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Title: Synchrotron-based double imaging photoelectron/photoion coincidence spectroscopy of radicals produced in a flow tube: OH and OD

Abstract

In this study, we present a microwave discharge flow tube coupled with a double imaging electron/ion coincidence device and vacuum ultraviolet (VUV) synchrotron radiation. The system has been applied to the study of the photoelectron spectroscopy of the well-known radicals OH and OD. The coincidence imaging scheme provides a high selectivity and yields the spectra of the pure radicals, removing the ever-present contributions from excess reactants, background, or secondary products, and therefore obviating the need for a prior knowledge of all possible byproducts. The photoelectron spectra encompassing the X3Σ– ground state of the OH+ and OD+ cations have been extracted and the vibrational constants compared satisfactorily to existing literature values. Future advantages of this approach include measurement of high resolution VUV spectroscopy of radicals, their absolute photoionization cross section, and species/isomer identification in chemical reactions as a function of time.

Authors:
ORCiD logo [1];  [1];  [1];  [1];  [2];  [2];  [2];  [3];  [3];  [4]
+ Show Author Affiliations
  1. Synchrotron SOLEIL, L'Orme des Merisiers, Gif sur Yvette (France)
  2. Univ. de Lille, Villeneuve d'Ascq (France)
  3. Sandia National Lab. (SNL-CA), Livermore, CA (United States)
  4. Univ. Bordeaux, Talence Cedex (France)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1235922
Alternate Identifier(s):
OSTI ID: 1228217
Report Number(s):
SAND-2015-3596J
Journal ID: ISSN 0021-9606; JCPSA6; 583721; TRN: US1600387
Grant/Contract Number:  
AC04-94AL85000
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Volume: 142; Journal Issue: 16; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
74 ATOMIC AND MOLECULAR PHYSICS; ionization; photons; atomic and molecular beams; flow visualization; image sensors

Citation Formats

Garcia, Gustavo A., Tang, Xiaofeng, Gil, Jean -Francois, Nahon, Laurent, Ward, Michael, Batut, Sebastien, Fittschen, Christa, Taatjes, Craig A., Osborn, David L., and Loison, Jean -Christophe. Synchrotron-based double imaging photoelectron/photoion coincidence spectroscopy of radicals produced in a flow tube: OH and OD. United States: N. p., 2015. Web. doi:10.1063/1.4918634.
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Garcia, Gustavo A., Tang, Xiaofeng, Gil, Jean -Francois, Nahon, Laurent, Ward, Michael, Batut, Sebastien, Fittschen, Christa, Taatjes, Craig A., Osborn, David L., & Loison, Jean -Christophe. Synchrotron-based double imaging photoelectron/photoion coincidence spectroscopy of radicals produced in a flow tube: OH and OD. United States. https://doi.org/10.1063/1.4918634
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Garcia, Gustavo A., Tang, Xiaofeng, Gil, Jean -Francois, Nahon, Laurent, Ward, Michael, Batut, Sebastien, Fittschen, Christa, Taatjes, Craig A., Osborn, David L., and Loison, Jean -Christophe. Thu . "Synchrotron-based double imaging photoelectron/photoion coincidence spectroscopy of radicals produced in a flow tube: OH and OD". United States. https://doi.org/10.1063/1.4918634. https://www.osti.gov/servlets/purl/1235922.
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@article{osti_1235922,
title = {Synchrotron-based double imaging photoelectron/photoion coincidence spectroscopy of radicals produced in a flow tube: OH and OD},
author = {Garcia, Gustavo A. and Tang, Xiaofeng and Gil, Jean -Francois and Nahon, Laurent and Ward, Michael and Batut, Sebastien and Fittschen, Christa and Taatjes, Craig A. and Osborn, David L. and Loison, Jean -Christophe},
abstractNote = {In this study, we present a microwave discharge flow tube coupled with a double imaging electron/ion coincidence device and vacuum ultraviolet (VUV) synchrotron radiation. The system has been applied to the study of the photoelectron spectroscopy of the well-known radicals OH and OD. The coincidence imaging scheme provides a high selectivity and yields the spectra of the pure radicals, removing the ever-present contributions from excess reactants, background, or secondary products, and therefore obviating the need for a prior knowledge of all possible byproducts. The photoelectron spectra encompassing the X3Σ– ground state of the OH+ and OD+ cations have been extracted and the vibrational constants compared satisfactorily to existing literature values. Future advantages of this approach include measurement of high resolution VUV spectroscopy of radicals, their absolute photoionization cross section, and species/isomer identification in chemical reactions as a function of time.},
doi = {10.1063/1.4918634},
journal = {Journal of Chemical Physics},
number = 16,
volume = 142,
place = {United States},
year = {Thu Apr 23 00:00:00 EDT 2015},
month = {Thu Apr 23 00:00:00 EDT 2015}
}
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https://doi.org/10.1063/1.4918634
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Works referenced in this record:

