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Title: Quantifying sources of black carbon in western North America using observationally based analysis and an emission tagging technique in the Community Atmosphere Model

Abstract

The Community Atmosphere Model (CAM5), equipped with a technique to tag black carbon (BC) emissions by source regions and types, has been employed to establish source–receptor relationships for atmospheric BC and its deposition to snow over western North America. The CAM5 simulation was conducted with meteorological fields constrained by reanalysis for year 2013 when measurements of BC in both near-surface air and snow are available for model evaluation. We find that CAM5 has a significant low bias in predicted mixing ratios of BC in snow but only a small low bias in predicted atmospheric concentrations over northwestern USA and western Canada. Even with a strong low bias in snow mixing ratios, radiative transfer calculations show that the BC-in-snow darkening effect is substantially larger than the BC dimming effect at the surface by atmospheric BC. Local sources contribute more to near-surface atmospheric BC and to deposition than distant sources, while the latter are more important in the middle and upper troposphere where wet removal is relatively weak. Fossil fuel (FF) is the dominant source type for total column BC burden over the two regions. FF is also the dominant local source type for BC column burden, deposition, and near-surface BC, whilemore » for all distant source regions combined the contribution of biomass/biofuel (BB) is larger than FF. An observationally based positive matrix factorization (PMF) analysis of the snow-impurity chemistry is conducted to quantitatively evaluate the CAM5 BC source-type attribution. Furthermore, while CAM5 is qualitatively consistent with the PMF analysis with respect to partitioning of BC originating from BB and FF emissions, it significantly underestimates the relative contribution of BB. In addition to a possible low bias in BB emissions used in the simulation, the model is likely missing a significant source of snow darkening from local soil found in the observations.« less

Authors:
; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL)
Sponsoring Org.:
USDOE Office of Science (SC), Biological and Environmental Research (BER)
OSTI Identifier:
1226386
Alternate Identifier(s):
OSTI ID: 1227599
Report Number(s):
PNNL-SA-108978
Journal ID: ISSN 1680-7324
Grant/Contract Number:  
AC05-76RLO1830; AC05-76RL01830
Resource Type:
Published Article
Journal Name:
Atmospheric Chemistry and Physics (Online)
Additional Journal Information:
Journal Name: Atmospheric Chemistry and Physics (Online) Journal Volume: 15 Journal Issue: 22; Journal ID: ISSN 1680-7324
Publisher:
Copernicus Publications, EGU
Country of Publication:
Germany
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES; Environmental Molecular Sciences Laboratory

