, December 2011
- Stuckert, Nicholas R.; Yang, Ralph T.
- Environmental Science & Technology, Vol. 45, Issue 23
Stabilization of Amine-Containing CO 2 Adsorbents: Dramatic Effect of Water Vapor
journal, May 2010
- Sayari, Abdelhamid; Belmabkhout, Youssef
- Journal of the American Chemical Society, Vol. 132, Issue 18
Designing Adsorbents for CO 2 Capture from Flue Gas-Hyperbranched Aminosilicas Capable of Capturing CO 2 Reversibly
journal, March 2008
- Hicks, Jason C.; Drese, Jeffrey H.; Fauth, Daniel J.
- Journal of the American Chemical Society, Vol. 130, Issue 10
Molecular basket sorbents polyethylenimine–SBA-15 for CO2 capture from flue gas: Characterization and sorption properties
journal, March 2013
- Wang, Xiaoxing; Ma, Xiaoliang; Song, Chunshan
- Microporous and Mesoporous Materials, Vol. 169
Hollow fiber adsorbents for CO2 capture: Kinetic sorption performance
journal, July 2011
- Lively, Ryan P.; Leta, Daniel P.; DeRites, Bruce A.
- Chemical Engineering Journal, Vol. 171, Issue 3
Carbon Dioxide Capture Using Poly(ethylenimine)-Impregnated Poly(methyl methacrylate)-Supported Sorbents
journal, May 2014
- Jung, Hyunchul; Jo, Dong Hyun; Lee, Chang Hun
- Energy & Fuels, Vol. 28, Issue 6
Sponges with covalently tethered amines for high-efficiency carbon capture
journal, December 2014
- Qi, Genggeng; Fu, Liling; Giannelis, Emmanuel P.
- Nature Communications, Vol. 5, Issue 1
Hollow Fiber Adsorbents for CO 2 Removal from Flue Gas
journal, August 2009
- Lively, Ryan P.; Chance, Ronald R.; Kelley, B. T.
- Industrial & Engineering Chemistry Research, Vol. 48, Issue 15
Adsorption of CO2-containing gas mixtures over amine-bearing pore-expanded MCM-41 silica: application for CO2 separation
journal, March 2011
- Belmabkhout, Youssef; Serna-Guerrero, Rodrigo; Sayari, Abdelhamid
- Adsorption, Vol. 17, Issue 2