Crossed-beam DC slice imaging of fluorine atom reactions with linear alkanes

Shi, Yuanyuan; Kamasah, Alexander; Joalland, Baptiste; Suits, Arthur G.

doi:10.1063/1.4919099

Title: Crossed-beam DC slice imaging of fluorine atom reactions with linear alkanes

Authors:

Shi, Yuanyuan ^[1]; Kamasah, Alexander ^[1]; Joalland, Baptiste ^[1];

^[1]

Department of Chemistry, Wayne State University, 5101 Cass Avenue, Detroit, Michigan 48202, USA

Publication Date:: Thu May 14 00:00:00 EDT 2015

Sponsoring Org.:: USDOE

OSTI Identifier:: 1228256

Grant/Contract Number:: FG02-04ER15593

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: The Journal of Chemical Physics

Additional Journal Information:: Journal Name: The Journal of Chemical Physics Journal Volume: 142 Journal Issue: 18; Journal ID: ISSN 0021-9606

Publisher:: American Institute of Physics

Country of Publication:: United States

Language:: English

Citation Formats


                    Shi, Yuanyuan, Kamasah, Alexander, Joalland, Baptiste, and Suits, Arthur G. Crossed-beam DC slice imaging of fluorine atom reactions with linear alkanes.  United States: N. p., 2015. 
Web.  doi:10.1063/1.4919099.

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                    Shi, Yuanyuan, Kamasah, Alexander, Joalland, Baptiste, & Suits, Arthur G. Crossed-beam DC slice imaging of fluorine atom reactions with linear alkanes.  United States.  https://doi.org/10.1063/1.4919099

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                    Shi, Yuanyuan, Kamasah, Alexander, Joalland, Baptiste, and Suits, Arthur G. Thu .  
"Crossed-beam DC slice imaging of fluorine atom reactions with linear alkanes".  United States.  https://doi.org/10.1063/1.4919099.

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@article{osti_1228256,

  title        = {Crossed-beam DC slice imaging of fluorine atom reactions with linear alkanes},

  author       = {Shi, Yuanyuan and Kamasah, Alexander and Joalland, Baptiste and Suits, Arthur G.},

  abstractNote = {},

  doi          = {10.1063/1.4919099},

  journal      = {The Journal of Chemical Physics},

  number       = 18,

  volume       = 142,

  place        = {United States},

  year         = {Thu May 14 00:00:00 EDT 2015},

  month        = {Thu May 14 00:00:00 EDT 2015}

}

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Works referenced in this record:

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Title: Crossed-beam DC slice imaging of fluorine atom reactions with linear alkanes

Citation Formats

Dynamical Resonances Accessible Only by Reagent Vibrational Excitation in the F + HD->HF + D Reaction journal, December 2013

Chemical reaction dynamics: Combination of two models journal, October 1990

The relative reactivity of CH3D molecules with excited symmetric and antisymmetric stretching vibrations journal, November 2003

The relative reactivity of the stretch–bend combination vibrations of CH4 in the Cl (2P3/2)+CH4 reaction journal, June 2002

Molecular beam studies of the F+H 2 reaction journal, April 1985

State-Specific Correlation of Coincident Product Pairs in the F + CD4 Reaction journal, May 2003

Molecular beam studies of the F+D 2 and F+HD reactions journal, April 1985

Resonance-Mediated Chemical Reaction: F + H D → H F + D journal, August 2000

Direct current slice imaging journal, April 2003

Location of Energy Barriers. I. Effect on the Dynamics of Reactions A + BC journal, August 1969

Do Vibrational Excitations of CHD3 Preferentially Promote Reactivity Toward the Chlorine Atom? journal, June 2007

CH Stretching Excitation in the Early Barrier F + CHD3 Reaction Inhibits CH Bond Cleavage journal, July 2009

The Transition State of the F + H2 Reaction journal, December 1993

Some Concepts in Reaction Dynamics journal, May 1987

Dynamical Resonances in the Fluorine Atom Reaction with the Hydrogen Molecule journal, August 2008

Dynamics of the Simplest Reaction of a Carbon Atom in a Tetrahedral Environment journal, November 2003

Reaction dynamics of F+HD→HF+D at low energies: Resonant tunneling mechanism journal, May 2002

Probing the resonance potential in the F atom reaction with hydrogen deuteride with spectroscopic accuracy journal, August 2008

Comparison of near-threshold reactivity of ground-state and spin-orbit excited chlorine atoms with methane journal, July 2001

Transition-State Spectroscopy of Partial Wave Resonances in the F + HD Reaction journal, March 2010

Reactive scattering dynamics in atom+polyatomic systems: F+C2H6→HF(v,J)+C2H5 journal, March 2005

Dynamics of Chlorine Atom Reactions with Hydrocarbons: Insights from Imaging the Radical Product in Crossed Beams journal, August 2014

Reactions at suprathreshold energy: Evidence of a kinematic limit to the internal energy of the products journal, January 2001