Citation Formats

Zhang, R., Wang, H., Hegg, D. A., Qian, Y., Doherty, S. J., Dang, C., Ma, P.-L., Rasch, P. J., and Fu, Q. Quantifying sources of black carbon in western North America using observationally based analysis and an emission tagging technique in the Community Atmosphere Model. Germany: N. p., 2015. Web. doi:10.5194/acp-15-12805-2015.
Zhang, R., Wang, H., Hegg, D. A., Qian, Y., Doherty, S. J., Dang, C., Ma, P.-L., Rasch, P. J., & Fu, Q. Quantifying sources of black carbon in western North America using observationally based analysis and an emission tagging technique in the Community Atmosphere Model. Germany. https://doi.org/10.5194/acp-15-12805-2015
Zhang, R., Wang, H., Hegg, D. A., Qian, Y., Doherty, S. J., Dang, C., Ma, P.-L., Rasch, P. J., and Fu, Q. Wed . "Quantifying sources of black carbon in western North America using observationally based analysis and an emission tagging technique in the Community Atmosphere Model". Germany. https://doi.org/10.5194/acp-15-12805-2015.
@article{osti_1226386,
title = {Quantifying sources of black carbon in western North America using observationally based analysis and an emission tagging technique in the Community Atmosphere Model},
author = {Zhang, R. and Wang, H. and Hegg, D. A. and Qian, Y. and Doherty, S. J. and Dang, C. and Ma, P.-L. and Rasch, P. J. and Fu, Q.},
abstractNote = {The Community Atmosphere Model (CAM5), equipped with a technique to tag black carbon (BC) emissions by source regions and types, has been employed to establish source–receptor relationships for atmospheric BC and its deposition to snow over western North America. The CAM5 simulation was conducted with meteorological fields constrained by reanalysis for year 2013 when measurements of BC in both near-surface air and snow are available for model evaluation. We find that CAM5 has a significant low bias in predicted mixing ratios of BC in snow but only a small low bias in predicted atmospheric concentrations over northwestern USA and western Canada. Even with a strong low bias in snow mixing ratios, radiative transfer calculations show that the BC-in-snow darkening effect is substantially larger than the BC dimming effect at the surface by atmospheric BC. Local sources contribute more to near-surface atmospheric BC and to deposition than distant sources, while the latter are more important in the middle and upper troposphere where wet removal is relatively weak. Fossil fuel (FF) is the dominant source type for total column BC burden over the two regions. FF is also the dominant local source type for BC column burden, deposition, and near-surface BC, while for all distant source regions combined the contribution of biomass/biofuel (BB) is larger than FF. An observationally based positive matrix factorization (PMF) analysis of the snow-impurity chemistry is conducted to quantitatively evaluate the CAM5 BC source-type attribution. Furthermore, while CAM5 is qualitatively consistent with the PMF analysis with respect to partitioning of BC originating from BB and FF emissions, it significantly underestimates the relative contribution of BB. In addition to a possible low bias in BB emissions used in the simulation, the model is likely missing a significant source of snow darkening from local soil found in the observations.},
doi = {10.5194/acp-15-12805-2015},
journal = {Atmospheric Chemistry and Physics (Online)},
number = 22,
volume = 15,
place = {Germany},
year = {Wed Nov 18 00:00:00 EST 2015},
month = {Wed Nov 18 00:00:00 EST 2015}
}

Journal Article:
Free Publicly Available Full Text
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https://doi.org/10.5194/acp-15-12805-2015

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Works referenced in this record:

Black carbon in the Arctic: the underestimated role of gas flaring and residential combustion emissions
journal, January 2013

  • Stohl, A.; Klimont, Z.; Eckhardt, S.
  • Atmospheric Chemistry and Physics, Vol. 13, Issue 17
  • DOI: 10.5194/acp-13-8833-2013

Black carbon and other light-absorbing particles in snow of central North America: Black carbon in North American snow
journal, November 2014

  • Doherty, Sarah J.; Dang, Cheng; Hegg, Dean A.
  • Journal of Geophysical Research: Atmospheres, Vol. 119, Issue 22
  • DOI: 10.1002/2014JD022350

Origin and radiative forcing of black carbon transported to the Himalayas and Tibetan Plateau
journal, January 2011

  • Kopacz, M.; Mauzerall, D. L.; Wang, J.
  • Atmospheric Chemistry and Physics, Vol. 11, Issue 6
  • DOI: 10.5194/acp-11-2837-2011

Quantifying light absorption by organic carbon in Western North American snow by serial chemical extractions
journal, September 2014

  • Dang, Cheng; Hegg, Dean A.
  • Journal of Geophysical Research: Atmospheres, Vol. 119, Issue 17
  • DOI: 10.1002/2014JD022156

Arctic surface temperature change to emissions of black carbon within Arctic or midlatitudes: ARCTIC CLIMATE RESPONSE TO BLACK CARBON
journal, July 2013

  • Sand, Maria; Berntsen, Terje Koren; Seland, Øyvind
  • Journal of Geophysical Research: Atmospheres, Vol. 118, Issue 14
  • DOI: 10.1002/jgrd.50613

Export efficiency of black carbon aerosol in continental outflow: Global implications
journal, January 2005