Enols Are Common Intermediates in Hydrocarbon Oxidation
journal, June 2005

Recent Applications of Synchrotron VUV Photoionization Mass Spectrometry: Insight into Combustion Chemistry
journal, January 2010

  • Li, Yuyang; Qi, Fei
  • Accounts of Chemical Research, Vol. 43, Issue 1
  • DOI: 10.1021/ar900130b

Chemical dynamics, molecular energetics, and kinetics at the synchrotron
journal, January 2010

  • Leone, Stephen R.; Ahmed, Musahid; Wilson, Kevin R.
  • Physical Chemistry Chemical Physics, Vol. 12, Issue 25
  • DOI: 10.1039/c001707h

Direct Kinetic Measurements of Criegee Intermediate (CH2OO) Formed by Reaction of CH2I with O2
journal, January 2012

Combustion chemistry probed by synchrotron VUV photoionization mass spectrometry
journal, January 2013

Imaging photoelectron photoion coincidence spectroscopy with velocity focusing electron optics
journal, March 2009

  • Bodi, Andras; Johnson, Melanie; Gerber, Thomas
  • Review of Scientific Instruments, Vol. 80, Issue 3
  • DOI: 10.1063/1.3082016

A versatile electron-ion coincidence spectrometer for photoelectron momentum imaging and threshold spectroscopy on mass selected ions using synchrotron radiation
journal, February 2009

  • Garcia, Gustavo A.; Soldi-Lose, Héloïse; Nahon, Laurent
  • Review of Scientific Instruments, Vol. 80, Issue 2
  • DOI: 10.1063/1.3079331

A threshold photoelectron-photoion coincidence spectrometer with double velocity imaging using synchrotron radiation
journal, November 2009

  • Tang, Xiaofeng; Zhou, Xiaoguo; Niu, Mingli
  • Review of Scientific Instruments, Vol. 80, Issue 11
  • DOI: 10.1063/1.3250872

A photoelectron velocity map imaging spectrometer for experiments combining synchrotron and laser radiations
journal, March 2011

  • O’Keeffe, P.; Bolognesi, P.; Coreno, M.
  • Review of Scientific Instruments, Vol. 82, Issue 3
  • DOI: 10.1063/1.3563723

A new double imaging velocity focusing coincidence experiment: i 2 PEPICO
journal, August 2012

  • Bodi, Andras; Hemberger, Patrick; Gerber, Thomas
  • Review of Scientific Instruments, Vol. 83, Issue 8
  • DOI: 10.1063/1.4742769

Photoionization of 2-pyridone and 2-hydroxypyridine
journal, January 2010

  • Poully, J. C.; Schermann, J. P.; Nieuwjaer, N.
  • Physical Chemistry Chemical Physics, Vol. 12, Issue 14
  • DOI: 10.1039/b923630a

Generation and High-Resolution Photoelectron Spectroscopy of Small Organic Radicals in Cold Supersonic Expansions
journal, April 2003

  • Willitsch, Stefan; Dyke, John M.; Merkt, Frédéric
  • Helvetica Chimica Acta, Vol. 86, Issue 4
  • DOI: 10.1002/hlca.200390100

Electron ionization, photoionization and photoelectron/photoion coincidence spectroscopy in mass-spectrometric investigations of a low-pressure ethylene/oxygen flame
journal, January 2015

  • Felsmann, Daniel; Moshammer, Kai; Krüger, Julia
  • Proceedings of the Combustion Institute, Vol. 35, Issue 1
  • DOI: 10.1016/j.proci.2014.05.151

In situ flame chemistry tracing by imaging photoelectron photoion coincidence spectroscopy
journal, February 2014

  • Oßwald, P.; Hemberger, P.; Bierkandt, T.
  • Review of Scientific Instruments, Vol. 85, Issue 2
  • DOI: 10.1063/1.4861175

Mass-Resolved Isomer-Selective Chemical Analysis with Imaging Photoelectron Photoion Coincidence Spectroscopy
journal, August 2013

  • Bodi, Andras; Hemberger, Patrick; Osborn, David L.
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 17
  • DOI: 10.1021/jz401500c

DELICIOUS III: A multipurpose double imaging particle coincidence spectrometer for gas phase vacuum ultraviolet photodynamics studies
journal, May 2013