Direct-Dynamics Study of the F + CH 4 , C 2 H 6 , C 3 H 8 , and i -C 4 H 10 Reactions † journal, April 2009

Experimental Investigation of Resonances in Reactive Scattering: The F + H 2 Reaction journal, July 1984

Reactive excitation functions for F+p-H2/n-H2/D2 and the vibrational branching for F+HD journal, September 2000

UV photodissociation of oxalyl chloride yields four fragments from one photon absorption journal, May 1997

CH Stretching Excitation Steers the F Atom to the CD Bond in the F + CHD 3 Reaction journal, December 2009

Dynamics of Cl + propane, butanes revisited: a crossed beam slice imaging study journal, January 2014

Crossed-beam dc slice imaging of chlorine atom reactions with pentane isomers journal, April 2010

Dynamics of H and D abstraction in the reaction of Cl atom with butane-1,1,1,4,4,4-d6 journal, January 2011

Photodissociation of heptane isomers and relative ionization efficiencies of butyl and propyl radicals at 157 nm journal, January 2009

Communication: Experimental and theoretical investigations of the effects of the reactant bending excitations in the F+CHD3 reaction journal, October 2010

Note: A short-pulse high-intensity molecular beam valve based on a piezoelectric stack actuator journal, November 2014

Dynamical Resonances Accessible Only by Reagent Vibrational Excitation in the F + HD->HF + D Reaction
journal, December 2013

Chemical reaction dynamics: Combination of two models
journal, October 1990

The relative reactivity of CH3D molecules with excited symmetric and antisymmetric stretching vibrations
journal, November 2003

The relative reactivity of the stretch–bend combination vibrations of CH4 in the Cl (2P3/2)+CH4 reaction
journal, June 2002

Molecular beam studies of the F+H ₂ reaction
journal, April 1985

State-Specific Correlation of Coincident Product Pairs in the F + CD4 Reaction
journal, May 2003

Molecular beam studies of the F+D ₂ and F+HD reactions
journal, April 1985

Resonance-Mediated Chemical Reaction: $F + H D \to H F + D$
journal, August 2000

Direct current slice imaging
journal, April 2003

Location of Energy Barriers. I. Effect on the Dynamics of Reactions A + BC
journal, August 1969

Do Vibrational Excitations of CHD3 Preferentially Promote Reactivity Toward the Chlorine Atom?
journal, June 2007

CH Stretching Excitation in the Early Barrier F + CHD3 Reaction Inhibits CH Bond Cleavage
journal, July 2009

The Transition State of the F + H2 Reaction
journal, December 1993

Some Concepts in Reaction Dynamics
journal, May 1987

Dynamical Resonances in the Fluorine Atom Reaction with the Hydrogen Molecule
journal, August 2008

Dynamics of the Simplest Reaction of a Carbon Atom in a Tetrahedral Environment
journal, November 2003

Reaction dynamics of F+HD→HF+D at low energies: Resonant tunneling mechanism
journal, May 2002

Probing the resonance potential in the F atom reaction with hydrogen deuteride with spectroscopic accuracy
journal, August 2008

Comparison of near-threshold reactivity of ground-state and spin-orbit excited chlorine atoms with methane
journal, July 2001

Transition-State Spectroscopy of Partial Wave Resonances in the F + HD Reaction
journal, March 2010

Reactive scattering dynamics in atom+polyatomic systems: F+C2H6→HF(v,J)+C2H5
journal, March 2005

Dynamics of Chlorine Atom Reactions with Hydrocarbons: Insights from Imaging the Radical Product in Crossed Beams
journal, August 2014

Reactions at suprathreshold energy: Evidence of a kinematic limit to the internal energy of the products
journal, January 2001

Direct-Dynamics Study of the F + CH ₄ , C ₂ H ₆ , C ₃ H ₈ , and i -C ₄ H ₁₀ Reactions ^†
journal, April 2009

Experimental Investigation of Resonances in Reactive Scattering: The F + $H_{2}$ Reaction
journal, July 1984

Reactive excitation functions for F+p-H2/n-H2/D2 and the vibrational branching for F+HD
journal, September 2000

UV photodissociation of oxalyl chloride yields four fragments from one photon absorption
journal, May 1997

CH Stretching Excitation Steers the F Atom to the CD Bond in the F + CHD ₃ Reaction
journal, December 2009

Dynamics of Cl + propane, butanes revisited: a crossed beam slice imaging study
journal, January 2014

Crossed-beam dc slice imaging of chlorine atom reactions with pentane isomers
journal, April 2010

Dynamics of H and D abstraction in the reaction of Cl atom with butane-1,1,1,4,4,4-d6
journal, January 2011

Photodissociation of heptane isomers and relative ionization efficiencies of butyl and propyl radicals at 157 nm
journal, January 2009

Communication: Experimental and theoretical investigations of the effects of the reactant bending excitations in the F+CHD3 reaction
journal, October 2010

Note: A short-pulse high-intensity molecular beam valve based on a piezoelectric stack actuator
journal, November 2014