Black soot and the survival of Tibetan glaciers
journal, December 2009

  • Xu, Baiqing; Cao, Junji; Hansen, James
  • Proceedings of the National Academy of Sciences, Vol. 106, Issue 52
  • DOI: 10.1073/pnas.0910444106

The IMPROVE_A Temperature Protocol for Thermal/Optical Carbon Analysis: Maintaining Consistency with a Long-Term Database
journal, September 2007

  • Chow, Judith C.; Watson, John G.; Chen, L. -W. Antony
  • Journal of the Air & Waste Management Association, Vol. 57, Issue 9
  • DOI: 10.3155/1047-3289.57.9.1014

Springtime warming and reduced snow cover from carbonaceous particles
journal, January 2009

  • Flanner, M. G.; Zender, C. S.; Hess, P. G.
  • Atmospheric Chemistry and Physics, Vol. 9, Issue 7
  • DOI: 10.5194/acp-9-2481-2009

Cost-effective control of air quality and greenhouse gases in Europe: Modeling and policy applications
journal, December 2011


Variations and sources of the equivalent black carbon in the high Arctic revealed by long-term observations at Alert and Barrow: 1989–2003
journal, January 2006

  • Sharma, S.; Andrews, E.; Barrie, L. A.
  • Journal of Geophysical Research, Vol. 111, Issue D14
  • DOI: 10.1029/2005JD006581

Trans-pacific dust transport: integrated analysis of NASA/CALIPSO and a global aerosol transport model
journal, January 2009

  • Eguchi, K.; Uno, I.; Yumimoto, K.
  • Atmospheric Chemistry and Physics, Vol. 9, Issue 9
  • DOI: 10.5194/acp-9-3137-2009

Light absorption from particulate impurities in snow and ice determined by spectrophotometric analysis of filters
journal, January 2011

  • Grenfell, Thomas C.; Doherty, Sarah J.; Clarke, Antony D.
  • Applied Optics, Vol. 50, Issue 14
  • DOI: 10.1364/AO.50.002037

Bounding the role of black carbon in the climate system: A scientific assessment: BLACK CARBON IN THE CLIMATE SYSTEM
journal, June 2013

  • Bond, T. C.; Doherty, S. J.; Fahey, D. W.
  • Journal of Geophysical Research: Atmospheres, Vol. 118, Issue 11
  • DOI: 10.1002/jgrd.50171

Source Attribution of Black Carbon in Arctic Snow
journal, June 2009

  • Hegg, Dean A.; Warren, Stephen G.; Grenfell, Thomas C.
  • Environmental Science & Technology, Vol. 43, Issue 11
  • DOI: 10.1021/es803623f

The role of circulation features on black carbon transport into the Arctic in the Community Atmosphere Model version 5 (CAM5): BC TRANSPORT IN OFF-LINE CAM5
journal, May 2013

  • Ma, Po-Lun; Rasch, Philip J.; Wang, Hailong
  • Journal of Geophysical Research: Atmospheres, Vol. 118, Issue 10
  • DOI: 10.1002/jgrd.50411

An AeroCom assessment of black carbon in Arctic snow and sea ice
journal, January 2014

  • Jiao, C.; Flanner, M. G.; Balkanski, Y.
  • Atmospheric Chemistry and Physics, Vol. 14, Issue 5
  • DOI: 10.5194/acp-14-2399-2014

Optical properties of aged Asian aerosols observed over the U.S. Pacific Northwest
journal, January 2010

  • Fischer, E. V.; Jaffe, D. A.; Marley, N. A.
  • Journal of Geophysical Research, Vol. 115, Issue D20
  • DOI: 10.1029/2010JD013943

A Model for the Spectral Albedo of Snow. II: Snow Containing Atmospheric Aerosols
journal, December 1980


Black carbon in seasonal snow across northern Xinjiang in northwestern China
journal, October 2012


MERRA: NASA’s Modern-Era Retrospective Analysis for Research and Applications
journal, July 2011