  • Garcia, G. A.; Cunha de Miranda, B. K.; Tia, M.
  • Review of Scientific Instruments, Vol. 84, Issue 5
  • DOI: 10.1063/1.4807751

CH 3 + Formation in the Dissociation of Energy-Selected CH 3 F + Studied by Double Imaging Electron/Ion Coincidences
journal, November 2014

  • Tang, Xiaofeng; Garcia, Gustavo A.; Nahon, Laurent
  • The Journal of Physical Chemistry A, Vol. 119, Issue 23
  • DOI: 10.1021/jp510319b

Unravelling combustion mechanisms through a quantitative understanding of elementary reactions
journal, January 2005

  • Miller, James A.; Pilling, Michael J.; Troe, Jürgen
  • Proceedings of the Combustion Institute, Vol. 30, Issue 1
  • DOI: 10.1016/j.proci.2004.08.281

Measurement of OH and HO 2 in the Troposphere
journal, December 2003

  • Heard, Dwayne E.; Pilling, Michael J.
  • Chemical Reviews, Vol. 103, Issue 12
  • DOI: 10.1021/cr020522s

Atmospheric Degradation of Volatile Organic Compounds
journal, December 2003

  • Atkinson, Roger; Arey, Janet
  • Chemical Reviews, Vol. 103, Issue 12
  • DOI: 10.1021/cr0206420

The Ultraviolet Emission Spectra of OH + and OD + . Rotational Structure and Perturbations in the A 3 Π i – X 3 Σ − Transition
journal, February 1975

  • Merer, A. J.; Malm, D. N.; Martin, R. W.
  • Canadian Journal of Physics, Vol. 53, Issue 3
  • DOI: 10.1139/p75-037

Relative photoionization cross section study of OH and OD from 68 nm to 95 nm
journal, November 1995

  • Cutler, J. N.; He, Z. X.; Samson, J. A. R.
  • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 28, Issue 21
  • DOI: 10.1088/0953-4075/28/21/007

Photoionization of OH in the region 750–950 Å
journal, September 1984

Study of the OH and OD radicals with photoelectron spectroscopy using synchrotron radiation
journal, January 1999

  • Barr, Jonathan D.; De Fanis, Alberto; Dyke, John M.
  • The Journal of Chemical Physics, Vol. 110, Issue 1
  • DOI: 10.1063/1.478069

The photoelectron spectra of the OH and OD radicals
journal, February 1977

U.V. photoelectron spectroscopy of OH and OD radicals
journal, February 1984

Photoionization studies of the atmospherically important species N and OH at the Elettra synchrotron radiation source
journal, March 2005

  • Innocenti, F.; Zuin, L.; Costa, M. L.
  • Journal of Electron Spectroscopy and Related Phenomena, Vol. 142, Issue 3
  • DOI: 10.1016/j.elspec.2004.09.022

Rotationally resolved threshold photoelectron spectra of OH and OD
journal, July 1992

  • Wiedmann, R. T.; Tonkyn, R. G.; White, M. G.
  • The Journal of Chemical Physics, Vol. 97, Issue 2
  • DOI: 10.1063/1.463179

A 1+1 Ionization Scheme for Sensitive Detection of the OH Radical †
journal, September 2003

  • McRaven, Chris; Alnis, Janis; Furneaux, Brendan
  • The Journal of Physical Chemistry A, Vol. 107, Issue 37
  • DOI: 10.1021/jp0344545

Kinetic and mechanistic investigations of fluorine atom + water/water-d2 and fluorine atom + hydrogen/deuterium over the temperature range 240-373 K
journal, May 1989

  • Stevens, Philip S.; Brune, William H.; Anderson, James G.
  • The Journal of Physical Chemistry, Vol. 93, Issue 10
  • DOI: 10.1021/j100347a040

Photoelectron and photofragment velocity map imaging of state-selected molecular oxygen dissociation/ionization dynamics
journal, August 1997

  • Parker, D. H.; Eppink, A. T. J. B.
  • The Journal of Chemical Physics, Vol. 107, Issue 7
  • DOI: 10.1063/1.474624

Time‐of‐Flight Mass Spectrometer with Improved Resolution
journal, December 1955

  • Wiley, W. C.; McLaren, I. H.
  • Review of Scientific Instruments, Vol. 26, Issue 12
  • DOI: 10.1063/1.1715212

Two-dimensional charged particle image inversion using a polar basis function expansion
journal, November 2004

  • Garcia, Gustavo A.; Nahon, Laurent; Powis, Ivan
  • Review of Scientific Instruments, Vol. 75, Issue 11
  • DOI: 10.1063/1.1807578