Arctic Air Pollution: Origins and Impacts
journal, March 2007


Black carbon and other light-absorbing impurities in snow across Northern China: LIGHT-ABSORBING IMPURITIES IN SNOW
journal, February 2013

  • Wang, Xin; Doherty, Sarah J.; Huang, Jianping
  • Journal of Geophysical Research: Atmospheres, Vol. 118, Issue 3
  • DOI: 10.1029/2012JD018291

Sensitivity of remote aerosol distributions to representation of cloud–aerosol interactions in a global climate model
journal, January 2013

  • Wang, H.; Easter, R. C.; Rasch, P. J.
  • Geoscientific Model Development, Vol. 6, Issue 3
  • DOI: 10.5194/gmd-6-765-2013

A sensitivity study on modeling black carbon in snow and its radiative forcing over the Arctic and Northern China
journal, May 2014


Transport of Asian air pollution to North America
journal, March 1999

  • Jaffe, Dan; Anderson, Theodore; Covert, Dave
  • Geophysical Research Letters, Vol. 26, Issue 6
  • DOI: 10.1029/1999GL900100

Source attribution of insoluble light-absorbing particles in seasonal snow across northern China
journal, January 2013


Global fire emissions and the contribution of deforestation, savanna, forest, agricultural, and peat fires (1997–2009)
journal, January 2010

  • van der Werf, G. R.; Randerson, J. T.; Giglio, L.
  • Atmospheric Chemistry and Physics, Vol. 10, Issue 23
  • DOI: 10.5194/acp-10-11707-2010

Long-term trends of black carbon and sulphate aerosol in the Arctic: changes in atmospheric transport and source region emissions
journal, January 2010

  • Hirdman, D.; Burkhart, J. F.; Sodemann, H.
  • Atmospheric Chemistry and Physics, Vol. 10, Issue 19
  • DOI: 10.5194/acp-10-9351-2010

Historical (1850–2000) gridded anthropogenic and biomass burning emissions of reactive gases and aerosols: methodology and application
journal, January 2010

  • Lamarque, J. -F.; Bond, T. C.; Eyring, V.
  • Atmospheric Chemistry and Physics, Vol. 10, Issue 15
  • DOI: 10.5194/acp-10-7017-2010

Evaluation of preindustrial to present-day black carbon and its albedo forcing from Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP)
journal, January 2013

  • Lee, Y. H.; Lamarque, J. -F.; Flanner, M. G.
  • Atmospheric Chemistry and Physics, Vol. 13, Issue 5
  • DOI: 10.5194/acp-13-2607-2013

Evaluating the climate and air quality impacts of short-lived pollutants
journal, January 2015


Sources of carbonaceous aerosols and deposited black carbon in the Arctic in winter-spring: implications for radiative forcing
journal, January 2011


Relative contributions of anthropogenic emissions to black carbon aerosol in the Arctic
journal, January 2010

  • Huang, L.; Gong, S. L.; Jia, C. Q.
  • Journal of Geophysical Research, Vol. 115, Issue D19
  • DOI: 10.1029/2009JD013592

Soot climate forcing via snow and ice albedos
journal, December 2003

  • Hansen, J.; Nazarenko, L.
  • Proceedings of the National Academy of Sciences, Vol. 101, Issue 2
  • DOI: 10.1073/pnas.2237157100

Climate response to regional radiative forcing during the twentieth century
journal, March 2009

  • Shindell, Drew; Faluvegi, Greg
  • Nature Geoscience, Vol. 2, Issue 4
  • DOI: 10.1038/ngeo473

Simulating black carbon and dust and their radiative forcing in seasonal snow: a case study over North China with field campaign measurements
journal, January 2014


Sensitivity studies on the impacts of Tibetan Plateau snowpack pollution on the Asian hydrological cycle and monsoon climate
journal, January 2011

  • Qian, Y.; Flanner, M. G.; Leung, L. R.
  • Atmospheric Chemistry and Physics, Vol. 11, Issue 5
  • DOI: 10.5194/acp-11-1929-2011