Experimental and theoretical study of a differentially pumped absorption gas cell used as a low energy-pass filter in the vacuum ultraviolet photon energy range
journal, January 2000

  • Mercier, B.; Compin, M.; Prevost, C.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 18, Issue 5
  • DOI: 10.1116/1.1288196

Molecular beam photoelectron spectroscopy and femtosecond intramolecular dynamics of H 2 O + and D 2 O +
journal, December 1986

  • Reutt, J. E.; Wang, L. S.; Lee, Y. T.
  • The Journal of Chemical Physics, Vol. 85, Issue 12
  • DOI: 10.1063/1.451379

Absolute Photoionization Cross Section of the Methyl Radical
journal, June 2010

  • Loison, Jean-Christophe
  • The Journal of Physical Chemistry A, Vol. 114, Issue 23
  • DOI: 10.1021/jp1024312

Absolute Photoionization Cross Section of the Ethyl Radical in the Range 8–11.5 eV: Synchrotron and Vacuum Ultraviolet Laser Measurements
journal, June 2011

  • Gans, Bérenger; Garcia, Gustavo A.; Boyé-Péronne, Séverine
  • The Journal of Physical Chemistry A, Vol. 115, Issue 21
  • DOI: 10.1021/jp202648m

Threshold Photoelectron Spectroscopy of Cyclopropenylidene, Chlorocyclopropenylidene, and Their Deuterated Isotopomeres †
journal, October 2010

  • Hemberger, Patrick; Noller, Bastian; Steinbauer, Michael
  • The Journal of Physical Chemistry A, Vol. 114, Issue 42
  • DOI: 10.1021/jp104019d

Photoionization of Propargyl and Bromopropargyl Radicals: A Threshold Photoelectron Spectroscopic Study
journal, March 2011

  • Hemberger, Patrick; Lang, Melanie; Noller, Bastian
  • The Journal of Physical Chemistry A, Vol. 115, Issue 11
  • DOI: 10.1021/jp112110j

Comprehensive vacuum ultraviolet photoionization study of the CF 3 • trifluoromethyl radical using synchrotron radiation
journal, May 2012

  • Dossmann (Soldi-Lose), Héloïse; Garcia, Gustavo A.; Nahon, Laurent
  • The Journal of Chemical Physics, Vol. 136, Issue 20
  • DOI: 10.1063/1.4719529

VUV Photodynamics and Chiral Asymmetry in the Photoionization of Gas Phase Alanine Enantiomers
journal, April 2014

  • Tia, Maurice; Cunha de Miranda, Barbara; Daly, Steven
  • The Journal of Physical Chemistry A, Vol. 118, Issue 15
  • DOI: 10.1021/jp5016142

Atmospheric Degradation of Volatile Organic Compounds
journal, March 2004

Imaging photoelectron photoion coincidence spectroscopy with velocity focusing electron optics
text, January 2009

  • Zsolt, Gengeliczki,; Tomas, Baer,; Melanie, Johnson,
  • The University of North Carolina at Chapel Hill University Libraries
  • DOI: 10.17615/1wdm-f957
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    Photodissociation and photoionisation of atoms and molecules of astrophysical interest
    journal, June 2017

    Vacuum upgrade and enhanced performances of the double imaging electron/ion coincidence end-station at the vacuum ultraviolet beamline DESIRS
    journal, December 2015

    • Tang, Xiaofeng; Garcia, Gustavo A.; Gil, Jean-François
    • Review of Scientific Instruments, Vol. 86, Issue 12
    • DOI: 10.1063/1.4937624

    Vacuum ultraviolet photoionization cross section of the hydroxyl radical
    journal, May 2018

    • Dodson, Leah G.; Savee, John D.; Gozem, Samer
    • The Journal of Chemical Physics, Vol. 148, Issue 18
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    Experimental and theoretical threshold photoelectron spectra of methylene
    journal, December 2018

    • Coudert, L. H.; Gans, B.; Holzmeier, F.
    • The Journal of Chemical Physics, Vol. 149, Issue 22
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    Quantifying the photoionization cross section of the hydroxyl radical
    journal, April 2019

    • Harper, O. J.; Hassenfratz, M.; Loison, J. -C.
    • The Journal of Chemical Physics, Vol. 150, Issue 14
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    To see C 2 : Single-photon ionization of the dicarbon molecule
    journal, January 2020

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    • The Journal of Chemical Physics, Vol. 152, Issue 4
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    Traceable measurements of He, Ne, Ar, Kr, and Xe photoionization cross sections in the EUV spectral range
    journal, June 2018

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