Black carbon in soils and sediments: Analysis, distribution, implications, and current challenges
journal, September 2000

  • Schmidt, Michael W. I.; Noack, Angela G.
  • Global Biogeochemical Cycles, Vol. 14, Issue 3
  • DOI: 10.1029/1999GB001208

Soot in the Arctic snowpack: a cause for perturbations in radiative transfer
journal, January 1985


Light-absorbing impurities in Arctic snow
journal, January 2010

  • Doherty, S. J.; Warren, S. G.; Grenfell, T. C.
  • Atmospheric Chemistry and Physics, Vol. 10, Issue 23
  • DOI: 10.5194/acp-10-11647-2010

Black carbon record based on a shallow Himalayan ice core and its climatic implications
journal, January 2008


Hemispheric Aerosol Vertical Profiles: Anthropogenic Impacts on Optical Depth and Cloud Nuclei
journal, September 2010


Present-day springtime high-latitude surface albedo as a predictor of simulated climate sensitivity
journal, January 2007

  • Levis, Samuel; Bonan, Gordon B.; Lawrence, Peter J.
  • Geophysical Research Letters, Vol. 34, Issue 17
  • DOI: 10.1029/2007GL030775

Present-day climate forcing and response from black carbon in snow
journal, January 2007

  • Flanner, Mark G.; Zender, Charles S.; Randerson, James T.
  • Journal of Geophysical Research, Vol. 112, Issue D11
  • DOI: 10.1029/2006JD008003

Spatial and seasonal trends in particle concentration and optical extinction in the United States
journal, January 1994

  • Malm, William C.; Sisler, James F.; Huffman, Dale
  • Journal of Geophysical Research, Vol. 99, Issue D1
  • DOI: 10.1029/93JD02916

Emissions of primary aerosol and precursor gases in the years 2000 and 1750 prescribed data-sets for AeroCom
journal, January 2006

  • Dentener, F.; Kinne, S.; Bond, T.
  • Atmospheric Chemistry and Physics, Vol. 6, Issue 12
  • DOI: 10.5194/acp-6-4321-2006

Modeling historical long-term trends of sulfate, ammonium, and elemental carbon over Europe: A comparison with ice core records in the Alps
journal, January 2007

  • Fagerli, Hilde; Legrand, Michel; Preunkert, Susanne
  • Journal of Geophysical Research, Vol. 112, Issue D23
  • DOI: 10.1029/2006JD008044

Evaluation of black carbon estimations in global aerosol models
journal, January 2009


Black carbon in the atmosphere and snow, from pre-industrial times until present
journal, January 2011

  • Skeie, R. B.; Berntsen, T.; Myhre, G.
  • Atmospheric Chemistry and Physics, Vol. 11, Issue 14
  • DOI: 10.5194/acp-11-6809-2011

Observed vertical redistribution of black carbon and other insoluble light-absorbing particles in melting snow: MELT REDISTRIBUTION OF BC IN SNOW
journal, June 2013

  • Doherty, Sarah J.; Grenfell, Thomas C.; Forsström, Sanja
  • Journal of Geophysical Research: Atmospheres, Vol. 118, Issue 11
  • DOI: 10.1002/jgrd.50235

Characteristics of atmospheric transport into the Arctic troposphere
journal, January 2006


Transpacific transport of Asian anthropogenic aerosols and its impact on surface air quality in the United States
journal, January 2006

  • Heald, Colette L.; Jacob, Daniel J.; Park, Rokjin J.
  • Journal of Geophysical Research, Vol. 111, Issue D14
  • DOI: 10.1029/2005JD006847

Trans-Pacific transport of black carbon and fine aerosols ( D < 2.5 μ m) into North America
journal, January 2007

  • Hadley, O. L.; Ramanathan, V.; Carmichael, G. R.
  • Journal of Geophysical Research, Vol. 112, Issue D5
  • DOI: 10.1029/2006JD007632

Dust and Black Carbon in Seasonal Snow Across Northern China
journal, February 2011

  • Huang, Jianping; Fu, Qiang; Zhang, Wu
  • Bulletin of the American Meteorological Society, Vol. 92, Issue 2
  • DOI: 10.1175/2010BAMS3064.1

Continental scale Antarctic deposition of sulphur and black carbon from anthropogenic and volcanic sources
journal, January 2010

  • Graf, H. -F.; Shirsat, S. V.; Oppenheimer, C.
  • Atmospheric Chemistry and Physics, Vol. 10, Issue 5
  • DOI: 10.5194/acp-10-2457-2010

A climatologically significant aerosol longwave indirect effect in the Arctic
journal, January 2006


Sources of light-absorbing aerosol in arctic snow and their seasonal variation
journal, January 2010

  • Hegg, Dean A.; Warren, Stephen G.; Grenfell, Thomas C.
  • Atmospheric Chemistry and Physics, Vol. 10, Issue 22
  • DOI: 10.5194/acp-10-10923-2010

The dri thermal/optical reflectance carbon analysis system: description, evaluation and applications in U.S. Air quality studies
journal, June 1993

  • Chow, Judith C.; Watson, John G.; Pritchett, Lyle C.
  • Atmospheric Environment. Part A. General Topics, Vol. 27, Issue 8
  • DOI: 10.1016/0960-1686(93)90245-T

Aerosols from Overseas Rival Domestic Emissions over North America
journal, August 2012


Quantifying sources, transport, deposition, and radiative forcing of black carbon over the Himalayas and Tibetan Plateau
journal, January 2015


Biomass burning contribution to black carbon in the Western United States Mountain Ranges
journal, January 2011


Source identification of short-lived air pollutants in the Arctic using statistical analysis of measurement data and particle dispersion model output
journal, January 2010

  • Hirdman, D.; Sodemann, H.; Eckhardt, S.
  • Atmospheric Chemistry and Physics, Vol. 10, Issue 2
  • DOI: 10.5194/acp-10-669-2010

A multi-model assessment of pollution transport to the Arctic
journal, January 2008

  • Shindell, D. T.; Chin, M.; Dentener, F.
  • Atmospheric Chemistry and Physics, Vol. 8, Issue 17
  • DOI: 10.5194/acp-8-5353-2008

Intercontinental transport of pollution and dust aerosols: implications for regional air quality
journal, January 2007

  • Chin, Mian; Diehl, T.; Ginoux, P.
  • Atmospheric Chemistry and Physics, Vol. 7, Issue 21
  • DOI: 10.5194/acp-7-5501-2007

16-year simulation of Arctic black carbon: Transport, source contribution, and sensitivity analysis on deposition: 16 YR TRANSPORT OF BC TO THE ARCTIC
journal, January 2013

  • Sharma, S.; Ishizawa, M.; Chan, D.
  • Journal of Geophysical Research: Atmospheres, Vol. 118, Issue 2
  • DOI: 10.1029/2012JD017774

Use of Soil Properties to Determine the Historical Extent of Two Western Washington Prairies
journal, July 2011

  • Hegarty, Joshua; Zabowski, Darlene; Bakker, Jonathan D.
  • Northwest Science, Vol. 85, Issue 2
  • DOI: 10.3955/046.085.0204

Light-absorbing particles in snow and ice: Measurement and modeling of climatic and hydrological impact
journal, November 2014

  • Qian, Yun; Yasunari, Teppei J.; Doherty, Sarah J.
  • Advances in Atmospheric Sciences, Vol. 32, Issue 1
  • DOI: 10.1007/s00376-014-0010-0

Response of Colorado River runoff to dust radiative forcing in snow
journal, September 2010

  • Painter, T. H.; Deems, J. S.; Belnap, J.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 40
  • DOI: 10.1073/pnas.0913139107